CN101906717B - Product turning liquid into printing and production method thereof - Google Patents
Product turning liquid into printing and production method thereof Download PDFInfo
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- CN101906717B CN101906717B CN2010102252530A CN201010225253A CN101906717B CN 101906717 B CN101906717 B CN 101906717B CN 2010102252530 A CN2010102252530 A CN 2010102252530A CN 201010225253 A CN201010225253 A CN 201010225253A CN 101906717 B CN101906717 B CN 101906717B
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- turning liquid
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- 238000007639 printing Methods 0.000 title claims abstract description 55
- 239000007788 liquid Substances 0.000 title claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 114
- 239000005871 repellent Substances 0.000 claims abstract description 62
- 230000002940 repellent Effects 0.000 claims abstract description 62
- 239000004744 fabric Substances 0.000 claims abstract description 54
- 239000000758 substrate Substances 0.000 claims abstract description 38
- 239000006260 foam Substances 0.000 claims description 29
- 239000004604 Blowing Agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- 239000003381 stabilizer Substances 0.000 claims description 18
- 238000002360 preparation method Methods 0.000 claims description 13
- -1 ester acid amide Chemical class 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 6
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical class CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 6
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 150000001940 cyclopentanes Chemical class 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 238000009736 wetting Methods 0.000 abstract description 5
- 239000004753 textile Substances 0.000 abstract description 4
- 210000002700 urine Anatomy 0.000 abstract description 2
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- 206010012374 Depressed mood Diseases 0.000 abstract 1
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- 239000003795 chemical substances by application Substances 0.000 description 16
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 10
- 238000004078 waterproofing Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
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- 238000012512 characterization method Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
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- 229920000151 polyglycol Polymers 0.000 description 4
- 239000010695 polyglycol Substances 0.000 description 4
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- 241000322338 Loeseliastrum Species 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 238000004144 decalcomania Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
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- 239000003960 organic solvent Substances 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
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- 230000008569 process Effects 0.000 description 2
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- 238000007592 spray painting technique Methods 0.000 description 2
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- 239000000975 dye Substances 0.000 description 1
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- 150000004676 glycans Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
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- 230000002045 lasting effect Effects 0.000 description 1
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- 238000010422 painting Methods 0.000 description 1
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- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
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- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a product turning liquid into printing and a production method thereof. A water repellent layer with colorless patterns is formed on a hydrophilic substrate, so that different areas of the substrate surface respectively have water repellency and hydrophilicity. When the substrate is wetted, the patterns of the areas of the water repellent layer with the colorless patterns can be clearly shown because of different water content. Therefore, the product turning liquid into printing has multiple uses, for example, the product can reduce visual unhappiness caused by local wetness of fabric surface when a human body sweats, can be used for showing a urine wetting function of paper diapers of children, and can also be used as textiles of face towel, bath towel and the like for the children; and when the face towel or bath towel is wetted, patterns or flowers or figures thereon can be shown vividly, and the curiosity of the children is enhanced.
Description
Technical field
The present invention relates to a kind of latent photomechanical printing and spend technology, particularly production technology of turning liquid into printing technology and products thereof.
Background technology
The basic conception that traditional stamp forms in people's brains is to demonstrate observable bright-coloured pattern decorative pattern through the fabric face after the stamp processing, and no matter how environment of living in changes institute's stamp type pattern consistently, and promptly the stamp pattern is static.Latent photomechanical printing is spent technology to be meant certain special material employing screen painting mode or ink-jet printed mode is printed on the substrate, the printing technique that the design on the substrate is occurred with ambient temperature, bright and dark light, the dried variation of wetting of fabric etc.The turning liquid into printing technology is that latent the photomechanical printing spent a kind of in the technology.
The colored type figure line of product turning liquid into printing is that naked eyes can't be seen under common ambient conditions.Its product causes the flickering variation of design according to the change of conditions such as self humidity.When product was in drying regime, design was cannot see on its surface; After meeting water or other liquid, just have design on the substrate and appear.After water evaporates drying on the substrate, design can be vanished from sight again, and this process can circulate repeatedly.Product turning liquid into printing is a kind of coating or the stamp product that utilizes the exploitation of stamp means.
Chinese patent ZL02111616.4 " method of textile color-changing printing and its products " discloses and has a kind ofly utilized colourless hydrophily slurry that fabric is carried out method for printing.This method is primarily aimed at the strong Nylon Taffeta fabric of water proofing property of waterproof apparatus such as being applied to umbrella, raincoat, canopy; With the colourless hydrophily slurry that contains soluble starch thickener, polyvinyl alcohol slurry and thickener; Refuse water treatment two steps after adopting first stamp; That is: but the hydrophily at stamp reinforced fiber stamp position is refused water treatment and is made the stamp position have WATER REPELLENCY with exterior domain, meets the purpose that water manifests decalcomania thereby reach.But the problem that said method exists is that the substrate that is processed can only be the strong Nylon Taffeta fabric of water proofing property, and it is bigger to refuse the region area of water, is used for gas permeability, comfortableness that garment material can have a strong impact on fabric.
One Chinese patent application 02117254.4 " a kind of batching of wet development calico and preparation technology " discloses the stamp liquid medicine of the special chemical industry water of a kind of usefulness, special waterproofing agent, emulsifying agent and water preparation, but does not explain that which material employed special chemical industry water and special waterproofing agent are.Give fabric waterproof property with this liquid medicine stamp, can manifest designed patterns in advance after fabric is soaked in water.But the subject matter that this patented method exists is operation length consuming time, needs insulation 1～2 hour (see this patent application the 6th page of inverse of specification the 2nd section), is unfavorable for forming the fabric of good hand touch.Another part one Chinese patent application 03139962.2 of same applicant " containing the calico of the wet batching of developing and the method for making wet development calico " and has proposed to comprise polyoxy ether emulsifying agent, fluorine system contains aluminium hydrocarbon waterproofing agent, sulfonic group or alkyl polyglycol ether bleeding agent, organic solvent are introduced agent and water like electricity oil wet development batching; Give fabric waterproof property with this wet batching stamp that develops; Can be widely used in waterproof apparatus such as umbrella, raincoat, canopy, on non-watertight apparatus such as swimming suit, swimming trunks, baby diaper and the clothing.But the patterned layer in this patent application is a neccessary composition with APEO emulsifying agent and sulfonic group and alkyl polyglycol ether mixture bleeding agent, and the use of bleeding agent is unfavorable for forming clear pattern.In addition, employed slurry contains organic solvent, and human body and environment are brought disagreeableness problem.
More than the fabric feeling that makes in three patent applications all not good, when human body is worn, do not feel like oneself.
Therefore, also need be to human body and the non-harmful raw material of environment, make the fabric feeling that makes good, washable and when moistening, can clearly manifest the product and the production method of pattern.
Summary of the invention
For achieving the above object; The present invention provides a kind of product turning liquid into printing; This product forms colourless pattern by hydrophilic substrates with on this hydrophilic substrates water repellent layer constitutes, and said water repellent layer contains water repellent and is selected from least a auxiliary material in thickener and the blowing agent.
The present invention also provides a kind of production method of product turning liquid into printing, and this method comprises: preparation contains water repellent and the step that is selected from the turning liquid into printing water paste of at least a auxiliary material in thickener and the blowing agent; With according to predetermined pattern, on hydrophilic substrates, form the step of water repellent layer.
More advantageously, can also comprise in the water repellent layer of product turning liquid into printing of the present invention and refuse the water synergist.
In the product turning liquid into printing of the present invention, said hydrophilic substrates has WATER REPELLENCY through the zone of water repellent coating or stamp arrangement, without the regional possess hydrophilic property of coating or stamp arrangement.When substrate is wetted, utilize the difference refuse water and hydrophilic segment bound water to reach the effect of display pattern under the hygrometric state, that is, pass through refusing the aqua region pattern and can clearly reveal behind water repellent coating or the stamp.This turning liquid into printing is different from traditional stamp part and is: under the drying condition on the substrate pattern be invisible, have only when substrate soaking or wetting condition under pattern can display.
Therefore, the present invention has multiple use, and local wet the filtering of fabric face brought visual unhappyly in the time of can reducing human body and perspire to the people, also can be used for children's paper diaper and show the wet function of urine to give.In addition, can also be used for textiless such as face-cloth that children use or bath towel, when face-cloth or bath towel were wetting, top pattern or decorative pattern can display vivid, with reality, are convenient to strengthen children's curiosity, improve children's intelligence.
The present invention is not because the turning liquid into printing slurry that uses contains organic solvent, so be friendly to human body and environment, can directly carry out stamp to fabric, can carry out stamp to cut-parts yet, can accurately lock the waste of stamp position and minimizing cloth.The stamp mode that adopts very little to feel influence, even almost not influence, thus both guaranteed the good soft feel of finished product fabric, can give its new function again.
Turning liquid into printing slurry of the present invention has the operation of curing weak point consuming time to turning liquid into printing method of the present invention, the little and production efficiency advantages of higher to the infringement of substrate owing to using.
In addition, the application can also be used for the foam printing technology and have extensive use, can print the multiple substrate that comprises textiles, paper and macromolecular material.Particularly, product of the present invention can be used for the clothes of summer or when motion dress, not only comfortable and easy to wearly also can improve the not good outward appearance that clothes cause because of perspiration.In addition, if on fabric, be printed on the sign of company, also can reach purpose to company's propaganda.
The specific embodiment
Product turning liquid into printing of the present invention forms colourless pattern by hydrophilic substrates with on this hydrophilic substrates water repellent layer constitutes, and said water repellent layer contains water repellent and is selected from least a auxiliary material in thickener and the blowing agent; Perhaps said water repellent layer is made up of water repellent and at least a auxiliary material that is selected from thickener and the blowing agent, and wherein when said water repellent layer contained blowing agent, this water repellent layer can also contain foam stabiliser.
A concrete technical scheme of the present invention is that said water repellent layer is made up of water repellent and thickener.
Also concrete technical scheme of the present invention is that said water repellent layer is made up of water repellent, blowing agent and foam stabiliser.
Another concrete technical scheme of the present invention is, said water repellent layer is by water repellent, blowing agent and foam stabiliser, and refuses the water synergist and/or thickener constitutes.
Said water repellent has and reduces the function that substrate surface tension force presents substrate surface to refuse the water effect.The present invention has no particular limits water repellent, can use any water repellent finishing agent that is used for textiles, preferably uses at least a water repellent in fluorocarbons, paraffin-aluminum soap and the organosilicon.
The main purpose of said thickener is the viscosity that increases coating or stamp treatment fluid, and its decalcomania can not be spread, and then improves the clear patterns degree.The present invention does not have particular restriction to thickener, as long as it can be compatible with water repellent, do not refuse the water effect and gets final product and do not influence it.Preferred thickening is at least a thickener in acrylic polymer, polybasic carboxylic acid class or the polysaccharide polymer.
The main purpose of said blowing agent is to produce stable, uniform foam.Be applicable to that blowing agent of the present invention can select fatty amine and derivatives class or cyclopentanes for use.
The main purpose of said foam stabiliser is to keep the stability of foam in use and transmission course, prolongs stabilization time.That said foam stabiliser can be selected for use is silicone based, at least a foam stabiliser in stearic acid amide class, hard ester acid amide class or the alkyl ethoxy compound.
If employing foam coating or spray-painting then can perhaps abandon using thickener and reduce through accurately controlling applied amount.But the employing foam coating need add blowing agent and/or foam stabiliser when coating paste prepares.
In said water repellent layer, the weight ratio of water repellent and thickener be 1 to 200: 0 to 100, the weight ratio of water repellent and blowing agent be 1 to 200: 0 to 50, wherein the content of thickener and blowing agent is not 0 simultaneously.And when water repellent layer contained foam stabiliser, the weight ratio of said blowing agent and foam stabiliser was 1: 1 to 50: 1.
In case of necessity, water repellent layer of the present invention can also contain and refuses the water synergist.When said water repellent layer contains when refusing the water synergist, water repellent with refuse water synergist weight ratio be 1 to 200: 1 to 100.A concrete technical scheme of the present invention is that said water repellent layer is made up of water repellent and thickener.
The described water synergist of refusing has the durability that improves water repellent and makes the washable function of the waterproofing function of product lasting.Be applicable to that the water synergist of refusing of the present invention is be selected from polyurethane and isocyanates at least a.
Be applicable to that substrate of the present invention is a hydrophilic substrates, said substrate also comprises paper, macromolecule material film etc. except fabric.Fabric is knitting, the tatting or the nonwoven fabric of any institutional framework, and composition can be any one or a few of natural fabric, chemical fibre, natural and chemical fiber blending or yarns interwoven.Paper comprises various hydrophily paper.Macromolecular material can be various hydrophilic resins.Product turning liquid into printing of the present invention can be the sportswear in towel or summer.
The present invention also provides the production method of above-mentioned product turning liquid into printing, and this method comprises: preparation contains water repellent and the step that is selected from the turning liquid into printing slurry of at least a auxiliary material of refusing in water synergist, thickener and the blowing agent; With according to predetermined pattern, on hydrophilic substrates, form the step of water repellent layer.
Saidly be applied to water repellent layer pattern on the substrate for refusing aqua region, the area size occupies 0.01%～99% of whole substrate area size.
According to predetermined pattern, on hydrophilic substrates, form in the step of water repellent layer employed system and net available photoresists exposure system net or preparing printing screen.
Among the present invention; The step of preparation turning liquid into printing slurry can for: in container, add water repellent 1～200 gram, refuse water synergist 0～100 gram, thickener 1～100 gram; And to add water to final solution be 1 kilogram; This mixed liquor was stirred 1～60 minute, promptly obtain weight and be 1 kilogram water paste; Perhaps in container, add: water repellent 1～200 gram, refuse water synergist 0～100 gram, blowing agent 1～50 gram; Foam stabiliser 0～50 gram; Water 1～2000 gram stirs mixed liquor 1～120 minute, promptly obtains the foamed slurry of volume for about 3～25 times of the preceding liquid volumes of foaming.
In the present invention, as the kiering of the fabric of substrate, dye, soap, operations such as fixation, oven dry are the conventional processing step that uses in the dyeing.
Among the present invention, the method that on hydrophilic substrates, forms water repellent layer comprises coating and Decal, the known technology of process using dyeing and the equipment of coating or stamp.Every can the method that chemicals be applied to substrate one side can the employing.For example, said coating includes but not limited to, scraper coating, floating-point coating, foam coating, spray-painting, transfer coated or cylinder coating; Said Decal includes but not limited to, roller printing, PLATE SCREAM PRINTING, ROTARY SCREAM PRINTING or Computerized ink-jetting stamp.
The common process step that is embodied as this area of preparation coating or stamp net and coating or stamp, concrete condition need be confirmed according to the pattern of equipment and needs.Any regular or irregular pattern can adopt.The pattern of stamp will directly determine to refuse the ratio of water section and hydrophilic segment.
In the present invention, carry out local WATER REPELLENCY coating or stamp according to predetermined pattern, behind coating or stamp, dry, and when needed, the substrate after the oven dry is carried out wash water in the given side of substrate.
Can the fabric behind coating or the stamp directly be baked, baking temperature is 110～180 ℃, preferably adopts 150～170 ℃.The time of baking is 0.5～10 minute, preferably adopts 2～4 minutes, and too high or time of temperature passes the aberration that all can influence fabric for a long time and feel etc.Fabric after baking can adopt the ordinary skill in the art to wash so that remove the residue chemistry article of fabric face, and highlights the definition and the plentiful soft hand feeling of fabric of pattern under the hygrometric state more.
Below further specify the present invention with the mode of embodiment, but the present invention is not limited in following embodiment.
The production method of embodiment 1:40S/2 navy blue LACOSTE turning liquid into printing knitted fabric is following:
The according to the form below obtaining liq becomes concentrator:
| Component | Weight (gram) |
| Organic fluorine water-refusing agent (NTX-100, Nano Tex) | 20 |
| Acrylic acid ester thickener (FS-200E, Dandong Fixed Star Fine Chemical Co., Ltd) | 30 |
| Water | 950 |
Under 12000 rev/mins condition, stir 1 kilogram of the water paste obtained in 10 minutes, through applying plain net that prepared beforehand is printed on Esquel Logo well slurry is coated onto the front of fabric, bake subsequently, condition is: 160 ℃ of temperature, 3 minutes time.
Obtain the 40S/2 navy blue LACOSTE turning liquid into printing knitted fabric of this instance through above-mentioned steps.The clear patterns degree is 1.2mm.This clear patterns kilsyth basalt characterization method is seen the PRINTED FABRIC evaluation portion.
The production method of the orange plain weave turning liquid into printing of embodiment 2:30S/1 single face knitted fabric is following:
Identical with embodiment one method, but according to becoming concentrator like the following table obtaining liq:
| Component | Weight (gram) |
| Organic fluorine water-refusing agent (Nt-x100, Nano Tex) | 200 |
| Acrylic acid ester thickener (FS-200E, Dandong Fixed Star Fine Chemical Co., Ltd) | 40 |
| Polyurethane refuse the water synergist (FF, Clariant) | 10 |
| Water | 750 |
Through applying plain net that prepared beforehand is printed on the HB printed words well slurry is coated onto the front of fabric, bakes subsequently, condition is: 160 ℃ of temperature, 3 minutes time.
Obtain the orange plain weave turning liquid into printing of the 30S/1 single face knitted fabric of this instance through above-mentioned steps.
This example can obviously improve the fabric washability, and experience is washing more than 10 times, and it is clear that pattern interface still keeps.Wash the back definition for 10 times and can reach 1.2mm.This clear patterns kilsyth basalt characterization method is seen the PRINTED FABRIC evaluation portion.
Embodiment 3:32S/1 single face spends the production method of grey plain weave turning liquid into printing knitted fabric following:
By becoming concentrator like following table preparation foam liquid:
| Component | Weight (gram) |
| Paraffin-aluminum salt water repellent (JVA, Ciba) | 18 |
| Fat amine blowing agent (Diphasol HP, Ciba) | 10 |
| Stearic acid amide class foam stabilizer (Dicrylan FL, Ciba) | 10 |
| Water | 200 |
Under 2500 rev/mins condition, stir foaming and obtained about 2 liters foam oar material in 15 minutes, through applying plain net that prepared beforehand is printed on the AD printed words well slurry is coated onto the front of fabric, bake subsequently, condition is: 160 ℃ of temperature, 2 minutes time.
The 32S/1 single face that obtains this instance through above-mentioned steps is spent grey plain weave turning liquid into printing knitted fabric.Definition is 1.2mm.This clear patterns kilsyth basalt characterization method is seen the PRINTED FABRIC evaluation portion.
The production method of the blue plain weave turning liquid into printing of embodiment 4:32S/1 single face knitted fabric is following
By becoming concentrator like following table preparation foam liquid:
| Component | Weight (gram) |
| Organosilicon water repellent (DC-772, Dow Corning) | 20 |
| Fat amine blowing agent (Diphasol HP, Ciba) | 10 |
| Stearic acid amide class foam stabilizer (Dicrylan FL, Ciba) | 15 |
| Polyurethane refuse the water synergist (FF, Clariant) | 10 |
| Water | 100 |
Under 2500 rev/mins condition, stir foaming and obtained about 1 liter foam oar material in 10 minutes; Through applying the front that plain net that prepared beforehand is printed on the NK printed words well is coated onto slurry in fabric; Used net is different with front embodiment, and pattern bakes by refusing random staggered the forming of water spot and hydrophilic point subsequently on the plain net; Condition is: 160 ℃ of temperature, 2 minutes time.
Obtain the blue plain weave turning liquid into printing of the 32S/1 single face knitted fabric of this instance through above-mentioned steps.Definition is 1.2mm.Wash the back definition for 10 times and can reach 1.4mm.This clear patterns kilsyth basalt characterization method is seen the PRINTED FABRIC evaluation portion.
Embodiment 5: the paper stamp
Get one of lotus flower board white paper for daily use, become the seal slurry by following formulated liquid:
| Component | Weight (gram) |
| The organic fluorine water-refusing agent (Nt-x100, NanoTex) | 10 |
| Fat amine blowing agent (Diphasol HP, Ciba) | 10 |
| Stearic acid amide class foam stabilizer (Dicrylan FL, Ciba) | 10 |
| Water | 100 |
Under 2500 rev/mins condition, stir the foamed slurry of the about 100ML obtained in 10 minutes, the plain net that is printed on the NK printed words through prepared beforehand well is coated onto the front of paper with slurry, puts into the plain net baking oven, 80 ℃ of oven dry, and the time is 2 minutes.
Obtain the turning liquid into printing paper of this instance through above-mentioned steps.Definition is 1mm.This clear patterns kilsyth basalt characterization method is seen the PRINTED FABRIC evaluation portion.
Embodiment 6: the bath towel stamp
Get one of Guangzhou refined wash with watercolours light green color superfine fibre bath towel, specification 70cm * 160cm, press following formulated foamed slurry:
| Component | Weight (gram) |
| The organic fluorine water-refusing agent (Nt-x100, NanoTex) | 7 |
| Fat amine blowing agent (Diphasol HP, Ciba) | 1 |
| Stearic acid amide class foam stabilizer (Dicrylan FL, Ciba) | 20 |
| Water | 100 |
Under 2500 rev/mins condition, stir and obtained the foamed slurry that volume is about 1 liter in 15 minutes, the plain net that is printed on the NK printed words through prepared beforehand well is coated onto the front of bath towel with slurry, bakes subsequently, and condition is: 160 ℃ of temperature, 3 minutes time.Obtain the turning liquid into printing bath towel of this instance through above-mentioned steps.
Comparative example 1
With the blue plain weave turning liquid into printing of the identical preparation of the method 32S/1 single face knitted fabric of embodiment 2, only be to use the slurry of following composition preparation:
| Component | Weight (gram) |
| The APEO emulsifying agent | 2 |
| 407# electricity oil | 30 |
| Sulfonic group and alkyl polyglycol ether mixture bleeding agent | 2 |
| Carbon aluminium hydrogen compound waterproofing agent | 20 |
| Water | 46 |
Comparative example 2
With the orange plain weave turning liquid into printing of the identical preparation of the method 30S/1 single face knitted fabric of embodiment 4, only be to use the slurry of following composition preparation:
| Component | Weight (gram) |
| The APEO emulsifying agent | 2 |
| 407# electricity oil | 33 |
| Sulfonic group and alkyl polyglycol ether mixture bleeding agent | 2 |
| Carbon aluminium hydrogen compound waterproofing agent | 15 |
| Water | 48 |
PRINTED FABRIC is estimated:
With following method the decalcomania of embodiment and comparative example is estimated: utilization standard network (1200 orders; The flower type is 3cm by length, and width is 0.1mm～2mm, and every hollow out lines that do not wait at a distance from 20 thicknesses of 0.1mm gradual change are formed); The turning liquid into printing fabric that obtains by each embodiment and comparative example; Wetting at ambient temperature, make that pattern can manifest fully on the fabric, this moment naked eyes can observe even straight, do not have the width of the minimum hollow out lines of breakpoint to be definition.Each fabric is carried out 10 washings, measure the clear patterns degree afterwards once more.Evaluation result sees the following form.
Claims (9)
1. product turning liquid into printing; This product forms colourless pattern by hydrophilic substrates with on this hydrophilic substrates water repellent layer constitutes; Water repellent layer on the said hydrophilic substrates forms through the foam coating method, and said water repellent layer contains water repellent and blowing agent, wherein in said water repellent layer; The weight ratio of water repellent and blowing agent be 1 to 200: 0 to 50, wherein the content of blowing agent is not 0.
2. product turning liquid into printing according to claim 1, wherein said water repellent layer is made up of water repellent and blowing agent.
3. product turning liquid into printing according to claim 1 and 2, wherein this water repellent layer also contains foam stabiliser, and the weight ratio of said blowing agent and foam stabiliser is 1: 1 to 50: 1.
4. product turning liquid into printing according to claim 1 and 2, wherein water repellent is at least a water repellent that is selected from fluorocarbons, paraffin-aluminum salt and the organosilicon; Described blowing agent is for being selected from fatty amine or cyclopentanes.
5. product turning liquid into printing according to claim 3, wherein said foam stabiliser are at least a foam stabiliser that is selected from silicone based, stearic acid amide class, hard ester acid amide class or the alkyl ethoxy compound.
6. product turning liquid into printing according to claim 1 and 2; Wherein said water repellent layer also contains refuses the water synergist; The said water synergist of refusing is to be selected from least a in polyurethane and the isocyanates, and water repellent and refuse water synergist weight ratio be 1 to 200: 1 to 100.
7. product turning liquid into printing according to claim 1, wherein said hydrophilic substrates are fabric or paper.
8. product turning liquid into printing according to claim 1, said product are the sportswear in towel or summer.
9. the production method of any described product turning liquid into printing of claim 1 to 8, this method comprises: preparation contains the step of the turning liquid into printing water paste of water repellent and blowing agent; With according to predetermined pattern, on hydrophilic substrates, form the step of water repellent layer.
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| CN102805430B (en) * | 2011-05-30 | 2015-07-01 | 广东溢达纺织有限公司 | Multifunctional knitted garment and manufacturing method thereof |
| CN102433778A (en) * | 2011-10-22 | 2012-05-02 | 蔡艺萍 | Production process of water-sensitive printed fabric |
| CN103774099B (en) * | 2014-01-20 | 2017-02-08 | 东莞市和域战士纳米科技有限公司 | Plasma production method for water-sense printing on surface of workpiece |
| CN105274871A (en) * | 2015-04-07 | 2016-01-27 | 时兴纺整(苏州)有限公司 | Invisible pattern surface treatment technology for cloth showing patterns meeting water |
| CN104939408B (en) * | 2015-06-30 | 2017-04-12 | 绍兴市睿晟纺织品有限公司 | Manufacturing process of water printing composite fabric |
| KR101612232B1 (en) * | 2015-09-10 | 2016-04-12 | 황태준 | Textile for leisure, and Manufacturing method thereof, and a leisure cap manufactured by the method |
| CN106758314A (en) * | 2016-11-11 | 2017-05-31 | 苏州市兴丰强纺织科技有限公司 | A kind of water becomes printed fabric and its production technology |
| CN106592273B (en) * | 2016-11-28 | 2019-03-26 | 恩平锦兴纺织印染企业有限公司 | A kind of production technology of waterproof and oilproof touching water change printed fabric |
| CN110495660A (en) * | 2018-05-16 | 2019-11-26 | 东莞超盈纺织有限公司 | A fabric that maintains wearing comfort and elegant appearance during exercise |
| CN108998991A (en) * | 2018-08-17 | 2018-12-14 | 宁波大千纺织品有限公司 | A kind of preparation method of stealth moisture absorption colour developing knitting fabric |
| CN111851095A (en) * | 2020-08-10 | 2020-10-30 | 福建华峰运动用品科技有限公司 | Waterproof printing paste, water-sensitive developing printed fabric using waterproof printing paste and preparation method |
| CN114103327B (en) * | 2021-11-22 | 2023-08-15 | 上海楚桦仪器科技有限公司 | Improved non-woven fabric, preparation method and disposable perineum drape |
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