CN1521145A - Crystalline glaze with metallic luster for ceramic of building sanitation - Google Patents
Crystalline glaze with metallic luster for ceramic of building sanitation Download PDFInfo
- Publication number
- CN1521145A CN1521145A CNA031180906A CN03118090A CN1521145A CN 1521145 A CN1521145 A CN 1521145A CN A031180906 A CNA031180906 A CN A031180906A CN 03118090 A CN03118090 A CN 03118090A CN 1521145 A CN1521145 A CN 1521145A
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- Prior art keywords
- glaze
- ceramic
- oxide
- crystalline glaze
- crystalline
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- 239000000919 ceramic Substances 0.000 title claims abstract description 18
- 239000002932 luster Substances 0.000 title abstract description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004327 boric acid Substances 0.000 claims abstract description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 14
- 238000010276 construction Methods 0.000 claims description 12
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 8
- 229960004643 cupric oxide Drugs 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000005034 decoration Methods 0.000 abstract description 4
- 239000013078 crystal Substances 0.000 abstract description 3
- 230000004907 flux Effects 0.000 abstract description 3
- 239000002241 glass-ceramic Substances 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 239000010949 copper Substances 0.000 abstract description 2
- 229910052814 silicon oxide Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract 2
- 239000003086 colorant Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 210000004127 vitreous body Anatomy 0.000 abstract 1
- 239000000463 material Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000005496 eutectics Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 241001300078 Vitrea Species 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000048 melt cooling Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The crystalline glaze with metallic color and luster for building and sanitary ceramic is produced with zinc oxide, silicon oxide or titanium oxide as the crystallizing matter, low temperature fused block and boric acid as flux for forming glaze vitreous body, and the oxide of Cu, Fe, Mn, Ti and other metal as coloring agent, and through common ceramic glaze producing process. It is applied to the surface of building and sanitary ceramic and baked through fast continuous procedure. Adopting special short crystal forming period forms glass ceramic layer with metallic color and luster on the glaze surface and makes the glaze possess decorative metallic color and luster and high mechanical strength similar to glass ceramic. The present invention may be used widely in the surface decoration of various building ceramic products and sanitary ceramic products.
Description
The invention belongs to the new enamel of a kind of construction sanitary ceramic decoration.
Generally adopt glassiness color glaze to decorate at present in the construction sanitary ceramic field, these color glaze have with the base substrate cooperation better, in a great variety, lower-price characteristic, but it exists glaze softer, can not form defectives such as metalluster.The crystalline glaze technology is also used in the daily art pottery, and a kind of decoration glaze of star, needle-like or the thick aggregate of floral leaf shape also can not form full overglaze metallic luster but it is just distributing on glaze.Now along with people to improving constantly that the construction sanitary ceramic decorative art requires, each enterprise constantly releases the product of various imitative stone materials, but all still untapped construction sanitary ceramic product that goes out to imitate metalluster.
The objective of the invention is to develop the new glaze of metallic surface glossy construction sanitary ceramic such as a kind of imitative gold and silver, copper.
Technology contents of the present invention mainly is the prescription problem that solves glaze, and according to the graceful crystallization theory of Thailand, the melt crystallization at first will have the one-tenth eutectic substance that is in hypersaturated state, to form nucleus; When next is the melt cooling, must in the crystalline range of this material, be incubated, so that the nucleus growing, and the different choice of holding temperature and soaking time can be controlled brilliant size and the shape of spending again.Imitative metalluster crystalline glaze can produce brilliant flower under certain calcining system, brilliant flower specification comprises large, medium and small, crystallite flower, and brilliant flower Board Lot, distribution density can be controlled by technological measures such as crystal seed ratio, glaze amount, calcining systems.Large, medium and small, brilliant flower is because the light refraction effect of wafer produces reflecting effect, and is painted by metal oxide, forms versicolor gloss.The present invention is exactly a this reflective characteristic of utilizing brilliant flower, develops from prescription to be fit to the crystalline glaze prescription that construction sanitary ceramic becomes the porcelain scope, and wherein zinc oxide, silicon oxide and titanium oxide are the eutectic substance that becomes of above-mentioned glaze; Low temperature melts alkynes, boric acid for forming the Vitrea flux raw material of glaze; Cupric oxide, ferric oxide, manganese oxide, titanium oxide etc. are tinting material, and it is painted that glaze glass and crystalline substance are spent.Because crystallizing layer of the present invention is thicker, crystal grain distributes uniform, is equivalent to form a glass-ceramic layer in billet surface, has improved the physical strength of glaze layer greatly, thereby ornamental brick has been risen to the class level of polished tile.
The object of the present invention is achieved like this: with the one-tenth eutectic substance of crystalline glaze, form Vitrea flux raw material of glaze and metal oxide tinting material and mix by a certain percentage, be made by the preparation method of general pottery with glaze.
Golden gloss crystalline glaze material formula weight percent is formed:
Low temperature frit: 30～75% boric acid: 0.1～3% zinc oxide: 20～35%
Titanium oxide: 1～35% cupric oxide: 0.1～0.5%
Coppery gloss crystalline glaze material formula weight percent is formed:
Low temperature frit: 30～75% boric acid, 0.1～3% zinc oxide: 20～35%
Titanium oxide: 1～35% ferric oxide: 0.5～5% manganese oxide: 0.5～3%
Silvering crystalline glaze material formula weight percent is formed:
Low temperature frit 30～75%, boric acid 0.1～0.3%, zinc oxide 20～35%
Cupric oxide 0.1～2.5%
The low temperature frit that this assembly side uses comprises a kind of of glass, boron frit, lead frit and plumbous boron frit.
Compared with prior art, the present invention has following characteristics:
1, having utilized the reflecting effect of brilliant flower wafer in the crystalline glaze, produced the glaze with metalluster, made that the surface decoration effect of construction sanitary ceramic is abundanter, is a brand-new field.
2, because this crystalline glaze is equivalent to form one deck devitrified glass on base substrate, improves the overglaze physical strength greatly, as imposed on the floor tile, will rise to ornamental brick the class level of polished tile.
Embodiment one: golden gloss crystalline glaze material formula weight percent composition is:
Low temperature frit: 65% boric acid: 2% zinc oxide: 26%
Titanium oxide: 6.6% cupric oxide: 0.4%
Embodiment two: coppery gloss crystalline glaze material formula weight percent composition is:
Low temperature frit: 65% boric acid: 2% zinc oxide: 26%
Titanium oxide: 4% ferric oxide: 1.5% manganese oxide: 1.5%
Embodiment three: silvering crystalline glaze material formula weight percent composition is:
Low temperature frit: 65% boric acid: 2.5% zinc oxide: 31%
Cupric oxide: 1.5%
Above-mentioned glaze preparation technology controlling index is:
1, glaze fineness: 10000-hole sieve surpluss 0.01～1.5%
2, glaze concentration: 15～75%
3, glazing thickness: 0.01～5.0mm
4, glazing mode: drench, soak, spray, get rid of glaze and all can.
Above-mentioned glaze is imposed on when burning till on the floor tile, and its heating curve that burns till roller kiln is:
Normal temperature → 800～1300 ℃ 20～60mim;
800～1300℃→ 600～1220℃ 1～60mim；
At 600～1220 ℃ of soaking time: 5～120mim.
Claims (4)
1, a kind of construction sanitary ceramic metalluster crystalline glaze is characterized in that: the basic percentage composition part and the proportioning of this crystallization glaze are:
Raw material: proportioning (wt%)
Low temperature frit: 30～75%
Boric acid: 0.1～3%
Zinc oxide: 20～35%
2, construction sanitary ceramic according to claim 1 metalluster crystalline glaze is characterized in that: being golden glossy crystalline glaze is to have added 1～35% titanium oxide and 0.1～0.5% cupric oxide in its basic proportioning.
3, construction sanitary ceramic according to claim 1 metalluster crystalline glaze is characterized in that: being coppery glossy crystalline glaze is to have added 1～35% titanium oxide, 0.5～5% ferric oxide and 0.5～3% manganese oxide in its basic proportioning.
4, construction sanitary ceramic according to claim 1 metalluster crystalline glaze is characterized in that: be silvery crystalline glaze and be add 0.1～2.5% cupric oxide in its basic proportioning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031180906A CN1521145A (en) | 2003-02-14 | 2003-02-14 | Crystalline glaze with metallic luster for ceramic of building sanitation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031180906A CN1521145A (en) | 2003-02-14 | 2003-02-14 | Crystalline glaze with metallic luster for ceramic of building sanitation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1521145A true CN1521145A (en) | 2004-08-18 |
Family
ID=34284823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031180906A Pending CN1521145A (en) | 2003-02-14 | 2003-02-14 | Crystalline glaze with metallic luster for ceramic of building sanitation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1521145A (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1321094C (en) * | 2005-12-23 | 2007-06-13 | 胡武强 | Ceramic glaze material and method for burning ceramic glaze |
| CN100410197C (en) * | 2007-02-02 | 2008-08-13 | 南安协进建材有限公司 | A kind of metal glaze production method |
| CN100455549C (en) * | 2007-06-14 | 2009-01-28 | 湖南华联瓷业股份有限公司 | Medium and high temperature sintered coarse crystalline Fe-Ti glaze and its prepn process |
| CN101880178A (en) * | 2010-07-13 | 2010-11-10 | 广东道氏标准制釉股份有限公司 | Ceramic glazed tile with gold metal effect and preparation method thereof |
| CN101935233A (en) * | 2010-09-28 | 2011-01-05 | 广东道氏标准制釉股份有限公司 | A kind of low-temperature silver-white metallic luster glaze and preparation method thereof |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102701792A (en) * | 2012-06-19 | 2012-10-03 | 卡罗比亚釉料（昆山）有限公司 | Black glaze for preparing ceramic |
| CN102795839A (en) * | 2012-08-22 | 2012-11-28 | 陈永定 | Method for manufacturing red clay flambe-glazed pottery product |
| CN103992695A (en) * | 2014-05-21 | 2014-08-20 | 佛山远牧数码科技有限公司 | Ceramic printing ink with crystallizing effect, and preparation and application methods thereof |
| CN104193411A (en) * | 2014-08-05 | 2014-12-10 | 广东道氏技术股份有限公司 | Crystalline glaze for sanitary ceramic sanitary ware and preparation process thereof |
| CN105152685A (en) * | 2015-10-19 | 2015-12-16 | 福建省德化县华茂陶瓷有限公司 | Matte metal glaze, matte metal glaze ceramic product prepared from same and preparation method of matte metal glaze ceramic product |
| CN105565907A (en) * | 2015-12-23 | 2016-05-11 | 蒙娜丽莎集团股份有限公司 | Production method of flambe crystal pattern seeding color-fixing ceramic tile |
| CN106430967A (en) * | 2016-08-31 | 2017-02-22 | 广东金意陶陶瓷有限公司 | Dyeing-assistant fancy glaze capable of promoting pigment color development and ceramic tile prepared from same |
| CN106565281A (en) * | 2016-11-14 | 2017-04-19 | 蒙娜丽莎集团股份有限公司 | Fully-polished-glaze ceramic tile with metal particles and metallic luster and manufacturing method thereof |
| CN106626935A (en) * | 2016-09-30 | 2017-05-10 | 詹良富 | High-temperature preparing method of metallic color effect embosses capable of overlaying gold and metallic color effect embosses |
| CN106747660A (en) * | 2015-11-20 | 2017-05-31 | 广东顺祥陶瓷有限公司 | A kind of zinc boron fritted glaze high |
| CN108715517A (en) * | 2018-08-30 | 2018-10-30 | 佛山市荣冠玻璃建材有限公司 | Potlery tile low temperature is burnt joss sticks Bin golden metallic luster glaze and preparation method slowly |
| US20210269370A1 (en) * | 2005-05-09 | 2021-09-02 | Ideal Standard International Nv | Antimicrobial Glaze and Porcelain Enamel via Double Layer Glaze with High Zinc Content |
| CN113562976A (en) * | 2021-09-24 | 2021-10-29 | 佛山市道氏科技有限公司 | Gold foil effect particles for ceramics, preparation method of gold foil effect particles and glaze |
| CN115140941A (en) * | 2022-07-25 | 2022-10-04 | 景德镇欧神诺陶瓷有限公司 | Full-raw silver gray metallic luster glaze, foundation wall brick and preparation method thereof |
-
2003
- 2003-02-14 CN CNA031180906A patent/CN1521145A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210269370A1 (en) * | 2005-05-09 | 2021-09-02 | Ideal Standard International Nv | Antimicrobial Glaze and Porcelain Enamel via Double Layer Glaze with High Zinc Content |
| CN1321094C (en) * | 2005-12-23 | 2007-06-13 | 胡武强 | Ceramic glaze material and method for burning ceramic glaze |
| CN100410197C (en) * | 2007-02-02 | 2008-08-13 | 南安协进建材有限公司 | A kind of metal glaze production method |
| CN100455549C (en) * | 2007-06-14 | 2009-01-28 | 湖南华联瓷业股份有限公司 | Medium and high temperature sintered coarse crystalline Fe-Ti glaze and its prepn process |
| CN101880178A (en) * | 2010-07-13 | 2010-11-10 | 广东道氏标准制釉股份有限公司 | Ceramic glazed tile with gold metal effect and preparation method thereof |
| CN101880178B (en) * | 2010-07-13 | 2012-03-28 | 广东道氏技术股份有限公司 | Ceramic glazed tile with gold metal effect and preparation method thereof |
| CN101935233A (en) * | 2010-09-28 | 2011-01-05 | 广东道氏标准制釉股份有限公司 | A kind of low-temperature silver-white metallic luster glaze and preparation method thereof |
| CN101935233B (en) * | 2010-09-28 | 2011-07-27 | 广东道氏标准制釉股份有限公司 | Low-temperature glaze with silver white metal luster and preparation method thereof |
| CN102249739A (en) * | 2011-05-26 | 2011-11-23 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102249739B (en) * | 2011-05-26 | 2013-01-16 | 山西高陶瓷业有限责任公司 | Preparation method of carbon-golden metallic luster crystalline glaze |
| CN102701792A (en) * | 2012-06-19 | 2012-10-03 | 卡罗比亚釉料（昆山）有限公司 | Black glaze for preparing ceramic |
| CN102701792B (en) * | 2012-06-19 | 2014-02-05 | 卡罗比亚釉料（昆山）有限公司 | Black glaze for preparing ceramic |
| CN102795839B (en) * | 2012-08-22 | 2014-03-05 | 陈永定 | Method for manufacturing red clay flambe-glazed pottery product |
| CN102795839A (en) * | 2012-08-22 | 2012-11-28 | 陈永定 | Method for manufacturing red clay flambe-glazed pottery product |
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| CN105152685A (en) * | 2015-10-19 | 2015-12-16 | 福建省德化县华茂陶瓷有限公司 | Matte metal glaze, matte metal glaze ceramic product prepared from same and preparation method of matte metal glaze ceramic product |
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| CN105565907A (en) * | 2015-12-23 | 2016-05-11 | 蒙娜丽莎集团股份有限公司 | Production method of flambe crystal pattern seeding color-fixing ceramic tile |
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| CN106626935A (en) * | 2016-09-30 | 2017-05-10 | 詹良富 | High-temperature preparing method of metallic color effect embosses capable of overlaying gold and metallic color effect embosses |
| CN106565281B (en) * | 2016-11-14 | 2019-09-06 | 蒙娜丽莎集团股份有限公司 | A full polished glazed ceramic tile with metal particles and luster and preparation method thereof |
| CN106565281A (en) * | 2016-11-14 | 2017-04-19 | 蒙娜丽莎集团股份有限公司 | Fully-polished-glaze ceramic tile with metal particles and metallic luster and manufacturing method thereof |
| CN108715517A (en) * | 2018-08-30 | 2018-10-30 | 佛山市荣冠玻璃建材有限公司 | Potlery tile low temperature is burnt joss sticks Bin golden metallic luster glaze and preparation method slowly |
| CN113562976A (en) * | 2021-09-24 | 2021-10-29 | 佛山市道氏科技有限公司 | Gold foil effect particles for ceramics, preparation method of gold foil effect particles and glaze |
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