CN1231668A - 含2－杂原子取代的环戊二烯基金属配合物和烯烃聚合方法 - Google Patents

含2－杂原子取代的环戊二烯基金属配合物和烯烃聚合方法 Download PDF

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Publication number
CN1231668A
CN1231668A CN97198208A CN97198208A CN1231668A CN 1231668 A CN1231668 A CN 1231668A CN 97198208 A CN97198208 A CN 97198208A CN 97198208 A CN97198208 A CN 97198208A CN 1231668 A CN1231668 A CN 1231668A
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alkyl
dimethyl
metal complexes
group
inden
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Chinese (zh)
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J·克洛辛
W·J·小克鲁佩
P·N·尼凯斯
J·T·帕顿
D·R·维尔森
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Dow Chemical Co
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Dow Chemical Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN97198208A 1996-08-08 1997-07-28 含2－杂原子取代的环戊二烯基金属配合物和烯烃聚合方法 Pending CN1231668A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US2376896P 1996-08-08 1996-08-08
US60/023,768 1996-08-08

Publications (1)

Publication Number Publication Date
CN1231668A true CN1231668A (zh) 1999-10-13

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CN97198208A Pending CN1231668A (zh) 1996-08-08 1997-07-28 含2－杂原子取代的环戊二烯基金属配合物和烯烃聚合方法

Country Status (21)

Country Link
EP (1) EP1021454A1 (id)
JP (1) JP2000516608A (id)
KR (1) KR20000029853A (id)
CN (1) CN1231668A (id)
AR (1) AR009034A1 (id)
AU (1) AU716659B2 (id)
BR (1) BR9711115A (id)
CA (1) CA2262377A1 (id)
CO (1) CO4870709A1 (id)
CZ (1) CZ42499A3 (id)
HU (1) HUP9904148A3 (id)
ID (1) ID18005A (id)
NO (1) NO990546L (id)
NZ (1) NZ333877A (id)
PL (1) PL331526A1 (id)
RU (1) RU2196776C2 (id)
SA (1) SA97180735B1 (id)
SK (1) SK15299A3 (id)
TR (1) TR199900589T2 (id)
WO (1) WO1998006728A1 (id)
ZA (2) ZA976998B (id)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102101897A (zh) * 2010-12-24 2011-06-22 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
CN103249755A (zh) * 2010-09-15 2013-08-14 株式会社日本触媒 可作为热潜在性聚合引发剂使用的组合物

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FI971565A7 (fi) * 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
DE19809159A1 (de) 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
CA2365229A1 (en) 1999-04-29 2000-11-09 Dow Global Technologies Inc. Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
CA2368010A1 (en) 1999-05-13 2000-11-23 Dow Global Technologies Inc. Metal complexes containing bridging heteroatom for olefin-polymerization process
CA2368111A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
EP1194431B1 (en) 1999-06-04 2005-06-22 Dow Global Technologies Inc. Boron-substituted cyclopentadienes and metal complexes thereof
EP1253158A1 (en) * 1999-12-10 2002-10-30 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
KR100714508B1 (ko) * 1999-12-10 2007-05-07 다우 글로벌 테크놀로지스 인크. 치환된 4족 금속 착체, 촉매 및 올레핀 중합 방법
ES2239665T3 (es) 2000-01-18 2005-10-01 Basell Polyolefine Gmbh Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos.
GB0001232D0 (en) * 2000-01-19 2000-03-08 Borealis Polymers Oy Polymerisation catalysts
EP1248806A1 (en) * 2000-01-19 2002-10-16 Borealis Technology Oy Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
US7098356B2 (en) 2002-03-14 2006-08-29 Dow Global Technologies Inc. Substituted indenyl metal complexes and polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
RU2373592C1 (ru) * 2006-09-11 2009-11-20 Асахи Касеи Кабусики Кайся Полимерный электролит, способ его получения и электрохимический элемент
BRPI1015130B1 (pt) 2009-07-28 2019-11-26 Univation Tech Llc processo de polimerização usando um catalisador de geometria limitada suportado
KR101791810B1 (ko) 2014-03-21 2017-10-30 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌 프로필렌 공중합체의 제조 방법
PL3245258T3 (pl) 2015-01-06 2020-01-31 Scg Chemicals Co., Ltd. MIKROSFERY SiO₂ Z WARSTWOWYM PODWÓJNYM WODOROTLENKIEM I SPOSOBY ICH OTRZYMYWANIA
KR102010630B1 (ko) * 2016-01-20 2019-08-13 한화토탈 주식회사 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
WO2018175073A1 (en) * 2017-03-23 2018-09-27 Exxonmobil Chemical Patents Inc. Catalyst systems and methods for preparing and using the same
KR102643986B1 (ko) 2017-09-29 2024-03-07 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
WO2020174346A1 (ko) 2019-02-28 2020-09-03 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
KR102714698B1 (ko) 2019-02-28 2024-10-10 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법
CN113039217B (zh) 2019-09-27 2023-05-12 株式会社Lg化学 混杂负载型催化剂和使用该催化剂制备聚烯烃的方法

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NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
ATE198207T1 (de) * 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103249755A (zh) * 2010-09-15 2013-08-14 株式会社日本触媒 可作为热潜在性聚合引发剂使用的组合物
CN102101897A (zh) * 2010-12-24 2011-06-22 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用
CN102101897B (zh) * 2010-12-24 2013-02-06 上海化工研究院 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用

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HUP9904148A2 (hu) 2000-03-28
ZA976998B (en) 1999-02-08
NZ333877A (en) 2000-08-25
RU2196776C2 (ru) 2003-01-20
SA97180735B1 (ar) 2006-10-08
PL331526A1 (en) 1999-07-19
WO1998006728A1 (en) 1998-02-19
EP1021454A1 (en) 2000-07-26
ZA976999B (en) 1999-02-08
ID18005A (id) 1998-02-19
NO990546L (no) 1999-03-29
AU3964797A (en) 1998-03-06
AU716659B2 (en) 2000-03-02
SK15299A3 (en) 2000-03-13
CA2262377A1 (en) 1998-02-19
JP2000516608A (ja) 2000-12-12
HUP9904148A3 (en) 2003-03-28
AR009034A1 (es) 2000-03-08
BR9711115A (pt) 1999-08-17
CO4870709A1 (es) 1999-12-27
NO990546D0 (no) 1999-02-05
CZ42499A3 (cs) 1999-07-14
KR20000029853A (ko) 2000-05-25
TR199900589T2 (xx) 1999-07-21

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