CN116815519A - Preparation process of moisture-absorbing, heating, antibacterial, antistatic and heat-preserving acetic acid fabric - Google Patents
Preparation process of moisture-absorbing, heating, antibacterial, antistatic and heat-preserving acetic acid fabric Download PDFInfo
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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Abstract
Description
技术领域Technical field
本发明属于功能面料领域,涉及一种吸湿发热抗菌、抗静电、保温的醋酸面料的制备工艺。The invention belongs to the field of functional fabrics and relates to a preparation process of a hygroscopic, heat-generating, antibacterial, antistatic and heat-insulating acetic acid fabric.
背景技术Background technique
在制造面料时,人们通常会考虑许多因素,例如面料的质地、强度、柔软度、耐久性和舒适度等。然而,随着人们对纺织品性能的要求越来越高,吸湿排汗与吸湿发热附带抗菌性能成为了越来越重要的因素。When manufacturing fabrics, people usually consider many factors, such as the texture, strength, softness, durability, and comfort of the fabric. However, as people have higher and higher requirements for the performance of textiles, moisture wicking and moisture absorption and heat generation with antibacterial properties have become more and more important factors.
在过去,许多面料的吸湿排汗、吸湿发热和抗菌性能都不尽如人意。例如,一些传统的纤维材料如棉花和羊毛等,虽然能吸收大量水分,但却需要很长时间才能实现干燥,同时也缺乏吸湿排汗和吸湿发热的性能。而一些合成纤维如聚酯和尼龙等则可以更快地干燥,但它们却缺乏吸湿发热的性能。此外,许多面料还容易滋生细菌和微生物,导致异味和感染等问题。In the past, many fabrics had unsatisfactory moisture-wicking, moisture-wicking and antibacterial properties. For example, some traditional fiber materials such as cotton and wool can absorb a large amount of moisture, but they take a long time to dry, and they also lack moisture wicking and moisture absorption and heat generation properties. Some synthetic fibers such as polyester and nylon can dry faster, but they lack the ability to absorb moisture and generate heat. In addition, many fabrics are prone to harbor bacteria and microorganisms, leading to problems such as odor and infection.
近年来,由伊士曼公司研发的Naia二醋纤维已经成为了一种备受关注的纤维材料。Naia二醋纤维是一种纤维素纤维,由可持续的原材料木浆制成,Naia纤维具有许多细小的孔隙和微纤维,可以快速吸收汗水和湿气,并迅速将其蒸发掉,从而保持人体的干爽和舒适,得益于其纤维结构和化学性质,Naia纤维具有出色的吸湿排汗和吸湿发热性能。同时,Naia纤维还具有抗菌性能,可以有效抑制细菌和微生物的滋生,避免异味和感染等问题的发生。In recent years, Naia diethyl acetate fiber developed by Eastman Company has become a fiber material that has attracted much attention. Naia diacetate fiber is a cellulose fiber made from sustainable raw material wood pulp. Naia fiber has many small pores and microfibers, which can quickly absorb sweat and moisture and evaporate them quickly, thus keeping the human body Dry and comfortable, Naia fiber has excellent moisture-wicking and moisture-wicking properties thanks to its fiber structure and chemical properties. At the same time, Naia fiber also has antibacterial properties, which can effectively inhibit the growth of bacteria and microorganisms and avoid problems such as odor and infection.
对于Naia二醋纤维,如果能利用其特点,做到扬长避短,在纺纱阶段,加入莫代尔、腈纶纤维中和加强其特性,使其具有:吸湿排汗、吸湿发热性能,抗菌性能,抗静电和保温性能,则能够完美的解决市场上缺乏吸湿发热抗菌、抗静电、保温的面料的问题。For Naia diacetate fiber, if we can make use of its characteristics to maximize its strengths and avoid weaknesses, during the spinning stage, add modal and acrylic fibers to neutralize and strengthen its characteristics, so that it has: moisture wicking, moisture absorption and heating properties, antibacterial properties, antistatic and Thermal insulation performance can perfectly solve the problem of lack of moisture-absorbing, heat-generating, antibacterial, antistatic, and thermal insulation fabrics on the market.
发明内容Contents of the invention
为了解决上述问题,本发明的目的在于提供一种吸湿发热抗菌、抗静电、保温的醋酸面料的制备工艺,能够利用腈纶纤维及莫代尔纤维中和并加强二醋酸纤维的特性,使其具有:吸湿排汗、吸湿发热,抗菌,抗静电和保温的性能,可以应用于各种领域,例如家居内衣、床上用品和内衣等领域。In order to solve the above problems, the purpose of the present invention is to provide a preparation process for a hygroscopic, heat-generating, antibacterial, antistatic, and heat-insulating acetate fabric, which can utilize acrylic fiber and modal fiber to neutralize and strengthen the characteristics of diacetate fiber, so that it has: hygroscopicity It has perspiration-wicking, moisture-absorbing and heat-generating, antibacterial, antistatic and thermal insulation properties and can be used in various fields, such as home underwear, bedding and underwear.
为了实现上述目的,本发明的技术方案如下。In order to achieve the above objects, the technical solutions of the present invention are as follows.
本发明提供一种吸湿发热抗菌、抗静电、保温的醋酸面料的制备工艺,包括有以下步骤:The invention provides a preparation process for a hygroscopic, heat-generating, antibacterial, antistatic and heat-insulating acetate fabric, which includes the following steps:
S1:将二醋酸纤维与腈纶纤维及莫代尔纤维混纺成纱线,再与氨纶织成面料,然后将所得面料进行预定型处理;S1: Blend diacetate fiber with acrylic fiber and modal fiber into yarn, then weave it with spandex into fabric, and then pre-shape the resulting fabric;
S2:加入纯碱和精练除油剂进行前处理,去除纺纱及织布流程中的油,以及面料仓存运输形成的土污及其它污垢,提高面料吸水性;S2: Add soda ash and refining degreaser for pre-treatment to remove oil in the spinning and weaving processes, as well as soil and other dirt caused by fabric storage and transportation, and improve the water absorption of the fabric;
S3:依次进行染腈纶和染棉处理,分别对面料中的腈纶纤维和莫代尔纤维染色;S3: Carry out dyeing of acrylic and cotton in sequence, and dye acrylic fiber and modal fiber in the fabric respectively;
S4:依次经过过酸、皂洗、水洗和酸洗后处理;其中过酸用于中和染色过程中加入的碱,防止布面返碱;皂洗用于提高织物的色牢度;水洗和酸洗用于提高织物的柔软度;S4: It undergoes post-processing of peracid, soaping, water washing and pickling in sequence; peracid is used to neutralize the alkali added during the dyeing process to prevent the cloth surface from returning to alkali; soaping is used to improve the color fastness of the fabric; water washing and Acid washing is used to increase the softness of fabrics;
S5:烘干后起绒;S5: lint after drying;
S6:在定型机的定型液槽中加入吸水速干整理剂进行定型前处理,然后运用定型机定型。S6: Add water-absorbing and quick-drying finishing agent into the setting liquid tank of the setting machine for pre-setting treatment, and then use the setting machine to set the shape.
进一步地,步骤S1中,所述混纺的纱线由35%的Naia-二醋酸纤维、30%的莫代尔纤维和35%腈纶纤维组成,氨纶采用30D氨纶。Further, in step S1, the blended yarn is composed of 35% Naia-diacetate fiber, 30% modal fiber and 35% acrylic fiber, and the spandex is 30D spandex.
进一步地,步骤S1中采用提花机将纱线与氨纶织成面料,提花织机采用26针提花针织机。Further, in step S1, a jacquard machine is used to weave the yarn and spandex into fabric, and the jacquard loom uses a 26-needle jacquard knitting machine.
进一步地,所述除油剂为精练除油剂,包括有JF-1041、PRETEX生产的Pe-4145。Further, the degreaser is a refined degreaser, including JF-1041 and Pe-4145 produced by PRETEX.
进一步地,步骤S1中,定型的工艺条件为:温度180~220℃,车速22~26米/分钟。Further, in step S1, the shaping process conditions are: temperature 180-220°C, vehicle speed 22-26 meters/minute.
进一步地,步骤S2中,前处理的条件为:在染色机中于70~90℃下处理10~30分钟。Further, in step S2, the pre-treatment conditions are: processing in a dyeing machine at 70-90°C for 10-30 minutes.
进一步地,步骤S3中,染腈纶的方法为:染浴中加入阳离子染料,元明粉,纯碱和均染剂,在100~110℃下染色;染棉的方法为:染浴中加入活性染料,元明粉,纯碱和活性均染剂,在55~65℃下染色。Further, in step S3, the method of dyeing acrylic fiber is: adding cationic dye, Yuanming powder, soda ash and leveling agent to the dye bath, and dyeing at 100-110°C; the method of dyeing cotton is: adding reactive dyes to the dye bath. , Yuanming powder, soda ash and reactive leveling agent, dyeing at 55~65℃.
进一步地,步骤S5中,起绒具体包括:用36棍抓毛机起绒,车速14~18米/分钟;用10槽两棍烫光机烫光起绒,车速18~22米/分钟;用键轮液压剪毛机修剪毛茸的高度,车速18~22米/分钟。Further, in step S5, the raising specifically includes: using a 36-roll nap machine to raise the nap, with a speed of 14 to 18 meters/minute; using a 10-slot two-roll ironing machine to burn the nap, with a speed of 18 to 22 meters/minute; Use a keywheel hydraulic shearing machine to trim the hair height at a speed of 18 to 22 meters/minute.
进一步地,步骤S6中,吸水速干整理剂为不含硅的亲水性的聚合物分散液,包括有聚丙烯酸酯、聚乙烯酸酯、聚丙烯醇,赋予了面料极佳的吸水排汗;定型处理的工艺条件为150~170℃,车速20~24米/分钟。Further, in step S6, the water-absorbing and quick-drying finishing agent is a silicon-free hydrophilic polymer dispersion, including polyacrylate, polyvinyl ester, and polypropylene alcohol, which gives the fabric excellent water absorption and perspiration. ;The process conditions for shaping treatment are 150~170℃, and the vehicle speed is 20~24 meters/minute.
本发明的有益效果在于,与现有技术相比:The beneficial effects of the present invention are that, compared with the prior art:
首先,本发明在二醋酸纤维中加入莫代尔、腈纶纤维进行纺纱,莫代尔能够在低温环境下吸收空气中的水分,形成保暖层,提供吸湿发热的效果,腈纶纤维易起绒且具有保温的性能,二者能够中和和加强二醋酸纤维的特性,使其具有:吸湿排汗、吸湿发热,抗菌,抗静电和保温的性能;First, the present invention adds modal and acrylic fiber to diacetate fiber for spinning. Modal can absorb moisture in the air in a low-temperature environment to form a thermal insulation layer, providing a hygroscopic and heating effect. Acrylic fiber is easy to fluff and has thermal insulation properties. , both of which can neutralize and strengthen the properties of diacetate fiber, giving it the following properties: moisture wicking, moisture absorption and heat generation, antibacterial, antistatic and thermal insulation properties;
其次,在本发明中,面料布身细腻柔软蓬松,透气速干,抗菌效果好,面料提花织造的结构赋予面料小蜂窝的空间,与面料的起绒毛茸形造保温的空气瓤,形成保温的防护层;面料中的二醋酸纤维的表面具有凹槽通道,可使水分沿着凹槽通道快速流通,快速传递身体的汗水,将湿气导离皮肤表面,保持皮肤持续干爽;二醋酸纤维的吸湿速干性能维持体表干爽,抗菌性能阻击有害细菌,高效抑菌维护体表环境的洁净;Secondly, in the present invention, the fabric body is delicate, soft and fluffy, breathable and quick-drying, and has good antibacterial effect. The jacquard weaving structure of the fabric gives the fabric a small honeycomb space, which together with the fluffy and fluffy shape of the fabric creates an insulating air mass, forming a heat-insulating Protective layer; the surface of the diacetate fiber in the fabric has grooved channels, which can quickly circulate moisture along the grooved channels, quickly transfer body sweat, conduct moisture away from the skin surface, and keep the skin dry; the diacetate fiber The moisture-absorbing and quick-drying properties keep the body surface dry, the antibacterial properties block harmful bacteria, and the highly effective antibacterial properties maintain the cleanliness of the body surface environment;
最后,Naia纤维源自可持续的原材料,其制造过程中的环境影响也得到了有效控制和减少,具有可持续性和环保性,符合现代消费者对产品的高要求和期望。Finally, Naia fiber is derived from sustainable raw materials, and the environmental impact during its manufacturing process has been effectively controlled and reduced. It is sustainable and environmentally friendly, and meets the high requirements and expectations of modern consumers for products.
具体实施方式Detailed ways
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the purpose, technical solutions and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with examples. It should be understood that the specific embodiments described here are only used to explain the present invention and are not intended to limit the present invention.
为实现上述目的,本发明的技术方案如下。In order to achieve the above objects, the technical solutions of the present invention are as follows.
实施例1:Example 1:
采用以下步骤制作吸湿发热抗菌、抗静电、保温的醋酸面料:Use the following steps to make acetic acid fabrics that absorb moisture, generate heat, are antibacterial, antistatic, and have thermal insulation properties:
S1:将35%的Naia-二醋酸纤维、30%的莫代尔纤维和35%腈纶纤维混纺成纱线,再采用26针提花针织机将纱线与30D氨纶织成面料,然后将所得面料进行预定型处理,定型的工艺条件为:温度180℃,车速22米/分钟;S1: 35% Naia diacetate fiber, 30% modal fiber and 35% acrylic fiber are blended into yarn, and then a 26-needle jacquard knitting machine is used to knit the yarn and 30D spandex into fabric, and then the resulting fabric is pre-ordered The process conditions for shaping treatment and shaping are: temperature 180°C, vehicle speed 22 meters/minute;
S2:加入纯碱和PRETEX(普锐斯)公司生产Pe-4145进行前处理,去除纺纱及织布流程中的油,以及面料仓存运输形成的土污及其它污垢,提高面料吸水性,前处理的条件为:在染色机中于70℃下处理30分钟;S2: Add soda ash and Pe-4145 produced by PRETEX (Prius) Company for pre-treatment to remove oil in the spinning and weaving processes, as well as soil and other dirt caused by fabric storage and transportation, and improve the water absorption of the fabric. Pre-treatment The conditions are: process in a dyeing machine at 70°C for 30 minutes;
S3:依次进行染腈纶和染棉处理,分别对面料中的腈纶纤维和莫代尔纤维染色;染腈纶的方法为:染浴中加入阳离子染料,元明粉,纯碱和均染剂,在100℃下染色;染棉的方法为:染浴中加入活性染料,元明粉,纯碱和活性均染剂,在55℃下染色。S3: Dye acrylic fiber and dye cotton in sequence, and dye acrylic fiber and modal fiber in the fabric respectively; the method of dyeing acrylic fiber is: add cationic dye, Yuanming powder, soda ash and leveling agent to the dye bath, and dye it at 100℃ Dyeing; the method of dyeing cotton is: add reactive dyes, Yuanming powder, soda ash and reactive leveling agent to the dye bath, and dye at 55°C.
S4:依次经过过酸、皂洗、水洗和酸洗后处理;其中过酸用于中和染色过程中加入的碱,防止布面返碱;皂洗用于提高织物的色牢度;水洗和酸洗用于提高织物的柔软度;S4: It undergoes post-processing of peracid, soaping, water washing and pickling in sequence; peracid is used to neutralize the alkali added during the dyeing process to prevent the cloth surface from returning to alkali; soaping is used to improve the color fastness of the fabric; water washing and Acid washing is used to increase the softness of fabrics;
S5:烘干后起绒,起绒具体包括:用36棍抓毛机起绒,车速14米/分钟;用10槽两棍烫光机烫光起绒,车速18米/分钟;用键轮液压剪毛机修剪毛茸的高度,车速18米/分钟;S5: Raising after drying. Raising specifically includes: using a 36-stick nap machine to raise nap, the speed is 14 meters/minute; using a 10-slot two-stick ironing machine to burn the nap, the speed is 18 meters/minute; using a key wheel The hydraulic shearing machine can cut hair at a height of 18 meters/minute;
S6:在定型机的定型液槽中加入聚丙烯酸酯进行定型前处理,然后运用定型机定型,定型处理的工艺条件为150℃,车速20米/分钟。S6: Add polyacrylate to the setting liquid tank of the setting machine for pre-setting treatment, and then use the setting machine to set the shape. The process conditions for the setting treatment are 150°C and a vehicle speed of 20 meters/minute.
实施例2:采用以下步骤制作吸湿发热抗菌、抗静电、保温的醋酸面料:Example 2: Use the following steps to prepare acetic acid fabric that is hygroscopic, heat-generating, antibacterial, antistatic, and heat-insulating:
S1:将35%的Naia-二醋酸纤维、30%的莫代尔纤维和35%腈纶纤维混纺成纱线,再采用26针提花针织机将纱线与30D氨纶织成面料,然后将所得面料进行预定型处理,定型的工艺条件为:温度220℃,车速26米/分钟;S1: 35% Naia diacetate fiber, 30% modal fiber and 35% acrylic fiber are blended into yarn, and then a 26-needle jacquard knitting machine is used to knit the yarn and 30D spandex into fabric, and then the resulting fabric is pre-ordered The process conditions for shaping treatment and shaping are: temperature 220°C, vehicle speed 26 meters/minute;
S2:加入纯碱和PRETEX(普锐斯)公司生产Pe-4145进行前处理,去除纺纱及织布流程中的油,以及面料仓存运输形成的土污及其它污垢,提高面料吸水性,前处理的条件为:在染色机中于90℃下处理10分钟;S2: Add soda ash and Pe-4145 produced by PRETEX (Prius) Company for pre-treatment to remove oil in the spinning and weaving processes, as well as soil and other dirt caused by fabric storage and transportation, and improve the water absorption of the fabric. Pre-treatment The conditions are: treated in a dyeing machine at 90°C for 10 minutes;
S3:依次进行染腈纶和染棉处理,分别对面料中的腈纶纤维和莫代尔纤维染色;染腈纶的方法为:染浴中加入阳离子染料,元明粉,纯碱和均染剂,在110℃下染色;染棉的方法为:染浴中加入活性染料,元明粉,纯碱和活性均染剂,在65℃下染色。S3: Dye acrylic fiber and dye cotton in sequence to dye acrylic fiber and modal fiber in the fabric respectively; the method of dyeing acrylic fiber is: add cationic dye, Yuanming powder, soda ash and leveling agent to the dye bath at 110℃ Dyeing; the method of dyeing cotton is: add reactive dyes, Yuanming powder, soda ash and reactive leveling agent to the dye bath, and dye at 65°C.
S4:依次经过过酸、皂洗、水洗和酸洗后处理;其中过酸用于中和染色过程中加入的碱,防止布面返碱;皂洗用于提高织物的色牢度;水洗和酸洗用于提高织物的柔软度;S4: It undergoes post-processing of peracid, soaping, water washing and pickling in sequence; peracid is used to neutralize the alkali added during the dyeing process to prevent the cloth surface from returning to alkali; soaping is used to improve the color fastness of the fabric; water washing and Acid washing is used to increase the softness of fabrics;
S5:烘干后起绒,起绒具体包括:用36棍抓毛机起绒,车速18米/分钟;用10槽两棍烫光机烫光起绒,车速22米/分钟;用键轮液压剪毛机修剪毛茸的高度,车速22米/分钟;S5: Raising after drying. Raising specifically includes: using a 36-stick nap machine to raise nap, the speed is 18 meters/minute; using a 10-slot two-stick ironing machine to burn the nap, the speed is 22 meters/minute; using a key wheel The hydraulic shearing machine can cut hair at a height of 22 meters/minute;
S6:在定型机的定型液槽中加入聚丙烯酸酯进行定型前处理,然后运用定型机定型,定型处理的工艺条件为170℃,车速24米/分钟。S6: Add polyacrylate to the setting liquid tank of the setting machine for pre-setting treatment, and then use the setting machine to set the shape. The process conditions for the setting treatment are 170°C and a vehicle speed of 24 meters/minute.
将实施例1与实施例2制作的醋酸面料送到天纺标(深圳)检验认证股份有限公司进行保温率、抗菌抗静电吸湿发热、吸湿排汗检验,样品名称:醋酸暖皮Y1359T面料,检验日期:2023-05-09至2023-05-13。The acetic acid fabrics produced in Examples 1 and 2 were sent to Tianfangbiao (Shenzhen) Inspection and Certification Co., Ltd. for thermal insulation rate, antibacterial, antistatic, moisture absorption and heat generation, and moisture absorption and perspiration testing. Sample name: Acetate warm leather Y1359T fabric, inspection Date: 2023-05-09 to 2023-05-13.
实施例1的保温率检验结果见表1,抗菌抗静电吸湿发热的检验结果见表2,吸湿排汗检验结果见表3。The heat preservation rate test results of Example 1 are shown in Table 1, the antibacterial, antistatic, moisture absorption and heat test results are shown in Table 2, and the moisture absorption and perspiration test results are shown in Table 3.
实施例2的保温率检验结果见表4,抗菌抗静电吸湿发热的检验结果见表5,吸湿排汗检验结果见表6。The heat preservation rate test results of Example 2 are shown in Table 4, the antibacterial, antistatic, moisture absorption and heat test results are shown in Table 5, and the moisture absorption and perspiration test results are shown in Table 6.
表1:Table 1:
表2:Table 2:
表3:table 3:
表4:Table 4:
表5:table 5:
表6:Table 6:
由上表1-6可知,实施例1和2制作的吸湿发热抗菌、抗静电、保温的醋酸面料均具有很好的吸湿发热抗菌、抗静电、保温性能,满足国家标准的要求。It can be seen from Tables 1-6 above that the hygroscopic, heat-generating, antibacterial, antistatic, and heat-insulating acetate fabrics produced in Examples 1 and 2 all have good hygroscopic, heat-generating, antibacterial, antistatic, and heat-insulating properties and meet the requirements of national standards.
以上实施例仅用于阐述本发明,而本发明的保护范围并非仅仅局限于以上实施例。所述技术领域的普通技术人员依据以上本发明公开的内容和各参数所取范围,均可实现本发明的目的。The above embodiments are only used to illustrate the present invention, and the protection scope of the present invention is not limited only to the above embodiments. Those of ordinary skill in the technical field can achieve the purpose of the present invention based on the above disclosure of the present invention and the range of each parameter.
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