CN112543789A - 高吸收性树脂及其制备方法 - Google Patents

高吸收性树脂及其制备方法 Download PDF

Info

Publication number
CN112543789A
CN112543789A CN201880096198.4A CN201880096198A CN112543789A CN 112543789 A CN112543789 A CN 112543789A CN 201880096198 A CN201880096198 A CN 201880096198A CN 112543789 A CN112543789 A CN 112543789A
Authority
CN
China
Prior art keywords
solution
resin
blood
sodium polyacrylate
sample
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201880096198.4A
Other languages
English (en)
Other versions
CN112543789B (zh
Inventor
杨志亮
杨昊
杨阳
马廷玉
张香
姚美芹
姚金水
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Haoyue New Materials Co ltd
Original Assignee
Shandong Haoyue New Materials Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Haoyue New Materials Co ltd filed Critical Shandong Haoyue New Materials Co ltd
Publication of CN112543789A publication Critical patent/CN112543789A/zh
Application granted granted Critical
Publication of CN112543789B publication Critical patent/CN112543789B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/24Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42Use of materials characterised by their function or physical properties
    • A61L15/60Liquid-swellable gel-forming materials, e.g. super-absorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/265Synthetic macromolecular compounds modified or post-treated polymers
    • B01J20/267Cross-linked polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/075Macromolecular gels
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/24Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/245Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2400/00Materials characterised by their function or physical properties
    • A61L2400/04Materials for stopping bleeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/40Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48Sorbents characterised by the starting material used for their preparation
    • B01J2220/4812Sorbents characterised by the starting material used for their preparation the starting material being of organic character
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00Aspects relating to sorbent materials
    • B01J2220/50Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/68Superabsorbents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Hematology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

一种具有渐变式层级结构的吸血用聚丙烯酸钠高吸收性树脂,以及其制备方法。所述高吸收性树脂为经表面改性的聚丙烯酸钠树脂,所述表面改性包括使用由多价金属盐溶液A,以及由含有环氧基团的化合物和溶剂配制成的溶液B进行表面交联。

Description

PCT国内申请,说明书已公开。

Claims (20)

  1. PCT国内申请,权利要求书已公开。
CN201880096198.4A 2018-06-22 2018-06-22 高吸收性树脂及其制备方法 Active CN112543789B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2018/092326 WO2019241986A1 (zh) 2018-06-22 2018-06-22 高吸收性树脂及其制备方法

Publications (2)

Publication Number Publication Date
CN112543789A true CN112543789A (zh) 2021-03-23
CN112543789B CN112543789B (zh) 2022-12-27

Family

ID=68983082

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880096198.4A Active CN112543789B (zh) 2018-06-22 2018-06-22 高吸收性树脂及其制备方法

Country Status (5)

Country Link
US (1) US12214091B2 (zh)
EP (1) EP3812422A4 (zh)
JP (1) JP7128302B2 (zh)
CN (1) CN112543789B (zh)
WO (1) WO2019241986A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113136636A (zh) * 2021-05-12 2021-07-20 福建省福地化纤科技有限公司 一种超吸水es复合纤维及其制备方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019241986A1 (zh) * 2018-06-22 2019-12-26 山东昊月新材料股份有限公司 高吸收性树脂及其制备方法
EP4308056B1 (en) * 2021-03-18 2026-04-29 The Procter & Gamble Company Method for producing absorbent articles comprising water-absorbing resin

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806578A (en) * 1985-08-30 1989-02-21 Kao Corporation Process for producing highly absorptive resin
CN1696181A (zh) * 2005-06-14 2005-11-16 济南昊月树脂有限公司 聚丙烯酸钠吸水树脂表面改性方法
CN107501580A (zh) * 2017-08-29 2017-12-22 山东昊月新材料股份有限公司 一种具有渐变式层级结构的吸血用聚丙烯酸钠高吸收性树脂及其制备方法

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3001565A (en) * 1959-09-25 1961-09-26 Hospital Supply And Dev Compan Drainage bag
US4051086A (en) 1976-03-25 1977-09-27 Hercules Incorporated Absorption rate of absorbent polymers by treating with glyoxal
US5531724A (en) * 1987-01-14 1996-07-02 American Innotek, Inc. Fluid containment bag
US4911699A (en) * 1987-03-16 1990-03-27 Marlen Manufacturing & Development Co. Deodorizing ostomy pouch
US4914170A (en) * 1987-11-17 1990-04-03 Rohm And Haas Company Superabsorbent polymeric compositions and process for producing the same
JPH07242709A (ja) 1994-03-03 1995-09-19 Toagosei Co Ltd 吸水性樹脂の製造方法
US6231553B1 (en) * 1999-05-17 2001-05-15 Medi-South Products Inc. Colostomy bag
JP2002035580A (ja) 1999-06-24 2002-02-05 Sanyo Chem Ind Ltd 吸収剤組成物および吸収性物品
US7422577B2 (en) * 2003-06-27 2008-09-09 Hollister Incorporated Lubricating deodorant for ostomy pouches
US20060111682A1 (en) * 2004-06-24 2006-05-25 Schena Kenneth R Colostomy bag cleaning system
AU2005285763A1 (en) * 2004-09-24 2006-03-30 Nippon Shokubai Co., Ltd. Particulate water-absorbing agent containing water-absorbent resin as a main component
KR20070104663A (ko) * 2005-02-15 2007-10-26 니폰 쇼쿠바이 컴파니 리미티드 수 흡수제, 수 흡수제품 및 수 흡수제의 제조방법
US20060189962A1 (en) * 2005-02-23 2006-08-24 Burtoft Bonnie B Urinary Drainage Bag for Urinary Diversion to the Bellie Button
JP5091477B2 (ja) * 2005-04-12 2012-12-05 株式会社日本触媒 ポリアクリル酸(塩)系吸水性樹脂を主成分とする粒子状吸水剤、その製造方法、この粒子状吸水剤を用いた吸収体及び吸収性物品
EP1965841A1 (en) 2005-12-28 2008-09-10 Basf Se Process for production of a water-absorbing material
US7745507B2 (en) * 2006-04-10 2010-06-29 The Procter & Gamble Company Absorbent member comprising a modified water absorbent resin
JP2010501696A (ja) * 2006-08-31 2010-01-21 ビーエーエスエフ ソシエタス・ヨーロピア ポリアミンコーティングされた超吸収性ポリマー
JP5558096B2 (ja) * 2007-03-01 2014-07-23 株式会社日本触媒 吸水性樹脂を主成分とする粒子状吸水剤
JP2008247949A (ja) 2007-03-29 2008-10-16 San-Dia Polymer Ltd 吸収性樹脂粒子、吸収体及び吸収性物品
CN101641153B (zh) * 2007-04-05 2012-08-15 株式会社日本触媒 以吸水性树脂为主成分的粒子状吸水剂
JP5410412B2 (ja) * 2008-03-31 2014-02-05 株式会社日本触媒 吸水性樹脂を主成分とする粒子状吸水剤の製造方法及びその製造装置
US8292859B2 (en) * 2008-05-12 2012-10-23 Tyco Healthcare Group Lp Drainage device
US8273065B2 (en) * 2008-07-15 2012-09-25 Zora Singh Gill Ostomy bag odor control and irrigation system
US8357105B2 (en) * 2008-08-07 2013-01-22 Covidien Lp Anti-reflux mechanism for urine collection systems
US8167857B2 (en) * 2008-12-22 2012-05-01 Margarita James Ostomy suction system
KR101895624B1 (ko) * 2009-12-24 2018-09-05 가부시키가이샤 닛폰 쇼쿠바이 폴리아크릴산계 흡수성 수지분말 및 그 제조방법
CN102822209B (zh) * 2010-04-07 2014-09-03 株式会社日本触媒 聚丙烯酸(盐)系吸水性树脂粉末的制造方法、聚丙烯酸(盐)系吸水性树脂粉末
JP6113084B2 (ja) 2011-03-08 2017-04-12 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 改善された浸透性を有する吸水性ポリマー粒子を製造する方法
JP5599513B2 (ja) * 2011-06-29 2014-10-01 株式会社日本触媒 ポリアクリル酸(塩)系吸水性樹脂粉末及びその製造方法
CN103131028A (zh) 2011-11-25 2013-06-05 上海华谊丙烯酸有限公司 高吸水性树脂、其制备方法和用途
CN109608665A (zh) * 2012-08-30 2019-04-12 株式会社日本触媒 颗粒状吸水剂及其制造方法
KR102124670B1 (ko) * 2012-09-11 2020-06-18 가부시키가이샤 닛폰 쇼쿠바이 폴리아크릴산(염)계 흡수제의 제조 방법 및 그 흡수제
WO2014041969A1 (ja) * 2012-09-11 2014-03-20 株式会社日本触媒 ポリアクリル酸(塩)系吸水剤の製造方法及びその吸水剤
WO2014088012A1 (ja) * 2012-12-03 2014-06-12 株式会社日本触媒 ポリアクリル酸(塩)系吸水性樹脂およびその製造方法
CN106062058B (zh) * 2014-03-19 2019-04-23 长濑化成株式会社 吸水性树脂交联剂
US10537874B2 (en) * 2015-04-02 2020-01-21 Nippon Shokubai Co., Ltd. Method for producing particulate water-absorbing agent
CN109310984A (zh) * 2016-03-28 2019-02-05 株式会社日本触媒 吸水剂的制造方法
US20170281425A1 (en) * 2016-03-30 2017-10-05 Basf Se Fluid-absorbent article
JP7120739B2 (ja) 2016-08-04 2022-08-17 Sdpグローバル株式会社 吸収性樹脂組成物粒子及びその製造方法
CN106749803B (zh) * 2016-12-28 2019-02-19 山东昊月新材料股份有限公司 一种提高sap制备效率的工艺方法
JP7424832B2 (ja) * 2017-02-06 2024-01-30 ビーエーエスエフ ソシエタス・ヨーロピア 流体吸収性物品
EP3391958B1 (en) * 2017-04-19 2020-08-12 The Procter & Gamble Company Method of making surface-coated water-absorbing polymer particles in a microfluidic device
US11053370B2 (en) * 2017-04-19 2021-07-06 The Procter & Gamble Company Agglomerated superabsorbent polymer particles having a specific size ratio
CN109467738B (zh) * 2017-09-07 2021-07-02 刘常红 一种高吸水性树脂的制备方法
WO2019241986A1 (zh) * 2018-06-22 2019-12-26 山东昊月新材料股份有限公司 高吸收性树脂及其制备方法
WO2020123316A2 (en) * 2018-12-10 2020-06-18 10X Genomics, Inc. Methods for determining a location of a biological analyte in a biological sample
US11649485B2 (en) * 2019-01-06 2023-05-16 10X Genomics, Inc. Generating capture probes for spatial analysis
US11926867B2 (en) * 2019-01-06 2024-03-12 10X Genomics, Inc. Generating capture probes for spatial analysis
CA3184904A1 (en) * 2020-06-02 2021-12-09 Convatec Limited An ostomy pouch
US20220296407A1 (en) * 2021-03-17 2022-09-22 Justin Sims Ostomy Bag Assembly

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806578A (en) * 1985-08-30 1989-02-21 Kao Corporation Process for producing highly absorptive resin
CN1696181A (zh) * 2005-06-14 2005-11-16 济南昊月树脂有限公司 聚丙烯酸钠吸水树脂表面改性方法
CN107501580A (zh) * 2017-08-29 2017-12-22 山东昊月新材料股份有限公司 一种具有渐变式层级结构的吸血用聚丙烯酸钠高吸收性树脂及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113136636A (zh) * 2021-05-12 2021-07-20 福建省福地化纤科技有限公司 一种超吸水es复合纤维及其制备方法

Also Published As

Publication number Publication date
US12214091B2 (en) 2025-02-04
JP2021528543A (ja) 2021-10-21
US20210268139A1 (en) 2021-09-02
WO2019241986A1 (zh) 2019-12-26
JP7128302B2 (ja) 2022-08-30
EP3812422A1 (en) 2021-04-28
EP3812422A4 (en) 2021-07-07
CN112543789B (zh) 2022-12-27

Similar Documents

Publication Publication Date Title
TWI487717B (zh) 具有容量增加之超吸收性聚合物
US8476189B1 (en) Process for superabsorbent polymer and crosslinker composition
US6410616B1 (en) Crosslinked polymer particle and its production process and use
RU2518063C2 (ru) Способ производства суперабсорбирующего полимерного геля с суперабсорбирующими полимерными тонкоизмельченными частицами
JP5301159B2 (ja) 吸水剤及びこれを用いた吸水体、並びに吸水剤の製造方法
KR101827038B1 (ko) 성능 특성이 개선된 미립자형 초흡수성 중합체 조성물
US9440220B2 (en) Superabsorbent polymer with crosslinker
CN109467738B (zh) 一种高吸水性树脂的制备方法
US20140031498A1 (en) High permeability superabsorbent polymer compositions
KR20070007162A (ko) 수성-액체-흡수제 및 그의 제조 방법
MXPA99002053A (en) Hygroscopic agent and its production process and
BR112015025560B1 (pt) Composição de polímero superabsorvente particulado, e seu processo de produção
JP2005113117A (ja) 吸水性樹脂組成物とその製造方法
TW200526277A (en) Particulate water-absorbent resin composition and its production process
CN112543789A (zh) 高吸收性树脂及其制备方法
CN101410177A (zh) 吸水剂、使用所述吸水剂的吸水芯片以及制备吸水剂的方法
CN107501580A (zh) 一种具有渐变式层级结构的吸血用聚丙烯酸钠高吸收性树脂及其制备方法
AU2018307483A1 (en) Absorbent article having a reduced humidity level
JP4746292B2 (ja) 吸水性樹脂組成物の製造方法
JP2019116636A (ja) 架橋剤を含む超吸収性ポリマー
KR20210013644A (ko) 나노기공 초흡수성 입자를 함유하는 흡수 용품
Grouli et al. A new approach for assessing the absorption of disposable baby diapers and

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Highly absorbent resin and its preparation method

Effective date of registration: 20230330

Granted publication date: 20221227

Pledgee: Shandong Tongsheng Financing Guarantee Co.,Ltd.

Pledgor: SHANDONG HAOYUE NEW MATERIALS Co.,Ltd.

Registration number: Y2023980036763

PE01 Entry into force of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Granted publication date: 20221227

Pledgee: Shandong Tongsheng Financing Guarantee Co.,Ltd.

Pledgor: SHANDONG HAOYUE NEW MATERIALS Co.,Ltd.

Registration number: Y2023980036763

PC01 Cancellation of the registration of the contract for pledge of patent right