CN116180297A - Preparation process and application of antibacterial flame-retardant high-strength composite carpet base cloth - Google Patents

Preparation process and application of antibacterial flame-retardant high-strength composite carpet base cloth Download PDF

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CN116180297A
CN116180297A CN202211675244.0A CN202211675244A CN116180297A CN 116180297 A CN116180297 A CN 116180297A CN 202211675244 A CN202211675244 A CN 202211675244A CN 116180297 A CN116180297 A CN 116180297A
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flame
bio
retardant
carpet base
spinning
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CN116180297B (en
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徐志强
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Suzhou Swan Lake Felt Co ltd
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Suzhou Swan Lake Felt Co ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G27/00Floor fabrics; Fastenings therefor
    • A47G27/02Carpets; Stair runners; Bedside rugs; Foot mats
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G27/00Floor fabrics; Fastenings therefor
    • A47G27/02Carpets; Stair runners; Bedside rugs; Foot mats
    • A47G27/0243Features of decorative rugs or carpets
    • A47G27/0281Resisting skidding or creeping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/02Layer formed of wires, e.g. mesh
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • B32B3/085Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts spaced apart pieces on the surface of a layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
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    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
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    • D01D10/02Heat treatment
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    • D01D5/08Melt spinning methods
    • D01D5/084Heating filaments, threads or the like, leaving the spinnerettes
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    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes
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    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
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    • D01D5/12Stretch-spinning methods
    • DTEXTILES; PAPER
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    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • DTEXTILES; PAPER
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    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
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    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/002With diagonal warps or wefts
    • DTEXTILES; PAPER
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    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
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    • D03D13/008Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
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    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
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    • D03D15/242Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
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    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
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    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
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    • D03D15/573Tensile strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

本发明属于复合地毯基布制备领域,具体公开了一种抗菌阻燃高强度复合地毯基布的制备工艺和应用,所述地毯基布(100)由阻燃聚酯纤维和生物基纤维以及金属丝交织而成;所述阻燃聚酯纤维经线构成经线(110),所述金属丝构成纬线(120),所述生物基纤维构成斜线(130);所述生物基纤维由以下步骤制备而成:在纺丝过程中,将生物基纤维冷却至微熔融状态,随后在上述生物基纤维表面均匀喷淋数层纳米银离子,黏附于生物基纤维表面,随后冷却至常温,获得所述生物基纤维;按质量份数计算,所述生物基纤维含有100份的PLA、15‑20份的聚羟基烷酸酯、5‑10份的木质素;所述纳米银离子5‑15份;本发明所述的地毯基布强度高,抗菌阻燃效果好,绿色环保。

Figure 202211675244

The invention belongs to the field of composite carpet base fabric preparation, and specifically discloses a preparation process and application of an antibacterial and flame-retardant high-strength composite carpet base fabric. The carpet base fabric (100) is made of flame-retardant polyester fiber, bio-based fiber and metal The warps of the flame-retardant polyester fibers constitute the warps (110), the metal wires constitute the wefts (120), and the bio-based fibers constitute oblique threads (130); the bio-based fibers are prepared by the following steps Formation: During the spinning process, the bio-based fiber is cooled to a slightly molten state, and then several layers of nano-silver ions are evenly sprayed on the surface of the bio-based fiber to adhere to the surface of the bio-based fiber, and then cooled to room temperature to obtain the described Bio-based fiber; calculated in parts by mass, the bio-based fiber contains 100 parts of PLA, 15-20 parts of polyhydroxyalkanoate, 5-10 parts of lignin; 5-15 parts of the nano-silver ion; The carpet base cloth of the invention has high strength, good antibacterial and flame retardant effect, and is environmentally friendly.

Figure 202211675244

Description

一种抗菌阻燃高强度复合地毯基布的制备工艺和应用Preparation process and application of an antibacterial and flame-retardant high-strength composite carpet base fabric

技术领域technical field

本发明属于复合地毯基布制备领域,具体公开了一种抗菌阻燃高强度复合地毯基布的制备工艺和应用。The invention belongs to the field of composite carpet base cloth preparation, and specifically discloses a preparation process and application of an antibacterial, flame-retardant, high-strength composite carpet base cloth.

背景技术Background technique

地毯,是以棉、麻、毛、丝、草纱线等天然纤维或化学合成纤维类原料,经手工或机械工艺进行编结、栽绒或纺织而成的地面铺敷物。它是世界范围内具有悠久历史传统的工艺美术品类之一。覆盖于住宅、宾馆、酒店、会议室、娱乐场所、体育馆、展览厅、车辆、船舶、飞机等的地面,有减少噪声、隔热和装饰效果改善脚感、防止滑倒、防止空气污染。住宅内部使用区域为厨房、卧室、床边、茶几沙发、卫生间、客厅。常见的地毯绒纱用纤维原料分为天然纤维、化学纤维及混纺三种。其中天然纤维有羊毛、真丝、棉和黄麻等;化学纤维有黏胶短纤、尼龙B CF长丝及短纤、腈纶短纤、丙纶B CF长丝及短纤和涤纶短纤;混纺有羊毛/尼龙、羊毛/黏胶、羊毛/腈纶、羊毛/涤纶和羊毛/黄麻等。化纤(合成纤维)地毯采用尼龙纤维(锦纶)、聚丙烯纤维(丙纶)、聚丙烯腈纤维(腈纶)、聚酯纤维(涤纶)、定型丝、PTT等化学纤维为主要原料制做。它的最大特点是耐磨性强,同时克服了纯毛地毯易腐蚀、易霉变的缺点;,但阻燃性、抗静电性相对又要差一些。Carpet is a floor covering made of cotton, linen, wool, silk, grass yarn and other natural fibers or chemical synthetic fiber materials, which are braided, tufted or woven by hand or mechanically. It is one of the arts and crafts categories with a long history and tradition in the world. Covering the ground of residences, hotels, hotels, conference rooms, entertainment venues, gymnasiums, exhibition halls, vehicles, ships, aircraft, etc., it can reduce noise, heat insulation and decoration effects to improve foot feel, prevent slipping, and prevent air pollution. The internal use area of the house is the kitchen, bedroom, bedside, coffee table sofa, bathroom, and living room. The common fiber raw materials for carpet yarn are divided into three types: natural fiber, chemical fiber and blended. Among them, natural fibers include wool, silk, cotton and jute, etc.; chemical fibers include viscose staple fiber, nylon B CF filament and staple fiber, acrylic staple fiber, polypropylene B CF filament and staple fiber, and polyester staple fiber; /Nylon, Wool/Viscose, Wool/Acrylic, Wool/Polyester and Wool/Jute etc. Chemical fiber (synthetic fiber) carpets are made of chemical fibers such as nylon fiber (nylon), polypropylene fiber (polypropylene fiber), polyacrylonitrile fiber (acrylic fiber), polyester fiber (polyester), stereotyped silk, and PTT. Its biggest feature is its strong wear resistance, and at the same time overcomes the shortcomings of pure wool carpets that are easy to corrode and mildew; however, its flame retardancy and antistatic property are relatively poor.

发明内容Contents of the invention

为了解决上述问题,本发明公开了一种抗菌阻燃高强度复合地毯基布的制备工艺和应用。In order to solve the above problems, the invention discloses a preparation process and application of an antibacterial and flame-retardant high-strength composite carpet base cloth.

本发明的技术方案如下:Technical scheme of the present invention is as follows:

一种抗菌阻燃高强度复合地毯基布,所述地毯基布由阻燃聚酯纤维和生物基纤维以及金属丝交织而成;An antibacterial and flame-retardant high-strength composite carpet base cloth, which is formed by interweaving flame-retardant polyester fibers, bio-based fibers and metal wires;

所述阻燃聚酯纤维经线构成经线,所述金属丝构成纬线,所述生物基纤维构成斜线。本方案中,阻燃聚酯纤维赋予了地毯基布韧性、一定的拉伸性和阻燃性,而金属丝赋予了地毯基布高强度和阻燃性,生物基纤维赋予了地毯基布较好的抗菌性和韧性。综合的使用经纬交叉以及斜线的编制方案,最终制备的地毯基布强度高,阻燃性能好,抗菌性能强,并且绿色环保。The warp threads of the flame-retardant polyester fibers constitute the warp threads, the metal wires constitute the weft threads, and the bio-based fibers constitute the oblique threads. In this scheme, the flame-retardant polyester fiber endows the carpet base fabric with toughness, certain stretchability and flame retardancy, while the metal wire endows the carpet base fabric with high strength and flame retardancy, and the bio-based fiber endows the carpet base fabric with a relatively strong Good antibacterial properties and toughness. By comprehensively using the weaving scheme of warp and weft intersecting and oblique lines, the final prepared carpet base fabric has high strength, good flame retardancy, strong antibacterial performance, and is environmentally friendly.

进一步的,上述一种抗菌阻燃高强度复合地毯基布,所述生物基纤维由以下步骤制备而成:Further, the above-mentioned antibacterial and flame-retardant high-strength composite carpet base fabric, the bio-based fiber is prepared by the following steps:

在纺丝过程中,将生物基纤维冷却至微熔融状态,随后在上述生物基纤维表面均匀喷淋数层纳米银离子,黏附于生物基纤维表面,随后冷却至常温,获得所述生物基纤维;During the spinning process, the bio-based fiber is cooled to a slightly molten state, and then several layers of nano-silver ions are uniformly sprayed on the surface of the bio-based fiber to adhere to the surface of the bio-based fiber, and then cooled to normal temperature to obtain the bio-based fiber ;

按质量份数计算,所述生物基纤维含有100份的PLA、15-20份的聚羟基烷酸酯、5-10份的木质素;所述纳米银离子5-15份。优选的,上述纳米银离子的平均粒径为50nm。Calculated in parts by mass, the bio-based fiber contains 100 parts of PLA, 15-20 parts of polyhydroxyalkanoate, 5-10 parts of lignin; and 5-15 parts of the nano silver ion. Preferably, the average particle size of the above-mentioned nano-silver ions is 50nm.

进一步的,上述一种抗菌阻燃高强度复合地毯基布,所述微熔融状态的温度为155-185℃之间。Further, in the aforementioned antibacterial and flame-retardant high-strength composite carpet base fabric, the temperature in the slightly molten state is between 155-185°C.

进一步的,上述一种抗菌阻燃高强度复合地毯基布,所述地毯基布下表面设有阻燃防滑胶层,所述阻燃防滑胶层的下表面设有若干阻燃防滑胶粒,所述若干阻燃防滑胶粒在阻燃防滑胶层的下表面呈网格阵列状排布。在上述基布的下表面设置阻燃防滑胶层,使之能够更好的贴合地面。Further, the above-mentioned antibacterial, flame-retardant and high-strength composite carpet base cloth, the lower surface of the carpet base cloth is provided with a flame-retardant anti-slip rubber layer, and the lower surface of the flame-retardant anti-slip rubber layer is provided with a number of flame-retardant and anti-slip rubber particles. A plurality of flame-retardant anti-skid rubber particles are arranged in a grid array on the lower surface of the flame-retardant anti-skid rubber layer. A flame-retardant anti-slip rubber layer is arranged on the lower surface of the above-mentioned base cloth, so that it can fit the ground better.

进一步的,上述一种抗菌阻燃高强度复合地毯基布,所述斜线与经线的角度为45度。经过实验,发现45度角结构强度最好。Further, in the above-mentioned antibacterial and flame-retardant high-strength composite carpet base fabric, the angle between the oblique line and the warp line is 45 degrees. After experiments, it was found that the structural strength of the 45-degree angle is the best.

进一步的,上述一种抗菌阻燃高强度复合地毯基布,所述金属丝为镁合金丝。使用镁合金,密度小,强度高,弹性模量大,耐腐蚀性好。Further, in the aforementioned antibacterial and flame-retardant high-strength composite carpet base fabric, the metal wires are magnesium alloy wires. Magnesium alloy is used, which has low density, high strength, large elastic modulus and good corrosion resistance.

进一步的,上述一种抗菌阻燃高强度复合地毯基布,所述经线平均直径为50μm,所述纬线平均直径为30μm,所述斜线平均直径为40μm。Further, in the above-mentioned antibacterial and flame-retardant high-strength composite carpet base fabric, the average diameter of the warp is 50 μm, the average diameter of the weft is 30 μm, and the average diameter of the oblique lines is 40 μm.

进一步的,上述一种抗菌阻燃高强度复合地毯基布的制备方法,包括以下步骤:Further, the preparation method of the above-mentioned antibacterial and flame-retardant high-strength composite carpet base cloth comprises the following steps:

S1将配方量的PLA、聚羟基烷酸酯和木质素共混后加入挤压机系统,加热熔融后挤出纺丝熔融液;S1 Blend the PLA, polyhydroxyalkanoate and lignin in the formula amount and add them to the extruder system, heat and melt and extrude the spinning melt;

S2将纺丝熔融液经过熔体输送管道送入纺丝箱进行纺丝;纺丝箱包含上箱体、下箱体和纺丝组件,纺丝熔融液经过上、下箱体后从纺丝组件的喷丝板喷出丝束;上箱体的纺丝温度控制在195-205℃,下箱体的纺丝温度控制在210~220℃;S2 Send the spinning melt to the spinning box through the melt conveying pipeline for spinning; the spinning box includes an upper box, a lower box and a spinning assembly, and the spinning melt passes through the upper and lower boxes and then from the spinning The spinneret of the component ejects tow; the spinning temperature of the upper box is controlled at 195-205°C, and the spinning temperature of the lower box is controlled at 210-220°C;

S3丝束经过喷丝板下方的缓冷器和单体抽吸部件后,进入控温组合冷却部件,利用环吹的热风和双侧吹的冷风使丝束缓慢冷却至微熔融状态,随后立刻均匀喷淋数层纳米银离子,黏附于生物基纤维表面,得到初生纤维,随后降温至90℃以下;After the S3 tow passes through the slow cooler under the spinneret and the monomer suction part, it enters the temperature-controlled combined cooling part, and the tow is slowly cooled to a slightly molten state by using the hot air blown around the spinneret and the cold air blown from both sides, and then immediately Evenly spray several layers of nano-silver ions, adhere to the surface of bio-based fibers to obtain primary fibers, and then cool down to below 90°C;

S4对初生纤维进行牵伸卷绕,控制牵伸温度为85~95℃,牵伸速度为500~800m/min,最终卷绕后得到生物基纤维;S4 stretches and winds the as-spun fibers, controls the drafting temperature at 85-95°C, and the drafting speed at 500-800m/min, and finally obtains bio-based fibers after winding;

S5将阻燃聚酯纤维经线构成经线,所述金属丝构成纬线,所述生物基纤维构成斜线;其中每cm2基布含有经线30-50根,纬线25-35根,斜线20-40根,所述斜线呈X型对称设置。上述制备方法简单,制备成本低。S5 forms warp threads from flame-retardant polyester fibers, the metal wires form weft threads, and the bio-based fibers form oblique threads; wherein each cm 2 of the base fabric contains 30-50 warp threads, 25-35 weft threads, and 20-20 oblique threads. 40, the slashes are arranged symmetrically in an X shape. The above preparation method is simple and the preparation cost is low.

进一步的,上述一种抗菌阻燃高强度复合地毯基布的制备方法,所述挤压机步骤具体包括以下步骤:Further, the preparation method of the above-mentioned antibacterial and flame-retardant high-strength composite carpet base cloth, the extruder step specifically includes the following steps:

在长径比L/O=24的双螺杆挤出机上挤出,双螺杆挤出机有1D-6D共6个区段和模头区组成;将PLA加到双螺杆挤出机位于1D处的进料口,将聚羟基烷酸酯加入位于双螺护挤出机2D处的注料口,将木质素加到双螺杆挤出机3D处的进料口,最终挤出纺丝熔融液;Extrude on a twin-screw extruder with an aspect ratio of L/O=24. The twin-screw extruder consists of 6 sections from 1D to 6D and a die head area; add PLA to the twin-screw extruder at 1D The feed port of the polyhydroxyalkanoate is added to the feed port at the 2D place of the twin-screw extruder, and the lignin is added to the feed port at the 3D place of the twin-screw extruder, and finally the spinning melt is extruded ;

挤出各区温度如下The extrusion temperature of each zone is as follows

第一区120℃~130℃第二区135℃~145℃The first zone 120℃~130℃ The second zone 135℃~145℃

第三区145℃~155℃第四区155℃~165℃The third zone 145℃~155℃ The fourth zone 155℃~165℃

第五区165℃~175℃第六区175℃~185℃The fifth zone 165℃~175℃ The sixth zone 175℃~185℃

模头区180~195℃。Die zone 180 ~ 195 ℃.

相比现有技术,本发明具有如下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

本方案中,阻燃聚酯纤维赋予了地毯基布韧性、一定的拉伸性和阻燃性,而金属丝赋予了地毯基布高强度和阻燃性,生物基纤维赋予了地毯基布较好的抗菌性、韧性和机械强度。综合的使用经纬交叉以及斜线的编制方案,最终制备的地毯基布强度高,阻燃性能好,抗菌性能强,并且绿色环保。In this scheme, the flame-retardant polyester fiber endows the carpet base fabric with toughness, certain stretchability and flame retardancy, while the metal wire endows the carpet base fabric with high strength and flame retardancy, and the bio-based fiber endows the carpet base fabric with a relatively strong Good antimicrobial properties, toughness and mechanical strength. By comprehensively using the weaving scheme of warp and weft intersecting and oblique lines, the final prepared carpet base fabric has high strength, good flame retardancy, strong antibacterial performance, and is environmentally friendly.

附图说明Description of drawings

图1为本发明中一种抗菌阻燃高强度复合地毯基布的侧方示意图;Fig. 1 is the side schematic diagram of a kind of antibacterial flame-retardant high-strength composite carpet base cloth among the present invention;

图2为本发明中一种抗菌阻燃高强度复合地毯基布的微观结构示意图;Fig. 2 is a microstructure schematic diagram of a kind of antibacterial flame-retardant high-strength composite carpet base cloth in the present invention;

图3为测试例中抑菌率的示意图;Fig. 3 is the schematic diagram of antibacterial rate in the test example;

图4位测试例中撕裂强度(Mpa)的示意图。Schematic diagram of tear strength (Mpa) in Fig. 4 test cases.

具体实施方式Detailed ways

下面对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。The following clearly and completely describes the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only some of the embodiments of the present invention, but not all of them. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the protection scope of the present invention.

本发明实施例中使用的试剂或仪器未注明生产厂商者,均为可以通过市购获得的常规试剂产品。The reagents or instruments used in the examples of the present invention are not indicated by the manufacturer, but are all commercially available conventional reagent products.

实施例1Example 1

如图1和2所示的一种抗菌阻燃高强度复合地毯基布,所述地毯基布100由阻燃聚酯纤维和生物基纤维以及金属丝交织而成;A kind of antibacterial flame-retardant high-strength composite carpet base cloth as shown in Figure 1 and 2, described carpet base cloth 100 is interwoven by flame-retardant polyester fiber and bio-based fiber and metal wire;

所述阻燃聚酯纤维经线构成经线110,所述金属丝构成纬线120,所述生物基纤维构成斜线130;The flame-retardant polyester fiber warps constitute the warps 110, the metal wires constitute the wefts 120, and the bio-based fibers constitute the diagonals 130;

所述生物基纤维由以下步骤制备而成:The bio-based fiber is prepared by the following steps:

在纺丝过程中,将生物基纤维冷却至微熔融状态,随后在上述生物基纤维表面均匀喷淋数层纳米银离子,黏附于生物基纤维表面,随后冷却至常温,获得所述生物基纤维;During the spinning process, the bio-based fiber is cooled to a slightly molten state, and then several layers of nano-silver ions are uniformly sprayed on the surface of the bio-based fiber to adhere to the surface of the bio-based fiber, and then cooled to normal temperature to obtain the bio-based fiber ;

按质量份数计算,所述生物基纤维含有100份的PLA、15份的聚羟基烷酸酯、5份的木质素;所述纳米银离子5份;Calculated in parts by mass, the bio-based fiber contains 100 parts of PLA, 15 parts of polyhydroxyalkanoate, 5 parts of lignin; 5 parts of nano silver ions;

所述微熔融状态的温度为155-185℃之间;The temperature in the slightly molten state is between 155-185°C;

所述地毯基布100下表面设有阻燃防滑胶层200,所述阻燃防滑胶层的下表面设有若干阻燃防滑胶粒201,所述若干阻燃防滑胶粒201在阻燃防滑胶层200的下表面呈网格阵列状排布;The lower surface of the carpet base cloth 100 is provided with a flame retardant anti-skid rubber layer 200, and the lower surface of the flame retardant anti-skid rubber layer is provided with a number of flame retardant anti-skid rubber particles 201, and the number of flame retardant anti-skid rubber particles 201 are used in the flame retardant and anti-skid layer. The lower surface of the adhesive layer 200 is arranged in a grid array;

斜线130与经线110的角度为45度;The angle between the oblique line 130 and the meridian 110 is 45 degrees;

所述金属丝为镁合金丝;The metal wire is a magnesium alloy wire;

所述经线110平均直径为50μm,所述纬线120平均直径为30μm,所述斜线130平均直径为40μm;The average diameter of the warp 110 is 50 μm, the average diameter of the weft 120 is 30 μm, and the average diameter of the oblique line 130 is 40 μm;

上述抗菌阻燃高强度复合地毯基布的制备方法,包括以下步骤:The preparation method of the above-mentioned antibacterial and flame-retardant high-strength composite carpet base cloth comprises the following steps:

S1将配方量的PLA、聚羟基烷酸酯和木质素共混后加入挤压机系统,加热熔融后挤出纺丝熔融液;S1 Blend the PLA, polyhydroxyalkanoate and lignin in the formula amount and add them to the extruder system, heat and melt and extrude the spinning melt;

S2将纺丝熔融液经过熔体输送管道送入纺丝箱进行纺丝;纺丝箱包含上箱体、下箱体和纺丝组件,纺丝熔融液经过上、下箱体后从纺丝组件的喷丝板喷出丝束;上箱体的纺丝温度控制在195-205℃,下箱体的纺丝温度控制在210~220℃;S2 Send the spinning melt to the spinning box through the melt conveying pipeline for spinning; the spinning box includes an upper box, a lower box and a spinning assembly, and the spinning melt passes through the upper and lower boxes and then from the spinning The spinneret of the component ejects tow; the spinning temperature of the upper box is controlled at 195-205°C, and the spinning temperature of the lower box is controlled at 210-220°C;

S3丝束经过喷丝板下方的缓冷器和单体抽吸部件后,进入控温组合冷却部件,利用环吹的热风和双侧吹的冷风使丝束缓慢冷却至微熔融状态,随后立刻均匀喷淋数层纳米银离子,黏附于生物基纤维表面,得到初生纤维,随后降温至90℃以下;After the S3 tow passes through the slow cooler under the spinneret and the monomer suction part, it enters the temperature-controlled combined cooling part, and the tow is slowly cooled to a slightly molten state by using the hot air blown around the spinneret and the cold air blown from both sides, and then immediately Evenly spray several layers of nano-silver ions, adhere to the surface of bio-based fibers to obtain primary fibers, and then cool down to below 90°C;

S4对初生纤维进行牵伸卷绕,控制牵伸温度为85~95℃,牵伸速度为500~800m/min,最终卷绕后得到生物基纤维;S4 stretches and winds the as-spun fibers, controls the drafting temperature at 85-95°C, and the drafting speed at 500-800m/min, and finally obtains bio-based fibers after winding;

S5将阻燃聚酯纤维经线构成经线110,所述金属丝构成纬线120,所述生物基纤维构成斜线130;其中每cm3基布含有经线110 30根,纬线120 25根,斜线130 20根,所述斜线130呈X型对称设置。S5 forms the warp thread 110 by the flame-retardant polyester fiber warp thread, the metal wire forms the weft thread 120, and the bio-based fiber forms the slash thread 130; wherein each cm 3 base cloth contains 30 warp threads 110, 25 weft threads 120, and slash thread 130 There are 20 oblique lines 130 arranged symmetrically in an X shape.

所述步骤S1具体包括以下步骤:The step S1 specifically includes the following steps:

在长径比L/O=24的双螺杆挤出机上挤出,双螺杆挤出机有1D-6D共6个区段和模头区组成;将PLA加到双螺杆挤出机位于1D处的进料口,将聚羟基烷酸酯加入位于双螺护挤出机2D处的注料口,将木质素加到双螺杆挤出机3D处的进料口,最终挤出纺丝熔融液;Extrude on a twin-screw extruder with an aspect ratio of L/O=24. The twin-screw extruder consists of 6 sections from 1D to 6D and a die head area; add PLA to the twin-screw extruder at 1D The feed port of the polyhydroxyalkanoate is added to the feed port at the 2D place of the twin-screw extruder, and the lignin is added to the feed port at the 3D place of the twin-screw extruder, and finally the spinning melt is extruded ;

挤出各区温度如下The extrusion temperature of each zone is as follows

第一区120℃~130℃第二区135℃~145℃The first zone 120℃~130℃ The second zone 135℃~145℃

第三区145℃~155℃第四区155℃~165℃The third zone 145℃~155℃ The fourth zone 155℃~165℃

第五区165℃~175℃第六区175℃~185℃The fifth zone 165℃~175℃ The sixth zone 175℃~185℃

模头区180~195℃。Die zone 180 ~ 195 ℃.

实施例2Example 2

一种抗菌阻燃高强度复合地毯基布,所述地毯基布100由阻燃聚酯纤维和生物基纤维以及金属丝交织而成;An antibacterial and flame-retardant high-strength composite carpet base cloth, the carpet base cloth 100 is formed by interweaving flame-retardant polyester fibers, bio-based fibers and metal wires;

所述阻燃聚酯纤维经线构成经线110,所述金属丝构成纬线120,所述生物基纤维构成斜线130;The flame-retardant polyester fiber warps constitute the warps 110, the metal wires constitute the wefts 120, and the bio-based fibers constitute the diagonals 130;

所述生物基纤维由以下步骤制备而成:The bio-based fiber is prepared by the following steps:

在纺丝过程中,将生物基纤维冷却至微熔融状态,随后在上述生物基纤维表面均匀喷淋数层纳米银离子,黏附于生物基纤维表面,随后冷却至常温,获得所述生物基纤维;During the spinning process, the bio-based fiber is cooled to a slightly molten state, and then several layers of nano-silver ions are uniformly sprayed on the surface of the bio-based fiber to adhere to the surface of the bio-based fiber, and then cooled to normal temperature to obtain the bio-based fiber ;

按质量份数计算,所述生物基纤维含有100份的PLA、18份的聚羟基烷酸酯、8份的木质素;所述纳米银离子10份;Calculated in parts by mass, the bio-based fiber contains 100 parts of PLA, 18 parts of polyhydroxyalkanoate, and 8 parts of lignin; 10 parts of nano silver ions;

所述微熔融状态的温度为155-185℃之间;The temperature in the slightly molten state is between 155-185°C;

所述地毯基布100下表面设有阻燃防滑胶层200,所述阻燃防滑胶层的下表面设有若干阻燃防滑胶粒201,所述若干阻燃防滑胶粒201在阻燃防滑胶层200的下表面呈网格阵列状排布;The lower surface of the carpet base cloth 100 is provided with a flame retardant anti-skid rubber layer 200, and the lower surface of the flame retardant anti-skid rubber layer is provided with a number of flame retardant anti-skid rubber particles 201, and the number of flame retardant anti-skid rubber particles 201 are used in the flame retardant and anti-skid layer. The lower surface of the adhesive layer 200 is arranged in a grid array;

斜线130与经线110的角度为45度;The angle between the oblique line 130 and the meridian 110 is 45 degrees;

所述金属丝为镁合金丝;The metal wire is a magnesium alloy wire;

所述经线110平均直径为50μm,所述纬线120平均直径为30μm,所述斜线130平均直径为40μm;The average diameter of the warp 110 is 50 μm, the average diameter of the weft 120 is 30 μm, and the average diameter of the oblique line 130 is 40 μm;

上述抗菌阻燃高强度复合地毯基布的制备方法,包括以下步骤:The preparation method of the above-mentioned antibacterial and flame-retardant high-strength composite carpet base cloth comprises the following steps:

S1将配方量的PLA、聚羟基烷酸酯和木质素共混后加入挤压机系统,加热熔融后挤出纺丝熔融液;S1 Blend the PLA, polyhydroxyalkanoate and lignin in the formula amount and add them to the extruder system, heat and melt and extrude the spinning melt;

S2将纺丝熔融液经过熔体输送管道送入纺丝箱进行纺丝;纺丝箱包含上箱体、下箱体和纺丝组件,纺丝熔融液经过上、下箱体后从纺丝组件的喷丝板喷出丝束;上箱体的纺丝温度控制在195-205℃,下箱体的纺丝温度控制在210~220℃;S2 Send the spinning melt to the spinning box through the melt conveying pipeline for spinning; the spinning box includes an upper box, a lower box and a spinning assembly, and the spinning melt passes through the upper and lower boxes and then from the spinning The spinneret of the component ejects tow; the spinning temperature of the upper box is controlled at 195-205°C, and the spinning temperature of the lower box is controlled at 210-220°C;

S3丝束经过喷丝板下方的缓冷器和单体抽吸部件后,进入控温组合冷却部件,利用环吹的热风和双侧吹的冷风使丝束缓慢冷却至微熔融状态,随后立刻均匀喷淋数层纳米银离子,黏附于生物基纤维表面,得到初生纤维,随后降温至90℃以下;After the S3 tow passes through the slow cooler under the spinneret and the monomer suction part, it enters the temperature-controlled combined cooling part, and the tow is slowly cooled to a slightly molten state by using the hot air blown around the spinneret and the cold air blown from both sides, and then immediately Evenly spray several layers of nano-silver ions, adhere to the surface of bio-based fibers to obtain primary fibers, and then cool down to below 90°C;

S4对初生纤维进行牵伸卷绕,控制牵伸温度为85~95℃,牵伸速度为500~800m/min,最终卷绕后得到生物基纤维;S4 stretches and winds the as-spun fibers, controls the drafting temperature at 85-95°C, and the drafting speed at 500-800m/min, and finally obtains bio-based fibers after winding;

S5将阻燃聚酯纤维经线构成经线110,所述金属丝构成纬线120,所述生物基纤维构成斜线130;其中每cm3基布含有经线110 40根,纬线120 30根,斜线130 30根,所述斜线130呈X型对称设置。S5 forms the warp thread 110 with the flame-retardant polyester fiber warp thread, the metal wire forms the weft thread 120, and the bio-based fiber forms the slash thread 130; wherein each cm 3 base cloth contains 40 warp threads 110, 30 weft threads 120, and slash thread 130 There are 30 oblique lines 130 arranged symmetrically in an X shape.

所述步骤S1具体包括以下步骤:The step S1 specifically includes the following steps:

在长径比L/O=24的双螺杆挤出机上挤出,双螺杆挤出机有1D-6D共6个区段和模头区组成;将PLA加到双螺杆挤出机位于1D处的进料口,将聚羟基烷酸酯加入位于双螺护挤出机2D处的注料口,将木质素加到双螺杆挤出机3D处的进料口,最终挤出纺丝熔融液;Extrude on a twin-screw extruder with an aspect ratio of L/O=24. The twin-screw extruder consists of 6 sections from 1D to 6D and a die head area; add PLA to the twin-screw extruder at 1D The feed port of the polyhydroxyalkanoate is added to the feed port at the 2D place of the twin-screw extruder, and the lignin is added to the feed port at the 3D place of the twin-screw extruder, and finally the spinning melt is extruded ;

挤出各区温度如下The extrusion temperature of each zone is as follows

第一区120℃~130℃第二区135℃~145℃The first zone 120℃~130℃ The second zone 135℃~145℃

第三区145℃~155℃第四区155℃~165℃The third zone 145℃~155℃ The fourth zone 155℃~165℃

第五区165℃~175℃第六区175℃~185℃The fifth zone 165℃~175℃ The sixth zone 175℃~185℃

模头区180~195℃。Die zone 180 ~ 195 ℃.

实施例3Example 3

一种抗菌阻燃高强度复合地毯基布,所述地毯基布100由阻燃聚酯纤维和生物基纤维以及金属丝交织而成;An antibacterial and flame-retardant high-strength composite carpet base cloth, the carpet base cloth 100 is formed by interweaving flame-retardant polyester fibers, bio-based fibers and metal wires;

所述阻燃聚酯纤维经线构成经线110,所述金属丝构成纬线120,所述生物基纤维构成斜线130;The flame-retardant polyester fiber warps constitute the warps 110, the metal wires constitute the wefts 120, and the bio-based fibers constitute the diagonals 130;

所述生物基纤维由以下步骤制备而成:The bio-based fiber is prepared by the following steps:

在纺丝过程中,将生物基纤维冷却至微熔融状态,随后在上述生物基纤维表面均匀喷淋数层纳米银离子,黏附于生物基纤维表面,随后冷却至常温,获得所述生物基纤维;During the spinning process, the bio-based fiber is cooled to a slightly molten state, and then several layers of nano-silver ions are evenly sprayed on the surface of the bio-based fiber to adhere to the surface of the bio-based fiber, and then cooled to normal temperature to obtain the bio-based fiber. ;

按质量份数计算,所述生物基纤维含有100份的PLA、20份的聚羟基烷酸酯、10份的木质素;所述纳米银离子15份;Calculated in parts by mass, the bio-based fiber contains 100 parts of PLA, 20 parts of polyhydroxyalkanoate, and 10 parts of lignin; 15 parts of the nano silver ion;

所述微熔融状态的温度为155-185℃之间;The temperature in the slightly molten state is between 155-185°C;

所述地毯基布100下表面设有阻燃防滑胶层200,所述阻燃防滑胶层的下表面设有若干阻燃防滑胶粒201,所述若干阻燃防滑胶粒201在阻燃防滑胶层200的下表面呈网格阵列状排布;The lower surface of the carpet base cloth 100 is provided with a flame-retardant anti-skid rubber layer 200, and the lower surface of the flame-retardant anti-skid rubber layer is provided with a number of flame-retardant anti-skid rubber particles 201, and the number of flame-resistant anti-skid rubber particles 201 are used in the flame-retardant and anti-skid layer. The lower surface of the adhesive layer 200 is arranged in a grid array;

斜线130与经线110的角度为45度;The angle between the oblique line 130 and the meridian 110 is 45 degrees;

所述金属丝为镁合金丝;The metal wire is a magnesium alloy wire;

所述经线110平均直径为50μm,所述纬线120平均直径为30μm,所述斜线130平均直径为40μm;The average diameter of the warp 110 is 50 μm, the average diameter of the weft 120 is 30 μm, and the average diameter of the oblique line 130 is 40 μm;

上述抗菌阻燃高强度复合地毯基布的制备方法,包括以下步骤:The preparation method of the above-mentioned antibacterial and flame-retardant high-strength composite carpet base cloth comprises the following steps:

S1将配方量的PLA、聚羟基烷酸酯和木质素共混后加入挤压机系统,加热熔融后挤出纺丝熔融液;S1 Blend the PLA, polyhydroxyalkanoate and lignin in the formula amount and add them to the extruder system, heat and melt and extrude the spinning melt;

S2将纺丝熔融液经过熔体输送管道送入纺丝箱进行纺丝;纺丝箱包含上箱体、下箱体和纺丝组件,纺丝熔融液经过上、下箱体后从纺丝组件的喷丝板喷出丝束;上箱体的纺丝温度控制在195-205℃,下箱体的纺丝温度控制在210~220℃;S2 Send the spinning melt into the spinning box through the melt conveying pipeline for spinning; The spinneret of the component ejects tow; the spinning temperature of the upper box is controlled at 195-205°C, and the spinning temperature of the lower box is controlled at 210-220°C;

S3丝束经过喷丝板下方的缓冷器和单体抽吸部件后,进入控温组合冷却部件,利用环吹的热风和双侧吹的冷风使丝束缓慢冷却至微熔融状态,随后立刻均匀喷淋数层纳米银离子,黏附于生物基纤维表面,得到初生纤维,随后降温至90℃以下;After the S3 tow passes through the slow cooler under the spinneret and the monomer suction part, it enters the temperature-controlled combined cooling part, and the tow is slowly cooled to a slightly molten state by using the hot air blown around the spinneret and the cold air blown from both sides, and then immediately Evenly spray several layers of nano-silver ions, adhere to the surface of bio-based fibers to obtain primary fibers, and then cool down to below 90°C;

S4对初生纤维进行牵伸卷绕,控制牵伸温度为85~95℃,牵伸速度为500~800m/min,最终卷绕后得到生物基纤维;S4 stretches and winds the as-spun fibers, controls the drafting temperature at 85-95°C, and the drafting speed at 500-800m/min, and finally obtains bio-based fibers after winding;

S5将阻燃聚酯纤维经线构成经线110,所述金属丝构成纬线120,所述生物基纤维构成斜线130;其中每cm3基布含有经线110 50根,纬线120 35根,斜线130 40根,所述斜线130呈X型对称设置。S5 forms warp thread 110 with flame-retardant polyester fiber warp thread, described metal wire forms weft thread 120, and described bio-based fiber forms slash thread 130; wherein every cm 3 base cloth contains 50 warp threads 110, 35 weft threads 120, and slash thread 130 There are 40 oblique lines 130 arranged symmetrically in an X shape.

所述步骤S1具体包括以下步骤:The step S1 specifically includes the following steps:

在长径比L/O=24的双螺杆挤出机上挤出,双螺杆挤出机有1D-6D共6个区段和模头区组成;将PLA加到双螺杆挤出机位于1D处的进料口,将聚羟基烷酸酯加入位于双螺护挤出机2D处的注料口,将木质素加到双螺杆挤出机3D处的进料口,最终挤出纺丝熔融液;It is extruded on a twin-screw extruder with an aspect ratio of L/O=24. The twin-screw extruder consists of 6 sections from 1D to 6D and a die head area; add PLA to the twin-screw extruder at 1D The feed port of the polyhydroxyalkanoate is added to the feed port at the 2D place of the twin-screw extruder, and the lignin is added to the feed port at the 3D place of the twin-screw extruder, and finally the spinning melt is extruded ;

挤出各区温度如下The extrusion temperature of each zone is as follows

第一区120℃~130℃第二区135℃~145℃The first zone 120℃~130℃ The second zone 135℃~145℃

第三区145℃~155℃第四区155℃~165℃The third zone 145℃~155℃ The fourth zone 155℃~165℃

第五区165℃~175℃第六区175℃~185℃The fifth zone 165℃~175℃ The sixth zone 175℃~185℃

模头区180~195℃。Die zone 180 ~ 195 ℃.

对比例1Comparative example 1

不含有生物基纤维,其余同实施例2Does not contain bio-based fiber, the rest are the same as in Example 2

测试例test case

性能检测试验performance test

检测方法/试验方法Detection method/test method

大肠杆菌抑菌率的测试按GB/T20944.2-2007纺织品抗菌性能的评价规定进行性能检测,当抑菌值≥1或抑菌率≥90.00%,样品具有抗菌效果。结果见表1和图3和图4所示。The test of the antibacterial rate of Escherichia coli is carried out in accordance with the provisions of GB/T20944.2-2007 on the evaluation of the antibacterial performance of textiles. When the antibacterial value ≥ 1 or the antibacterial rate ≥ 90.00%, the sample has antibacterial effect. The results are shown in Table 1 and Figures 3 and 4.

抑菌率(%)Bacteriostatic rate (%) 阻燃温度(℃)Flame retardant temperature (℃) 撕裂强度(Mpa)Tear strength (Mpa) 实施例1Example 1 97.597.5 320320 15.2515.25 实施例2Example 2 98.298.2 332332 16.3416.34 实施例3Example 3 99.599.5 337337 17.1517.15 对比例1Comparative example 1 85.285.2 314314 10.2510.25

.

结果见表1所示,本发明所述的一种抗菌阻燃高强度复合地毯基布,阻燃聚酯纤维赋予了地毯基布韧性、一定的拉伸性和阻燃性,而金属丝赋予了地毯基布高强度和阻燃性,生物基纤维赋予了地毯基布较好的抗菌性、韧性和机械强度。综合的使用经纬交叉以及斜线的编制方案,最终制备的地毯基布强度高,阻燃性能好,抗菌性能强,并且绿色环保。The results are shown in Table 1. In the antibacterial and flame-retardant high-strength composite carpet base fabric of the present invention, the flame-retardant polyester fiber imparts toughness, certain stretchability and flame retardancy to the carpet base fabric, while the metal wire imparts The high strength and flame retardancy of the carpet base fabric are guaranteed, and the bio-based fiber endows the carpet base fabric with better antibacterial properties, toughness and mechanical strength. By comprehensively using the weaving scheme of warp and weft intersecting and oblique lines, the final prepared carpet base fabric has high strength, good flame retardancy, strong antibacterial performance, and is environmentally friendly.

发明的有限几种优选实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。The descriptions of the limited preferred embodiments of the invention are relatively specific and detailed, but should not be construed as limiting the patent scope of the invention. It should be noted that, for those skilled in the art, several modifications and improvements can be made without departing from the concept of the present invention, and these all belong to the protection scope of the present invention.

Claims (10)

1.一种抗菌阻燃高强度复合地毯基布,其特征在于,所述地毯基布(100)由阻燃聚酯纤维和生物基纤维以及金属丝交织而成;1. An antibacterial, flame-retardant, high-strength composite carpet base fabric, characterized in that the carpet base fabric (100) is interwoven with flame-retardant polyester fibers, bio-based fibers and metal wires; 所述阻燃聚酯纤维经线构成经线(110),所述金属丝构成纬线(120),所述生物基纤维构成斜线(130)。The flame-retardant polyester fiber warps constitute warp threads (110), the metal wires constitute weft threads (120), and the bio-based fibers constitute oblique threads (130). 2.根据权利要求1所述的一种抗菌阻燃高强度复合地毯基布,其特征在于,所述生物基纤维由以下步骤制备而成:2. A kind of antibacterial and flame-retardant high-strength composite carpet base fabric according to claim 1, wherein the bio-based fiber is prepared from the following steps: 在纺丝过程中,将生物基纤维冷却至微熔融状态,随后在上述生物基纤维表面均匀喷淋数层纳米银离子,黏附于生物基纤维表面,随后冷却至常温,获得所述生物基纤维;During the spinning process, the bio-based fiber is cooled to a slightly molten state, and then several layers of nano-silver ions are uniformly sprayed on the surface of the bio-based fiber to adhere to the surface of the bio-based fiber, and then cooled to normal temperature to obtain the bio-based fiber ; 按质量份数计算,所述生物基纤维含有100份的PLA、15-20份的聚羟基烷酸酯、5-10份的木质素;所述纳米银离子5-15份。Calculated in parts by mass, the bio-based fiber contains 100 parts of PLA, 15-20 parts of polyhydroxyalkanoate, 5-10 parts of lignin; and 5-15 parts of the nano silver ion. 3.根据权利要求2所述的一种抗菌阻燃高强度复合地毯基布,其特征在于,所述微熔融状态的温度为155-185℃之间。3. The antibacterial and flame-retardant high-strength composite carpet base fabric according to claim 2, characterized in that the temperature in the slightly molten state is between 155-185°C. 4.根据权利要求1所述的一种抗菌阻燃高强度复合地毯基布,其特征在于,所述地毯基布(100)下表面设有阻燃防滑胶层(200),所述阻燃防滑胶层的下表面设有若干阻燃防滑胶粒(201),所述若干阻燃防滑胶粒(201)在阻燃防滑胶层(200)的下表面呈网格阵列状排布。4. An antibacterial and flame-retardant high-strength composite carpet base fabric according to claim 1, characterized in that, the lower surface of the carpet base fabric (100) is provided with a flame-retardant anti-slip rubber layer (200), and the flame-retardant The lower surface of the anti-skid rubber layer is provided with a number of flame-retardant anti-skid rubber particles (201), and the several flame-resistant anti-skid rubber particles (201) are arranged in a grid array on the lower surface of the flame-resistant anti-skid rubber layer (200). 5.根据权利要求1所述的一种抗菌阻燃高强度复合地毯基布,其特征在于,斜线(130)与经线(110)的角度为45度。5. The antibacterial and flame-retardant high-strength composite carpet base fabric according to claim 1, characterized in that, the angle between the oblique line (130) and the warp line (110) is 45 degrees. 6.根据权利要求1所述的一种抗菌阻燃高强度复合地毯基布,其特征在于,所述金属丝为镁合金丝。6. The antibacterial and flame-retardant high-strength composite carpet base fabric according to claim 1, wherein the metal wire is a magnesium alloy wire. 7.根据权利要求1所述的一种抗菌阻燃高强度复合地毯基布,其特征在于,所述经线(110)平均直径为50μm,所述纬线(120)平均直径为30μm,所述斜线(130)平均直径为40μm。7. The antibacterial and flame-retardant high-strength composite carpet base fabric according to claim 1, characterized in that, the average diameter of the warp (110) is 50 μm, the average diameter of the weft (120) is 30 μm, and the oblique The wires ( 130 ) have an average diameter of 40 μm. 8.如权利要求1-7任一项所述的抗菌阻燃高强度复合地毯基布的制备方法,其特征在于,包括以下步骤:8. the preparation method of the antibacterial flame-retardant high-strength composite carpet base cloth as described in any one of claim 1-7, is characterized in that, comprises the following steps: S1将配方量的PLA、聚羟基烷酸酯和木质素共混后加入挤压机系统,加热熔融后挤出纺丝熔融液;S1 Blend the PLA, polyhydroxyalkanoate and lignin in the formula amount and add them to the extruder system, heat and melt and extrude the spinning melt; S2将纺丝熔融液经过熔体输送管道送入纺丝箱进行纺丝;纺丝箱包含上箱体、下箱体和纺丝组件,纺丝熔融液经过上、下箱体后从纺丝组件的喷丝板喷出丝束;上箱体的纺丝温度控制在195-205℃,下箱体的纺丝温度控制在210~220℃;S2 Send the spinning melt to the spinning box through the melt conveying pipeline for spinning; the spinning box includes an upper box, a lower box and a spinning assembly, and the spinning melt passes through the upper and lower boxes and then from the spinning The spinneret of the component ejects tow; the spinning temperature of the upper box is controlled at 195-205°C, and the spinning temperature of the lower box is controlled at 210-220°C; S3丝束经过喷丝板下方的缓冷器和单体抽吸部件后,进入控温组合冷却部件,利用环吹的热风和双侧吹的冷风使丝束缓慢冷却至微熔融状态,随后立刻均匀喷淋数层纳米银离子,黏附于生物基纤维表面,得到初生纤维,随后降温至90℃以下;After the S3 tow passes through the slow cooler under the spinneret and the monomer suction part, it enters the temperature-controlled combined cooling part, and the tow is slowly cooled to a slightly molten state by using the hot air blown around the spinneret and the cold air blown from both sides, and then immediately Evenly spray several layers of nano-silver ions, adhere to the surface of bio-based fibers to obtain primary fibers, and then cool down to below 90°C; S4对初生纤维进行牵伸卷绕,控制牵伸温度为85~95℃,牵伸速度为500~800m/min,最终卷绕后得到生物基纤维;S4 stretches and winds the as-spun fibers, controls the drafting temperature at 85-95°C, and the drafting speed at 500-800m/min, and finally obtains bio-based fibers after winding; S5将阻燃聚酯纤维经线构成经线(110),所述金属丝构成纬线(120),所述生物基纤维构成斜线(130);其中每cm2基布含有经线(110)30-50根,纬线(120)25-35根,斜线(130)20-40根,所述斜线(130)呈X型对称设置。S5 Use flame-retardant polyester fiber warps to form warps (110), the metal wires to form wefts (120), and the bio-based fibers to form slashes (130); wherein each cm 2 of the base fabric contains 30-50 warps (110) There are 25-35 weft threads (120) and 20-40 oblique threads (130), and the oblique threads (130) are arranged symmetrically in an X shape. 9.根据权利要求8所述的制备方法,其特征在于,所述步骤S1具体包括以下步骤:9. The preparation method according to claim 8, wherein said step S1 specifically comprises the following steps: 在长径比L/O=24的双螺杆挤出机上挤出,双螺杆挤出机有1D-6D共6个区段和模头区组成;将PLA加到双螺杆挤出机位于1D处的进料口,将聚羟基烷酸酯加入位于双螺护挤出机2D处的注料口,将木质素加到双螺杆挤出机3D处的进料口,最终挤出纺丝熔融液;Extrude on a twin-screw extruder with an aspect ratio of L/O=24. The twin-screw extruder consists of 6 sections from 1D to 6D and a die head area; add PLA to the twin-screw extruder at 1D The feed port of the polyhydroxyalkanoate is added to the feed port at the 2D place of the twin-screw extruder, and the lignin is added to the feed port at the 3D place of the twin-screw extruder, and finally the spinning melt is extruded ; 挤出各区温度如下The extrusion temperature of each zone is as follows 第一区120℃~130℃第二区135℃~145℃The first zone 120℃~130℃ The second zone 135℃~145℃ 第三区 145℃~155℃第四区155℃~165℃The third zone 145℃~155℃ The fourth zone 155℃~165℃ 第五区165℃~175℃第六区175℃~185℃The fifth zone 165℃~175℃ The sixth zone 175℃~185℃ 模头区180~195℃。Die zone 180 ~ 195 ℃. 10.如权利要求1-7任一项所述的抗菌阻燃高强度复合地毯基布在制备露营地毯中的用途。10. the purposes of the antibacterial flame-retardant high-strength composite carpet base cloth as described in any one of claim 1-7 in the preparation camping carpet.
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CN121046981A (en) * 2025-11-05 2025-12-02 嘉兴市天之华喷织有限公司 A bio-based antibacterial yarn

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CN205917382U (en) * 2016-07-28 2017-02-01 扬州纪元纺织有限公司 High strength is look folding cloth alternately
CN109518478A (en) * 2017-09-19 2019-03-26 扬州亿诺无纺有限公司 A kind of Multifunctional blanket base fabric
CN111376554A (en) * 2020-03-28 2020-07-07 深圳市歌中歌服饰有限公司 Antibacterial special fabric with four-layer structure
CN115012050A (en) * 2022-06-24 2022-09-06 宁波禾素纤维有限公司 Production process of PHBV and PLA blended bio-based fiber

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KR20090051305A (en) * 2007-11-19 2009-05-22 이규주 Functional coating manufacturing method
CN105239194A (en) * 2015-11-20 2016-01-13 王庆 Method of preparing flame-retarding anti-microbial polylactic acid fibers, spinning fibers into yarn and making fabric
CN205576395U (en) * 2016-02-26 2016-09-14 江阴科强工业胶带有限公司 Sealed adhesive tape of rice font skeleton cloth and applied this fabric one -tenth
CN205917382U (en) * 2016-07-28 2017-02-01 扬州纪元纺织有限公司 High strength is look folding cloth alternately
CN109518478A (en) * 2017-09-19 2019-03-26 扬州亿诺无纺有限公司 A kind of Multifunctional blanket base fabric
CN111376554A (en) * 2020-03-28 2020-07-07 深圳市歌中歌服饰有限公司 Antibacterial special fabric with four-layer structure
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN121046981A (en) * 2025-11-05 2025-12-02 嘉兴市天之华喷织有限公司 A bio-based antibacterial yarn

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