CN111395017A - Environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste and preparation method thereof - Google Patents
Environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste and preparation method thereof Download PDFInfo
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- CN111395017A CN111395017A CN202010322357.7A CN202010322357A CN111395017A CN 111395017 A CN111395017 A CN 111395017A CN 202010322357 A CN202010322357 A CN 202010322357A CN 111395017 A CN111395017 A CN 111395017A
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- China
- Prior art keywords
- parts
- resistant
- triazine
- printing paste
- invisible printing
- Prior art date
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- 238000004061 bleaching Methods 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 29
- 239000002562 thickening agent Substances 0.000 claims abstract description 24
- -1 triazine compound Chemical class 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000001914 filtration Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 150000003918 triazines Chemical class 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 38
- 238000003756 stirring Methods 0.000 claims description 32
- 239000002518 antifoaming agent Substances 0.000 claims description 16
- 239000005995 Aluminium silicate Substances 0.000 claims description 14
- 235000012211 aluminium silicate Nutrition 0.000 claims description 14
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 239000002383 tung oil Substances 0.000 claims description 12
- CZGWDPMDAIPURF-UHFFFAOYSA-N (4,6-dihydrazinyl-1,3,5-triazin-2-yl)hydrazine Chemical compound NNC1=NC(NN)=NC(NN)=N1 CZGWDPMDAIPURF-UHFFFAOYSA-N 0.000 claims description 11
- IAPOJJPFEQXKLL-UHFFFAOYSA-N 6-(3,4-dihydro-2h-pyrrol-5-yl)quinoline Chemical compound C1CCN=C1C1=CC=C(N=CC=C2)C2=C1 IAPOJJPFEQXKLL-UHFFFAOYSA-N 0.000 claims description 11
- 239000003906 humectant Substances 0.000 claims description 10
- 239000003755 preservative agent Substances 0.000 claims description 10
- 230000002335 preservative effect Effects 0.000 claims description 10
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 7
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 7
- UMWWHOXOVPIGFD-UHFFFAOYSA-N 2-methyl-3-sulfanylidene-1,2,4-triazinane-5,6-dione Chemical compound CN1NC(=O)C(=O)N=C1S UMWWHOXOVPIGFD-UHFFFAOYSA-N 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000003973 paint Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 3
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 2
- VWVZIRPJPFJGFE-UHFFFAOYSA-N 1,3,5-tribenzyl-1,3,5-triazinane Chemical compound C=1C=CC=CC=1CN(CN(CC=1C=CC=CC=1)C1)CN1CC1=CC=CC=C1 VWVZIRPJPFJGFE-UHFFFAOYSA-N 0.000 claims description 2
- HBQUOLGAXBYZGR-UHFFFAOYSA-N 2,4,6-triphenyl-1,3,5-triazine Chemical compound C1=CC=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 HBQUOLGAXBYZGR-UHFFFAOYSA-N 0.000 claims description 2
- FJERMCQUSONQAU-UHFFFAOYSA-N 2,4,6-tripyridin-2-yl-1h-triazine Chemical compound N1N(C=2N=CC=CC=2)N=C(C=2N=CC=CC=2)C=C1C1=CC=CC=N1 FJERMCQUSONQAU-UHFFFAOYSA-N 0.000 claims description 2
- YYQRNQDOTOKYJU-UHFFFAOYSA-N 2,4,6-tripyrrolidin-1-yl-1,3,5-triazine Chemical compound C1CCCN1C1=NC(N2CCCC2)=NC(N2CCCC2)=N1 YYQRNQDOTOKYJU-UHFFFAOYSA-N 0.000 claims description 2
- NXFQWRWXEYTOTK-UHFFFAOYSA-N 2-methyl-4-amino-6-methoxy-s-triazine Chemical compound COC1=NC(C)=NC(N)=N1 NXFQWRWXEYTOTK-UHFFFAOYSA-N 0.000 claims description 2
- NCSCAWXVGUIUEY-UHFFFAOYSA-N n-(6-methyl-3-oxo-2,5-dihydro-1,2,4-triazin-4-yl)acetamide Chemical compound CC(=O)NN1CC(C)=NNC1=O NCSCAWXVGUIUEY-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 50
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 11
- 239000000460 chlorine Substances 0.000 abstract description 11
- 229910052801 chlorine Inorganic materials 0.000 abstract description 11
- 239000000853 adhesive Substances 0.000 abstract description 5
- 229920000715 Mucilage Polymers 0.000 abstract description 2
- 239000004744 fabric Substances 0.000 description 51
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 17
- 238000004043 dyeing Methods 0.000 description 17
- 239000006224 matting agent Substances 0.000 description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 7
- 229920000570 polyether Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 5
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000002035 prolonged effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 239000008149 soap solution Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- HEMSJLNVJJUYEU-UHFFFAOYSA-N 6-ethoxy-2-n-methyl-1,3,5-triazine-2,4-diamine Chemical compound CCOC1=NC(N)=NC(NC)=N1 HEMSJLNVJJUYEU-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229930184510 Mallotus Natural products 0.000 description 1
- 241001060384 Mallotus <angiosperm> Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000008782 xin-kang Substances 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/6426—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/6515—Hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention relates to the technical field of printing mucilage, and relates to environment-friendly chlorine bleaching-resistant and sunlight-resistant invisible printing paste which comprises the following components in parts by weight: 20-30 parts of water-based acrylic emulsion; 5-15 parts of inorganic matting powder; 15-20 parts of an organic delustering agent; 1-5 parts of triazine compounds; 3-9 parts of a thickening agent. The preparation method of the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the following steps: mixing a water-based acrylic emulsion, an organic delustering agent and a triazine compound; and (2) adding inorganic matting powder and a thickening agent, and filtering to obtain the environment-friendly chlorine bleaching-resistant and sunlight-resistant invisible printing paste. The invention has the effects of improving the fastness to sunlight and shading effect of the invisible printing paste.
Description
Technical Field
The invention relates to the technical field of printing mucilage, in particular to environment-friendly chlorine bleaching-resistant and sunlight-resistant invisible printing paste and a preparation method thereof.
Background
At present, along with the improvement of the living standard of people, the demand of people on the aesthetic degree of dress and fabrics is also higher and higher, therefore, people can adopt printing adhesive cement to print and dye on clothes so that the clothes style is various usually, thereby satisfying the different demands of consumers more easily.
In order to make clothes or fabrics more expensive, people usually print and print invisible printing paste on polyester satin, nylon or silk to shield bright parts of the clothes or fabrics and show a dark-colored effect, so that the clothes or fabrics show the dark-colored effect if hidden, and the clothes or fabrics are more expensive.
However, when people wear clothes to move outdoors or use curtains made of fabrics to shield sunlight, the clothes or the fabrics are easily exposed to the sunlight, and because the invisible printing paste is generally made of high polymer materials, the high polymer materials are easy to age under the sunlight condition, the shading effect of the invisible printing paste is easily affected, and further the appearance of the clothes or the fabrics is easily affected, so that the clothes or the fabrics still have room for improvement.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide the environment-friendly chlorine bleaching-resistant and sunlight-resistant invisible printing paste.
Aiming at the defects in the prior art, the invention also aims to provide a preparation method of the environment-friendly chlorine bleaching-resistant and sunlight-resistant invisible printing paste.
The above object of the present invention is achieved by the following technical solutions:
the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the following components in parts by weight:
20-30 parts of water-based acrylic emulsion;
5-15 parts of inorganic matting powder;
15-20 parts of an organic delustering agent;
1-5 parts of triazine compounds;
3-9 parts of a thickening agent.
By adopting the technical scheme, the triazine compound is used as the light fastness improver, so that the light fastness of the invisible printing paste is favorably improved, the invisible printing paste is not easy to age under the sunlight condition, the shading effect of the invisible printing paste is not easy to be influenced, and the attractive effect of clothes or fabrics is not easy to be influenced.
By adopting the synergistic cooperation of the inorganic matting agent and the organic matting agent, the shading effect of the invisible printing paste is favorably improved, so that the attractive effect of clothes or fabrics is not easily influenced.
By adding the thickening agent, the consistency of the invisible printing paste can be better adjusted, so that the inorganic matting powder and the organic matting agent can be better and uniformly dispersed, the shading effect of the invisible printing paste can be better improved, and the attractive effect of clothes or fabrics can be less prone to being influenced.
By adopting the water-based acrylic emulsion as the adhesive, the adhesive property of the invisible printing paste and clothes or fabrics is favorably improved, so that the fastness to chlorine bleaching, the washing fastness and the rubbing fastness of the invisible printing paste are higher.
The substances do not contain formaldehyde and other substances which are not environment-friendly, are not easy to influence the environment and human health, and are favorable for better improving the safety performance and the environment-friendly performance of the invisible printing paste.
The present invention in a preferred example may be further configured to: the inorganic matting powder comprises the following components in parts by weight:
3-5 parts of kaolin;
1-8 parts of silicon dioxide;
1-2 parts of diatomite.
By adopting the technical scheme, the kaolin, the silicon dioxide and the diatomite are matched with each other in a synergistic manner according to a specific proportion, so that the shading effect of the invisible printing paste is favorably improved, and the attractive effect of clothes or fabrics is better; meanwhile, the softness of the clothes or the fabrics is improved better, so that the hand feeling of the printed clothes or the fabrics is softer and smoother.
The present invention in a preferred example may be further configured to: the organic delustering agent comprises the following components in parts by mass:
7-10 parts of wax emulsion;
8-10 parts of tung oil.
By adopting the technical scheme, the wax emulsion and the tung oil are matched in a synergistic manner in a specific ratio, so that the shading effect of the invisible printing paste is favorably improved, and the attractive effect of clothes or fabrics is better; meanwhile, the softness of the clothes or the fabrics is improved better, so that the hand feeling of the printed clothes or the fabrics is softer and smoother, and the printed clothes or the fabrics are more popular with consumers.
The present invention in a preferred example may be further configured to: the inorganic matting powder comprises the following components in parts by weight:
3-5 parts of kaolin;
1-8 parts of silicon dioxide;
1-2 parts of diatomite;
the organic delustering agent comprises the following components in parts by mass:
7-10 parts of wax emulsion;
8-10 parts of tung oil.
By adopting the technical scheme, the kaolin, the silicon dioxide, the diatomite, the wax emulsion and the tung oil in a specific proportion are matched with each other in a synergistic manner, so that the shading effect of the invisible printing paste is favorably improved, and clothes or fabrics obtained by printing and dyeing have better attractive effect and are more easily welcomed by consumers; meanwhile, the fastness to chlorine bleaching, the washing fastness and the rubbing fastness of the invisible printing paste can be improved better, so that the aesthetic effect of the invisible printing paste is not influenced easily after washing for many times, the service life of clothes or fabrics can be prolonged better to a certain extent, and the clothes or fabrics obtained by printing and dyeing can be popular with consumers more easily.
The present invention in a preferred example may be further configured to: the triazine compound includes 2, 5-dihydro-6-hydroxy-2-methyl-5-oxo-3-mercapto-1, 2, 4-triazine, 1, 3, 5-triazine, 2-amino-4-methoxy-6-methyl-1, 3, 5-triazine, 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine, 4-acetylamino-6-methyl-3-oxo-2, 3, 4, 5-tetrahydro-1, 2, 4-triazine, 2, 4, 6-tris (2-pyridyl) triazine, 2, 4, 6-triphenyltriazine, 2, 4, 6-trimorpholin-1, 3, 5-triazine, 1, 3, 5-tribenzylhexahydro-1, 3, 5-triazine, 2, 4, 6-trihydrazino-1, 3, 5-triazine, 2, 4, 6-tris (pyrrolidin-1-yl) -1, 3, 5-triazine.
By adopting the technical scheme, the one or more triazine compounds in the substances are used as the light fastness improving agent, so that the light fastness of the prepared invisible printing paste is favorably and better enhanced, the attractive effect of the clothes or fabrics obtained by printing and dyeing is less susceptible to the influence of the light, and the attractive effect of the clothes or fabrics obtained by printing and dyeing is less susceptible to the influence.
The present invention in a preferred example may be further configured to: the triazine compound comprises the following components in parts by mass:
0.5-3 parts of 2, 4, 6-trimorpholine-1, 3, 5-triazine;
0.3-1 part of 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine;
0.2 to 1 portion of 2, 4, 6-trihydrazino-1, 3, 5-triazine.
The present invention in a preferred example may be further configured to: the triazine compound comprises the following components in parts by mass:
2 parts of 2, 4, 6-trimorpholine-1, 3, 5-triazine;
0.8 part of 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine;
0.5 part of 2, 4, 6-trihydrazino-1, 3, 5-triazine.
By adopting the technical scheme, 2, 4, 6-trimorpholine-1, 3, 5-triazine, 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine and 2, 4, 6-trihydrazino-1, 3, 5-triazine in a specific proportion are cooperatively matched with each other, so that the sunlight fastness of the invisible printing paste is favorably improved, the attractive effect of clothes or fabrics obtained by printing and dyeing is less easily influenced by sunlight, and the clothes or fabrics are favorably welcomed by consumers; meanwhile, the fastness to chlorine bleaching, the washing fastness and the rubbing fastness of the invisible printing paste can be better enhanced to a certain extent, so that the attractive effect of the invisible printing paste after being washed for multiple times is not easily influenced, and the service life of clothes or fabrics can be better prolonged to a certain extent.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
1-4 parts of 2-amino-2-methyl-1-propanol.
By adopting the technical scheme, the 2-amino-2 methyl-1-propanol is added, so that the stability of the invisible printing paste is favorably improved, the inorganic matting powder is favorably and uniformly dispersed in the invisible printing paste, the shading effect of the invisible printing paste is favorably improved, and clothes or fabrics obtained by printing and dyeing have better attractive appearance and are more easily welcomed by consumers.
The present invention in a preferred example may be further configured to: the paint also comprises the following components in parts by mass:
7-13 parts of a humectant;
0.3-1.5 parts of defoaming agent;
0.5-1.3 parts of preservative.
By adopting the technical scheme, the humectant is added, so that the moisture retention and the lubrication degree of the invisible printing paste can be better enhanced, the surface of the invisible printing paste printed and dried is softer and smoother, and the hand feeling of the invisible printing paste printed and dried can be better improved; meanwhile, the condition that the invisible printing paste is cracked due to drying is more difficult to occur after printing and dyeing, the invisible printing paste is favorable for better keeping the printing and dyeing attractive effect, and the service life of the invisible printing paste after printing and dyeing is favorably prolonged.
In the invention, the humectant can be one or more of glycerin, butanediol, polyethylene glycol, propylene glycol, hexanediol, xylitol, polypropylene glycol, amino acid, sodium lactate, urea and environment-friendly solvent oil; preferably, the humectant is a mixture of glycerin, propylene glycol and environmentally friendly solvent oil.
By adding the defoaming agent, the bubble phenomenon in the invisible printing paste can be better reduced, so that the crater phenomenon on the surface of the invisible printing paste can be better reduced, and the attractive effect of the invisible printing paste can be better improved.
In the invention, the defoaming agent can be one or more of non-silicon defoaming agent, organic silicon defoaming agent, polyether defoaming agent and polyether modified organic silicon defoaming agent; preferably, the defoamer is a silicone polyether defoamer.
Through adding the preservative, the quality guarantee period of the invisible printing paste can be prolonged better, so that the invisible printing paste is less prone to mildew, and the attractive effect of the invisible printing paste is less prone to influence.
In the present invention, the preservative may be cresol, xylenol, benzoic acid, sodium benzoate, sorbic acid. One or more of methylisothiazolinone, methyl p-hydroxybenzoate and benzisothiazolinone; preferably, the preservative is benzisothiazolinone.
The second aim of the invention is realized by the following technical scheme:
a preparation method of environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the following steps:
step (1), mixing the water-based acrylic emulsion, the organic delustering agent and the triazine compound, and stirring for 10-20min to form a premix;
and (2) adding inorganic matting powder into the premix, stirring for 30-50min, adding a thickening agent, stirring for 20-30min, and filtering to obtain the environment-friendly chlorine-bleaching-resistant and sun-resistant invisible printing paste.
By adopting the technical scheme, the components are favorably and mutually cooperated to play a role better by controlling the adding sequence of the components, and meanwhile, the inorganic matting powder is favorably and uniformly dispersed in the invisible printing paste better, so that the shading effect and the light fastness of the invisible printing paste are favorably and better improved, the attractive effect of the invisible printing paste is not easily influenced by sunlight, and clothes or fabrics obtained by printing and dyeing are more easily welcomed by consumers.
In summary, the invention includes at least one of the following beneficial technical effects:
1. by adopting the triazine compound as the light fastness improver, the light fastness of the invisible printing paste is favorably enhanced, so that the shading effect of the invisible printing paste is less susceptible to influence, and the attractive effect of clothes or fabrics is less susceptible to influence;
2. by adopting the synergistic cooperation of the inorganic matting agent and the organic matting agent, the shading effect of the invisible printing paste is favorably improved, so that the attractive effect of clothes or fabrics is not easily influenced;
3. by adding the thickening agent, the consistency of the invisible printing paste can be better adjusted, the inorganic matting powder and the organic matting agent can be better and uniformly dispersed, the shading effect of the invisible printing paste can be better improved, and the attractive effect of clothes or fabrics can be more difficultly influenced;
4. by adopting the water-based acrylic emulsion as the adhesive, the adhesive property of the invisible printing paste and clothes or fabrics is favorably improved, so that the washing fastness and the rubbing fastness of the invisible printing paste are higher;
5. the substances do not contain formaldehyde and other substances which are not environment-friendly, are not easy to influence the environment and human health, and are favorable for better improving the safety performance and the environment-friendly performance of the invisible printing paste.
Drawings
FIG. 1 is a process flow chart of a preparation method of the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings.
In the following examples, an aqueous acrylic emulsion having a model number of 2817 was used as the aqueous acrylic emulsion.
In the following examples, the kaolin used was one having a particle size of 1250 mesh in 999, model No. of auspicious silica powder, Inc., Bo Ai county.
In the following examples, the silica used was 14808-60-7, which is a type of silica available from Shanghai Nong practice Co.
In the following examples, diatomaceous earth available from Hebei Xinxu mineral products Co., Ltd, as No. xx-203, was used.
In the following examples, titanium dioxide of model 13463-67-7 from Hubei Xin Hongli chemical Co., Ltd was used.
In the following examples, BYK-AQUACER-539 wax emulsion available from Chongqing Kaiyn chemical Co., Ltd was used as the wax emulsion.
In the following examples, the tung oil used was 99 model tung oil from kepler biosciences ltd, Shandong.
In the following examples, 2, 4, 6-trimorpholine-1, 3, 5-triazine, model 16303-23-4, was used as 2, 4, 6-trimorpholine-1, 3, 5-triazine from Dorset scientific development Co.
In the following examples, 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine, model 62096-63-3 from Mallotus Chemicals, Inc., was used as the 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine.
In the following examples, 2, 4, 6-trihydrazino-1, 3, 5-triazine available from Shangzhou Shangjie chemical Co., Ltd, as 2, 4, 6-trihydrazino-1, 3, 5-triazine, was used.
In the following examples, PTF thickener was prepared from ASE60 from Nantong Yongle chemical Co.
In the following examples, 2-amino-2-methyl-1-propanol having a product number of 2854-16-2 from Hubei Xinkang pharmaceutical chemical Co., Ltd was used.
In the following examples, glycerol having a product number of 56-81-5 from Junteng chemical Co., Ltd, Jinan province is used as glycerol.
In the following examples, propylene glycol of 57-55-6, a product number of Jiangsu Jiaren chemical Co., Ltd, was used.
In the following examples, the environment-friendly solvent oil is 125487 available from Jinan Xiangtai chemical Limited.
In the following examples, a silicone polyether defoaming agent of AT2021, available from Antai Fine chemical Co., Ltd, Dongguan, was used as the silicone polyether defoaming agent.
In the following examples, benzisothiazolinone available from Jinan Rongxin Fine chemical Co., Ltd under the product number 3634-33-5 was used.
Example 1
The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the raw materials with the components and the content shown in the table 1, wherein the unit of the content of each component in the table 1 is kg.
Referring to fig. 1, the preparation method of the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste disclosed by the invention comprises the following steps:
and (1) cleaning a dispersion cylinder, adding the aqueous acrylic emulsion, the organic delustering agent and the triazine compound into the dispersion cylinder, stirring at the rotating speed of 1500r/min for 10min, and uniformly mixing and dispersing to form a premix.
And (2) adding inorganic matting powder into the premix while stirring, stirring for 30min, adding a thickening agent, stirring for 20min, and filtering by using a 180-mesh gauze to obtain the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste.
In this example, the organic matting agent is a wax emulsion; the triazine compound is 2, 5-dihydro-6-hydroxy-2-methyl-5-oxo-3-mercapto-1, 2, 4-triazine; the inorganic matting powder is kaolin; the thickener is a PTF thickener.
Example 2
The difference from example 1 is that:
the components and contents of the raw materials are shown in table 1;
the stirring time in the step (1) is 15 min;
adding inorganic matting powder in the step (2), and stirring for 40 min; adding thickener, and stirring for 25 min; the filtered gauze was 190 mesh.
Example 3
The difference from example 1 is that:
the components and contents of the raw materials are shown in table 1;
the stirring time in the step (1) is 20 min;
adding inorganic matting powder in the step (2), and stirring for 50 min; adding thickener, and stirring for 30 min; the gauze was 200 mesh.
Example 4
The difference from example 1 is that:
the components and contents of the raw materials are shown in table 1;
the stirring time in the step (1) is 18 min;
adding inorganic matting powder in the step (2), and stirring for 48 min; adding thickener, and stirring for 27 min; the gauze was 195 mesh.
TABLE 1
Examples 5 to 16
The difference from example 4 is that: the composition and content of the inorganic matting powder are shown in table 2, and the unit of the content of each component in table 2 is kg.
TABLE 2
Examples 17 to 25
The difference from example 4 is that: the composition and content of the organic matting agent are shown in table 3, and the unit of the content of each component in table 3 is kg.
TABLE 3
Examples 26 to 41
The difference from example 4 is that: the composition and content of the inorganic matting agent and the organic matting agent are shown in table 4, and the unit of the content of each component in table 4 is kg.
TABLE 4
| Kaolin clay | Silicon dioxide | Diatomite | Titanium dioxide | Wax emulsion | Tung oil | Polymethyl urea resin | |
| Example 26 | 3 | 8 | 1 | 0 | 7 | 10 | 0 |
| Example 27 | 5 | 1 | 2 | 0 | 10 | 8 | 0 |
| Example 28 | 4 | 4.5 | 1.5 | 0 | 8.5 | 9 | 0 |
| Example 29 | 3.5 | 6 | 1.6 | 0 | 8 | 8.5 | 0 |
| Example 30 | 1 | 10 | 0.5 | 0 | 12 | 5 | 0 |
| Example 31 | 8 | 0.5 | 3 | 0 | 5 | 12 | 0 |
| Example 32 | 0 | 9.5 | 1.6 | 0 | 8 | 8.5 | 0 |
| Example 33 | 3.5 | 0 | 7.6 | 0 | 8 | 8.5 | 0 |
| Example 34 | 5.1 | 6 | 0 | 0 | 8 | 8.5 | 0 |
| Example 35 | 0 | 6 | 1.6 | 3.5 | 8 | 8.5 | 0 |
| Example 36 | 3.5 | 0 | 1.6 | 6 | 8 | 8.5 | 0 |
| Example 37 | 3.5 | 6 | 0 | 1.6 | 8 | 8.5 | 0 |
| Example 38 | 3.5 | 6 | 1.6 | 0 | 0 | 16.5 | 0 |
| Example 39 | 3.5 | 6 | 1.6 | 0 | 16.5 | 0 | 0 |
| Example 40 | 3.5 | 6 | 1.6 | 0 | 0 | 8.5 | 8 |
| EXAMPLE 41 | 3.5 | 6 | 1.6 | 0 | 8 | 0 | 8.5 |
Examples 42 to 53
The difference from example 4 is that: the composition and content of the triazine compounds are shown in table 5, and the unit of the content of each component in table 5 is kg.
TABLE 5
Examples 54 to 57
The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the raw materials with the components and the content shown in table 6, wherein the unit of the content of each component in table 6 is kg.
A preparation method of environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the following steps:
and (1) cleaning a dispersion cylinder, sequentially adding the water-based acrylic emulsion, the organic delustering agent, the triazine compound and 2-amino-2-methyl-1-propanol into the dispersion cylinder, stirring at the rotating speed of 1500r/min for 18min, and uniformly mixing and dispersing to form a premix.
And (2) adding the inorganic matting powder into the premix while stirring, stirring for 48min, adding the thickening agent, stirring for 27min, and filtering by using a 195-mesh gauze to obtain the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste.
In this example, the organic matting agent is a wax emulsion; the triazine compound is 2, 5-dihydro-6-hydroxy-2-methyl-5-oxo-3-mercapto-1, 2, 4-triazine; the inorganic matting powder is kaolin; the thickener is a PTF thickener.
TABLE 6
Examples 58 to 61
The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the raw materials with the components and the content shown in table 7, wherein the unit of the content of each component in table 7 is kg.
A preparation method of environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the following steps:
and (1) cleaning a dispersion tank, sequentially adding the aqueous acrylic emulsion, the organic delustering agent, the humectant, the defoaming agent, the triazine compound and the preservative into the dispersion tank, stirring at the rotating speed of 1500r/min for 18min after the addition is finished, and uniformly mixing and dispersing to form a premix.
And (2) adding the inorganic matting powder into the premix while stirring, stirring for 48min, adding the thickening agent, stirring for 27min, and filtering by using a 195-mesh gauze to obtain the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste.
In the above examples, the organic matting agent is a wax emulsion; the humectant is glycerol; the defoaming agent is a silicon polyether defoaming agent; the triazine compound is 2, 5-dihydro-6-hydroxy-2-methyl-5-oxo-3-mercapto-1, 2, 4-triazine; the preservative is benzisothiazolinone; the inorganic matting powder is kaolin; the thickener is a PTF thickener.
TABLE 7
Examples 62 to 65
The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the raw materials with the components and the content shown in the table 8, wherein the unit of the content of each component in the table 8 is kg.
A preparation method of environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste comprises the following steps:
and (1) cleaning a dispersion tank, sequentially adding the aqueous acrylic emulsion, the organic delustering agent, the humectant, the defoaming agent, the 2-amino-2-methyl-1-propanol, the triazine compound and the preservative into the dispersion tank, stirring at the rotating speed of 1500r/min after the addition is finished, stirring for 18min, and uniformly mixing and dispersing to form a premix.
And (2) adding the inorganic matting powder into the premix while stirring, stirring for 48min, adding the thickening agent, stirring for 27min, and filtering by using a 195-mesh gauze to obtain the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste.
In the above embodiment, the organic matting agent is a mixture of wax emulsion and tung oil; the humectant is a mixture of glycerol, propylene glycol and environment-friendly solvent oil; the defoaming agent is a silicon polyether defoaming agent; the triazine compound is a mixture of 2, 4, 6-trimorpholine-1, 3, 5-triazine, 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine and 2, 4, 6-trihydrazino-1, 3, 5-triazine; the preservative is benzisothiazolinone; the inorganic matting powder is a mixture of kaolin, silicon dioxide and diatomite; the thickener is a PTF thickener.
TABLE 8
Comparative examples 1 to 5
The difference from example 4 is that:
the components and contents of the raw materials are shown in table 9.
TABLE 9
Experiment 1
The pH values of the invisible printing pastes prepared in the above examples and comparative examples were measured by a PHS-2C type acidimeter using a two-point calibration method.
Experiment 2
The viscosities (mPa. s) of the invisible printing pastes prepared in the above examples and comparative examples were measured by a rotational viscometer model NDJ-1.
Experiment 3
The soft smoothness and the shading effect of the fabric printed by the invisible printing paste prepared by the above examples and comparative examples are detected, and the detection method comprises the following steps:
the same Chinese silk with the same quality is firstly ironed and laid on a printing table, an 800-mesh floor screen plate is selected, the Chinese silk is subjected to scraping and printing twice, the Chinese silk is dried by hot air, and the Chinese silk is baked for 3min at the high temperature of 150 ℃ to prepare a sample.
The samples prepared in each example and comparative example were evaluated by manual hand touch and observation by randomly selecting 20 volunteers, and the average value of all the evaluations was taken. Wherein the soft grade is 0-5 grade, and the higher the grade is, the higher the soft and smooth degree of the hand feeling of the fabric is; the shading effect is classified into 0-5 grade, and the higher the grade is, the more obvious the shading effect of the fabric is, and the more easily the dark pattern of the invisible printing paste appears.
Experiment 4
The grade of fastness to chlorine of the invisible printing pastes prepared in the above examples and comparative examples was tested according to GB/T7-69-1997 fastness to hypochlorite bleaching in the textile color test.
Experiment 5
The light fastness ratings of the invisible printing pastes prepared in the above examples and comparative examples were tested according to ISO105-B02 textile-color fastness test.
Experiment 6
The color fastness to washing (60 ℃) of the printed dough of the invisible printing paste prepared in the above examples and comparative examples was measured as follows:
the principle is as follows: the textile sample is sewed with lining fabric, placed in soap solution, mechanically stirred under the condition of specified time and temperature, washed and dried, and then the color change of the sample and the staining of the lining fabric are evaluated by using a gray card.
And (4) testing standard: ISO105C 03;
sample preparation, four sides of 4 × 10cm are sewed;
multi-fiber lining: acetate, cotton, nylon, terylene, acrylic fiber and wool;
and (3) testing conditions are as follows: temperature: 60 ℃, sweat content: 1:50, time: and (3) 30 min.
The preparation standards of the reagents are 4 g/L synthetic detergent and 2 g/L anhydrous sodium carbonate.
The method comprises the following operation steps:
the prepared combination sample is placed in a container, and soap solution preheated to a predetermined temperature (bath ratio: 1:50) is injected and treated at a predetermined temperature for a predetermined time.
And taking out the combined sample, washing the combined sample twice by using cold water, then flushing the combined sample in flowing water for 10min, squeezing out water, disassembling the combined sample, connecting the linings of the samples by only one short-edge suture line, and suspending the combined sample in air at 30 ℃ for drying.
The samples were evaluated for change as received (fading) and for the tack of the lining fabric using a grey sample card.
Experiment 7
The crocking fastness grades of the invisible printing pastes prepared in the above examples and comparative examples are tested by a crocking fastness tester according to GB3920-1983 method for testing crocking fastness of textiles.
The data from the above experiments are shown in Table 10.
Watch 10
According to the data comparison of the examples 4 to 16 in table 10, the kaolin, the silicon dioxide and the diatomite in specific proportions are adopted to cooperate with each other, so that the shading effect of the invisible printing paste is favorably improved, the dark flower effect of the fabric obtained by printing and dyeing is better, meanwhile, the softness of the fabric obtained by printing and dyeing is favorably improved, the hand feeling of the fabric is softer and smoother, any component is lacked or any proportion is changed, and the shading effect and the softness of the invisible printing paste are easily greatly influenced.
According to the comparison of the data of the embodiment 4 and the embodiments 17 to 25 in table 10, the wax emulsion and the tung oil in a specific ratio are adopted to cooperate with each other, so that the shading effect of the invisible printing paste is favorably improved, the dark flower effect of the fabric obtained by printing and dyeing is better, meanwhile, the softness of the fabric obtained by printing and dyeing is favorably improved, the hand feeling of the fabric is softer and smoother, any component is lacked or any ratio is changed, and the shading effect and the softness of the invisible printing paste are easily influenced greatly.
According to the comparison of the data of the embodiment 4 and the embodiments 26 to 41 in table 10, the kaolin, the silicon dioxide, the diatomite, the wax emulsion and the tung oil in a specific ratio are adopted to cooperate with each other, so that the shading effect of the invisible printing paste is favorably improved, the dark flower effect of the fabric obtained by printing and dyeing is better, meanwhile, the softness of the fabric obtained by printing and dyeing is favorably improved, the hand feeling of the fabric is softer and smoother, any component is lacked or any ratio is changed, and the shading effect and the softness of the invisible printing paste are easily greatly influenced.
According to the comparison of the data of example 4 and examples 42 to 53 in table 10, 2, 4, 6-trimorpholine-1, 3, 5-triazine, 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine and 2, 4, 6-trihydrazino-1, 3, 5-triazine are used in a specific ratio to cooperate with each other, so that the light fastness of the invisible printing paste is improved better, and simultaneously, the chlorine fastness, the washing fastness and the rubbing fastness of the invisible printing paste are improved to a certain extent.
According to the comparison of the data of the example 4 and the examples 54 to 57 in the table 10, the addition of the 2-amino-2-methyl-1-propanol is beneficial to better improving the stability of the invisible printing paste, and is beneficial to better and uniformly dispersing the inorganic matting powder in the invisible printing paste, thereby being beneficial to better improving the shading effect of the invisible printing paste.
According to the comparison of the data of the example 4 and the examples 58 to 61 in the table 10, the softness of the fabric obtained by the invisible printing paste printing and dyeing can be improved better by adding the humectant, the defoamer and the preservative, so that the hand feeling of the fabric is softer and smoother.
According to the comparison of the data of example 4 and comparative examples 1-5 in Table 10, the triazine compounds are beneficial to better improve the light fastness of the invisible printing paste; only when the inorganic matting powder and the organic matting agent are matched with each other synergistically, the shading effect of the invisible printing paste can be better improved; the invisible printing paste is easy to have great influence on the light fastness, shading effect, fastness to chlorine bleaching, fastness to washing and rubbing fastness of the invisible printing paste due to the lack of any component or the change of the using amount of any component.
The embodiments of the present invention are preferred embodiments of the present invention, and the scope of the present invention is not limited by these embodiments, so: all equivalent changes made according to the structure, shape and principle of the invention are covered by the protection scope of the invention.
Claims (10)
1. The environment-friendly chlorine-bleaching-resistant and sun-drying-resistant invisible printing paste is characterized in that: the paint comprises the following components in parts by mass:
20-30 parts of water-based acrylic emulsion;
5-15 parts of inorganic matting powder;
15-20 parts of an organic delustering agent;
1-5 parts of triazine compounds;
3-9 parts of a thickening agent.
2. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste as claimed in claim 1, is characterized in that: the inorganic matting powder comprises the following components in parts by weight:
3-5 parts of kaolin;
1-8 parts of silicon dioxide;
1-2 parts of diatomite.
3. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste as claimed in claim 1, is characterized in that: the organic delustering agent comprises the following components in parts by mass:
7-10 parts of wax emulsion;
8-10 parts of tung oil.
4. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste as claimed in claim 1, is characterized in that: the inorganic matting powder comprises the following components in parts by weight:
3-5 parts of kaolin;
1-8 parts of silicon dioxide;
1-2 parts of diatomite;
the organic delustering agent comprises the following components in parts by mass:
7-10 parts of wax emulsion;
8-10 parts of tung oil.
5. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste according to any one of claims 1 to 4, which is characterized in that: the triazine compound includes 2, 5-dihydro-6-hydroxy-2-methyl-5-oxo-3-mercapto-1, 2, 4-triazine, 1, 3, 5-triazine, 2-amino-4-methoxy-6-methyl-1, 3, 5-triazine, 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine, 4-acetylamino-6-methyl-3-oxo-2, 3, 4, 5-tetrahydro-1, 2, 4-triazine, 2, 4, 6-tris (2-pyridyl) triazine, 2, 4, 6-triphenyltriazine, 2, 4, 6-trimorpholin-1, 3, 5-triazine, 1, 3, 5-tribenzylhexahydro-1, 3, 5-triazine, 2, 4, 6-trihydrazino-1, 3, 5-triazine, 2, 4, 6-tris (pyrrolidin-1-yl) -1, 3, 5-triazine.
6. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste as claimed in claim 5, is characterized in that: the triazine compound comprises the following components in parts by mass:
0.5-3 parts of 2, 4, 6-trimorpholine-1, 3, 5-triazine;
0.3-1 part of 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine;
0.2 to 1 portion of 2, 4, 6-trihydrazino-1, 3, 5-triazine.
7. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste as claimed in claim 6, is characterized in that: the triazine compound comprises the following components in parts by mass:
2 parts of 2, 4, 6-trimorpholine-1, 3, 5-triazine;
0.8 part of 2-amino-4-ethoxy-6-methylamino-1, 3, 5-triazine;
0.5 part of 2, 4, 6-trihydrazino-1, 3, 5-triazine.
8. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste according to any one of claims 1 to 4, which is characterized in that: the paint also comprises the following components in parts by mass:
1-4 parts of 2-amino-2-methyl-1-propanol.
9. The environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste according to any one of claims 1 to 4, which is characterized in that: the paint also comprises the following components in parts by mass:
7-13 parts of a humectant;
0.3-1.5 parts of defoaming agent;
0.5-1.3 parts of preservative.
10. The preparation method of the environment-friendly chlorine-bleaching-resistant and sunlight-resistant invisible printing paste as claimed in claim 1, characterized by comprising the following steps: the method comprises the following steps:
step (1), mixing the water-based acrylic emulsion, the organic delustering agent and the triazine compound, and stirring for 10-20min to form a premix;
and (2) adding inorganic matting powder into the premix, stirring for 30-50min, adding a thickening agent, stirring for 20-30min, and filtering to obtain the environment-friendly chlorine-bleaching-resistant and sun-resistant invisible printing paste.
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| CN117327026A (en) * | 2023-09-28 | 2024-01-02 | 江苏集萃光敏电子材料研究所有限公司 | Anti-yellowing additive for optical materials, preparation method thereof and composition containing anti-yellowing additive |
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