CN116103811A - A kind of graphene mosquito repellent fabric and preparation method - Google Patents

A kind of graphene mosquito repellent fabric and preparation method Download PDF

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CN116103811A
CN116103811A CN202211655969.3A CN202211655969A CN116103811A CN 116103811 A CN116103811 A CN 116103811A CN 202211655969 A CN202211655969 A CN 202211655969A CN 116103811 A CN116103811 A CN 116103811A
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graphene
fibers
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周龑
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Fujian Tianxin Hi Tech New Material Co ltd
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/233—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads protein-based, e.g. wool or silk
    • D03D15/235—Cashmere or silk
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/587—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads adhesive; fusible
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/04—Linen
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00—Protein-based fibres, e.g. animal fibres
    • D10B2211/01—Natural animal fibres, e.g. keratin fibres
    • D10B2211/04—Silk
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
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Abstract

The invention provides a graphene mosquito-repellent fabric and a preparation method thereof, wherein the graphene mosquito-repellent fabric comprises the following components in percentage by weight: 30-40% of graphene fibers, 40-50% of other fibers and 10-20% of a preparation, wherein the mass content of graphene in the graphene fibers is 1-2%, the graphene raw materials adopted by the graphene fibers are graphene or amino modified graphene, and the fabric preparation method comprises the steps of S1, spinning the fibers into yarns, and weaving by using a loom; s2, desizing and heat preservation are carried out; s3, dyeing and cleaning; s4, drying and shaping are carried out, the graphene mosquito-repellent fabric is soft, and the mosquito-repellent preparation is prepared in the nano-scale microcapsules and the nano-scale microcapsules are fixed in the fibers, so that the effect of the graphene mosquito-repellent fabric is slowly released to achieve the effect of long-term mosquito-repellent, the process replaces the process of treating the textile fabric by using the mosquito-repellent liquid in the prior art, and related diseases caused by the mosquito-repellent liquid by textile workers are avoided.

Description

一种石墨烯驱蚊面料及制备方法A kind of graphene mosquito repellent fabric and preparation method

技术领域technical field

本发明涉及面料技术领域，具体涉及一种石墨烯驱蚊面料及制备方法。The invention relates to the technical field of fabrics, in particular to a graphene mosquito repelling fabric and a preparation method thereof.

背景技术Background technique

现阶段驱蚊面料一般有两种，一种在基布层和面料层之间做驱蚊夹层，一种是由驱蚊液处理后的纤维编织而成。其中，驱蚊液中一般都含有合成趋避剂，如DEET(N,N—二乙基间甲苯甲酰胺)，这类趋避剂会对人体健康产生不良影响，如可以引发神经系统疾病、脑病和皮肤病等。At present, there are generally two types of mosquito repellent fabrics, one is a mosquito repellent interlayer between the base fabric layer and the fabric layer, and the other is woven from fibers treated with mosquito repellent liquid. Among them, mosquito repellants generally contain synthetic repellents, such as DEET (N,N-diethyl-m-toluamide), which will have adverse effects on human health, such as neurological diseases, encephalopathy and skin diseases, etc.

发明内容Contents of the invention

本发明的目的在于提供一种石墨烯驱蚊面料及制备方法，以解决背景技术中的问题。The object of the present invention is to provide a kind of graphene mosquito repelling fabric and preparation method, to solve the problem in the background technology.

为了达到上述目的，本发明采用这样的技术方案：In order to achieve the above object, the present invention adopts such technical scheme:

作为本发明的第一方面提供一种石墨烯驱蚊面料，包括按重量百分数计的如下组分：30-40％的石墨烯纤维、40-50％的其他纤维以及10-20％的制剂。As a first aspect of the present invention, a graphene mosquito repellent fabric is provided, which includes the following components by weight percentage: 30-40% graphene fibers, 40-50% other fibers and 10-20% preparations.

进一步的，所述石墨烯纤维中，石墨烯质量含量为1-2％，所述石墨烯纤维采用的石墨烯原料为石墨烯或氨基改性石墨烯。Further, in the graphene fiber, the graphene mass content is 1-2%, and the graphene raw material used in the graphene fiber is graphene or amino-modified graphene.

进一步的，所述制剂包括1-10％石墨烯、润湿渗透剂1-15％、粘合剂3-10％、有机溶剂15-30％、余量为水；所述润湿渗透剂为阴离子、阳离子或非离子表面活性剂中的至少一种。Further, the preparation includes 1-10% graphene, 1-15% wetting and penetrating agent, 3-10% binder, 15-30% organic solvent, and the balance is water; the wetting and penetrating agent is At least one of anionic, cationic or nonionic surfactants.

进一步的，所述制剂的制备方法包括以下步骤：Further, the preparation method of the preparation includes the following steps:

(1)称取各组分备用；(1) take each component for subsequent use;

(2)将石墨烯与水混合配成溶液，并移至反应釜中；(2) Graphene is mixed with water to form a solution, and moved to the reactor;

(3)将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在40-70℃温度下高速搅拌30-60min得到成品。(3) Add adhesive, wetting and penetrating agent, and organic solvent into the above reaction kettle, and stir at a high speed at 40-70° C. for 30-60 minutes to obtain a finished product.

进一步的，所述其他纤维包括棉纤维、黏胶纤维、蚕丝纤维、天丝纤维、亚麻纤维中的一种或几种。Further, the other fibers include one or more of cotton fibers, viscose fibers, silk fibers, tencel fibers, and flax fibers.

作为本发明的第二方面提供一种石墨烯驱蚊面料的制备方法，包括如下步骤：Provide a kind of preparation method of graphene mosquito repellent fabric as second aspect of the present invention, comprise the steps:

S1、将纤维纺成纱线，利用织机进行织造；S1. Spin the fiber into yarn and weave it on a loom;

S2、进行退浆和保温；S2, desizing and heat preservation;

S3、进行染色和清洗；S3, dyeing and cleaning;

S4、进行烘干和定型。S4, drying and shaping.

进一步的，所述步骤S1中，包括将制剂设置于纳米级微胶囊中，并将纳米级微胶囊固定在纤维中。Further, in the step S1, it includes disposing the preparation in nanoscale microcapsules, and fixing the nanoscale microcapsules in the fibers.

进一步的，步骤S2中，在90～95℃下保温40～45分钟，浴比：1:(10～15)，溶液PH值控制在4～5，步骤S3中，染色温度低于90℃。Further, in step S2, keep warm at 90-95°C for 40-45 minutes, bath ratio: 1:(10-15), and control the pH value of the solution at 4-5. In step S3, the dyeing temperature is lower than 90°C.

进一步的，步骤S4中，利用定型机烘干，温度85～90℃，烘干时间10～100分钟；定型时加适量防水剂和柔软剂，带液率1.5％，在100℃下，以布料传输速度1～2m/min进行定型。Further, in step S4, use a sizing machine to dry at a temperature of 85 to 90°C and a drying time of 10 to 100 minutes; add an appropriate amount of water repellent and softener when setting the shape, and the liquid retention rate is 1.5%. The transmission speed is 1~2m/min for shaping.

采用上述技术方案后，本发明具有如下有益效果：After adopting the above technical scheme, the present invention has the following beneficial effects:

本发明的石墨烯驱蚊面料，面料柔和，通过将驱蚊制剂制备于纳米级微胶囊中并将该纳米级微胶囊固定于纤维中，从而使其效果缓慢释放达到长久驱蚊的功效，其工艺代替了现有技术中通过驱蚊液处理纺织面料，避免了纺织工人因驱蚊液造成相关的疾病。The graphene mosquito repellent fabric of the present invention has a soft fabric, and the mosquito repellent preparation is prepared in nano-scale microcapsules and the nano-scale microcapsules are fixed in fibers, so that the effect is slowly released to achieve long-term mosquito repellent effect. The process replaces the treatment of textile fabrics with mosquito repellent in the prior art, and avoids related diseases caused by the mosquito repellent to textile workers.

具体实施方式Detailed ways

为了进一步解释本发明的技术方案，下面对具体实施例进行详细阐述。In order to further explain the technical solution of the present invention, specific examples are described in detail below.

实施例1Example 1

本发明提供提供一种石墨烯驱蚊面料，采用如下材料组分：30％的石墨烯纤维、50％的其他纤维以及20％的制剂，石墨烯纤维中，石墨烯质量含量为1％；The present invention provides a graphene mosquito repellent fabric, which adopts the following material components: 30% graphene fibers, 50% other fibers and 20% preparations, and the graphene mass content in the graphene fibers is 1%;

进一步的，制剂的制备方法包括以下步骤：Further, the preparation method of the preparation comprises the following steps:

(1)称取各组分备用，制剂采用3％石墨烯、润湿渗透剂8％、粘合剂7％、有机溶剂18％、余量为水；润湿渗透剂为阴离子表面活性剂；(1) Weighing each component for subsequent use, the preparation adopts 3% graphene, 8% wetting and penetrating agent, 7% of binder, 18% of organic solvent, and the balance is water; the wetting and penetrating agent is an anionic surfactant;

(2)将石墨烯与水混合配成溶液，并移至反应釜中；(2) Graphene is mixed with water to form a solution, and moved to the reactor;

(3)将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在60℃温度下高速搅拌(3) Add the adhesive, wetting and penetrating agent, and organic solvent into the above reaction kettle, and stir at a high speed at 60°C

45min得到成品。45min to get the finished product.

进一步的，所述其他纤维包括棉纤维、黏胶纤维、蚕丝纤维、天丝纤维、亚麻纤维中的一种或几种。Further, the other fibers include one or more of cotton fibers, viscose fibers, silk fibers, tencel fibers, and flax fibers.

作为本发明的第二方面提供一种石墨烯驱蚊面料的制备方法，包括如下步骤：Provide a kind of preparation method of graphene mosquito repellent fabric as second aspect of the present invention, comprise the steps:

S1、将黏胶纤维和蚕丝纤维纺成纱线，再将卡拉胶、琼胶等亲水性高分子胶凝剂2添加到离子交换水中，以规定的温度(例如90℃)加热该离子交换水，使亲水性高分子胶凝剂2溶解，由此调配出溶解有亲水性高分子胶凝剂2的水溶液，接着，向上述亲水性高分子胶凝剂水溶液中添加两亲性物质以及制剂成品后，例如用螺旋桨式搅拌机进行搅拌混合，由此得到亲水性高分子胶凝剂水溶液与两亲性物质的混合物，混合物中亲水性高分子胶凝剂包覆制剂并以胶囊形式分散于两性物质中，再将胶囊外壳上的两亲性物质去除，最后将该胶囊固定于纱线上，利用织机进行织造；S1. Spin viscose fiber and silk fiber into yarn, then add hydrophilic polymer gelling agent 2 such as carrageenan and agar gel into ion exchange water, and heat the ion exchange water at a specified temperature (for example, 90°C). water to dissolve the hydrophilic polymer gelling agent 2, thereby preparing an aqueous solution in which the hydrophilic polymer gelling agent 2 is dissolved, and then adding amphiphilic After the substance and the preparation are finished, they are stirred and mixed, for example, with a propeller mixer, thereby obtaining a mixture of an aqueous solution of a hydrophilic polymer gelling agent and an amphiphilic substance. In the mixture, the hydrophilic polymer gelling agent coats the preparation and is mixed with The capsule form is dispersed in the amphiphilic substance, and then the amphiphilic substance on the shell of the capsule is removed, and finally the capsule is fixed on the yarn and woven by a loom;

S2、进行退浆和保温，在90℃下保温40分钟，浴比：1:12，溶液PH值控制为4；S2. Carry out desizing and heat preservation, heat preservation at 90°C for 40 minutes, bath ratio: 1:12, and control the pH value of the solution to 4;

S3、进行染色和清洗，染色温度低于90℃；S3, carry out dyeing and cleaning, the dyeing temperature is lower than 90 ℃;

S4、进行烘干和定型，利用定型机烘干，温度85℃，烘干时间30分钟；定型时加适量防水剂和柔软剂，带液率1.5％，在100℃下，以布料传输速度1～2m/min进行定型。S4. Carry out drying and setting, use setting machine to dry, temperature 85 ℃, drying time 30 minutes; Add proper amount of water repellent and softener when setting the shape, liquid retention rate 1.5%, at 100 ℃, with cloth transmission speed 1 ~2m/min for shaping.

实施例2Example 2

本发明提供提供一种石墨烯驱蚊面料，采用如下材料组分：40％的石墨烯纤维、45％的其他纤维以及15％的制剂，石墨烯纤维中，石墨烯质量含量为2％；The present invention provides a graphene mosquito repellent fabric, which adopts the following material components: 40% graphene fibers, 45% other fibers and 15% preparations, and the graphene mass content in the graphene fibers is 2%;

进一步的，制剂的制备方法包括以下步骤：Further, the preparation method of the preparation comprises the following steps:

(1)称取各组分备用，制剂采用5％石墨烯、润湿渗透剂12％、粘合剂10％、有机溶剂25％、余量为水；润湿渗透剂为阴离子表面活性剂；(1) Weighing each component for subsequent use, the preparation adopts 5% graphene, 12% of wetting and penetrating agent, 10% of binder, 25% of organic solvent, and the balance is water; the wetting and penetrating agent is an anionic surfactant;

(2)将石墨烯与水混合配成溶液，并移至反应釜中；(2) Graphene is mixed with water to form a solution, and moved to the reactor;

(3)将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在60℃温度下高速搅拌(3) Add the adhesive, wetting and penetrating agent, and organic solvent into the above reaction kettle, and stir at a high speed at 60°C

45min得到成品。45min to get the finished product.

进一步的，所述其他纤维包括棉纤维、黏胶纤维、蚕丝纤维、天丝纤维、亚麻纤维中的一种或几种。Further, the other fibers include one or more of cotton fibers, viscose fibers, silk fibers, tencel fibers, and flax fibers.

作为本发明的第二方面提供一种石墨烯驱蚊面料的制备方法，包括如下步骤：Provide a kind of preparation method of graphene mosquito repellent fabric as second aspect of the present invention, comprise the steps:

S1、该步骤与实施例1相同；S1, this step is identical with embodiment 1;

S2、进行退浆和保温，在90℃下保温45分钟，浴比：1:15，溶液PH值控制为4；S2. Carry out desizing and heat preservation, heat preservation at 90°C for 45 minutes, bath ratio: 1:15, and control the pH value of the solution to 4;

S3、进行染色和清洗，染色温度低于90℃；S3, carry out dyeing and cleaning, the dyeing temperature is lower than 90 ℃;

S4、进行烘干和定型，利用定型机烘干，温度85℃，烘干时间30分钟；定型时加适量防水剂和柔软剂，带液率1.5％，在100℃下，以布料传输速度1～2m/min进行定型。S4. Carry out drying and setting, use setting machine to dry, temperature 85 ℃, drying time 30 minutes; Add proper amount of water repellent and softener when setting the shape, liquid retention rate 1.5%, at 100 ℃, with cloth transmission speed 1 ~2m/min for shaping.

本发明的石墨烯驱蚊面料，面料柔和，通过将驱蚊制剂制备于纳米级微胶囊中并将该纳米级微胶囊固定于纤维中，从而使其效果缓慢释放达到长久驱蚊的功效，其工艺代替了现有技术中通过驱蚊液处理纺织面料，避免了纺织工人因驱蚊液造成相关的疾病。The graphene mosquito repellent fabric of the present invention has a soft fabric, and the mosquito repellent preparation is prepared in nano-scale microcapsules and the nano-scale microcapsules are fixed in fibers, so that the effect is slowly released to achieve long-term mosquito repellent effect. The process replaces the treatment of textile fabrics with mosquito repellent in the prior art, and avoids related diseases caused by the mosquito repellent to textile workers.

以上显示和描述了本发明的基本原理和主要特征和本发明的优点，对于本领域技术人员而言，显然本发明不限于上述示范性实施例的细节，而且在不背离本发明的精神或基本特征的情况下，能够以其他的具体形式实现本发明。因此，无论从哪一点来看，均应将实施例看作是示范性的，而且是非限制性的，本发明的范围由所附权利要求而不是上述说明限定，因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。The basic principles and main features of the present invention and the advantages of the present invention have been shown and described above. For those skilled in the art, it is obvious that the present invention is not limited to the details of the above-mentioned exemplary embodiments, and without departing from the spirit or basic principles of the present invention. The present invention can be implemented in other specific forms without any specific features. Accordingly, the embodiments should be regarded in all points of view as exemplary and not restrictive, the scope of the invention being defined by the appended claims rather than the foregoing description, and it is therefore intended that the scope of the invention be defined by the appended claims rather than by the foregoing description. All changes within the meaning and range of equivalents of the elements are embraced in the present invention.

此外，应当理解，虽然本说明书按照实施方式加以描述，但并非每个实施方式仅包含一个独立的技术方案，说明书的这种叙述方式仅仅是为清楚起见，本领域技术人员应当将说明书作为一个整体，各实施例中的技术方案也可以经适当组合，形成本领域技术人员可以理解的其他实施方式。In addition, it should be understood that although this specification is described according to implementation modes, not each implementation mode only includes an independent technical solution, and this description in the specification is only for clarity, and those skilled in the art should take the specification as a whole , the technical solutions in the various embodiments can also be properly combined to form other implementations that can be understood by those skilled in the art.

Claims (9)

1.一种石墨烯驱蚊面料，其特征在于：包括按重量百分数计的如下组分：30-40％的石墨烯纤维、40-50％的其他纤维以及10-20％的制剂。1. A graphene mosquito repellent fabric, characterized in that: comprising the following components by weight percentage: 30-40% graphene fibers, 40-50% other fibers and 10-20% preparations. 2.根据权利要求1所述的石墨烯驱蚊面料，其特征在于：所述石墨烯纤维中，石墨烯质量含量为1-2％，所述石墨烯纤维采用的石墨烯原料为石墨烯或氨基改性石墨烯。2. The graphene mosquito repelling fabric according to claim 1, characterized in that: in the graphene fiber, the graphene mass content is 1-2%, and the graphene raw material used by the graphene fiber is graphene or Amino-modified graphene. 3.根据权利要求1所述的石墨烯驱蚊面料，其特征在于：所述制剂包括1-10％石墨烯、润湿渗透剂1-15％、粘合剂3-10％、有机溶剂15-30％、余量为水；所述润湿渗透剂为阴离子、阳离子或非离子表面活性剂中的至少一种。3. The graphene mosquito repellent fabric according to claim 1, characterized in that: the preparation comprises 1-10% graphene, 1-15% wetting and penetrating agent, 3-10% adhesive, 15% organic solvent -30%, the balance is water; the wetting and penetrating agent is at least one of anionic, cationic or nonionic surfactants. 4.根据权利要求1所述的石墨烯驱蚊面料，其特征在于：所述制剂的制备方法包括以下步骤：4. graphene mosquito repelling fabric according to claim 1, is characterized in that: the preparation method of described preparation comprises the following steps: (1)称取各组分备用；(1) take each component for subsequent use; (2)将石墨烯与水混合配成溶液，并移至反应釜中；(2) Graphene is mixed with water to form a solution, and moved to the reactor; (3)将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在40-70℃温度下高速搅拌30-60min得到成品。(3) Add adhesive, wetting and penetrating agent, and organic solvent into the above reaction kettle, and stir at a high speed at 40-70° C. for 30-60 minutes to obtain a finished product. 5.根据权利要求1所述的石墨烯驱蚊面料，其特征在于：所述其他纤维包括棉纤维、黏胶纤维、蚕丝纤维、天丝纤维、亚麻纤维中的一种或几种。5. The graphene mosquito repellent fabric according to claim 1, characterized in that: said other fibers include one or more of cotton fibers, viscose fibers, silk fibers, tencel fibers, and flax fibers. 6.一种如权利要求1-5任一所述的石墨烯驱蚊面料的制备方法，其特征在于：包括如下步骤：6. A preparation method of the graphene mosquito repellent fabric as described in any one of claims 1-5, characterized in that: comprising the steps: S1、将纤维纺成纱线，利用织机进行织造；S1. Spin the fiber into yarn and weave it on a loom; S2、进行退浆和保温；S2, desizing and heat preservation; S3、进行染色和清洗；S3, dyeing and cleaning; S4、进行烘干和定型。S4, drying and shaping. 7.根据权利要求1所述的石墨烯驱蚊面料及制备方法，其特征在于：所述步骤S1中，包括将制剂设置于纳米级微胶囊中，并将纳米级微胶囊固定在纤维中。7. The graphene mosquito repellent fabric and its preparation method according to claim 1, characterized in that: said step S1 includes disposing the preparation in nano-scale microcapsules, and fixing the nano-scale microcapsules in the fibers. 8.根据权利要求1所述的石墨烯驱蚊面料及制备方法，其特征在于：步骤S2中，在90～95℃下保温40～45分钟，浴比：1:(10～15)，溶液PH值控制在4～5，步骤S3中，染色温度低于90℃。8. The graphene mosquito repellent fabric and preparation method according to claim 1, characterized in that: in step S2, heat preservation at 90-95°C for 40-45 minutes, bath ratio: 1:(10-15), solution The pH value is controlled at 4-5, and in step S3, the dyeing temperature is lower than 90°C. 9.根据权利要求1所述的石墨烯驱蚊面料及制备方法，其特征在于：步骤S4中，利用定型机烘干，温度85～90℃，烘干时间10～100分钟；定型时加适量防水剂和柔软剂，带液率1.5％，在100℃下，以布料传输速度1～2m/min进行定型。9. The graphene mosquito repellent fabric and preparation method according to claim 1, characterized in that: in step S4, use a setting machine to dry at a temperature of 85-90°C and a drying time of 10-100 minutes; add an appropriate amount when setting the shape Waterproofing agent and softening agent, with a liquid retention rate of 1.5%, at 100°C, with a cloth transmission speed of 1-2m/min for shaping.
CN202211655969.3A 2022-12-22 2022-12-22 A kind of graphene mosquito repellent fabric and preparation method Pending CN116103811A (en)

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Publication number Priority date Publication date Assignee Title
CN108348407A (en) * 2015-11-25 2018-07-31 麻沼株式会社 The preparation method of capsule
CN109463394A (en) * 2018-12-19 2019-03-15 南通强生石墨烯科技有限公司 A kind of graphene mosquito repellent auxiliary agent and the method for preparing graphene mosquito-repellent fabric
CN109594174A (en) * 2018-12-19 2019-04-09 南通强生石墨烯科技有限公司 A kind of graphene function of driving mosquitoes fabric and preparation method thereof
CN111621986A (en) * 2019-12-05 2020-09-04 山东汇高智慧纺织科技有限公司 Multifunctional fabric containing mosquito-repellent microcapsules and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108348407A (en) * 2015-11-25 2018-07-31 麻沼株式会社 The preparation method of capsule
CN109463394A (en) * 2018-12-19 2019-03-15 南通强生石墨烯科技有限公司 A kind of graphene mosquito repellent auxiliary agent and the method for preparing graphene mosquito-repellent fabric
CN109594174A (en) * 2018-12-19 2019-04-09 南通强生石墨烯科技有限公司 A kind of graphene function of driving mosquitoes fabric and preparation method thereof
CN111621986A (en) * 2019-12-05 2020-09-04 山东汇高智慧纺织科技有限公司 Multifunctional fabric containing mosquito-repellent microcapsules and preparation method thereof

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