CN107502987A - A kind of fire-retardant composite filament of high-strength polyester and its preparation technology - Google Patents
A kind of fire-retardant composite filament of high-strength polyester and its preparation technology Download PDFInfo
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- CN107502987A CN107502987A CN201710639219.XA CN201710639219A CN107502987A CN 107502987 A CN107502987 A CN 107502987A CN 201710639219 A CN201710639219 A CN 201710639219A CN 107502987 A CN107502987 A CN 107502987A
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- Prior art keywords
- fire
- preparation technology
- retardant
- composite filament
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- 239000002131 composite material Substances 0.000 title claims abstract description 35
- 239000003063 flame retardant Substances 0.000 title claims abstract description 33
- 229920000728 polyester Polymers 0.000 title claims abstract description 29
- 238000005516 engineering process Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 50
- 229920004933 Terylene® Polymers 0.000 claims abstract description 40
- 239000000835 fiber Substances 0.000 claims abstract description 35
- 238000009987 spinning Methods 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 19
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 229910052709 silver Inorganic materials 0.000 claims abstract description 14
- 239000004332 silver Substances 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000919 ceramic Substances 0.000 claims abstract description 11
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004952 Polyamide Substances 0.000 claims abstract description 6
- 229920002647 polyamide Polymers 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- -1 glycol ester Chemical class 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 12
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 10
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 7
- 239000003921 oil Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 229920000297 Rayon Polymers 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 239000002539 nanocarrier Substances 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 238000004804 winding Methods 0.000 claims description 3
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 3
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- 229920001778 nylon Polymers 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims 2
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 claims 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 1
- 238000009826 distribution Methods 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 description 12
- 239000002585 base Substances 0.000 description 9
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 6
- 239000004753 textile Substances 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000012675 alcoholic extract Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/106—Radiation shielding agents, e.g. absorbing, reflecting agents
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of fire-retardant composite filament of high-strength polyester and its preparation technology, including body, the body includes inner core and outer core, and the outer surface of body is coated with polytetrafluorethylecoatings coatings and ceramic base composite coating successively from inside to outside, the body is made up of silver system antibacterial matrices, uvioresistant master batch and copoly type phosphorous flame-retardant Terylene fiber resin, and its dispensing percentage is silver system antibacterial matrices 3%~10%.Polyester fiber provided by the invention, each group distribution ratio is scientific and reasonable, silver system antibacterial matrices, uvioresistant master batch, copoly type phosphorous flame-retardant Terylene fiber resin are organically combined by science, preoriented yarn is prepared, again by adding bullet deformation to produce low bullet Pet Textured Yarn, then terylene molten mass and polyamide fibre molten mass are entered into blend spinning case spinning after measuring pump-metered, so as to obtain the permanent multifunctional polyester fiber with antibacterial, uvioresistant and fire retardation, make the application of polyester fiber more extensive.
Description
Technical field
The present invention relates to terylene composite filament technical field, the fire-retardant composite filament of specially a kind of high-strength polyester and its work is prepared
Skill.
Background technology
The product that knitwear form by processing weaving is referred to as textile, can be divided into clothing textile, dress by purposes
Decorations textile, industrial goods three major types, clothing textile include making various weaving face fabrics and sewing thread, the pine of clothes
The weaving auxiliary material and knitted garment, gloves, socks etc. such as taut band, collar support, back boxing, decorative textile product can be divided into indoor article, bed
Bed linens and outdoor goods, including household cloth and dining room bath chamber wash articles for use, such as：Carpet, slip cover, chair, wall tapestry, patch, as
Cover, product, curtain, towel, tea cloth, the tablecloth, handkerchief etc. are spun, bedding include bedcover, sheet, quilt cover, quilt cover, woollen blanket, towel
Quilt, pillow, core, pillowcase etc., outdoor goods the wholesale various types of knitwear, common are Peng Gai including chinampa etc.
Cloth, firearms clothing, filter cloth, screen cloth, roadbed cloth etc., terylene are one of indispensable raw materials of knitwear, and terylene is to benzene with essence
Dioctyl phthalate（PTA）Or dimethyl terephthalate (DMT)（DMT）With second two（EG）For raw material through esterification or ester exchange and polycondensation reaction and
Obtained fiber-forming polymer --- polyethylene terephthalate（PET）, through fiber, great Liang Yong made of spinning and post processing
In manufacture clothing fabric and industrial product, terylene has extremely excellent setting performance, and spun polyester thread or fabric are raw after setting
Into it is flat very, fluffy form or rivel etc., in use through repeatedly washing, remain to prolonged constant.
Terylene is world wide production maximum, and most widely used synthetic fibers kind, terylene accounts for world's synthetic fibers yield
More than 60%, be largely used to the textiles such as dress material, bedding, various trimming cloth, defence and military particular fabric and other
Industrial fibre product, such as filtering material, insulating materials, tire cord, conveyer belt, terylene are works in three big synthetic fibers
The simplest one kind of skill, price is also relatively cheap, along with it have it is durable, elasticity it is good, be unlikely to deform, it is corrosion-resistant, insulation,
The features such as well-pressed, quick-drying washable, liked by people.From the point of view of terylene molecular composition, it is by short fat hydrocarbon chain, ester group, benzene
Ring, end alcoholic extract hydroxyl group are formed, and in terylene molecule in addition to it two end alcoholic extract hydroxyl groups be present, have no other polar groups, thus terylene is fine
Hydrophily extreme difference is tieed up, about contains 46% ester group in terylene molecule, hydrolysis, thermal cracking can occur when ester group is more than 200 DEG C, is met strong
Alkali then soap solution, reduces the degree of polymerization, the detergent washing powder of less than 100 DEG C common dosages has no effect to terylene；Terylene point
Also contain aliphatic hydrocarbon chain in son, it can make terylene molecule have certain flexibility, but can not be interior due to also having in terylene molecule
The phenyl ring of rotation, therefore the substantially rigid molecule of terylene macromolecular, strand are easy to keep line style, and therefore, terylene macromolecular is at this
Crystallization is readily formed under the conditions of one, therefore the crystallinity of terylene and orientation are higher, terylene has many uses, and is largely used to manufacture
Product in clothing and industry, flame-resistant terylene are of wide application, except fabrics for industrial use, building because having permanent fire retardant
Outside the effect that the performances such as interior trim, vehicles interior trim can not be substituted, many effects are also played in protective garment field,
According to fire retardant protective clothing national Specification, the department such as metallurgy, forestry, chemical industry, oil, fire-fighting should use fire retardant protective clothing, mesh
Preceding people uvioresistant, antibacterial or flame retardant area develop product development, but be only limitted to it is one-side to fiber carry out uvioresistant,
Antibacterial or fire-retardant modification, it is impossible to which how solution organically combines three, obtains more multifunctional application fiber in extensive range.
The content of the invention
It is an object of the invention to provide a kind of fire-retardant composite filament of high-strength polyester and its preparation technology, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides following technical scheme：A kind of fire-retardant composite filament of high-strength polyester and its preparation
Technique, including body, the body includes inner core and outer core, and the outer surface of body is coated with polytetrafluoroethyl-ne successively from inside to outside
Ene coatings and ceramic base composite coating, the body is by silver system antibacterial matrices, uvioresistant master batch and copoly type phosphorous flame-retardant terylene
Fiber-forming resin forms, and its dispensing percentage is silver system antibacterial matrices 3%~10%；Uvioresistant master batch 2%~13%；Copoly type phosphorus
It is flame-resistant terylene fiber-forming resin 77%~95%.
Preferably, the inner core is polyester fiber, and outer core is nylon fibre.
Preferably, the quantity of outer core is 12, and is connected between outer core and inner core by PVC viscose glues.
Preferably, the thickness of the polytetrafluorethylecoatings coatings is 30~100 μm.
Preferably, the thickness of the ceramic base composite coating is 50~90 μm.
Preferably, the uvioresistant master batch is the anti ultraviolet agent and percentage by weight by percentage by weight 15%~25%
75%~85% polyethylene terephthalate blending is made.
Preferably, the anti ultraviolet agent is inorganic, organic or composite inorganic and organic anti ultraviolet agent.
Preferably, the composite inorganic and organic anti ultraviolet agent are ultra-fine by the TiO2 of percentage by weight 6%~12%
The polyethylene terephthalate blending of powder, 8%~16% UV absorbers and surplus is made.
Preferably, silver system antibacterial matrices by percentage by weight be 10%~50% nano-silver ionic and nano-carrier
The polyethylene terephthalate blending of silica or basic zirconium phosphate and percentage by weight 60%~80% is made.
Preferably, its preparation technology comprises the following steps：
A, percentage by weight is taken as 20%~30% anti ultraviolet agent and the poly terephthalic acid of percentage by weight 70%~90%
Glycol ester is blended, and is extruded with screw extruder, pelletizing, and uvioresistant master batch is made, and wherein blending temperature is 220~270 DEG C, spiral shell
Bar rotating speed is 170~270rpm；
B, obtained uvioresistant master batch and copoly type phosphorous flame-retardant Terylene fiber resin are blended, preoriented yarn are made, then pass through
Bullet deformation is added to produce low bullet Pet Textured Yarn, wherein spinning condition is：270~400 DEG C of spinning temperature, spinning speed 50~
500m/min；
C, terylene molten mass and polyamide fibre molten mass enter blend spinning case spinning, blend spinning box temperature after measuring pump-metered
Spend for 265~325 DEG C, blend spinning case initial pressure is 75~110kgf/cm2；
D, spun tow passes through ring wind quenching, and ring blowing temperature is 18~30 DEG C, and ring blowing humidity is 55%~65%, ring
Cold air blast velocity is 0.5~0.8m/s；
E, boundling oils drawing and setting, and by spun tow boundling into monofilament, it is anti-make it that monofilament has by the drawing and setting that oils
Static behaviour and flatness；
F, coated with polytetrafluorethylecoatings coatings, ceramic base composite coating on monofilament；
H, wind, and winding speed is 50~500m/min；
I, packed after examining.
Compared with prior art, beneficial effects of the present invention are as follows：
1st, polyester fiber provided by the invention, each group distribution ratio is scientific and reasonable, by science by silver system antibacterial matrices, uvioresistant
Master batch, copoly type phosphorous flame-retardant Terylene fiber resin organically combine, and preoriented yarn is prepared, then by adding bullet deformation to produce
Low bullet Pet Textured Yarn, then the blend spinning case that enters of terylene molten mass and polyamide fibre molten mass after measuring pump-metered is spun
Silk, so as to obtain the permanent multifunctional polyester fiber with antibacterial, uvioresistant and fire retardation, make the application of polyester fiber
It is more extensive.
2nd, the present invention has been coated with polytetrafluorethylecoatings coatings and the compound painting of ceramic base successively from inside to outside in the outer surface of body
Layer, effectively increases the corrosion resistance of body, extends its service life.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention；
Fig. 2 is coating structure schematic diagram of the present invention；
Fig. 3 is inventive formulation form schematic diagram.
In figure：1 body, 11 inner cores, 12 outer cores, 2 polytetrafluorethylecoatings coatings, 3 ceramic base composite coatings.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on
Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made
Embodiment, belong to the scope of protection of the invention.
Refer to Fig. 1-3, a kind of fire-retardant composite filament of high-strength polyester and its preparation technology, including body 1, body 1 include interior
Core 11 and outer core 12, and the outer surface of body 1 is coated with polytetrafluorethylecoatings coatings 2 and ceramic base composite coating successively from inside to outside
3, the corrosion resistance of body 1 is effectively increased, extends its service life, body 1 is by silver system antibacterial matrices, uvioresistant master batch
Formed with copoly type phosphorous flame-retardant Terylene fiber resin, its dispensing percentage is silver system antibacterial matrices 3%~10%；Uvioresistant is female
Grain 2%~13%；Copoly type phosphorous flame-retardant Terylene fiber resin 77%~95%, inner core 11 are polyester fiber, and outer core 12 is brocade
Synthetic fibre fiber, the quantity of outer core 12 is 12, and is connected between outer core 12 and inner core 11 by PVC viscose glues, and polytetrafluoroethylene (PTFE) applies
The thickness of layer 2 is 30~100 μm, and the thickness of ceramic base composite coating 3 is 50~90 μm, and uvioresistant master batch is by percentage by weight
The polyethylene terephthalate blending of 15%~25% anti ultraviolet agent and percentage by weight 75%~85% is made, anti-purple
Outer dose is inorganic, organic or composite inorganic and organic anti ultraviolet agent, and composite inorganic and organic anti ultraviolet agent are by weight hundred
TiO2 superfine powders, the polyethylene terephthalate of 8%~16% UV absorbers and surplus point than 6%~12%
Ester blending is made, silver be antibacterial matrices by percentage by weight for 10%~50% nano-silver ionic and nano-carrier silica
Or the polyethylene terephthalate blending of basic zirconium phosphate and percentage by weight 60%~80% is made.
Its preparation technology comprises the following steps：
A, percentage by weight is taken as 20%~30% anti ultraviolet agent and the poly terephthalic acid of percentage by weight 70%~90%
Glycol ester is blended, and is extruded with screw extruder, pelletizing, and uvioresistant master batch is made, and wherein blending temperature is 220~270 DEG C, spiral shell
Bar rotating speed is 170~270rpm；
B, obtained uvioresistant master batch and copoly type phosphorous flame-retardant Terylene fiber resin are blended, preoriented yarn are made, then pass through
Bullet deformation is added to produce low bullet Pet Textured Yarn, wherein spinning condition is：270~400 DEG C of spinning temperature, spinning speed 50~
500m/min；
C, terylene molten mass and polyamide fibre molten mass enter blend spinning case spinning, blend spinning box temperature after measuring pump-metered
Spend for 265~325 DEG C, blend spinning case initial pressure is 75~110kgf/cm2；
D, spun tow passes through ring wind quenching, and ring blowing temperature is 18~30 DEG C, and ring blowing humidity is 55%~65%, ring
Cold air blast velocity is 0.5~0.8m/s；
E, boundling oils drawing and setting, and by spun tow boundling into monofilament, it is anti-make it that monofilament has by the drawing and setting that oils
Static behaviour and flatness；
F, coated with polytetrafluorethylecoatings coatings 2, ceramic base composite coating 3 on monofilament；
H, wind, and winding speed is 50~500m/min；
I, packed after examining.
In use, each group distribution ratio is scientific and reasonable, by science by silver system antibacterial matrices, uvioresistant master batch, copoly type
Phosphorous flame-retardant Terylene fiber resin organically combines, and preoriented yarn is prepared, then become by adding bullet deformation to produce low bullet terylene
Shape silk, terylene molten mass and polyamide fibre molten mass are then entered into blend spinning case spinning after measuring pump-metered, so as to
To the permanent multifunctional polyester fiber with antibacterial, uvioresistant and fire retardation, make the application of polyester fiber more extensive, together
When in the outer surface of body 1 be coated with polytetrafluorethylecoatings coatings 2 and ceramic base composite coating 3 successively from inside to outside, effectively improve
The corrosion resistance of body 1, extends its service life.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of fire-retardant composite filament of high-strength polyester and its preparation technology, including body（1）, it is characterised in that：The body（1）Bag
Include inner core（11）With outer core（12）, and body（1）Outer surface be coated with polytetrafluorethylecoatings coatings successively from inside to outside（2）And pottery
Porcelain base composite coating（3）, the body（1）By silver system antibacterial matrices, uvioresistant master batch and copoly type phosphorous flame-retardant terylene into fibre
Resin forms, and its dispensing percentage is silver system antibacterial matrices 3%~10%；Uvioresistant master batch 2%~13%；Copoly type phosphorus system hinders
Fire Terylene fiber resin 77%~95%.
2. a kind of fire-retardant composite filament of high-strength polyester according to claim 1 and its preparation technology, it is characterised in that：In described
Core（11）For polyester fiber, outer core（12）For nylon fibre.
3. a kind of fire-retardant composite filament of high-strength polyester according to claim 2 and its preparation technology, it is characterised in that：It is described outer
Core（12）Quantity be 12, and outer core（12）With inner core（11）Between connected by PVC viscose glues.
4. a kind of fire-retardant composite filament of high-strength polyester according to claim 1 and its preparation technology, it is characterised in that：It is described poly-
Tetrafluoroethene coating（2）Thickness be 30~100 μm.
5. a kind of fire-retardant composite filament of high-strength polyester according to claim 1 and its preparation technology, it is characterised in that：The pottery
Porcelain base composite coating（3）Thickness be 50~90 μm.
6. a kind of fire-retardant composite filament of high-strength polyester according to claim 1 and its preparation technology, it is characterised in that：It is described anti-
Ultraviolet master batch is by the anti ultraviolet agent of percentage by weight 15%~25% and the poly- terephthaldehyde of percentage by weight 75%~85%
Sour glycol ester blending is made.
7. a kind of fire-retardant composite filament of high-strength polyester according to claim 6 and its preparation technology, it is characterised in that：It is described anti-
Ultraviolet dose is inorganic, organic or composite inorganic and organic anti ultraviolet agent.
8. a kind of fire-retardant composite filament of high-strength polyester according to claim 7 and its preparation technology, it is characterised in that：It is described multiple
The inorganic and organic anti ultraviolet agent of mould assembly is TiO2 superfine powders, 8%~16% ultraviolet light by percentage by weight 6%~12%
Absorbent and the blending of the polyethylene terephthalate of surplus are made.
9. a kind of fire-retardant composite filament of high-strength polyester according to claim 1 and its preparation technology, it is characterised in that：The silver
Be antibacterial matrices by nano-silver ionic and nano-carrier silica that percentage by weight is 10%~50% or basic zirconium phosphate with
The polyethylene terephthalate blending of percentage by weight 60%~80% is made.
10. a kind of fire-retardant composite filament of high-strength polyester and its preparation technology according to any one of claim 1 to 9, its feature
It is：Its preparation technology comprises the following steps：
A, percentage by weight is taken as 20%~30% anti ultraviolet agent and the poly terephthalic acid of percentage by weight 70%~90%
Glycol ester is blended, and is extruded with screw extruder, pelletizing, and uvioresistant master batch is made, and wherein blending temperature is 220~270 DEG C, spiral shell
Bar rotating speed is 170~270rpm；
B, obtained uvioresistant master batch and copoly type phosphorous flame-retardant Terylene fiber resin are blended, preoriented yarn are made, then pass through
Bullet deformation is added to produce low bullet Pet Textured Yarn, wherein spinning condition is：270~400 DEG C of spinning temperature, spinning speed 50~
500m/min；
C, terylene molten mass and polyamide fibre molten mass enter blend spinning case spinning, blend spinning box temperature after measuring pump-metered
Spend for 265~325 DEG C, blend spinning case initial pressure is 75~110kgf/cm2；
D, spun tow passes through ring wind quenching, and ring blowing temperature is 18~30 DEG C, and ring blowing humidity is 55%~65%, ring
Cold air blast velocity is 0.5~0.8m/s；
E, boundling oils drawing and setting, and by spun tow boundling into monofilament, it is anti-make it that monofilament has by the drawing and setting that oils
Static behaviour and flatness；
F, polytetrafluorethylecoatings coatings are coated with monofilament（2）, ceramic base composite coating（3）；
H, wind, and winding speed is 50~500m/min；
I, packed after examining.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710639219.XA CN107502987A (en) | 2017-07-31 | 2017-07-31 | A kind of fire-retardant composite filament of high-strength polyester and its preparation technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710639219.XA CN107502987A (en) | 2017-07-31 | 2017-07-31 | A kind of fire-retardant composite filament of high-strength polyester and its preparation technology |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502987A true CN107502987A (en) | 2017-12-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710639219.XA Withdrawn CN107502987A (en) | 2017-07-31 | 2017-07-31 | A kind of fire-retardant composite filament of high-strength polyester and its preparation technology |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110552080A (en) * | 2019-09-04 | 2019-12-10 | 浙江迈实科技有限公司 | Slice spinning method for photocatalyst chemical fiber |
| CN110820080A (en) * | 2019-10-24 | 2020-02-21 | 张家港欣阳化纤有限公司 | Antibacterial, warm-keeping and flame-retardant composite filament and production process thereof |
-
2017
- 2017-07-31 CN CN201710639219.XA patent/CN107502987A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110552080A (en) * | 2019-09-04 | 2019-12-10 | 浙江迈实科技有限公司 | Slice spinning method for photocatalyst chemical fiber |
| CN110820080A (en) * | 2019-10-24 | 2020-02-21 | 张家港欣阳化纤有限公司 | Antibacterial, warm-keeping and flame-retardant composite filament and production process thereof |
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Application publication date: 20171222 |