CN116427180A - Warp knitting velvet fabric and preparation method thereof - Google Patents

Warp knitting velvet fabric and preparation method thereof Download PDF

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CN116427180A
CN116427180A CN202310451091.XA CN202310451091A CN116427180A CN 116427180 A CN116427180 A CN 116427180A CN 202310451091 A CN202310451091 A CN 202310451091A CN 116427180 A CN116427180 A CN 116427180A
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warp
blended
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fleece fabric
preparation
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CN116427180B (en
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金祖法
沈月香
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Hangzhou Zhongyi Cloth Industry Co ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0009Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/38Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C11/00Teasing, napping or otherwise roughening or raising pile of textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/128Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/126Permeability to liquids, absorption
    • D06N2209/128Non-permeable
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1685Wear resistance
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/10Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyurethanes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及纺织技术领域,尤其是涉及一种经编绒面料及其制备方法。其中,一种经编绒面料的制备方法,其制备过程包括:混纺包覆线的制备、织造、磨毛及整理,混纺包覆线经纺织制备得到坯布;磨毛后的坯布经整理液处理后,在坯布上形成硅氧膜层,降低了经编绒面料的表面张力及使得经编绒面料更柔顺,通过在经混纺包覆线中添加反应性纤维,使得硅氧膜层与混纺包覆线之间具有较好的结合强度,通过在混纺包覆线中引入氨纶纱,使得附有硅氧膜层的混纺包覆线的绒毛层叠的更密集,进而使得经编绒面料具有优异的防水性能及耐磨性能。The invention relates to the technical field of textiles, in particular to a warp-knitted fleece fabric and a preparation method thereof. Among them, a method for preparing warp-knitted velvet fabrics, the preparation process comprising: preparation of blended covered threads, weaving, sanding and finishing, blended covered threads are prepared by weaving to obtain gray cloth; gray cloth after sanding is treated with finishing liquid Finally, a silicon-oxygen film layer is formed on the gray cloth, which reduces the surface tension of the warp-knitted fleece fabric and makes the warp-knitted fleece fabric more supple. There is a good bonding strength between the covered threads. By introducing spandex yarn into the blended covered thread, the fluff of the blended covered thread with a silicone film layer is more densely stacked, which in turn makes the warp-knitted fleece fabric have excellent Waterproof performance and wear resistance.

Description

一种经编绒面料及其制备方法A kind of warp knitted fleece fabric and preparation method thereof

技术领域technical field

本发明涉及纺织技术领域,尤其是涉及一种经编绒面料及其制备方法。The invention relates to the technical field of textiles, in particular to a warp-knitted fleece fabric and a preparation method thereof.

背景技术Background technique

经编是属于针织领域的一种纺织工艺,即为用一组或几组平行排列的纱线于经向上喂入机器的工作针上,同时成圈而形成针织物;绒面料由起毛机将延展纤维拉断,形成毛绒;由于经编绒面料质地柔软、细腻、具有独特质感,经常被用作为沙发布面料,但是一般经编绒面料的防水性较差,在经编绒面料表面有水的情况下,水很容易渗入并形成污渍。Warp knitting is a textile process belonging to the field of knitting, which is to use one or several groups of parallel yarns on the working needles of the warp feeding machine to form knitted fabrics at the same time; The extended fibers are broken to form plush; because the warp-knitted fleece fabric is soft, delicate, and has a unique texture, it is often used as a sofa release fabric, but the waterproofness of the warp-knitted fleece fabric is generally poor, and there are some spots on the surface of the warp-knitted fleece fabric. In the case of water, water can easily seep in and form stains.

发明内容Contents of the invention

为了改善现有经编绒面料防水性较差的问题,本申请提供了一种经编绒面料及其制备方法。In order to improve the problem of poor water resistance of existing warp-knitted fleece fabrics, the application provides a warp-knitted fleece fabric and a preparation method thereof.

第一方面,本申请提供一种经编绒面料的制备方法,其制备过程如下:In a first aspect, the application provides a method for preparing a warp-knitted fleece fabric, the preparation process of which is as follows:

混纺包覆线的制备:将质量比为1:(0.5-1.5)的涤纶纤维和反应性纤维经混纺后制备得到涤纶混纺纱;然后将涤纶混纺纱包覆在氨纶纱上经假捻加工制备得到混纺包覆线,其中,涤纶混纺纱与氨纶纱的质量比为(4-6):1;Preparation of blended covered yarn: polyester fiber and reactive fiber with a mass ratio of 1: (0.5-1.5) are blended to prepare polyester blended yarn; then the polyester blended yarn is covered on spandex yarn by false twisting Processing and preparing to obtain a blended covered thread, wherein the mass ratio of the polyester blended yarn to the spandex yarn is (4-6):1;

织造:将混纺包覆线经织造形成坯布,织造时混纺包覆线的整经张力为1.4-1.8g/tex;Weaving: weaving the blended covered thread to form gray cloth, the warping tension of the blended covered thread is 1.4-1.8g/tex during weaving;

磨毛:对坯布的一面进行磨毛,使得坯布表层形成毛绒;Sanding: Sanding one side of the gray cloth to make the surface of the gray cloth form plush;

整理:对磨毛后的坯布使用60-80℃的整理液进行浸渍处理2-4h,浴比为(8-10):1;浸渍后沥干整理液,置于150-170℃的温度下加温10-15min,然后经水洗、皂洗、烘干后制备得到经编绒面料;Finishing: Use 60-80°C finishing solution to impregnate the sanded gray cloth for 2-4 hours, the liquor ratio is (8-10):1; drain the finishing solution after dipping, and place it at a temperature of 150-170°C Heating for 10-15 minutes, then washing, soaping, and drying to prepare warp-knitted fleece fabrics;

所述整理液的原料包括2-5份的聚甲基氢硅氧烷、2-3份的羟基封端二甲基羟基硅油、0.2-0.5份的聚醚改性聚硅氧烷、4-6份的烷基酚聚氧乙烯醚、0.06-0.1份的Pt催化剂及1000份的水。The raw materials of the finishing liquid include 2-5 parts of polymethylhydrogen siloxane, 2-3 parts of hydroxyl-terminated dimethyl hydroxy silicone oil, 0.2-0.5 parts of polyether modified polysiloxane, 4- 6 parts of alkylphenol polyoxyethylene ether, 0.06-0.1 part of Pt catalyst and 1000 parts of water.

通过采用上述技术方案,经整理液浸渍坯布,整理液在坯布上及坯布的绒毛上铺展,在高温下羟基封端二甲基羟基硅油及聚甲基氢硅氧烷发生反应,在坯布及绒毛上形成硅氧膜层,硅氧膜层降低了经编绒面料的表面张力以及使得经编绒面料更柔顺,聚甲基氢硅氧烷增强了反应形成的硅氧涂层与经编绒面料具有较好的结合强度,进而使得经编绒面料具有优异的防水性能及耐磨性能。By adopting the above technical scheme, the gray cloth is impregnated with the finishing liquid, and the finishing liquid spreads on the gray cloth and the fluff of the gray cloth, and the hydroxyl-terminated dimethyl hydroxy silicone oil and polymethylhydrogensiloxane react at high temperature, and the gray cloth and the fluff A silicone film layer is formed on the surface. The silicone film layer reduces the surface tension of the warp-knitted fleece fabric and makes the warp-knitted fleece fabric more supple. Polymethylhydrogen siloxane enhances the reaction between the silicone coating and the warp-knitted fleece fabric. It has good bonding strength, which makes the warp-knitted fleece fabric have excellent waterproof performance and wear resistance.

另外,由于聚甲基氢硅氧烷含有活泼氢,使得经聚甲基氢硅氧烷处理的面料容易发黄,本申请中,采用羟基封端二甲基羟基硅油与聚甲基氢硅氧烷配伍使用,增强经编绒面料的防水性、柔顺性及耐磨性能,同时改善经聚甲基氢硅氧烷处理的面料容易发黄问题。In addition, since polymethylhydrogensiloxane contains active hydrogen, the fabrics treated with polymethylhydrogensiloxane are prone to yellowing. In this application, hydroxyl-terminated dimethyl hydroxy silicone oil and polymethylhydrogensiloxane are used It can enhance the waterproofness, flexibility and abrasion resistance of warp-knitted fleece fabrics, and at the same time improve the yellowing problem of fabrics treated with polymethylhydrogensiloxane.

在本申请中,经编绒面料中采用氨纶纱,设置混纺包覆线整经时的张力1.4-1.8g/tex,使得制备得到的混纺包覆线具有一定弹性,使附有硅氧涂层的混纺包覆线的绒毛更密集,进一步提升了经编绒面料的防水性能及耐摩擦性能。In this application, spandex yarn is used in the warp-knitted fleece fabric, and the tension of the blended covered thread during warping is set to 1.4-1.8g/tex, so that the prepared blended covered thread has a certain degree of elasticity, and the silicon oxide coating is attached. The fluff of the blended covered thread is denser, which further improves the waterproof performance and friction resistance of the warp knitted fleece fabric.

优选的,所述反应性纤维为羊毛、蚕丝、粘胶纤维、棉纤维、麻纤维、莫代尔纤维中的一种。Preferably, the reactive fiber is one of wool, silk, viscose fiber, cotton fiber, hemp fiber and modal fiber.

通过采用上述技术方案,优选的反应性纤维与整理液配伍使用,增强了硅氧膜层与经编绒面料的结合强度,使得经编绒面料具有优异的耐摩擦性能及防水性能。By adopting the above technical scheme, the preferred reactive fiber is used in combination with the finishing solution, which enhances the bonding strength between the silicone film layer and the warp-knitted fleece fabric, making the warp-knitted fleece fabric have excellent friction resistance and waterproof performance.

优选的,所述浸渍处理包括第一次浸渍及第二次浸渍,所述第一次浸渍时间1-2h,所述第二次浸渍时间1-2h,所述坯布经第一次浸渍后静置8-12min,然后进行第二次浸渍。Preferably, the dipping treatment includes the first dipping and the second dipping, the first dipping time is 1-2h, the second dipping time is 1-2h, and the gray cloth is statically soaked after the first dipping Set aside for 8-12min, and then carry out the second impregnation.

通过采用上述技术方案,增加整理液在经编绒面料上存留的量,提升硅氧膜层的致密性,进而提升经编绒面料的耐摩擦性能及柔顺性能。By adopting the above technical scheme, the amount of finishing liquid remaining on the warp-knitted fleece fabric is increased, the compactness of the silicone film layer is improved, and the friction resistance and softness of the warp-knitted fleece fabric are improved.

优选的,所述整理液还包括2-6份的流平剂及0.06-0.1份的引发剂,所述流平剂为全氟辛基丙基丙烯酸酯、全氟环己基丙烯酸甲酯、丙烯酸烃类中的一种。Preferably, the finishing liquid also includes 2-6 parts of leveling agent and 0.06-0.1 part of initiator, and the leveling agent is perfluorooctyl propyl acrylate, perfluorocyclohexyl methyl acrylate, acrylic acid one of the hydrocarbons.

通过采用上述技术方案,在整理液中采用流平剂提升了硅氧膜层的质量,进一步,提升经编绒面料的防水性能及耐摩擦性能。By adopting the above technical scheme, the leveling agent is used in the finishing solution to improve the quality of the silicone film layer, and further, the waterproof performance and friction resistance of the warp-knitted fleece fabric are improved.

优选的,所述流平剂为丙烯酸烃类。Preferably, the leveling agent is acrylic hydrocarbon.

通过采用上述技术方案,丙烯酸烃类物质与全氟辛基丙基丙烯酸酯及全氟环己基丙烯酸甲酯相比,分子链短,分子链上没有大分子基团,更容易增强硅氧膜层的致密性,流平剂反应形成高分子网络进而提升硅氧涂层的致密性,进一步提升经编绒面料的防水性能及耐摩擦性能。By adopting the above technical scheme, compared with perfluorooctyl propyl acrylate and perfluorocyclohexyl methyl acrylate, acrylic hydrocarbons have shorter molecular chains and no macromolecular groups on the molecular chains, making it easier to strengthen the silicone film layer The leveling agent reacts to form a polymer network to improve the density of the silicone coating, and further improves the waterproof performance and friction resistance of the warp-knitted fleece fabric.

优选的,所述整理液还包括0.4-0.8份的膨润土及0.1-0.2份的PTFE微粉。Preferably, the finishing solution further includes 0.4-0.8 parts of bentonite and 0.1-0.2 parts of PTFE micropowder.

通过采用上述技术方案,膨润土与PTFE微粉配伍使用,膨润土提高PTFE微粉的分散性及增强整理液形成膜层的强度,进一步提升经编绒面料的耐摩擦性能及防水性能。By adopting the above technical scheme, bentonite is used in combination with PTFE micropowder, and bentonite improves the dispersibility of PTFE micropowder and enhances the strength of the film layer formed by the finishing solution, further improving the friction resistance and waterproof performance of the warp-knitted fleece fabric.

优选的,所述混纺包覆线在织造前使用微胶囊浸渍液在超声18-22KHz条件下处理4-6h,浴比为1:(8-10),所述微胶囊浸渍液的温度为65-85℃;Preferably, the blended covered wire is treated with microcapsule impregnating liquid for 4-6 hours under the condition of ultrasonic 18-22KHz before weaving, the liquor ratio is 1:(8-10), and the temperature of the microcapsule impregnating liquid is 65 -85°C;

所述微胶囊浸渍液的制备过程:将原料混合液升温到60-70℃、在搅拌速度为4000-7000r/min的条件下进行乳化搅拌30-40min;加入0.1-0.3份的盐酸,在温度60-70℃,在反应搅拌速度400-1000r/min条件下反应24-60h,制备得到微胶囊浸渍液;The preparation process of the microcapsule impregnating liquid: heat the raw material mixture to 60-70°C, emulsify and stir for 30-40min at a stirring speed of 4000-7000r/min; add 0.1-0.3 parts of hydrochloric acid, 60-70°C, react for 24-60h under the reaction stirring speed of 400-1000r/min, and prepare the microcapsule impregnation solution;

所述原料混合液包括2-4份的硬脂酸正丁酯、1-3份的十二烷基硫酸钠、4-8份的钛酸四丁酯、70-76份的去离子水及35-40份的乙醇。The raw material mixture comprises 2-4 parts of n-butyl stearate, 1-3 parts of sodium lauryl sulfate, 4-8 parts of tetrabutyl titanate, 70-76 parts of deionized water and 35-40 parts of ethanol.

通过上述技术方案,经过微胶囊浸渍液处理,在混纺包覆线中引入微胶囊,含有微胶囊的经编绒面料在使用中缓释硬脂酸丁酯,硬脂酸丁酯迁移到经编面料的表面,进一步,提升经编绒面料防水性能,并且增强经编绒面料防水性能的耐水洗性能,同时微胶囊增提升编绒面料的弹性,进而提升经编绒面料的耐摩擦性能。Through the above technical scheme, microcapsules are introduced into the blended coated thread after treatment with the microcapsule impregnation solution, and the warp-knitted fleece fabric containing the microcapsules releases butyl stearate slowly during use, and the butyl stearate migrates to the warp-knitted yarn. The surface of the fabric further improves the waterproof performance of the warp-knitted fleece fabric, and enhances the water-resistant performance of the warp-knitted fleece fabric. At the same time, the microcapsules increase the elasticity of the knitted fleece fabric, thereby improving the friction resistance of the warp-knitted fleece fabric.

整理液与微胶囊配伍使用,整理液形成的膜层增强微胶囊的强度,进一步,提升经编绒面料具有长效的防水性能及耐摩擦性能。The finishing liquid is used in combination with the microcapsules, and the film layer formed by the finishing liquid enhances the strength of the microcapsules, and further improves the long-term waterproof performance and friction resistance of the warp-knitted fleece fabric.

优选的,所述原料混合液还包括3-6份的羟基封端二甲基羟基硅油。Preferably, the raw material mixture also includes 3-6 parts of hydroxyl-terminated dimethyl hydroxy silicone oil.

通过上述技术方案,部分羟基封端二甲基羟基硅油连接在微胶囊的膜层上,使得微胶囊具有一定的疏水性能;另外,微胶囊缓释的硬脂酸正丁酯与羟基封端二甲基羟基硅油配伍使用,迁移到经编绒面料上整理液形成的膜层上,进一步提升经编绒面料的防水性能及耐磨性能。Through the above technical scheme, part of the hydroxyl-terminated dimethyl hydroxy silicone oil is connected to the film layer of the microcapsules, so that the microcapsules have certain hydrophobic properties; Methyl hydroxy silicone oil is used in combination to migrate to the film layer formed by the finishing solution on the warp-knitted fleece fabric to further improve the waterproof and wear-resistant performance of the warp-knitted fleece fabric.

优选的,所述乳化时搅拌速度为5000-6000r/min,加入盐酸后的搅拌速度为600-700r/min,反应温度为63-65℃,反应为45-50h。Preferably, the stirring speed during emulsification is 5000-6000r/min, the stirring speed after adding hydrochloric acid is 600-700r/min, the reaction temperature is 63-65°C, and the reaction time is 45-50h.

通过上述技术方案,乳化时搅拌速度太快,会导致微胶囊浸渍液中的气泡太多,导致微胶囊浸渍液中微胶囊的密度变小,使得浸渍微胶囊浸渍液后的混纺包覆线中的微胶囊的数量减少;乳化时搅拌速度太慢,微胶囊浸渍液中的乳胶粒粒径太大,导致浸入经编绒面料中微胶囊数量减少;加入盐酸后的搅拌速度太低,可能微胶囊间会发生黏连,微胶囊的粒径变大,加入盐酸后的搅拌速度太高,可能影响微胶囊的成膜,导致制备得到的微胶囊强度不足,使得经编绒面料的水洗后的防水性能变差。Through the above technical scheme, if the stirring speed is too fast during emulsification, there will be too many air bubbles in the microcapsule impregnating liquid, resulting in a decrease in the density of the microcapsules in the microcapsule impregnating liquid. The number of microcapsules is reduced; the stirring speed is too slow during emulsification, and the latex particle size in the microcapsule impregnation solution is too large, resulting in a decrease in the number of microcapsules immersed in the warp-knitted fleece fabric; the stirring speed after adding hydrochloric acid is too low, which may Adhesion will occur between the capsules, the particle size of the microcapsules will become larger, and the stirring speed after adding hydrochloric acid is too high, which may affect the film-forming of the microcapsules, resulting in insufficient strength of the prepared microcapsules, so that the warp-knitted fleece fabric after washing Water resistance deteriorates.

微胶囊浸渍液的制备过程中,合适的搅拌速度配伍合适的反应时间及反应温度,使得制备得到的微胶囊具有较小的粒径及较高的强度,使得经编绒面料具有优异的防水性能变及耐磨性能。In the preparation process of microcapsule impregnating liquid, suitable stirring speed is compatible with suitable reaction time and reaction temperature, so that the prepared microcapsules have smaller particle size and higher strength, so that the warp-knitted fleece fabric has excellent waterproof performance Variable and wear resistance.

第二方面,本申请提供一种经编绒面料。In a second aspect, the present application provides a warp-knitted fleece fabric.

一种经编绒面料,采用本申请中任一项经编绒面料的制备方法制备获得。A warp-knitted fleece fabric, prepared by any one of the warp-knitted fleece fabric preparation methods in the present application.

一种经编绒面料,不仅质地柔软、细腻、有独特质感,还具有优异的耐摩擦性能及防水性能,为沙发布面料的优选布料。A kind of warp-knitted fleece fabric, which is not only soft, fine and unique in texture, but also has excellent friction resistance and waterproof performance. It is the preferred fabric for sofa fabrics.

综上所述,本申请具有以下有益效果:In summary, the application has the following beneficial effects:

1、一种经编绒面料的制备过程包括:混纺包覆线的制备、织造、磨毛及整理,其中,混纺包覆线经纺织制备得到坯布;磨毛后的坯布经整理液处理后,在坯布上形成硅氧膜层,降低了经编绒面料的表面张力及使得经编绒面料更柔顺,通过在经混纺包覆线中添加反应性纤维,使得硅氧膜层与混纺包覆线之间具有较好的结合强度,通过在混纺包覆线中引入氨纶纱,使得附有硅氧膜层的混纺包覆线的绒毛层叠的更密集,进而使得经编绒面料具有优异的防水性能及耐磨性能。1. The preparation process of a warp-knitted velvet fabric comprises: preparation, weaving, sanding and finishing of the blended covered thread, wherein the blended covered thread is prepared by weaving to obtain a gray cloth; the sanded gray cloth is treated with a finishing solution, A silicone film layer is formed on the gray fabric, which reduces the surface tension of the warp-knitted fleece fabric and makes the warp-knitted fleece fabric more supple. By adding reactive fibers to the blended covering thread, the silicone film layer and the blended covering thread There is a good bonding strength between them. By introducing spandex yarn into the blended covering thread, the fluff of the blended covering thread with a silicone film layer is more densely stacked, so that the warp-knitted fleece fabric has excellent waterproof performance. and wear resistance.

2、通过在整理液中采用流平剂、膨润土与PTFE微粉配伍使用,相互协同增强了硅氧膜层的致密性及耐磨性,进一步,提升经编绒面料的防水性能及耐摩擦性能。2. Through the use of leveling agent, bentonite and PTFE micropowder in the finishing liquid, the compactness and wear resistance of the silicone film layer are synergistically enhanced, and the waterproof performance and friction resistance of the warp-knitted fleece fabric are further improved.

3、通过采用微胶囊浸渍液处理混纺包覆线,在混纺包覆线中引入微胶囊,整理液与微胶囊配伍使用,整理液形成的涂层增强微胶囊的强度,微胶囊使得经编绒面料具有一定弹性且缓释硬脂酸正丁酯与羟基封端二甲基羟基硅油,进一步增强经编绒面料的防水性能及耐摩擦性能。3. By using the microcapsule impregnating liquid to treat the blended coated thread, introducing microcapsules into the blended covered thread, the finishing liquid and the microcapsules are used together, the coating formed by the finishing liquid enhances the strength of the microcapsules, and the microcapsules make the warp knitted fleece The fabric has a certain degree of elasticity and slow-releases n-butyl stearate and hydroxyl-terminated dimethyl hydroxy silicone oil, which further enhances the waterproof performance and friction resistance of the warp-knitted fleece fabric.

具体实施方式Detailed ways

原料和/或中间体的制备例原料:PTFE微粉(粒径1-3μm)、羟基封端二甲基羟基硅油(粘度:20-40mm2/s)、聚甲基氢硅氧烷(粘度:10-50mm2/s)、PTFE微粉(平均粒径5μm)、膨润土(平均粒径13μm)、氨纶纱(30±5D)、涤纶纤维(3.5D、48mm)、棉纤维(39mm)、粘胶纤维(1.2D、38mm)、竹纤维(2.0D、65mm)。Preparation example of raw materials and/or intermediates Raw materials: PTFE micropowder (particle size 1-3μm), hydroxyl-terminated dimethyl hydroxy silicone oil (viscosity: 20-40mm2/s), polymethylhydrogensiloxane (viscosity: 10 -50mm2/s), PTFE powder (average particle size 5μm), bentonite (average particle size 13μm), spandex yarn (30±5D), polyester fiber (3.5D, 48mm), cotton fiber (39mm), viscose fiber ( 1.2D, 38mm), bamboo fiber (2.0D, 65mm).

制备例1Preparation Example 1

一种微胶囊浸渍液,使用的原料成分如表1,制备步骤如下:A kind of microcapsule dipping liquid, the raw material composition used is as table 1, and preparation steps are as follows:

微胶囊浸渍液的制备过程:将原料混合液升温到70℃、在搅拌速度为4000r/min的条件下进行乳化,乳化搅拌时间30min;加入质量分数为37.5%的盐酸溶液226mL,(盐酸溶液中约含有0.1kg的盐酸),在反应温度70℃,搅拌速度400r/min的条件下反应24h,制备得到微胶囊浸渍液。The preparation process of the microcapsule impregnation solution: the raw material mixture is heated to 70°C, emulsified under the condition of a stirring speed of 4000r/min, and the emulsification stirring time is 30min; adding 226mL of hydrochloric acid solution with a mass fraction of 37.5%, (in the hydrochloric acid solution contains about 0.1kg of hydrochloric acid), reacted for 24 hours at a reaction temperature of 70°C and a stirring speed of 400r/min to prepare a microcapsule impregnation solution.

其中,质量分数为37%的盐酸溶液的密度1.179g/cm3Among them, the density of hydrochloric acid solution with a mass fraction of 37% is 1.179g/cm 3 .

制备例2-4Preparation example 2-4

一种微胶囊浸渍液,与制备例1的区别在于:微胶囊浸渍液使用的原料种类不同,微胶囊浸渍液的制备工艺不同,具体如表1。A microcapsule impregnating solution, the difference from Preparation Example 1 is that: the types of raw materials used in the microcapsule impregnating solution are different, and the preparation process of the microcapsule impregnating solution is different, as shown in Table 1 for details.

表1制备例1-4中微胶囊浸渍液使用的原料种类,微胶囊浸渍液的制备工艺的设置列表The kind of raw material that microcapsule impregnating liquid uses in table 1 preparation example 1-4, the setting list of the preparation process of microcapsule impregnating liquid

Figure BDA0004197425350000041
Figure BDA0004197425350000041

Figure BDA0004197425350000051
Figure BDA0004197425350000051

制备例5-9Preparation example 5-9

一种微胶囊浸渍液,与制备例1的区别在于:微胶囊浸渍液的制备工艺不同,具体如表2。A microcapsule impregnating solution, the difference from Preparation Example 1 is that the preparation process of the microcapsule impregnating solution is different, as shown in Table 2.

表2制备例5-9及制备例1中微胶囊浸渍液的制备工艺设置列表Table 2 preparation example 5-9 and the preparation process setting list of microcapsule impregnating liquid in preparation example 1

区分distinguish 制备例1Preparation Example 1 制备例5Preparation Example 5 制备例6Preparation Example 6 制备例7Preparation Example 7 制备例8Preparation example 8 制备例9Preparation Example 9 乳化的搅拌速度/(r/min)Stirring speed of emulsification/(r/min) 40004000 50005000 60006000 70007000 40004000 70007000 反应的搅拌速度/(r/min)Stirring speed of reaction/(r/min) 400400 700700 600600 10001000 400400 10001000 反应温度/℃Reaction temperature/℃ 7070 6565 6363 6060 6565 6363 反应时间/hReaction time/h 24twenty four 4545 5050 6060 4545 5050

制备例10Preparation Example 10

一种整理液,其原料成分如表3,制备步骤如下:A kind of finishing liquid, its raw material composition is as table 3, and preparation steps are as follows:

将整理液的原料混合后,在搅拌速度为4000r/min的条件下搅拌时间20min,制备得到整理液。After mixing the raw materials of the finishing liquid, the stirring time was 20 min under the condition of a stirring speed of 4000 r/min to prepare the finishing liquid.

制备例11-14Preparation Examples 11-14

一种整理液,与制备例1的区别在于:整理液的原料种类不同,制备工艺不同,具体如表3。The difference between a finishing solution and Preparation Example 1 lies in that the raw materials of the finishing solution are different, and the preparation process is different, as shown in Table 3 for details.

表3制备例10-14的整理液的原料种类,制备工艺的设置列表The raw material type of the finishing liquid of table 3 preparation example 10-14, the setting list of preparation process

Figure BDA0004197425350000052
Figure BDA0004197425350000052

Figure BDA0004197425350000061
Figure BDA0004197425350000061

制备例15Preparation Example 15

一种整理液,与制备例10的区别在于:整理液的原料中不采用膨润土及PTFE微粉。A finishing solution, the difference from Preparation Example 10 is that bentonite and PTFE micropowder are not used in the raw materials of the finishing solution.

制备例16Preparation Example 16

一种整理液,与制备例10的区别在于:整理液的原料中不采用膨润土、PTFE微粉、全氟辛基丙基丙烯酸酯及偶氮二异丁腈。A finishing solution, which differs from Preparation Example 10 in that: bentonite, PTFE micropowder, perfluorooctyl propyl acrylate and azobisisobutyronitrile are not used in the raw materials of the finishing solution.

实施例Example

实施例1Example 1

一种经编绒面料的制备方法,采用的原料成分如表4-表5,采用如下制备步骤:A kind of preparation method of warp-knitted fleece fabric, the raw material composition that adopts is as table 4-table 5, adopts following preparation steps:

混纺包覆线的制备:首先,采用质量比为1:0.5的涤纶纤维及反应性纤维经混纺后形成涤纶混纺纱;然后,采用氨纶纱与涤纶混纺纱进行复合,形成由氨纶纱位于中心和包覆在氨纶纱上,并经假捻加工制备得到混纺包覆线。Preparation of blended covered yarn: firstly, polyester fiber and reactive fiber with a mass ratio of 1:0.5 are blended to form polyester blended yarn; then, spandex yarn and polyester blended yarn are used to compound to form spandex yarn The center is covered on the spandex yarn, and the blended covered thread is prepared by false twisting.

织造:在普通的长纤经编整经机上进行氨纶包覆纱整经时,织造时混纺包覆线的整经张力为1.4g/tex;采用混纺包覆线使用32G经编机进行编织,经编绒面料的组织形式为10/12//,制备得到200±10g/m2经编绒坯料。Weaving: When the spandex covered yarn is warped on an ordinary long fiber warp knitting machine, the warping tension of the blended covered thread is 1.4g/tex during weaving; the blended covered thread is used for weaving with a 32G warp knitting machine The weave form of the warp-knitted fleece fabric is 10/12//, and a 200±10g/ m2 warp-knitted fleece blank is prepared.

磨毛:通过磨毛装置对坯布的一侧面进行磨毛,使得坯布表层形成毛绒,磨毛时间3s,磨毛次数2次。Sanding: use the sanding device to sand one side of the gray cloth to form plush on the surface of the gray cloth. The sanding time is 3 seconds, and the number of sanding times is 2 times.

整理:对磨毛后的坯布使用整理液进行浸渍处理,浴比为8:1,在60℃的条件下,浸渍2h;浸渍后沥干整理液并在150℃的条件下放置15min进行反应,然后经水洗、皂洗、烘干后制备得到经编绒面料。Finishing: impregnate the sanded gray cloth with the finishing liquid, the liquor ratio is 8:1, and soak for 2 hours at 60°C; after dipping, drain the finishing liquid and place it at 150°C for 15 minutes to react. Then, the warp-knitted fleece fabric is prepared after washing with water, soaping and drying.

实施例2-3Example 2-3

一种经编绒面料的制备方法,与实施例1的区别在于,采用的原料重量设置不同;经编绒面料的制备工艺设置不同,具体如表4所示。A method for preparing a warp-knitted fleece fabric differs from Example 1 in that the weight of the raw material used is set differently; the preparation process of the warp-knitted fleece fabric is set differently, as shown in Table 4.

表4实施例1-3中采用的原料重量,经编绒面料的制备工艺设置列表The raw material weight that adopts in the embodiment 1-3 of table 4, the preparation process setting list of warp-knitted velvet fabric

区分distinguish 实施例1Example 1 实施例2Example 2 实施例3Example 3 涤纶混纺纱/kgPolyester blended yarn/kg 4040 5050 6060 氨纶纱/kgSpandex yarn/kg 1010 1010 1010 涤纶混纺纱与氨纶纱的质量比The mass ratio of polyester blended yarn to spandex yarn 4:14:1 5:15:1 6:16:1 混纺包覆线的整经张力/(g/tex)Warping tension of blended covered yarn/(g/tex) 1.41.4 1.61.6 1.81.8 磨毛时间/sGrinding time/s 33 55 88 磨毛次数/次Sanding times/time 22 22 11 整理液Finishing solution 制备例10Preparation Example 10 制备例11Preparation Example 11 制备例12Preparation Example 12 浴比bath ratio 8:18:1 9:19:1 10;110;1 浸渍温度/℃Immersion temperature/℃ 6060 7070 8080 浸渍时间/hImmersion time/h 44 33 22 反应温度/℃Reaction temperature/℃ 150150 160160 170170 反应时间/minReaction time/min 1515 1212 1010

实施例4-6Example 4-6

一种经编绒面料的制备方法,与实施例1的区别在于,制备涤纶混纺纱采用的纱线重量设置不同,具体如表5。A method for preparing a warp-knitted fleece fabric differs from that of Example 1 in that the weight of the yarn used to prepare the polyester blended yarn is set differently, as shown in Table 5 for details.

表5实施例4-6及实施例1中制备涤纶混纺纱采用的纱线重量列表The yarn weight list that polyester blended yarn adopts is prepared in table 5 embodiment 4-6 and embodiment 1

Figure BDA0004197425350000081
Figure BDA0004197425350000081

实施例7Example 7

一种经编绒面料的制备方法,与实施例1的区别在于,在整理步骤中,浸渍处理包括第一次浸渍及第二次浸渍,第一次浸渍时间1h后,出浴静置8min后,进行第二次1h浸渍。A method for preparing a warp-knitted fleece fabric, the difference from Example 1 is that in the finishing step, the dipping treatment includes the first dipping and the second dipping, after the first dipping time is 1h, after leaving the bath for 8min , for the second 1h immersion.

实施例8Example 8

一种经编绒面料的制备方法,与实施例1的区别在于,浸渍时间采用4h。A preparation method of warp-knitted fleece fabric, the difference from Example 1 is that the soaking time is 4h.

实施例9Example 9

一种经编绒面料的制备方法,与实施例1的区别在于,浸渍时间采用4h,并且浸渍分两次进行,依次为第一次浸渍及第二次浸渍,第一次浸渍时间2h后,出浴静置12min后,进行第二次2h浸渍。A preparation method of warp-knitted fleece fabric, the difference from Example 1 is that the dipping time is 4h, and the dipping is carried out twice, followed by the first dipping and the second dipping, after the first dipping time 2h, After leaving the bath to stand for 12 minutes, carry out the second immersion for 2 hours.

实施例10-13Examples 10-13

一种经编绒面料的制备方法,与实施例1的区别在于,整理液依次采用制备例13-16。A method for preparing a warp-knitted fleece fabric, the difference from Example 1 is that the finishing liquid is sequentially used in Preparation Examples 13-16.

实施例14Example 14

一种经编绒面料的制备方法,与实施例1的区别在于,混纺包覆线在织造前使用制备例1的微胶囊浸渍液进行浸渍处理,浴比为1:8,在浸渍温度为65℃,超声22KHz的条件下浸渍6h。A preparation method of warp-knitted fleece fabric, the difference from Example 1 is that the blended covered thread is dipped with the microcapsule dipping solution of Preparation Example 1 before weaving, the bath ratio is 1:8, and the dipping temperature is 65 ℃, impregnated for 6h under the condition of ultrasonic 22KHz.

实施例15-16Example 15-16

一种经编绒面料的制备方法,与实施例14的区别在于,采用的微胶囊浸渍液的制备例不同,浸渍条件设置不同,具体如表6。A method for preparing a warp-knitted fleece fabric differs from that of Example 14 in that the preparation of the microcapsule impregnation solution used is different, and the impregnation conditions are set differently, as shown in Table 6 for details.

表6实施例14-16中采用的微胶囊浸渍液的制备例设置,浸渍条件设置列表The preparation example setting of the microcapsule impregnation liquid adopted in the embodiment 14-16 of table 6, the list of impregnation condition settings

Figure BDA0004197425350000082
Figure BDA0004197425350000082

Figure BDA0004197425350000091
Figure BDA0004197425350000091

实施例17-22Examples 17-22

一种经编绒面料的制备方法,与实施例14的区别在于,依次采用制备例4-9的微胶囊浸渍液。A method for preparing a warp-knitted fleece fabric, which is different from that of Example 14 in that the microcapsule impregnation solutions of Preparation Examples 4-9 are sequentially used.

对比例comparative example

对比例1Comparative example 1

一种经编绒面料的制备方法,与实施例13的区别在于,不采用整理液进行浸渍处理。A method for preparing a warp-knitted fleece fabric differs from that of Example 13 in that no finishing solution is used for dipping treatment.

对比例2Comparative example 2

一种经编绒面料的制备方法,与实施例13的区别在于,涤纶混纺纱中不采用羊毛及整理液中不采用聚甲基氢硅氧烷。A method for preparing a warp-knitted fleece fabric, the difference from Example 13 is that no wool is used in the polyester blended yarn and no polymethylhydrogensiloxane is used in the finishing solution.

对比例3Comparative example 3

一种经编绒面料的制备方法,与实施例13的区别在于,涤纶混纺纱中不采用羊毛及及混纺包覆线整经时的张力为1.0g/tex。A method for preparing a warp-knitted fleece fabric, the difference from Example 13 is that the polyester blended yarn does not use wool and the tension of the blended covered thread is 1.0 g/tex during warping.

性能检测试验performance test

试验一:防水性能试验方法:根据GB/T4744-2013《纺织品防水性能的检测和评价静水压法》,采用静水压测试仪进行测定。Test 1: Waterproof performance test method: According to GB/T4744-2013 "Testing and Evaluation of Textile Waterproof Performance Hydrostatic Pressure Method", the hydrostatic pressure tester is used for measurement.

水洗方法:按照GB/T8629-2017《纺织品试验用家庭洗涤和干燥程序》进行水洗。Washing method: wash in accordance with GB/T8629-2017 "Household Washing and Drying Procedures for Textile Testing".

试验二:耐磨性能试验方法:采用型号为YG522N织物耐磨试验机测试,将经编绒面料裁剪成直径125mm的圆片作为待测试样,试样中间开孔,试验设置三个试样,试验结果均取平均值;采用回转平磨法在标准大气条件下进行脱毛率试验;对试样进行500次摩擦,然后根据失重率=(摩擦前质量-摩擦后质量)/摩擦前质量×100%计算出试验面料的失重率。Test 2: Abrasion resistance test method: use the model YG522N fabric abrasion tester to test, cut the warp-knitted fleece fabric into a disc with a diameter of 125mm as the sample to be tested, open a hole in the middle of the sample, and set up three samples for the test , the test results are averaged; the depilation rate test is carried out under standard atmospheric conditions by using the rotary flat grinding method; the sample is rubbed 500 times, and then according to the weight loss rate=(mass before rubbing-mass after rubbing)/mass before rubbing× 100% calculate the weight loss rate of the test fabric.

试验样品:以实施例1-22制备得到的经编绒面料作为试验样品,以对比例1-3制备得到的经编绒面料作为对照样品。Test samples: the warp-knitted fleece fabrics prepared in Examples 1-22 were used as test samples, and the warp-knitted fleece fabrics prepared in Comparative Examples 1-3 were used as control samples.

试验结果:实施例1-22和对比例1-3制备得到的经编绒面料的防水性能及耐磨性能,测试结果如表7所示:Test result: the waterproof performance and the abrasion resistance of the warp-knitted fleece fabric that embodiment 1-22 and comparative example 1-3 prepare, test result is as shown in table 7:

表7实施例1-22和对比例1-3制备得到的经编绒面料的防水性能及耐磨性能列表Table 7 embodiment 1-22 and comparative example 1-3 prepare the waterproof performance and the abrasion resistance performance list of the warp-knitted fleece fabric

Figure BDA0004197425350000101
Figure BDA0004197425350000101

结合实施例1-22和对比例1-3并结合表7可以看出:Can find out in conjunction with embodiment 1-22 and comparative example 1-3 and in conjunction with table 7:

实施例1-22制备得到的经编绒面料的水洗前静水压(50-65Kpa)高于对比例1-3制备得到的经编绒面料的水洗前静水压(39-48Kpa)。The hydrostatic pressure (50-65Kpa) before washing of the warp-knitted fleece fabric prepared in Example 1-22 is higher than that of the warp-knitted fleece fabric prepared in Comparative Example 1-3 (39-48Kpa).

实施例1-22制备得到的经编绒面料的水洗后静水压(46-62Kpa)高于对比例1-3制备得到的经编绒面料的水洗前静水压(33-43Kpa)。The hydrostatic pressure (46-62Kpa) after washing of the warp-knitted fleece fabric prepared in Example 1-22 is higher than the hydrostatic pressure (33-43Kpa) before washing of the warp-knitted fleece fabric prepared in Comparative Example 1-3.

实施例1-22制备得到的经编绒面料的失重率(0.46-0.61%)低于对比例1-3制备得到的经编绒面料的失重率(0.71-1.5%)。The weight loss rate (0.46-0.61%) of the warp-knitted fleece fabric prepared in Example 1-22 is lower than that of the warp-knitted fleece fabric prepared in Comparative Example 1-3 (0.71-1.5%).

表明经混纺包覆线纺织得到的坯布经整理液处理后,在坯布上形成硅氧膜层,降低了经编绒面料的表面张力及使得经编绒面料更柔顺,通过在经混纺包覆线中引入反应性纤维,增强了硅氧膜层与混纺包覆线之间具的结合强度,通过在混纺包覆线中引入氨纶纱,使得混纺包覆线的附有硅氧膜层的绒毛层叠的更紧密,进而使得经编绒面料具有优异的防水性能及耐磨性能;进一步,采用在整理液中采用流平剂、膨润土与PTFE微粉,且在混纺包覆线中引入微胶囊,进一步增强经编绒面料的防水性能及耐摩擦性能。It shows that after the gray cloth obtained by spinning the blended covered thread is treated with the finishing liquid, a silicon oxide film layer is formed on the gray cloth, which reduces the surface tension of the warp-knitted fleece fabric and makes the warp-knitted fleece fabric more supple. The introduction of reactive fibers in the blended yarn enhances the bonding strength between the silicone film layer and the blended covered thread. By introducing spandex yarn into the blended covered thread, the fuzz with the silicone film layer of the blended covered thread is laminated. The tighter, so that the warp-knitted fleece fabric has excellent waterproof and wear-resistant properties; further, using leveling agent, bentonite and PTFE micropowder in the finishing liquid, and introducing microcapsules into the blended coated thread, to further enhance Waterproof performance and friction resistance of warp knitted fleece fabric.

实施例7制备得到的经编绒面料的静水压高于实施例1、失重率低于实施例1;实施例9的经编绒面料的静水压高于实施例8、失重率低于实施例8,可能是因为浸渍分两次进行使得经编绒面料上形成的防水涂层更均匀,更紧密,使得经编绒面料具有较好的防水性能及耐磨性能。The hydrostatic pressure of the warp-knitted fleece fabric that embodiment 7 prepares is higher than embodiment 1, and the weight loss rate is lower than embodiment 1; The hydrostatic pressure of the warp-knitted fleece fabric of embodiment 9 is higher than embodiment 8, and the weight loss rate is lower than In Example 8, it may be that the waterproof coating formed on the warp-knitted fleece fabric is more uniform and compact because the impregnation is performed twice, so that the warp-knitted fleece fabric has better waterproof performance and wear resistance.

实施例10制备得到的经编绒面料的静水压高于实施例1、失重率低于实施例1;实施例2的经编绒面料的静水压高于实施例11、失重率低于实施例11,可能是因为丙烯酸烃类的流平剂的分子链较短,分子链上没有大的分子基团,流平剂聚合后形成的高分子膜层与聚甲基氢硅氧烷及羟基封端二甲基羟基硅油形成的膜层有较好的协同效果,使得整理液形成的膜层更紧密,进而提升了经编绒面料的防水性能及耐磨性能。The hydrostatic pressure of the warp-knitted fleece fabric that embodiment 10 prepares is higher than embodiment 1, and the weight loss rate is lower than embodiment 1; The hydrostatic pressure of the warp-knitted fleece fabric of embodiment 2 is higher than embodiment 11, and the weight loss rate is lower than Embodiment 11, probably because the molecular chain of the leveling agent of acrylic hydrocarbons is shorter, there is no large molecular group on the molecular chain, the macromolecule film layer that forms after leveling agent polymerization and polymethyl hydrogen siloxane and polymethyl hydrogen siloxane and The film layer formed by hydroxyl-terminated dimethyl hydroxy silicone oil has a better synergistic effect, which makes the film layer formed by the finishing solution tighter, thereby improving the waterproof performance and wear resistance of the warp-knitted fleece fabric.

实施例12-13制备得到的经编绒面料的静水压低于实施例1-11、失重率高于实施例1-11,表明膨润土、PTFE微粉及全氟辛基丙基丙烯酸酯配伍使用,使得经编绒面料具有较好的防水性能及耐磨性能,可能是因为膨润土提高PTFE微粉分散性能,PTFE微粉增强了整理液形成膜层的耐磨性,PTFE微粉与膨润土相互协同,进一步增强了经编绒面料的防水性能及耐磨性能。The hydrostatic pressure of the warp-knitted fleece fabric that embodiment 12-13 prepares is lower than embodiment 1-11, and the weight loss rate is higher than embodiment 1-11, shows that bentonite, PTFE micropowder and perfluorooctyl propyl acrylate are compatible to use, make The warp-knitted fleece fabric has good waterproof performance and wear resistance, which may be because bentonite improves the dispersion performance of PTFE powder, and PTFE powder enhances the wear resistance of the film formed by the finishing solution. The waterproof performance and wear resistance of velvet fabric.

实施例14-22制备得到的经编绒面料的静水压高于实施例1-13、失重率低于实施例1-13,表明混纺包覆线在织造前使用微胶囊浸渍液进行处理使得经编绒面料具有较好的防水性能及耐磨性能,可能是因为微胶囊缓释的缓释效果,缓释的硬脂酸正丁酯与羟基封端二甲基羟基硅油配伍使用,迁移到编绒面料上整理液形成的膜层上,进一步提升经编绒面料的防水性能及耐磨性能。The hydrostatic pressure of the warp-knitted fleece fabric prepared in Examples 14-22 is higher than that of Examples 1-13, and the weight loss rate is lower than that of Examples 1-13, indicating that the blended coated thread is treated with a microcapsule impregnation solution before weaving to make The warp-knitted fleece fabric has good waterproof performance and wear resistance, which may be due to the slow-release effect of microcapsules. The slow-release n-butyl stearate is compatible with hydroxyl-terminated dimethyl hydroxy silicone oil, and migrates to The film layer formed by the finishing liquid on the knitted fleece fabric further improves the waterproof performance and wear resistance of the warp knitted fleece fabric.

本具体实施例仅仅是对本申请的解释,其并不是对本申请的限制,本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改,但只要在本申请的权利要求范围内都受到专利法的保护。This specific embodiment is only an explanation of this application, and it is not a limitation of this application. Those skilled in the art can make modifications to this embodiment without creative contribution according to needs after reading this specification, but as long as the rights of this application All claims are protected by patent law.

Claims (10)

1. The preparation method of the warp knitting pile fabric is characterized by comprising the following preparation processes:
preparation of a blended coated wire: the mass ratio is 1: blending the polyester fiber (0.5-1.5) and the reactive fiber to obtain a polyester blended yarn; and then coating the terylene blended yarn on the spandex yarn, and performing false twisting to prepare the blended coated yarn, wherein the mass ratio of the terylene blended yarn to the spandex yarn is (4-6): 1, a step of;
weaving: weaving the blended coating line to form grey cloth, wherein the warping tension of the blended coating line is 1.4-1.8g/tex during weaving;
roughening: roughening one surface of the grey cloth to form plush on the surface layer of the grey cloth;
and (3) finishing: soaking the ground grey cloth with finishing liquid at 60-80 deg.c for 2-4 hr in bath ratio of 8-10 to 1; draining the finishing liquid after soaking, heating at 150-170 ℃ for 10-15min, and then washing, soaping and drying to obtain the warp knitting wool fabric;
the raw materials of the finishing liquid comprise 2-5 parts of polymethylhydrosiloxane, 2-3 parts of hydroxyl end-capped dimethyl hydroxyl silicone oil, 0.2-0.5 part of polyether modified polysiloxane, 4-6 parts of alkylphenol ethoxylates, 0.06-0.1 part of Pt catalyst and 1000 parts of water.
2. The method for producing warp knitting pile fabric according to claim 1, wherein the reactive fiber is one of wool, silk, viscose, cotton, hemp and modal.
3. The method according to claim 1, wherein in the finishing step, the impregnation treatment comprises a first impregnation and a second impregnation, the first impregnation is performed for 1-2 hours, the second impregnation is performed for 1-2 hours, and the raw fabric is left to stand for 8-12 minutes after the first impregnation, and then the second impregnation is performed.
4. The method for preparing the warp knitting pile fabric according to claim 1, wherein the finishing liquid further comprises 2-6 parts of a leveling agent and 0.06-0.1 part of an initiator, and the leveling agent is one of perfluorooctyl propyl acrylate, perfluorocyclohexyl methyl acrylate and acrylic hydrocarbon.
5. The method for producing warp knitting pile fabric according to claim 4, wherein the leveling agent is acrylic hydrocarbon.
6. The method for producing warp knitting pile fabric according to claim 4, wherein the finishing liquid further comprises 0.4-0.8 parts of bentonite and 0.1-0.2 parts of PTFE micropowder.
7. The method for preparing the warp knitting pile fabric according to claim 1, which is characterized in that: the blended coating line is treated for 4-6 hours under the condition of ultrasonic 18-22KHz by using microcapsule impregnating solution before weaving, and the bath ratio is 1: (8-10), wherein the temperature of the microcapsule impregnating solution is 65-85 ℃;
the preparation process of the microcapsule impregnating solution comprises the following steps: heating the raw material mixed solution to 60-70 ℃, and emulsifying and stirring for 30-40min under the condition of stirring speed of 4000-7000 r/min; adding 0.1-0.3 part of hydrochloric acid, and reacting for 24-60 hours at the temperature of 60-70 ℃ and the reaction stirring speed of 400-1000r/min to prepare microcapsule impregnating solution;
the raw material mixed solution comprises 2-4 parts of n-butyl stearate, 1-3 parts of sodium dodecyl sulfate, 4-8 parts of tetrabutyl titanate, 70-76 parts of deionized water and 35-40 parts of ethanol.
8. The method for producing warp knitting pile fabric according to claim 7, characterized in that: the raw material mixed solution also comprises 3-6 parts of hydroxyl-terminated dimethyl hydroxyl silicone oil.
9. The method for producing warp knitting pile fabric according to claim 7, characterized in that: the stirring speed during emulsification is 5000-6000r/min, the reaction stirring speed is 600-700r/min, the reaction temperature is 63-65 ℃ and the reaction time is 45-50h.
10. The warp knitting velvet fabric is characterized in that: the warp-knitted pile fabric prepared by the method for preparing the warp-knitted pile fabric according to any one of claims 1 to 9.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116949628A (en) * 2023-07-26 2023-10-27 浙江力达现代纺织有限公司 Mink velvet-imitated chenille yarn and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504178A (en) * 2011-11-01 2012-06-20 吴江市北厍盛源纺织品助剂厂 Preparation method of novel mono-component water-based polyurethane coating agent
CN103898766A (en) * 2014-02-26 2014-07-02 巨化集团技术中心 High-elastic straight organic silicon fabric coating agent and preparation method thereof
CN114517353A (en) * 2022-03-25 2022-05-20 杭州永前布业有限公司 Waterproof case fabric and production process thereof
CN115161866A (en) * 2022-05-20 2022-10-11 嘉兴华绰纺织股份有限公司 A production process of warp-knitted hydrophobic polyester fabric

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102504178A (en) * 2011-11-01 2012-06-20 吴江市北厍盛源纺织品助剂厂 Preparation method of novel mono-component water-based polyurethane coating agent
CN103898766A (en) * 2014-02-26 2014-07-02 巨化集团技术中心 High-elastic straight organic silicon fabric coating agent and preparation method thereof
CN114517353A (en) * 2022-03-25 2022-05-20 杭州永前布业有限公司 Waterproof case fabric and production process thereof
CN115161866A (en) * 2022-05-20 2022-10-11 嘉兴华绰纺织股份有限公司 A production process of warp-knitted hydrophobic polyester fabric

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116949628A (en) * 2023-07-26 2023-10-27 浙江力达现代纺织有限公司 Mink velvet-imitated chenille yarn and preparation process thereof

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