CN105200802B - A kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function - Google Patents
A kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function Download PDFInfo
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- CN105200802B CN105200802B CN201510686727.4A CN201510686727A CN105200802B CN 105200802 B CN105200802 B CN 105200802B CN 201510686727 A CN201510686727 A CN 201510686727A CN 105200802 B CN105200802 B CN 105200802B
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- frankincense
- microcapsules
- crease finishing
- finishing liquid
- wool
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- 239000004744 fabric Substances 0.000 title claims abstract description 93
- 210000002268 wool Anatomy 0.000 title claims abstract description 84
- 239000012298 atmosphere Substances 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000004863 Frankincense Substances 0.000 claims abstract description 138
- 235000003717 Boswellia sacra Nutrition 0.000 claims abstract description 133
- 235000012035 Boswellia serrata Nutrition 0.000 claims abstract description 133
- 241000717739 Boswellia sacra Species 0.000 claims abstract description 115
- 239000003094 microcapsule Substances 0.000 claims abstract description 104
- 239000007788 liquid Substances 0.000 claims abstract description 72
- 238000012545 processing Methods 0.000 claims abstract description 28
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 238000007710 freezing Methods 0.000 claims abstract description 16
- 230000008014 freezing Effects 0.000 claims abstract description 16
- 238000012805 post-processing Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 30
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000004094 surface-active agent Substances 0.000 claims description 21
- 239000004113 Sepiolite Substances 0.000 claims description 20
- 229910052624 sepiolite Inorganic materials 0.000 claims description 20
- 235000019355 sepiolite Nutrition 0.000 claims description 20
- 239000003595 mist Substances 0.000 claims description 19
- 239000004902 Softening Agent Substances 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 15
- 238000009987 spinning Methods 0.000 claims description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 239000000306 component Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 239000011265 semifinished product Substances 0.000 claims description 10
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- 235000010413 sodium alginate Nutrition 0.000 claims description 9
- 239000000661 sodium alginate Substances 0.000 claims description 9
- 229940005550 sodium alginate Drugs 0.000 claims description 9
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- 241000238631 Hexapoda Species 0.000 claims description 6
- 235000013871 bee wax Nutrition 0.000 claims description 6
- 239000012166 beeswax Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 6
- 239000001993 wax Substances 0.000 claims description 6
- 229920002972 Acrylic fiber Polymers 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 239000008358 core component Substances 0.000 claims description 5
- 238000010001 crabbing Methods 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 238000002386 leaching Methods 0.000 claims description 5
- -1 poly ammonia Ester Chemical class 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000005576 amination reaction Methods 0.000 claims description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 230000010148 water-pollination Effects 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 229920005749 polyurethane resin Polymers 0.000 abstract description 3
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 239000011162 core material Substances 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000341 volatile oil Substances 0.000 description 9
- 239000011347 resin Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000002131 composite material Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000007921 spray Substances 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- 244000251953 Agaricus brunnescens Species 0.000 description 3
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 3
- 206010011732 Cyst Diseases 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
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- 238000000498 ball milling Methods 0.000 description 2
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- 238000005253 cladding Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 239000004530 micro-emulsion Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920001206 natural gum Polymers 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
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- 238000010438 heat treatment Methods 0.000 description 1
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- 238000010409 ironing Methods 0.000 description 1
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
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- 238000010792 warming Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function, including the step such as fabric preparation, post processing, freezing processing, frankincense microcapsules anti-crease finishing.The present invention is by the advance carry out freezing processing of wool fabric, frankincense microcapsules anti-crease finishing liquid padding finishing is carried out again, wool fabric internal fiber internal voids increase after chilled processing, anti-crease finishing liquid is deeply soaked to fibrous inside space, Adhesion enhancement between polyurethane resin and wool fabric, frankincense is arranged into wool fabric by the form of microcapsules, utilize the characteristic that the crisp high temperature of frankincense low temperature is soft and chance is water-swellable, the slow-release time of frankincense microcapsules can be extended, assign wool fabric lasting fragrant atmosphere and healthcare function.
Description
Technical field
The present invention relates to fabric technical field, and in particular to a kind of system of the fragrant atmosphere light and thin wool cloth with healthcare function
Preparation Method.
Background technology
With deepening continuously for current functions of textile fabrics, various multifunctional fabrics arise at the historic moment.Perfume (or spice) of the prior art
Atmosphere fabric is mainly based upon microcapsules technology, by the way that champignon essence oil is coated in microcapsules, friction when wearing between fabric
Or the friction between fabric and human body skin makes microcapsules rupture, the effect of sustained release is reached, there is fabric relatively more lasting
Fragrant atmosphere releasing effect.Meanwhile, the champignon essence oil of above-mentioned fragrant atmosphere fabric is absorbed by human body respiration, can reach certain medicinal work(
Energy.Disclosed in 201110401213.1 and a kind of frankincense microcapsules are arranged to yam surface and the technical side of fabric is woven into
Case.But, above-mentioned essential oil microcapsules arrange gained fabric and there is following technological deficiency：Essential oil is mostly nonpolar molecule, it is impossible to
The vapor distributed with human sweat or skin is dissolved each other, and the essential oil on fabric can also be distinguished except sticking to skin surface
The loss into skin and air, the essential oil uptake of skin is smaller；The clothes that fabric is made need to be cleaned and pressed, cleaning
The high temperature of operation and clothes ironing is the main path for destroying microcapsules in fabric, can destroy the slow release effect of microcapsules.In addition,
Wool fiber diameter is smaller under normal temperature state, and dressing liquid can not deeply diffuse to cell interior, and padding finishing effect is not good, feel
It is poor.
The content of the invention
It is an object of the invention to overcome defect present in prior art, there is provided a kind of fragrant atmosphere with healthcare function is light
Containing the olibanum resin for having medical value and fragrance concurrently in the preparation method of thin wool fabric, gained wool fabric, have fabric
There are permanent fragrant and healthcare function.
To realize above-mentioned technique effect, the technical scheme is that：A kind of frivolous wool of fragrant atmosphere with healthcare function
The preparation method of fabric, it is characterised in that comprise the following steps：
S1：Two kinds of fibers are spun into fibre by configuration Merino wool and the ultra-fine special-shaped acrylic fibers of dralon by weight proportion
Spend for the high branch spinning of 520 ~ 580 public branch, progress warping processing of then being spinned to high branch regard the high branch spinning after warping as warp
Yarn and weft yarn knit to obtain wool fabric；
S2：Post processing, by cloth obtained by S1 through running boiling, move back dimension, crabbing, singe, braying, cropping processing, obtain wool
Fabric semi-finished product；
S3：Freezing processing, 20 ~ 30min is stood at a temperature of wool fabric semi-finished product obtained by S2 are placed in into -5 ~ 0 DEG C；
S4：Frankincense microcapsules anti-crease finishing, is immersed in frankincense microcapsules by the wool fabric after freezing processing obtained by S3 and resists
Wrinkle in dressing liquid, two leachings two are rolled, and through preliminary drying, are baked, then are dried through washing, be made the fragrant atmosphere light and thin wool cloth of healthcare function into
Product；
Wherein, meter frankincense microcapsules anti-crease finishing liquid by weight includes：5 ~ 13 parts of soluble polyurethane, softening agent
0.5 ~ 5 part, 0.01 ~ 1 part of surfactant, 4 ~ 8 parts of frankincense microcapsules, water 70 by main core component of nanoscale frankincense powder
Part and citric acid, the pH value of frankincense microcapsules anti-crease finishing liquid is 3 ~ 4.
Undergone phase transition by carrying out the moisture that fibrous inside is adsorbed in freezing processing, wool microstructure to wool fabric,
It is solid water i.e. by liquid water transitions, and increases with volume increase, wool fiber diameter increase, and internal voids, makes whole
Reason liquid energy is deeply impregnated into wool internal voids, can increase the contact area between polyurethane resin and wool fiber, is improved
Adhesion between the two, improves the feel and wearability of wool fabric.
Frankincense powder is that olibanum resin is the resin that plant bark oozes out, and is obtained by olibanum resin is crushed under low-temperature condition
Champignon raw material, frankincense resinous 60% ~ 70%, natural gum 27% ~ 35%, volatile oil 3% ~ 8% with blood-activating and qi-promoting, stimulates the menstrual flow only
Bitterly, effect of detumescence and promoting granulation, matter is crisp but heats after-tack, and water absorbent surface, which is swelled, after chance water becomes milky, with viscosity.Frankincense
Frankincense after the surface of wool fabric, microcapsules rupture is sticked to as the microcapsules of capsule-core can be dissolved in sweat or skin surface steaming
The vapor sent, because the viscosity of the aqueous solution can ensure that the overwhelming majority in swollen part sticks to skin surface, Huo Zheqian
In the scale for entering wool fiber, this point is different from frankincense essential oil microcapsules of the prior art, the rupture of frankincense essential oil microcapsules
Essential oil molecule is few to the loss amount of skin surface afterwards, i.e., the amount being finally absorbed by the skin is few.Stick to the frankincense of skin surface
Middle volatile oil is absorbed by the body by Cutaneous permeation or respiratory system suction, and resin helps to change in the scale of embedded wool fiber
The feel and wearability of wool fabric under kind dry environment.
The quality of olibanum resin is harder under normal temperature state, and its quality softens under high temperature, therefore occurs under normal temperature state micro-
After capsule-wall rupture, remaining cyst wall is also attached to capsule-core surface, and vapor is slowly swelled exposed capsule-core until capsule-core is consumed
Finish；Microcapsules can occur appropriate deformation and bear pressure to buffer it during fabric hot iron, it is ensured that hot iron is to microcapsules
Destruction, extend fabric fragrant atmosphere slow-release time.In addition, frankincense microcapsules experience capsule-core form solid-state after baked cooling-
The change of liquid-solid, in constitutionally stable spherical or spherical, compared with the microcapsules of liquid essence capsule-core, is not easily broken.
It is preferred that technical scheme be that frankincense microcapsules are double-deck wall material microcapsules, the inner side wall material contacted with capsule-core is main
Component is insect wax and/or beeswax, is that sodium alginate and/or shell are poly- positioned at the outside wall material key component of frankincense microcapsule exterior surface
Sugar.Esterification and crosslinking effect occurs for the masticinic acid in the fatty alcohol and frankincense that dissociate in inner side wall material insect wax and beeswax, to capsule-core material
Material is effectively coated, so as to form hydrophobic microcapsules, the effect of outer layer wall material is the condition of material heating flatiron over there
Under, it is ensured that cyst wall does not melt.
In order to ensure fluffy degree, penetrability, warmth retention property and the wearability of fabric, technical scheme preferably is, obtained by S1
The weight accounting of Merino wool is 50 ~ 70% in wool fabric.
It is preferred that technical scheme be, frankincense microcapsules anti-crease finishing liquid also include 0.05 ~ 5 part of frankincense micro mist, the frankincense
The average grain diameter of micro mist is no more than 100 μm.Frankincense micro mist, collated rear frankincense are added in frankincense microcapsules anti-crease finishing liquid
In resin and natural gum by dispersion mixing in polyurethane, can assign fabric denseer initial fragrant atmosphere and healthcare function, frankincense
The excessive quick dissolving for being unfavorable for it in aqueous of the average grain diameter of micro mist.
It is preferred that technical scheme be that the compound method of frankincense microcapsules anti-crease finishing liquid is：Frankincense micro mist is added into part
In water, high speed shear is disperseed, and is heated to 90 ~ 95 DEG C of 2 ~ 5min of insulation, is continued high speed shear and is disperseed to be cooled to room temperature, obtains crease-resistant
Dressing liquid A mixed liquors；Soluble polyurethane, softening agent, surfactant, the frankincense microcapsules by capsule-core of frankincense are added successively
It is added in remaining water, stirs and evenly mixs, obtain anti-crease finishing liquid B mixed liquors, by anti-crease finishing liquid A mixed liquors and anti-crease finishing liquid
B mixed liquors are mixed evenly, and are configured to frankincense microcapsules anti-crease finishing liquid.Above-mentioned compound method can make frankincense component evenly
Be scattered in dressing liquid, form homogeneous dispersion liquid.
It is preferred that technical scheme be, in S4 the temperature of frankincense microcapsules anti-crease finishing liquid be 5 ~ 10 DEG C, dip time be 4 ~
10min, bath raio is 1：（15~25）.Relatively low anti-crease finishing liquid pad temperature can maintain wool fiber after freezing processing compared with
Large inner space, it is ensured that dressing liquid rises up into infiltration.
Higher baking temperature can cause the cyst wall of microcapsules to melt, and sodium alginate and chitosan all have higher melt
Point, and the insect wax and beeswax thawing as inner side wall material can then form more effective cladding to the frankincense in it, contribute to enhancing
The bulk strength of microcapsules, technical scheme preferably is that preliminary drying temperature is 50 ~ 60 DEG C in S4, and preliminary drying time is 2 ~ 5min；Bake
Temperature is 95 ~ 115 DEG C, described to bake the time for 5 ~ 13min.
It is preferred that technical scheme be that the capsule-cores of frankincense microcapsules also includes nanoscale in nanoscale sepiolite powder, capsule-core
The weight ratio of sepiolite powder and frankincense is 1：（2~3）.Nanoscale sepiolite powder can adsorb the peculiar smell of wearer's body surface, protect
The fragrance that card frankincense is given out is more complete.
It is preferred that technical scheme be, softening agent be selected from amination polysiloxanes and quaternary ammonium cation containing polyether group
At least one of polyurethane-base polyether block Hydrophilic Silicone Micro Emulsion.The introducing of polyether group makes amino in molecular structure
Poly-organosilicon softening agent possesses hydrophily and reduces xanthochromia, and the intermolecular steric hindrance of softening agent is especially small, molecule master
Chain is submissive, can assign wool fabric unique " soft glutinous " soft style, can improve relatively skilled hand of the wool fabric because adhering to microcapsules
Feel and do not influence the hydrophily of wool fabric.
It is preferred that technical scheme be, surfactant be by rigid attachment group-CH2- double quaternary ammonium salt type the Shuangzi being coupled
Surfactant.Double quaternary ammonium salt type Gemini surface active agent CMC value is higher, it is possible to decrease the surface tension of dressing liquid, reaches
Deeper into the purpose of infiltration.
The advantages of the present invention are：
The present invention by the advance carry out freezing processing of wool fabric, then carry out frankincense microcapsules anti-crease finishing liquid pad it is whole
Reason, the wool fabric internal fiber internal voids increase after chilled processing, anti-crease finishing liquid deeply soaks empty to fibrous inside
Gap, Adhesion enhancement between polyurethane resin and wool fabric, frankincense is arranged into wool fabric by the form of microcapsules, profit
With the characteristic that the crisp high temperature of frankincense low temperature is soft and chance is water-swellable, extend the slow-release time of frankincense microcapsules, assign wool fabric and hold
Long fragrant atmosphere and healthcare function.
Embodiment
With reference to embodiment, the embodiment to the present invention is further described.Following examples are only used for more
Plus technical scheme is clearly demonstrated, and can not be limited the scope of the invention with this.
Embodiment 1
A kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function comprises the following steps：
S1：Two kinds of fibers are spun into fibre by configuration Merino wool and the ultra-fine special-shaped acrylic fibers of dralon by weight proportion
Spend for the high branch spinning of 520 public branch, warping processing then carried out to the spinning of high branch, using the high branch spinning after warping as warp thread and
Weft yarn knits to obtain wool fabric；
S2：Post processing, by cloth obtained by S1 through running boiling, move back dimension, crabbing, singe, braying, cropping processing, obtain wool
Fabric semi-finished product；
S3：Freezing processing, 20min is stood at a temperature of wool fabric semi-finished product obtained by S2 are placed in into -2 ~ 0 DEG C；
S4：Frankincense microcapsules anti-crease finishing, is immersed in frankincense microcapsules by the wool fabric after freezing processing obtained by S3 and resists
Wrinkle in dressing liquid, two leachings two are rolled, and through preliminary drying, are baked, then are dried through washing, be made the fragrant atmosphere light and thin wool cloth of healthcare function into
Product；
Wherein, meter frankincense microcapsules anti-crease finishing liquid by weight includes：13 parts of soluble polyurethane, softening agent 0.5
Part, 1 part of surfactant, 70 parts of 4 parts of frankincense microcapsules, water and citric acid by main core component of nanoscale frankincense powder,
The pH value of frankincense microcapsules anti-crease finishing liquid is 4.
Frankincense microcapsules are double-deck wall material microcapsules, and the inner side wall material key component contacted with capsule-core is insect wax, positioned at breast
The outside wall material key component of fragrant microcapsule exterior surface is sodium alginate.
The weight accounting of Merino wool is 50% in wool fabric obtained by S1.
Frankincense microcapsules anti-crease finishing liquid also includes 5 parts of frankincense micro mist, and the average grain diameter of frankincense micro mist is 50 μm.
The compound method of frankincense microcapsules anti-crease finishing liquid is：Frankincense micro mist is added in the water of part, high speed shear is disperseed,
95 DEG C of insulation 2min are heated to, continues high speed shear and disperses to be cooled to room temperature, obtain anti-crease finishing liquid A mixed liquors；By water solubility
Polyurethane, softening agent, surfactant, the frankincense microcapsules by capsule-core of frankincense are added in remaining water successively, and stirring is mixed
It is even, anti-crease finishing liquid B mixed liquors are obtained, anti-crease finishing liquid A mixed liquors are mixed evenly with anti-crease finishing liquid B mixed liquors,
It is configured to frankincense microcapsules anti-crease finishing liquid.
The temperature of frankincense microcapsules anti-crease finishing liquid is 10 DEG C in S4, and dip time is 4min, and bath raio is 1：25.
Preliminary drying temperature is 50 DEG C in S4, and preliminary drying time is 5min；Baking temperature is 95 DEG C, bakes the time for 13min.
The capsule-core of frankincense microcapsules also includes nanoscale sepiolite powder, nanoscale sepiolite powder and frankincense in capsule-core
Weight ratio is 1：2.
Softening agent is the amination polysiloxanes containing polyether group.
Surfactant is by rigid attachment group-CH2- double quaternary ammonium salt type the Gemini surface active agent being coupled.
Embodiment 2
A kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function comprises the following steps：
S1：Two kinds of fibers are spun into fibre by configuration Merino wool and the ultra-fine special-shaped acrylic fibers of dralon by weight proportion
Spend for the high branch spinning of 550 public branch, warping processing then carried out to the spinning of high branch, using the high branch spinning after warping as warp thread and
Weft yarn knits to obtain wool fabric；
S2：Post processing, by cloth obtained by S1 through running boiling, move back dimension, crabbing, singe, braying, cropping processing, obtain wool
Fabric semi-finished product；
S3：Freezing processing, 25min is stood at a temperature of wool fabric semi-finished product obtained by S2 are placed in into -4 ~ -2 DEG C；
S4：Frankincense microcapsules anti-crease finishing, is immersed in frankincense microcapsules by the wool fabric after freezing processing obtained by S3 and resists
Wrinkle in dressing liquid, two leachings two are rolled, and through preliminary drying, are baked, then are dried through washing, be made the fragrant atmosphere light and thin wool cloth of healthcare function into
Product；
Wherein, meter frankincense microcapsules anti-crease finishing liquid by weight includes：9 parts of soluble polyurethane, softening agent 2.5
Part, 0.5 part of surfactant, 70 parts of 6 parts of frankincense microcapsules, water by main core component of nanoscale frankincense powder and lemon
Acid, the pH value of frankincense microcapsules anti-crease finishing liquid is 3.5.
Frankincense microcapsules are double-deck wall material microcapsules, and the inner side wall material key component contacted with capsule-core is beeswax, positioned at breast
The outside wall material key component of fragrant microcapsule exterior surface is chitosan.
The weight accounting of Merino wool is 60% in wool fabric obtained by S1.
Frankincense microcapsules anti-crease finishing liquid also includes 2.5 parts of frankincense micro mist, the average grain diameter of frankincense micro mist for no more than 65 ~
95μm。
The compound method of frankincense microcapsules anti-crease finishing liquid is：Frankincense micro mist is added in the water of part, high speed shear is disperseed,
92 DEG C of insulation 3.5min are heated to, continues high speed shear and disperses to be cooled to room temperature, obtain anti-crease finishing liquid A mixed liquors；Will be water-soluble
Property polyurethane, softening agent, surfactant, the frankincense microcapsules by capsule-core of frankincense be added to successively in remaining water, stir
Mix, obtain anti-crease finishing liquid B mixed liquors, anti-crease finishing liquid A mixed liquors and anti-crease finishing liquid B mixed liquors are mixed equal
It is even, it is configured to frankincense microcapsules anti-crease finishing liquid.
The temperature of frankincense microcapsules anti-crease finishing liquid is 7.5 DEG C in S4, and dip time is 7min, and bath raio is 1：20.
Preliminary drying temperature is 55 DEG C in S4, and preliminary drying time is 3.5min；Baking temperature is 105 DEG C, bakes the time for 9min.
The capsule-core of frankincense microcapsules also includes nanoscale sepiolite powder, nanoscale sepiolite powder and frankincense in capsule-core
Weight ratio is 2：5.
Softening agent is quaternary ammonium cation polyurethane-base polyether block Hydrophilic Silicone Micro Emulsion.
Surfactant is by rigid attachment group-CH2- double quaternary ammonium salt type the Gemini surface active agent being coupled.
Embodiment 3
A kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function comprises the following steps：
S1：Two kinds of fibers are spun into fibre by configuration Merino wool and the ultra-fine special-shaped acrylic fibers of dralon by weight proportion
Spend for the high branch spinning of 580 public branch, warping processing then carried out to the spinning of high branch, using the high branch spinning after warping as warp thread and
Weft yarn knits to obtain wool fabric；
S2：Post processing, by cloth obtained by S1 through running boiling, move back dimension, crabbing, singe, braying, cropping processing, obtain wool
Fabric semi-finished product；
S3：Freezing processing, 30min is stood at a temperature of wool fabric semi-finished product obtained by S2 are placed in into -5 ~ -4 DEG C；
S4：Frankincense microcapsules anti-crease finishing, is immersed in frankincense microcapsules by the wool fabric after freezing processing obtained by S3 and resists
Wrinkle in dressing liquid, two leachings two are rolled, and through preliminary drying, are baked, then are dried through washing, be made the fragrant atmosphere light and thin wool cloth of healthcare function into
Product；
Wherein, meter frankincense microcapsules anti-crease finishing liquid by weight includes：5 parts of soluble polyurethane, 5 parts of softening agent,
0.01 part of surfactant, 70 parts of 8 parts of frankincense microcapsules, water and citric acid by main core component of nanoscale frankincense powder,
The pH value of frankincense microcapsules anti-crease finishing liquid is 3.
Frankincense microcapsules are double-deck wall material microcapsules, and inner side wall material key component contact with capsule-core is insect wax and beeswax,
It is sodium alginate and chitosan positioned at the outside wall material key component of frankincense microcapsule exterior surface.
The weight accounting of Merino wool is 70% in wool fabric obtained by S1.
Frankincense microcapsules anti-crease finishing liquid also includes 0.05 part of frankincense micro mist, and the average grain diameter of frankincense micro mist is 40 ~ 60 μm.
The compound method of frankincense microcapsules anti-crease finishing liquid is：Frankincense micro mist is added in the water of part, high speed shear is disperseed,
95 DEG C of insulation 2min are heated to, continues high speed shear and disperses to be cooled to room temperature, obtain anti-crease finishing liquid A mixed liquors；By water solubility
Polyurethane, softening agent, surfactant, the frankincense microcapsules by capsule-core of frankincense are added in remaining water successively, and stirring is mixed
It is even, anti-crease finishing liquid B mixed liquors are obtained, anti-crease finishing liquid A mixed liquors are mixed evenly with anti-crease finishing liquid B mixed liquors,
It is configured to frankincense microcapsules anti-crease finishing liquid.
The temperature of frankincense microcapsules anti-crease finishing liquid is 10 DEG C in S4, and dip time is 4min, and bath raio is 1：15.
Preliminary drying temperature is 60 DEG C in S4, and preliminary drying time is 2min；Baking temperature is 115 DEG C, bakes the time for 5min.
The capsule-core of frankincense microcapsules also includes nanoscale sepiolite powder, nanoscale sepiolite powder and frankincense in capsule-core
Weight ratio is 1：3.
Softening agent is hydrophilic for amination polysiloxanes and quaternary ammonium cation polyurethane-base polyether block containing polyether group
Property silicone softening agent weight compares 1:1 mixture.
Surfactant is by rigid attachment group-CH2- double quaternary ammonium salt type the Gemini surface active agent being coupled.
Comparative example 1
Sample in comparative example 1 is without freezing processing, remaining process conditions be the same as Example 2.
Comparative example 2
Frankincense microcapsules are single layer structure in frankincense microcapsules anti-crease finishing liquid in comparative example 2, i.e., not comprising positioned at breast
The outside wall material of fragrant microcapsule exterior surface, remaining process conditions be the same as Example 2.
Comparative example 3
Frankincense micro mist is free of in frankincense microcapsules anti-crease finishing liquid in comparative example 3.
Fragrant atmosphere is contrasted through artificial sense, and the sample initial flavor of comparative example 3 is far below embodiment 2；
The weighed contrast of sample, after the sample of identical weight is dried through frankincense microcapsules anti-crease finishing liquid, the weight of comparative example 1
Amount increase is slightly less than embodiment 2；
Sample is placed under high-power microscope and observed through 20 normal temperature cleanings and 10 120 ~ 130 DEG C of flatirons by sample, identical
The microcapsules number of embodiment 2 is 30 ~ 40% more than the sample of comparative example 2 under area.
The preparation method of microcapsules comprises the following steps in embodiment 1-3：
1st, frankincense sepiolite composite micro-powder is prepared：By weight fraction olibanum resin, 1 part is placed in 10 parts of water, it is warming up to 90 ~
95 DEG C, water mixed solution carries out 20 ~ 40min of high speed shear, and standing is cooled to room temperature, the frankincense aqueous solution is obtained, according to frankincense with receiving
Meter level sepiolite powder adds the frankincense aqueous solution and nanoscale sepiolite powder in ball mill, 1 ~ 4h of ball milling, temperature in ball mill
Degree is maintained at 5 ~ 10 DEG C, and mixed liquor obtained by ball milling is freeze-dried, obtains frankincense sepiolite composite micro-powder；
2nd, inner side wall material is coated on by frankincense sepiolite composite micro-powder outer surface using air suspension spraying process.
The concrete operations of inner side wall material cladding frankincense sepiolite composite micro-powder are：Inner side wall material is dissolved in solvent and formed
Inner side wall material solution（Percentage by weight is 20 ~ 25%）, frankincense sepiolite composite micro-powder is suspended in atmosphere with fluid bed, used
Spray gun is sprayed onto capsule-core surface under 3-5atm pressure, and solvent volatilization, wall material is attached to particle surface.Above-mentioned multiple spray can be carried out
Mist is coated, to reach predetermined wall material thickness.
3rd, outside wall material is coated on by frankincense sepiolite composite micro-powder outer surface using spray condensation method successively.
Percentage by weight is after 2 ~ 3% sodium alginate wall material solutions are uniformly mixed with frankincense sepiolite composite micro-powder, to pass through spray
Sprayed into after rose atomization in the calcium chloride solution of percentage by weight 2~3%, calcium ion reacts to form micro- with sodium alginate cross-linking
Capsule.
Although sodium alginate and chitosan can form the wall material with certain elasticity, comparatively speaking, sodium alginate tool
There is higher fusing point, the hot iron operation of fabric can be tackled.
The fabric is applied to make autumn and winter shirt fabric, wears next to the skin the active principles such as masticinic acid under state in frankincense
Can preferably it be absorbed by human body.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (9)
1. a kind of preparation method of the fragrant atmosphere light and thin wool cloth with healthcare function, it is characterised in that comprise the following steps：
S1：Merino wool and the ultra-fine special-shaped acrylic fibers of dralon are configured by weight proportion, and two kinds of fibers are spun into fiber number is
The high branch spinning of 520 ~ 580 public branch, then carries out warping processing to the spinning of high branch, using the high branch spinning after warping as warp thread and
Weft yarn knits to obtain wool fabric；
S2：Post processing, by cloth obtained by S1 through running boiling, move back dimension, crabbing, singe, braying, cropping processing, obtain wool fabric
Semi-finished product；
S3：Freezing processing, 20 ~ 30min is stood at a temperature of wool fabric semi-finished product obtained by S2 are placed in into -5 ~ 0 DEG C；
S4：Frankincense microcapsules anti-crease finishing, is immersed in frankincense microcapsules crease-resistant whole by the wool fabric after freezing processing obtained by S3
Manage in liquid, two leachings two are rolled, and through preliminary drying, are baked, then are dried through washing, and the fragrant atmosphere light and thin wool cloth finished product of healthcare function is made；
Wherein, meter frankincense microcapsules anti-crease finishing liquid by weight includes：5 ~ 13 parts of soluble polyurethane, softening agent 0.5 ~ 5
Part, 0.01 ~ 1 part of surfactant, 70 parts of 4 ~ 8 parts of frankincense microcapsules, water by main core component of nanoscale frankincense powder and
Citric acid, the pH value of frankincense microcapsules anti-crease finishing liquid is 3 ~ 4；
Frankincense microcapsules are double-deck wall material microcapsules, and the inner side wall material key component contacted with capsule-core is insect wax and/or beeswax, position
In frankincense microcapsule exterior surface outside wall material key component be sodium alginate and/or chitosan.
2. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 1 with healthcare function, it is characterised in that
The weight accounting of Merino wool is 50 ~ 70% in wool fabric obtained by S1.
3. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 1 with healthcare function, it is characterised in that
Frankincense microcapsules anti-crease finishing liquid also includes 0.05 ~ 5 part of frankincense micro mist, and the average grain diameter of the frankincense micro mist is no more than 100 μ
m。
4. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 3 with healthcare function, it is characterised in that
The compound method of frankincense microcapsules anti-crease finishing liquid is：Frankincense micro mist is added in the water of part, high speed shear is disperseed, and is heated to 90
~ 95 DEG C of 2 ~ 5min of insulation, continue high speed shear and disperse to be cooled to room temperature, obtain anti-crease finishing liquid A mixed liquors；By water-soluble poly ammonia
Ester, softening agent, surfactant, the frankincense microcapsules by capsule-core of frankincense are added in remaining water successively, stir and evenly mix, obtain
To anti-crease finishing liquid B mixed liquors, anti-crease finishing liquid A mixed liquors are mixed evenly with anti-crease finishing liquid B mixed liquors, are configured to
Frankincense microcapsules anti-crease finishing liquid.
5. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 1 with healthcare function, it is characterised in that
The temperature of frankincense microcapsules anti-crease finishing liquid is 5 ~ 10 DEG C in S4, and dip time is 4 ~ 10min, and bath raio is 1：（15~25）.
6. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 1 with healthcare function, it is characterised in that
Preliminary drying temperature is 50 ~ 60 DEG C in S4, and preliminary drying time is 2 ~ 5min；Baking temperature is 95 ~ 115 DEG C, it is described bake the time for 5 ~
13min。
7. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 4 with healthcare function, it is characterised in that
The capsule-core of frankincense microcapsules also includes nanoscale sepiolite powder, and the weight ratio of nanoscale sepiolite powder and frankincense is in capsule-core
1：（2~3）.
8. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 4 with healthcare function, it is characterised in that
Softening agent is to have selected from the amination polysiloxanes containing polyether group and quaternary ammonium cation polyurethane-base polyether block hydrophily
At least one of machine silicone softener.
9. the preparation method of the fragrant atmosphere light and thin wool cloth according to claim 8 with healthcare function, it is characterised in that
Surfactant is by rigid attachment group-CH2- double quaternary ammonium salt type the Gemini surface active agent being coupled.
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| CN108859342A (en) * | 2018-08-30 | 2018-11-23 | 相里海霞 | Functional sportswear fabric |
| CN110230140B (en) * | 2019-06-25 | 2022-10-04 | 芜湖昊顺服饰有限公司 | Pressing method of textile fibers |
| CN110496694B (en) * | 2019-08-30 | 2021-07-09 | 大连工业大学 | A kind of waste wool fiber powder and its preparation method and application |
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| CN110820333B (en) * | 2019-11-19 | 2022-01-04 | 河南民兴生物科技股份有限公司 | Preparation method for improving tussah silk fiber strength |
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| CN111893771B (en) * | 2020-07-30 | 2024-03-08 | 江苏阳光股份有限公司 | Anti-felting finishing method for wool fabric |
| CN112813680A (en) * | 2021-02-03 | 2021-05-18 | 百事基材料（青岛）股份有限公司 | Wool and cashmere large biological fiber containing active components of tangerine peel, orange and pomelo and preparation method thereof |
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