CN116288564A - An anti-oxidation process of acrylic electroplating - Google Patents

An anti-oxidation process of acrylic electroplating Download PDF

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CN116288564A
CN116288564A CN202310191555.8A CN202310191555A CN116288564A CN 116288564 A CN116288564 A CN 116288564A CN 202310191555 A CN202310191555 A CN 202310191555A CN 116288564 A CN116288564 A CN 116288564A
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acrylic
finished product
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electroplating
oxidation process
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张国军
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Guangdong Donghua Optoelectronics Technology Co ltd
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/54—Electroplating of non-metallic surfaces
    • C25D5/56—Electroplating of non-metallic surfaces of plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351—Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust

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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention provides an acrylic electroplating anti-oxidation process, which relates to the technical field of acrylic electroplating processes and comprises the following steps: step one: placing the semi-finished product of acrylic into a cleaning basket, spraying with clear water, and then cleaning glass with 8-20g/m 2 Uniformly coating the surface of the glass, cleaning for 7-9min by using a hairbrush, removing surface cleaning liquid from the cleaned acrylic semi-finished product in a secondary spraying mode, and finally drying by hot air; according to the invention, the protective film is formed on the surface of the acrylic semi-finished product through antioxidant treatment, so that the phenomenon that the acrylic semi-finished product is oxidized due to irradiation of ultraviolet lamps in the subsequent paint spraying and curing process of the surface of the acrylic semi-finished product is avoided, the yield of the acrylic semi-finished product is improved, and meanwhile, a good foundation is established for the later paint spraying through an electrostatic dust removing mode before paint spraying, so that the electroplating work of the acrylic semi-finished product is facilitated.

Description

一种亚克力电镀防氧化工艺An anti-oxidation process of acrylic electroplating

技术领域technical field

本发明涉及亚克力电镀工艺技术领域,尤其涉及一种亚克力电镀防氧化工艺。The invention relates to the technical field of acrylic electroplating technology, in particular to an anti-oxidation technology of acrylic electroplating.

背景技术Background technique

亚克力,又叫PMMA或有机玻璃,化学名称为聚甲基丙烯酸甲酯,是一种开发较早的重要可塑性高分子材料,具有较好的透明性、化学稳定性和耐候性、易染色、易加工、外观优美,在建筑业中有着广泛应用。有机玻璃产品通常可以分为浇注板、挤出板和模塑料,在亚克力电镀过程中,通常需要对其表面喷漆进行紫外固化处理,由于亚克力是一种有机玻璃,紫外线、氧气、湿热都容易造成亚克力的氧化和变色,从而在固化过程中容易造成氧化情况出现。Acrylic, also known as PMMA or plexiglass, and its chemical name is polymethyl methacrylate, is an important plastic polymer material developed earlier, with good transparency, chemical stability and weather resistance, easy to dye, easy It is widely used in the construction industry due to its beautiful processing and appearance. Plexiglass products can usually be divided into cast plate, extruded plate and molding compound. In the process of acrylic electroplating, it is usually necessary to carry out UV curing on the surface of the paint. Since acrylic is a kind of plexiglass, it is easy to cause Oxidation and discoloration of acrylic, which can easily cause oxidation during the curing process.

发明内容Contents of the invention

本发明的目的是为了解决现有技术中存在的缺点,而提出的一种亚克力电镀防氧化工艺。The purpose of the present invention is to solve the shortcomings in the prior art, and propose an acrylic electroplating anti-oxidation process.

为了实现上述目的,本发明采用了如下技术方案:一种亚克力电镀防氧化工艺,包括以下步骤:In order to achieve the above object, the present invention adopts the following technical scheme: an acrylic electroplating anti-oxidation process, comprising the following steps:

步骤一:将亚克力半成品放入清洗篮中使用清水喷淋,接着将玻璃清洗液按照8-20g/m2的量均匀涂抹到玻璃表面,并使用毛刷清洁7-9min,清洁后的亚克力半成品通过二次喷淋的方式去除表面清洗液,最后热风烘干;Step 1: Put the acrylic semi-finished product into the cleaning basket and spray it with clean water, then apply the glass cleaning solution evenly on the glass surface according to the amount of 8-20g/ m2 , and use a brush to clean it for 7-9min, the cleaned acrylic semi-finished product Remove the surface cleaning liquid by means of secondary spraying, and finally dry with hot air;

步骤二:将清洗后的亚克力半成品放入除尘器中,利用静电场使气体电离从而使尘粒带电吸附到电极上收尘;Step 2: Put the cleaned acrylic semi-finished product into the dust collector, use the electrostatic field to ionize the gas so that the dust particles are charged and adsorbed to the electrode to collect dust;

步骤三:通过抗氧化剂处理使亚克力半成品表面形成保护膜,成膜后的亚克力半成品再次水洗烘干;Step 3: Form a protective film on the surface of the acrylic semi-finished product through antioxidant treatment, and then wash and dry the acrylic semi-finished product after film formation;

步骤四:将底漆和亚克力半成品真空加热到75-80℃,压缩空气经油水分离机、冷干机和吸附式干燥剂净化后,经空气压缩机形成气流,将底漆雾化喷涂在玻璃表面;Step 4: Heat the primer and acrylic semi-finished products to 75-80°C in vacuum. After the compressed air is purified by an oil-water separator, a cold dryer and an adsorption desiccant, an airflow is formed by an air compressor, and the primer is atomized and sprayed on the glass. surface;

步骤五:使用紫外线对亚克力半成品光照,照射时间为6-8s,紫外线灯管与亚克力半成品距离为18cm;Step 5: Use ultraviolet rays to illuminate the acrylic semi-finished product, the irradiation time is 6-8s, and the distance between the ultraviolet lamp and the acrylic semi-finished product is 18cm;

步骤六:通过电镀方式为亚克力半成品表面镀膜,膜厚为20nm-500nm,镀膜后的亚克力半成品重复步骤四为表面喷涂面漆,喷涂后再重复步骤五进行光照工作,最后亚克力半成品电镀结束。Step 6: Coat the surface of the acrylic semi-finished product by electroplating, with a film thickness of 20nm-500nm. Repeat step 4 for the surface of the coated acrylic semi-finished product to spray the topcoat on the surface.

为了初步清洗亚克力半成品,本发明改进有,在步骤一中,玻璃清洗液是由十二烷基苯磺酸钠、聚丙三醇酯、单硬脂酸甘油酯以及单硬脂酸甘油酯和乙二醇丁醚、柠檬酸铵、高岭土、乙醇和异丙醇与去离子水混合而成。In order to initially clean the acrylic semi-finished product, the present invention is improved. In step one, the glass cleaning solution is made of sodium dodecylbenzenesulfonate, polyglycerol ester, glyceryl monostearate and glyceryl monostearate and ethyl alcohol. Glycol butyl ether, ammonium citrate, kaolin clay, ethanol and isopropanol mixed with deionized water.

为了烘干亚克力半成品,本发明改进有,在步骤一中,热风烘干的温度需控制在50-75℃。In order to dry the acrylic semi-finished product, the improvement of the present invention is that in step 1, the temperature of the hot air drying needs to be controlled at 50-75°C.

为了提高清洁效果,本发明改进有,在步骤一中,所述毛刷采用静电毛刷。In order to improve the cleaning effect, the present invention is improved in that in step 1, the brush is an electrostatic brush.

为了充分接触抗氧化剂,本发明改进有,在步骤三中,抗氧化剂处理通过浸泡或喷淋的方式,抗氧化剂浓度为2-5%。In order to fully contact the antioxidant, the improvement of the present invention is that in step 3, the antioxidant treatment is performed by soaking or spraying, and the concentration of the antioxidant is 2-5%.

为了清理亚克力半成品,本发明改进有,在步骤三中,水洗采用机械手下料方式,浸泡8-10s后将亚克力半成品从水中取出。In order to clean up the acrylic semi-finished product, the present invention is improved. In step 3, the water washing adopts the method of manipulator unloading, and the acrylic semi-finished product is taken out of the water after soaking for 8-10s.

为了达到抗氧化效果,本发明改进有,在步骤三中,抗氧化剂是由苯并三氮唑与甲基苯并三氮唑混合而成。In order to achieve the anti-oxidation effect, the present invention is improved in that in the third step, the antioxidant is formed by mixing benzotriazole and tolylbenzotriazole.

为了辅助喷涂,本发明改进有,在步骤四中,流水线线速为10-15m/min,所述底漆中含有重量比0.8%的附着力促进剂。In order to assist spraying, the present invention improves that in step 4, the line speed is 10-15m/min, and the primer contains 0.8% adhesion promoter by weight.

为了改变喷涂效果,本发明改进有,在步骤四中喷涂空气压力为0.25-0.35Mpa,漆雾雾化张角为45°,喷枪与玻璃表面的距离为12-14cm。In order to change the spraying effect, the present invention improves that in step 4, the spraying air pressure is 0.25-0.35Mpa, the atomization angle of the paint mist is 45°, and the distance between the spray gun and the glass surface is 12-14cm.

与现有技术相比,本发明的优点和积极效果在于,Compared with prior art, advantage and positive effect of the present invention are,

本发明中,通过抗氧化剂处理使亚克力半成品表面形成保护膜,进而避免了在后续对亚克力半成品表面喷漆固化过程中,因紫外线灯的照射造成亚克力半成品出现氧化现象,提高了亚克力半成品的成品良率,同时通过在喷漆之前进行静电除尘的方式,为后期的喷漆建立良好的基础,从而利于对亚克力半成品的电镀工作。In the present invention, a protective film is formed on the surface of the acrylic semi-finished product through anti-oxidant treatment, thereby avoiding the oxidation phenomenon of the acrylic semi-finished product caused by the irradiation of ultraviolet light in the subsequent process of spraying and curing the surface of the acrylic semi-finished product, and improving the finished product yield of the acrylic semi-finished product , At the same time, through the way of electrostatic dust removal before painting, a good foundation is established for the later painting, so as to facilitate the electroplating of acrylic semi-finished products.

附图说明Description of drawings

图1为本发明提出一种亚克力电镀防氧化工艺的流程图。Fig. 1 is a flow chart of an acrylic electroplating anti-oxidation process proposed by the present invention.

具体实施方式Detailed ways

为了能够更清楚地理解本发明的上述目的、特征和优点,下面结合附图和实施例对本发明做进一步说明。需要说明的是,在不冲突的情况下,本申请的实施例及实施例中的特征可以相互组合。In order to more clearly understand the above objects, features and advantages of the present invention, the present invention will be further described below in conjunction with the accompanying drawings and embodiments. It should be noted that, in the case of no conflict, the embodiments of the present application and the features in the embodiments can be combined with each other.

在下面的描述中阐述了很多具体细节以便于充分理解本发明,但是,本发明还可以采用不同于在此描述的其他方式来实施,因此,本发明并不限于下面公开说明书的具体实施例的限制。In the following description, many specific details are set forth in order to fully understand the present invention. However, the present invention can also be implemented in other ways than described here. Therefore, the present invention is not limited to the specific embodiments disclosed below. limit.

实施例一,请参阅图1,本发明提供一种技术方案:一种亚克力电镀防氧化工艺,包括以下步骤:Embodiment 1, please refer to Fig. 1, the present invention provides a technical solution: an anti-oxidation process of acrylic electroplating, comprising the following steps:

步骤一:将亚克力半成品放入清洗篮中使用清水喷淋,接着将玻璃清洗液按照10g/m2的量均匀涂抹到玻璃表面,并使用毛刷清洁7min,清洁后的亚克力半成品通过二次喷淋的方式去除表面清洗液,最后热风烘干;Step 1: Put the acrylic semi-finished product into the cleaning basket and spray it with clean water, then apply the glass cleaning solution evenly on the glass surface according to the amount of 10g/ m2 , and use a brush to clean it for 7 minutes. After cleaning, the acrylic semi-finished product is sprayed twice. Remove the surface cleaning solution by spraying, and finally dry with hot air;

步骤二:将清洗后的亚克力半成品放入除尘器中,利用静电场使气体电离从而使尘粒带电吸附到电极上收尘;Step 2: Put the cleaned acrylic semi-finished product into the dust collector, use the electrostatic field to ionize the gas so that the dust particles are charged and adsorbed to the electrode to collect dust;

步骤三:通过抗氧化剂处理使亚克力半成品表面形成保护膜,成膜后的亚克力半成品再次水洗烘干;Step 3: Form a protective film on the surface of the acrylic semi-finished product through antioxidant treatment, and then wash and dry the acrylic semi-finished product after film formation;

步骤四:将底漆和亚克力半成品真空加热到80℃,压缩空气经油水分离机、冷干机和吸附式干燥剂净化后,经空气压缩机形成气流,将底漆雾化喷涂在玻璃表面;Step 4: Vacuum heat the primer and acrylic semi-finished products to 80°C, the compressed air is purified by an oil-water separator, a cold dryer and an adsorption desiccant, and then an airflow is formed by an air compressor, and the primer is atomized and sprayed on the glass surface;

步骤五:使用紫外线对亚克力半成品光照,照射时间为8s,紫外线灯管与亚克力半成品距离为18cm;Step 5: Use ultraviolet light to illuminate the acrylic semi-finished product, the irradiation time is 8s, and the distance between the ultraviolet lamp and the acrylic semi-finished product is 18cm;

步骤六:通过电镀方式为亚克力半成品表面镀膜,膜厚为200nm,镀膜后的亚克力半成品重复步骤四为表面喷涂面漆,喷涂后再重复步骤五进行光照工作,最后亚克力半成品电镀结束。Step 6: Coat the surface of the acrylic semi-finished product by electroplating, with a film thickness of 200nm. Repeat step 4 of the coated acrylic semi-finished product to spray the topcoat on the surface.

在步骤一中,玻璃清洗液是由十二烷基苯磺酸钠、聚丙三醇酯、单硬脂酸甘油酯以及单硬脂酸甘油酯和乙二醇丁醚、柠檬酸铵、高岭土、乙醇和异丙醇与去离子水混合而成。In step one, the glass cleaning liquid is made of sodium dodecylbenzenesulfonate, polyglycerol ester, glyceryl monostearate and glyceryl monostearate and butyl glycol ether, ammonium citrate, kaolin, Ethanol and isopropanol mixed with deionized water.

在步骤一中,热风烘干的温度需控制在75℃。In step one, the temperature of hot air drying needs to be controlled at 75°C.

在步骤一中,毛刷采用静电毛刷,防静电毛刷在工业中常用作是清理灰尘的工具,比如清理SMD及PCB板的表面污物清理,产生的静电可泄放大地,它的作用机理就是利用防静电毛刷采用的导电塑料或金属材料制成手柄,防静电塑胶丝或金属丝、动物毛制成刷毛,具有防静电性能稳定,使用方便等特点。In step 1, the brush adopts an electrostatic brush. The anti-static brush is often used as a tool for cleaning dust in the industry, such as cleaning the surface dirt of SMD and PCB boards. The static electricity generated can be released to the ground. Its function The mechanism is to use the conductive plastic or metal material used in the anti-static brush to make the handle, and the anti-static plastic wire or metal wire, and animal hair to make the bristles. It has the characteristics of stable anti-static performance and convenient use.

在步骤三中,抗氧化剂处理通过浸泡或喷淋的方式,抗氧化剂浓度为5%。In the third step, the antioxidant treatment is carried out by soaking or spraying, and the antioxidant concentration is 5%.

在步骤三中,水洗采用机械手下料方式,浸泡10s后将亚克力半成品从水中取出。In the third step, the water washing adopts the method of manipulator unloading, and the acrylic semi-finished product is taken out of the water after soaking for 10 seconds.

在步骤三中,抗氧化剂是由苯并三氮唑与甲基苯并三氮唑混合而成。In the third step, the antioxidant is formed by mixing benzotriazole and tolylbenzotriazole.

在步骤四中,流水线线速为15m/min,底漆中含有重量比0.8%的附着力促进剂。In step 4, the linear speed of the assembly line is 15m/min, and the primer contains 0.8% by weight of adhesion promoter.

在步骤四中喷涂空气压力为0.25Mpa,漆雾雾化张角为45°,喷枪与玻璃表面的距离为14cm。In step 4, the spraying air pressure is 0.25Mpa, the atomization angle of the paint mist is 45°, and the distance between the spray gun and the glass surface is 14cm.

实施例二,请参阅图1,本发明提供一种技术方案:一种亚克力电镀防氧化工艺,包括以下步骤:Embodiment 2, please refer to Fig. 1, the present invention provides a technical solution: an anti-oxidation process of acrylic electroplating, comprising the following steps:

步骤一:将亚克力半成品放入清洗篮中使用清水喷淋,接着将玻璃清洗液按照16g/m2的量均匀涂抹到玻璃表面,并使用毛刷清洁8min,清洁后的亚克力半成品通过二次喷淋的方式去除表面清洗液,最后热风烘干;Step 1: Put the acrylic semi-finished product into the cleaning basket and spray it with clean water, then apply the glass cleaning solution evenly on the glass surface according to the amount of 16g/ m2 , and use a brush to clean it for 8 minutes. After cleaning, the acrylic semi-finished product is sprayed twice. Remove the surface cleaning solution by spraying, and finally dry with hot air;

步骤二:将清洗后的亚克力半成品放入除尘器中,利用静电场使气体电离从而使尘粒带电吸附到电极上收尘;Step 2: Put the cleaned acrylic semi-finished product into the dust collector, use the electrostatic field to ionize the gas so that the dust particles are charged and adsorbed to the electrode to collect dust;

步骤三:通过抗氧化剂处理使亚克力半成品表面形成保护膜,成膜后的亚克力半成品再次水洗烘干;Step 3: Form a protective film on the surface of the acrylic semi-finished product through antioxidant treatment, and then wash and dry the acrylic semi-finished product after film formation;

步骤四:将底漆和亚克力半成品真空加热到78℃,压缩空气经油水分离机、冷干机和吸附式干燥剂净化后,经空气压缩机形成气流,将底漆雾化喷涂在玻璃表面;Step 4: Vacuum heat the primer and acrylic semi-finished products to 78°C, the compressed air is purified by an oil-water separator, a cold dryer and an adsorption desiccant, and then an airflow is formed by an air compressor, and the primer is atomized and sprayed on the glass surface;

步骤五:使用紫外线对亚克力半成品光照,照射时间为7s,紫外线灯管与亚克力半成品距离为18cm;Step 5: Use ultraviolet rays to illuminate the acrylic semi-finished product, the irradiation time is 7s, and the distance between the ultraviolet lamp and the acrylic semi-finished product is 18cm;

步骤六:通过电镀方式为亚克力半成品表面镀膜,膜厚为100nm,镀膜后的亚克力半成品重复步骤四为表面喷涂面漆,喷涂后再重复步骤五进行光照工作,最后亚克力半成品电镀结束。Step 6: Coating the surface of the acrylic semi-finished product by electroplating, with a film thickness of 100nm. Repeat step 4 for the surface of the coated acrylic semi-finished product to spray the topcoat. After spraying, repeat step 5 for light work, and finally the acrylic semi-finished product is finished.

在步骤一中,玻璃清洗液是由十二烷基苯磺酸钠、聚丙三醇酯、单硬脂酸甘油酯以及单硬脂酸甘油酯和乙二醇丁醚、柠檬酸铵、高岭土、乙醇和异丙醇与去离子水混合而成。In step one, the glass cleaning liquid is made of sodium dodecylbenzenesulfonate, polyglycerol ester, glyceryl monostearate and glyceryl monostearate and butyl glycol ether, ammonium citrate, kaolin, Ethanol and isopropanol mixed with deionized water.

在步骤一中,热风烘干的温度需控制在60℃。In step one, the temperature of hot air drying needs to be controlled at 60°C.

在步骤一中,毛刷采用静电毛刷,防静电毛刷在工业中常用作是清理灰尘的工具,比如清理SMD及PCB板的表面污物清理,产生的静电可泄放大地,它的作用机理就是利用防静电毛刷采用的导电塑料或金属材料制成手柄,防静电塑胶丝或金属丝、动物毛制成刷毛,具有防静电性能稳定,使用方便等特点。In step 1, the brush adopts an electrostatic brush. The anti-static brush is often used as a tool for cleaning dust in the industry, such as cleaning the surface dirt of SMD and PCB boards. The static electricity generated can be released to the ground. Its function The mechanism is to use the conductive plastic or metal material used in the anti-static brush to make the handle, and the anti-static plastic wire or metal wire, and animal hair to make the bristles. It has the characteristics of stable anti-static performance and convenient use.

在步骤三中,抗氧化剂处理通过浸泡或喷淋的方式,抗氧化剂浓度为5%。In the third step, the antioxidant treatment is carried out by soaking or spraying, and the antioxidant concentration is 5%.

在步骤三中,水洗采用机械手下料方式,浸泡9s后将亚克力半成品从水中取出。In step 3, the water washing adopts the method of manipulator unloading, and the acrylic semi-finished product is taken out of the water after soaking for 9s.

在步骤三中,抗氧化剂是由苯并三氮唑与甲基苯并三氮唑混合而成。In the third step, the antioxidant is formed by mixing benzotriazole and tolylbenzotriazole.

在步骤四中,流水线线速为12m/min,底漆中含有重量比0.8%的附着力促进剂。In step 4, the linear speed of the assembly line is 12m/min, and the primer contains 0.8% by weight of adhesion promoter.

在步骤四中喷涂空气压力为0.35Mpa,漆雾雾化张角为45°,喷枪与玻璃表面的距离为14cm。In step 4, the spraying air pressure is 0.35Mpa, the atomization angle of the paint mist is 45°, and the distance between the spray gun and the glass surface is 14cm.

实施例三,请参阅图1,本发明提供一种技术方案:一种亚克力电镀防氧化工艺,包括以下步骤:Embodiment 3, please refer to Fig. 1, the present invention provides a technical solution: an anti-oxidation process of acrylic electroplating, including the following steps:

步骤一:将亚克力半成品放入清洗篮中使用清水喷淋,接着将玻璃清洗液按照9g/m2的量均匀涂抹到玻璃表面,并使用毛刷清洁7min,清洁后的亚克力半成品通过二次喷淋的方式去除表面清洗液,最后热风烘干;Step 1: Put the acrylic semi-finished product into the cleaning basket and spray it with clean water, then apply the glass cleaning solution evenly on the glass surface according to the amount of 9g/ m2 , and use a brush to clean it for 7 minutes. After cleaning, the acrylic semi-finished product is sprayed twice. Remove the surface cleaning solution by spraying, and finally dry with hot air;

步骤二:将清洗后的亚克力半成品放入除尘器中,利用静电场使气体电离从而使尘粒带电吸附到电极上收尘;Step 2: Put the cleaned acrylic semi-finished product into the dust collector, use the electrostatic field to ionize the gas so that the dust particles are charged and adsorbed to the electrode to collect dust;

步骤三:通过抗氧化剂处理使亚克力半成品表面形成保护膜,成膜后的亚克力半成品再次水洗烘干;Step 3: Form a protective film on the surface of the acrylic semi-finished product through antioxidant treatment, and then wash and dry the acrylic semi-finished product after film formation;

步骤四:将底漆和亚克力半成品真空加热到78℃,压缩空气经油水分离机、冷干机和吸附式干燥剂净化后,经空气压缩机形成气流,将底漆雾化喷涂在玻璃表面;Step 4: Vacuum heat the primer and acrylic semi-finished products to 78°C, the compressed air is purified by an oil-water separator, a cold dryer and an adsorption desiccant, and then an airflow is formed by an air compressor, and the primer is atomized and sprayed on the glass surface;

步骤五:使用紫外线对亚克力半成品光照,照射时间为6s,紫外线灯管与亚克力半成品距离为18cm;Step 5: Use ultraviolet rays to illuminate the acrylic semi-finished product, the irradiation time is 6s, and the distance between the ultraviolet lamp and the acrylic semi-finished product is 18cm;

步骤六:通过电镀方式为亚克力半成品表面镀膜,膜厚为80nm,镀膜后的亚克力半成品重复步骤四为表面喷涂面漆,喷涂后再重复步骤五进行光照工作,最后亚克力半成品电镀结束。Step 6: Coat the surface of the acrylic semi-finished product by electroplating, with a film thickness of 80nm. Repeat step 4 for the surface of the coated acrylic semi-finished product to spray the topcoat on the surface.

在步骤一中,玻璃清洗液是由十二烷基苯磺酸钠、聚丙三醇酯、单硬脂酸甘油酯以及单硬脂酸甘油酯和乙二醇丁醚、柠檬酸铵、高岭土、乙醇和异丙醇与去离子水混合而成。In step one, the glass cleaning liquid is made of sodium dodecylbenzenesulfonate, polyglycerol ester, glyceryl monostearate and glyceryl monostearate and butyl glycol ether, ammonium citrate, kaolin, Ethanol and isopropanol mixed with deionized water.

在步骤一中,热风烘干的温度需控制在50℃。In step one, the temperature of hot air drying needs to be controlled at 50°C.

在步骤一中,毛刷采用静电毛刷,防静电毛刷在工业中常用作是清理灰尘的工具,比如清理SMD及PCB板的表面污物清理,产生的静电可泄放大地,它的作用机理就是利用防静电毛刷采用的导电塑料或金属材料制成手柄,防静电塑胶丝或金属丝、动物毛制成刷毛,具有防静电性能稳定,使用方便等特点。In step 1, the brush adopts an electrostatic brush. The anti-static brush is often used as a tool for cleaning dust in the industry, such as cleaning the surface dirt of SMD and PCB boards. The static electricity generated can be released to the ground. Its function The mechanism is to use the conductive plastic or metal material used in the anti-static brush to make the handle, and the anti-static plastic wire or metal wire, and animal hair to make the bristles. It has the characteristics of stable anti-static performance and convenient use.

在步骤三中,抗氧化剂处理通过浸泡或喷淋的方式,抗氧化剂浓度为3%。In the third step, the antioxidant treatment is carried out by soaking or spraying, and the antioxidant concentration is 3%.

在步骤三中,水洗采用机械手下料方式,浸泡8s后将亚克力半成品从水中取出。In step 3, the water washing adopts the method of manipulator unloading, and the acrylic semi-finished product is taken out of the water after soaking for 8s.

在步骤三中,抗氧化剂是由苯并三氮唑与甲基苯并三氮唑混合而成。In the third step, the antioxidant is formed by mixing benzotriazole and tolylbenzotriazole.

在步骤四中,流水线线速为11m/min,底漆中含有重量比0.8%的附着力促进剂。In step 4, the linear speed of the assembly line is 11 m/min, and the primer contains 0.8% by weight of adhesion promoter.

在步骤四中喷涂空气压力为0.25Mpa,漆雾雾化张角为45°,喷枪与玻璃表面的距离为12cm。In step 4, the spraying air pressure is 0.25Mpa, the atomization angle of the paint mist is 45°, and the distance between the spray gun and the glass surface is 12cm.

本发明中,通过抗氧化剂处理使亚克力半成品表面形成保护膜,进而避免了在后续对亚克力半成品表面喷漆固化过程中,因紫外线灯的照射造成亚克力半成品出现氧化现象,提高了亚克力半成品的成品良率,同时通过在喷漆之前进行静电除尘的方式,为后期的喷漆建立良好的基础,从而利于对亚克力半成品的电镀工作。In the present invention, a protective film is formed on the surface of the acrylic semi-finished product through anti-oxidant treatment, thereby avoiding the oxidation phenomenon of the acrylic semi-finished product caused by the irradiation of ultraviolet light in the subsequent process of spraying and curing the surface of the acrylic semi-finished product, and improving the finished product yield of the acrylic semi-finished product , At the same time, through the way of electrostatic dust removal before painting, a good foundation is established for the later painting, so as to facilitate the electroplating of acrylic semi-finished products.

以上所述,仅是本发明的较佳实施例而已,并非是对本发明作其它形式的限制,任何熟悉本专业的技术人员可能利用上述揭示的技术内容加以变更或改型为等同变化的等效实施例应用于其它领域,但是凡是未脱离本发明技术方案内容,依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与改型,仍属于本发明技术方案的保护范围。The above is only a preferred embodiment of the present invention, and is not intended to limit the present invention to other forms. Any skilled person who is familiar with this profession may use the technical content disclosed above to change or modify the equivalent of equivalent changes. The embodiments are applied to other fields, but any simple modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention still belong to the protection scope of the technical solutions of the present invention without departing from the content of the technical solutions of the present invention.

Claims (9)

1.一种亚克力电镀防氧化工艺,其特征在于,包括以下步骤:1. an acrylic electroplating anti-oxidation process, is characterized in that, comprises the following steps: 步骤一:将亚克力半成品放入清洗篮中使用清水喷淋,接着将玻璃清洗液按照8-20g/m2的量均匀涂抹到玻璃表面,并使用毛刷清洁7-9min,清洁后的亚克力半成品通过二次喷淋的方式去除表面清洗液,最后热风烘干;Step 1: Put the acrylic semi-finished product into the cleaning basket and spray it with clean water, then apply the glass cleaning solution evenly on the glass surface according to the amount of 8-20g/ m2 , and use a brush to clean it for 7-9min, the cleaned acrylic semi-finished product Remove the surface cleaning liquid by means of secondary spraying, and finally dry with hot air; 步骤二:将清洗后的亚克力半成品放入除尘器中,利用静电场使气体电离从而使尘粒带电吸附到电极上收尘;Step 2: Put the cleaned acrylic semi-finished product into the dust collector, use the electrostatic field to ionize the gas so that the dust particles are charged and adsorbed to the electrode to collect dust; 步骤三:通过抗氧化剂处理使亚克力半成品表面形成保护膜,成膜后的亚克力半成品再次水洗烘干;Step 3: Form a protective film on the surface of the acrylic semi-finished product through antioxidant treatment, and then wash and dry the acrylic semi-finished product after film formation; 步骤四:将底漆和亚克力半成品真空加热到75-80℃,压缩空气经油水分离机、冷干机和吸附式干燥剂净化后,经空气压缩机形成气流,将底漆雾化喷涂在玻璃表面;Step 4: Heat the primer and acrylic semi-finished products to 75-80°C in vacuum. After the compressed air is purified by an oil-water separator, a cold dryer and an adsorption desiccant, an airflow is formed by an air compressor, and the primer is atomized and sprayed on the glass. surface; 步骤五:使用紫外线对亚克力半成品光照,照射时间为6-8s,紫外线灯管与亚克力半成品距离为18cm;Step 5: Use ultraviolet rays to illuminate the acrylic semi-finished product, the irradiation time is 6-8s, and the distance between the ultraviolet lamp and the acrylic semi-finished product is 18cm; 步骤六:通过电镀方式为亚克力半成品表面镀膜,膜厚为20nm-500nm,镀膜后的亚克力半成品重复步骤四为表面喷涂面漆,喷涂后再重复步骤五进行光照工作,最后亚克力半成品电镀结束。Step 6: Coat the surface of the acrylic semi-finished product by electroplating, with a film thickness of 20nm-500nm. Repeat step 4 for the surface of the coated acrylic semi-finished product to spray the topcoat on the surface. 2.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤一中,玻璃清洗液是由十二烷基苯磺酸钠、聚丙三醇酯、单硬脂酸甘油酯以及单硬脂酸甘油酯和乙二醇丁醚、柠檬酸铵、高岭土、乙醇和异丙醇与去离子水混合而成。2. The acrylic electroplating anti-oxidation process according to claim 1 is characterized in that: in step 1, the glass cleaning solution is composed of sodium dodecylbenzenesulfonate, polyglycerol ester, glyceryl monostearate and Glyceryl monostearate and butyl glycol ether, ammonium citrate, kaolin clay, ethanol and isopropanol mixed with deionized water. 3.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤一中,热风烘干的温度需控制在50-75℃。3. The anti-oxidation process of acrylic electroplating according to claim 1, characterized in that: in step 1, the temperature of hot air drying needs to be controlled at 50-75°C. 4.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤一中,所述毛刷采用静电毛刷。4. The anti-oxidation process of acrylic electroplating according to claim 1, characterized in that: in step 1, the brush is an electrostatic brush. 5.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤三中,抗氧化剂处理通过浸泡或喷淋的方式,抗氧化剂浓度为2-5%。5. The anti-oxidation process of acrylic electroplating according to claim 1, characterized in that: in step 3, the antioxidant treatment is by soaking or spraying, and the antioxidant concentration is 2-5%. 6.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤三中,水洗采用机械手下料方式,浸泡8-10s后将亚克力半成品从水中取出。6. The anti-oxidation process of acrylic electroplating according to claim 1, characterized in that: in step 3, the water washing adopts the method of manipulator unloading, and the acrylic semi-finished product is taken out of the water after soaking for 8-10s. 7.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤三中,抗氧化剂是由苯并三氮唑与甲基苯并三氮唑混合而成。7. The anti-oxidation process of acrylic electroplating according to claim 1, characterized in that: in step 3, the antioxidant is formed by mixing benzotriazole and tolylbenzotriazole. 8.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤四中,流水线线速为10-15m/min,所述底漆中含有重量比0.8%的附着力促进剂。8. The anti-oxidation process of acrylic electroplating according to claim 1, characterized in that: in step 4, the line speed is 10-15m/min, and the primer contains an adhesion promoter of 0.8% by weight. 9.根据权利要求1所述的亚克力电镀防氧化工艺,其特征在于:在步骤四中喷涂空气压力为0.25-0.35Mpa,漆雾雾化张角为45°,喷枪与玻璃表面的距离为12-14cm。9. The acrylic electroplating anti-oxidation process according to claim 1, characterized in that: in step 4, the spraying air pressure is 0.25-0.35Mpa, the atomization angle of the paint mist is 45°, and the distance between the spray gun and the glass surface is 12 -14cm.
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CN102276164A (en) * 2011-07-21 2011-12-14 杭州三晶工艺塑料有限公司 Process for performing vacuum plating on glass
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CN108620300A (en) * 2017-03-20 2018-10-09 合肥香炉立鼎电子科技有限公司 3D solid coating process flows
CN108690746A (en) * 2018-06-20 2018-10-23 孙康娴 A kind of Glass cleaner compositions and cleaning glass method
WO2019233042A1 (en) * 2018-06-05 2019-12-12 泰兴汤臣压克力有限公司 Preparation method for super-strong anti-ultraviolet special-effect colored acrylic plate

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102276164A (en) * 2011-07-21 2011-12-14 杭州三晶工艺塑料有限公司 Process for performing vacuum plating on glass
CN105921387A (en) * 2016-04-29 2016-09-07 南京晨光艺术工程有限公司 Coating process of outer surface of sculpture
CN108620300A (en) * 2017-03-20 2018-10-09 合肥香炉立鼎电子科技有限公司 3D solid coating process flows
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