CN1865590A - Form stable cellulose series fiber structure and its processing method - Google Patents
Form stable cellulose series fiber structure and its processing method Download PDFInfo
- Publication number
- CN1865590A CN1865590A CNA2006100824295A CN200610082429A CN1865590A CN 1865590 A CN1865590 A CN 1865590A CN A2006100824295 A CNA2006100824295 A CN A2006100824295A CN 200610082429 A CN200610082429 A CN 200610082429A CN 1865590 A CN1865590 A CN 1865590A
- Authority
- CN
- China
- Prior art keywords
- cellulose
- resin
- processing
- processing method
- fibrous structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000003672 processing method Methods 0.000 title claims abstract description 34
- 229920002678 cellulose Polymers 0.000 title claims abstract description 22
- 239000001913 cellulose Substances 0.000 title claims abstract description 22
- 239000000835 fiber Substances 0.000 title description 28
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 123
- 229920005989 resin Polymers 0.000 claims abstract description 105
- 239000011347 resin Substances 0.000 claims abstract description 105
- 239000003054 catalyst Substances 0.000 claims abstract description 64
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- 238000012545 processing Methods 0.000 claims abstract description 42
- 238000000034 method Methods 0.000 claims abstract description 41
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000011282 treatment Methods 0.000 claims abstract description 32
- 229940015043 glyoxal Drugs 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 239000011941 photocatalyst Substances 0.000 claims abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims description 3
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims description 3
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims 2
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(III) oxide Inorganic materials O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims 1
- 229920003043 Cellulose fiber Polymers 0.000 abstract description 34
- 230000037303 wrinkles Effects 0.000 abstract description 23
- 150000001412 amines Chemical class 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 description 21
- 239000012530 fluid Substances 0.000 description 15
- 230000000877 morphologic effect Effects 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 7
- 238000012805 post-processing Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- -1 compile thing Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000002781 deodorant agent Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- QQLILYBIARWEIF-UHFFFAOYSA-N 2-(2-hydroxyethylsulfonyl)ethanol Chemical compound OCCS(=O)(=O)CCO QQLILYBIARWEIF-UHFFFAOYSA-N 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 206010016590 Fibrin deposition on lens postoperative Diseases 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910000416 bismuth oxide Inorganic materials 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 238000002207 thermal evaporation Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- UWFRVQVNYNPBEF-UHFFFAOYSA-N 1-(2,4-dimethylphenyl)propan-1-one Chemical compound CCC(=O)C1=CC=C(C)C=C1C UWFRVQVNYNPBEF-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- HDPLHDGYGLENEI-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COC(C)COCC1CO1 HDPLHDGYGLENEI-UHFFFAOYSA-N 0.000 description 1
- SEFYJVFBMNOLBK-UHFFFAOYSA-N 2-[2-[2-(oxiran-2-ylmethoxy)ethoxy]ethoxymethyl]oxirane Chemical compound C1OC1COCCOCCOCC1CO1 SEFYJVFBMNOLBK-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical class CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical class CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- LTOATULEBMBWSO-UHFFFAOYSA-N acetic acid;2-ethoxyethanol Chemical compound CC(O)=O.CCOCCO LTOATULEBMBWSO-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000009992 mercerising Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/52—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment combined with mechanical treatment
- D06M13/53—Cooling; Steaming or heating, e.g. in fluidised beds; with molten metals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/062—Load-responsive characteristics stiff, shape retention
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
形态稳定性纤维素系纤维结构物的加工方法，是对纤维素系纤维结构物给予含有非甲醛树脂加工剂及树脂加工用催化剂的处理液后、进行热处理而使树脂加工剂与纤维素反应的形态稳定性纤维素系纤维结构物的加工方法，其中，在上述处理液的给予前或热处理后，使用含光催化剂的化学品处理纤维素系纤维结构物。采用本发明的加工方法，安全性高，也基本上不产生乙二醛系非甲醛树脂导致的胺臭，而且抑制白度降低，并且可对纤维素系纤维结构物赋予洗涤耐久性好的高的防皱性、高的W&W性。A method for processing a cellulose-based fibrous structure with form stability, which is to apply a treatment liquid containing a non-formaldehyde resin processing agent and a catalyst for resin processing to the cellulose-based fibrous structure, and then heat-treat the cellulose-based fibrous structure to cause the resin processing agent and cellulose to react A method for processing a form-stabilized cellulose-based fibrous structure, wherein the cellulose-based fibrous structure is treated with a photocatalyst-containing chemical before administration of the treatment liquid or after heat treatment. Adopt the processing method of the present invention, safety is high, also basically do not produce the amine odor that glyoxal type non-formaldehyde resin causes, and suppress whiteness to reduce, and can give the cellulose fiber structure good durability high Excellent wrinkle resistance, high W&W performance.
Description
Technical field
The present invention relates to the processing method of cellulose fibre works, more particularly, the whiteness that relates to the generation that do not produce free formaldehyde and can suppress the resin foul smell and grey cloth changes, can obtain the processing method of morphological stability cellulose fibre works of the high wrinkle resistant effect of form stable level and the morphological stability cellulose fibre works that adopts this method to make.
Background technology
In the past,, various resin finishing agent or resin finishing method have been studied for the morphological stability of giving wrinkle resistant or shrink resistance etc. to the cellulose fibre works.
Yet the grey cloth of cellulose fibre goes out the reason that wrinkle or grey cloth shrink, be cellulosic amorphous regions hydrogen bond by the effect of external force or water destroy deform, regeneration hydrogen bond and the consequence that produces in this state.
Grey cloth is given wrinkle resistant or shrink resistance by resin finishing, be utilize to use the resin finishing agent to make to generate between cellulosic molecule crosslinked, should be crosslinked by importing, above-mentioned hydrogen bond is subjected to the effect of external force or water to be difficult to destruction.This occasion, generally being to use Lauxite, glyoxal is the method for the so-called cellulose reactive resin of resin or melmac etc. as the resin finishing agent.
In addition, also know, use polyurethane resin to form film, limit the method that fiber moves in order to be to implement wrinkle resistant processing to grey cloth.
Yet, adopt to use the processing method of above-mentioned cellulose reactive resin, though can obtain wrinkle resistance to a certain degree really,, produce powerful the reduction along with the increase of resin content, also have resin hydrolyzing to produce the problem of free formaldehyde etc.In addition, use the method for polyurethane resin, though do not produce free formaldehyde, the gained wrinkle resistance is very low, can not obtain the wrinkle resistance of form stable level.
Also use formaldehyde during wrinkle resistant being processed with, but the formaldehyde of high concentration brings harmful effect to human body.Therefore, cellulosic resin cross-linking agent improves to the direction that the free formaldehyde generation is lower, and now, low formaldehyde type resin crosslinking agent is practicability.In addition, also proposed not produce fully the non-formaldehyde resin processing method of free formaldehyde, but can not obtain sufficient wrinkle resistance or whiteness, at present also not as form stable processing practicability.
As the processing method of using the non-formaldehyde resin processing agent that does not produce free formaldehyde, having proposed use (a) glyoxal is non-formaldehyde resin, (b) BHES (two hydroxyethyl sulfone), (c) epoxy resin, (d) the wrinkle resistant processing of polybasic carboxylic acid.But occasion (a) has the processing grey cloth because resin decomposes sex change and produces the smelly shortcoming that waits foreign odor of amine.(b), the occasion of (c) because the variation of whiteness is big, and occasion (d) is because the obvious hardening of feel, so during the high goods of the use resin concentration of form stable processing etc., the influence of problem is big, does not all have practicability.
In addition, known document related to the present invention has following.
[patent documentation 1] spy opens flat 10-168741 communique
Summary of the invention
The invention provides the processing method of the morphological stability cellulose fibre works that does not produce free formaldehyde, wrinkle resistance that the form stable given level that washing resistance is good is high and the good cellulose fibre works of form stable performance that adopts this method to make.
The result that the present inventor concentrates on studies in order to achieve the above object repeatedly, discovery is containing non-formaldehyde resin processing agent and resin finishing with behind the treatment fluid of catalyst to the cellulose fibre works, heat-treat in the processing method of the morphological stability cellulose fibre works that makes resin finishing agent and fibrin reaction, carry out preliminary treatment by before giving the resin finishing agent, giving photochemical catalyst in advance to the cellulose fibre works, or after giving the resin finishing agent and heat-treating, give photochemical catalyst and carry out post processing, can prevent that resin from decomposing the generation foul smell, suppress the variation of whiteness, simultaneously can not produce free formaldehyde, and give high wrinkle resistance to fiber structure, can obtain W﹠amp; The morphological stability cellulose fibre works that W (noniron finish) property is good, thus the present invention finished.
That is, as above-mentioned, do not produce the cellulose reactive resin of free formaldehyde fully, it is non-formaldehyde resin that (a) glyoxal is arranged, (b) BHES (two hydroxyethyl sulfone), (c) epoxy resin, (d) polybasic carboxylic acid.Yet (a) glyoxal is that non-formaldehyde resin has resin to decompose the smelly problem of sex change generation amine.(b) BHES is remarkable because of xanthochromia, can not bleach processing.(c) epoxy resin is because of making the cellulose green change of fluorescent whitening agent, so can not bleach processing, (d) polybasic carboxylic acid need once form acid anhydrides, owing to need high temperature etc. this moment, so the problem of variable color and feel hardening is arranged.(b), (c), (d) are because wrinkle resistance is also not enough, so be not suitable for the form stable processing of high wrinkle resistance.
In addition, to (a) glyoxal is non-formaldehyde resin, the catalyst that anti-resin decomposes sex change has also been proposed, but use when lacking reactive non-formaldehyde resin and obtain the high wrinkle resistance of form stable level with cellulose, in order to improve reactivity, resin concentration also must be high, and so the also necessary higher catalyst of choice reaction is insufficient.Except that such problem, even use these catalyst, the light time of also shining sunshine etc. in addition produces the problem of foul smell.The present invention is the research that can solve these conventional art problems, can give the form stable performance of height to the cellulose fibre works.
Therefore, the invention provides:
(1) processing method of morphological stability cellulose fibre works, be after the cellulose fibre works is contained non-formaldehyde resin processing agent and the treatment fluid of resin finishing with catalyst, heat-treat the processing method of the morphological stability cellulose fibre works that makes resin finishing agent and fibrin reaction, it is characterized in that, above-mentioned treatment fluid give preceding or heat treatment after, use the chemical treatments cellulose fibre works contain photochemical catalyst.
(2) above-mentioned (1) described processing method is characterized in that, gives the back at treatment fluid and carries out drying at 80-130 ℃, heat-treats at 140-170 ℃.
(3) above-mentioned (1) or (2) described processing method, wherein non-formaldehyde resin processing agent are that glyoxal is non-formaldehyde resin.
(4) any one described processing method of above-mentioned (1), (2) or (3), wherein non-formaldehyde resin processing agent is 10-30 quality % with respect to the adhesion amount of fiber structure.
(5) any one described processing method of above-mentioned (1)-(4), wherein the resin finishing catalyst is the catalyst that is selected from fluorine boronated compound, inorganic metal salt and inorganic acid.
(6) any one described processing method of above-mentioned (1)-(5), wherein resin finishing is the 1-6 quality % of resin finishing agent with the use amount of catalyst.
(7) any one described processing method of above-mentioned (1)-(6), wherein photochemical catalyst is the catalyst that is selected from titanium oxide, iron oxide, zinc oxide, tungstic acid, bismuth oxide, strontium titanates, cadmium oxide, cerium oxide, contains the silica composite titanium oxide.
(8) any one described processing method of above-mentioned (1)-(7), wherein photochemical catalyst is 0.1-5 quality % with respect to the adhesion amount of fiber structure.
(9) morphological stability cellulose fibre works is characterized in that, is to adopt any one described processing method of above-mentioned (1)-(8) to make.
Adopt processing method of the present invention, because of not producing free formaldehyde, so it is safe, it is smelly also not produce non-formaldehyde resin, particularly glyoxal basically and be the amine that non-formaldehyde resin causes, and suppress whiteness reduction and intensity reduction, and can give the good height wrinkle resistance of washing resistance, high W﹠amp to the cellulose fibre works; W.
Processing method of the present invention, be after the cellulose fibre works is contained non-formaldehyde resin processing agent and the resin finishing usefulness treatment fluid of catalyst, heat-treat the processing method of the morphological stability cellulose fibre works that makes resin finishing agent and fibrin reaction, above-mentioned treatment fluid give preceding or heat treatment after, use the chemical treatments cellulose fibre works contain photochemical catalyst.
Here, as cellulose fibre works of the present invention, can enumerate fabric, compile thing, nonwoven fabric etc.As the cellulose fibre that constitutes these fiber structures, can enumerate the native cellulose fibre of cotton, fiber crops etc., the regenerated celulose fibre of viscose rayon, cuprammonium rayon (cuprammonium rayon), テ Application セ Le (refined cellulose), koplon etc., the semi-regenerated fibre cellulose fiber of acetic acid esters etc.Wherein, consider, especially preferably contain more than the cotton fiber 30 quality %, particularly more than the 50 quality %, can be particularly suitable for using the fiber structure of cotton fiber 100 quality % from the viewpoint of water imbibition, hygroscopicity, feel etc.
To these cellulose fibre works, can implement as required in advance to singe, known processing such as destarch, kiering, bleaching, mercerising processing.In addition, this cloth also can dye or stamp.
Processing method of the present invention is used the above-mentioned fiber structure of chemical treatments that contains photochemical catalyst, makes photochemical catalyst attached on the fiber structure.This occasion is used the processing of the chemicals that contains photochemical catalyst, carries out before giving the resin finishing agent or after the heat treatment.By using photochemical catalyst, can utilize photochemical catalyst to prevent to use non-formaldehyde resin, particularly glyoxal is worrying stink compositions such as the amine of fibre structure deposits yields of occasion of non-formaldehyde resin processing is smelly, can further improve comfortableness.
Before giving the resin finishing agent, use the chemicals that contains photochemical catalyst to handle the occasion of (preliminary treatment), elder generation carries out drying after above-mentioned fiber structure is contained the chemicals (aqueous dispersions) of photochemical catalyst, makes and adheres to photochemical catalyst on the fiber structure.
Here, as the photochemical catalyst that uses among the present invention, for example can enumerate titanium oxide, iron oxide, zinc oxide, tungstic acid, bismuth oxide, strontium titanates, cadmium oxide, cerium oxide, contain silica composite titanium oxide etc., these can use slurried catalyst, pasty state catalyst and the grained catalyst that is dispersed in water, the alcohol etc. arbitrarily.
Among the present invention, have easy use and effect in mind, be particularly suitable for using titanium oxide and contain the silica composite titanium oxide.The crystal type of titanium oxide can be enumerated Detitanium-ore-type, rutile-type, and brookite type etc., the titanium oxide of any system of crystallization as long as have the photochemical catalyst performance, then can be fit to use.
The use amount of photochemical catalyst with respect to the quality of fiber structure (being untreated), is pressed the preferred 0.1-5 quality of solid component concentration %, preferred especially 0.5-4 quality %.The adhesion amount of photochemical catalyst is not brought into play deodorizing effect very little the time sometimes, and when too many, feel is hardened, and grey cloth intensity reduces sometimes, the color albefaction.
The method that makes fiber structure adhere to photochemical catalyst so long as can make fiber structure adhere to above-mentioned chemicals, then can be any method, can adopt the baking method of rolling, known method such as method in rubbing method, spray-on process, the bath.Wherein consider the preferred especially baking method of rolling of using from the viewpoint of operation or good economy performance.
The processing of baking method is rolled in employing, fiber structure is immersed in the chemicals that contains photochemical catalyst, in order to make photochemical catalyst become above-mentioned scope to the adhesion amount of fiber structure, for example press the pick-up rate jam of 50-70%, at baking temperature 90-170 ℃, especially handled 1-3 minute down at 100-150 ℃, particularly handled 1-2 minute, make fiber structure adhere to chemicals.Here, when baking temperature is too low, prolong the operation reduction drying time sometimes.
Then, above-mentioned fiber structure is contained non-formaldehyde resin processing agent and the resin finishing treatment fluid (aqueous dispersions) with catalyst, make fiber structure impregnation treatment fluid.
Among the present invention,, it is characterized in that using and dissociate the non-formaldehyde resin processing agent of formaldehyde the fiber structure after processed not as the resin finishing agent.As non-formaldehyde resin, can enumerate N, the glyoxal of N '-dimethyl dihydroxy ethylidene-urea etc. is that the polybasic carboxylic acid of non-formaldehyde resin, citric acid, BTCA, maleic acid, oxalic acid, adipic acid etc. is non-formaldehyde resin, the epoxy of ethylene glycol diglycidylether, diethylene glycol diglycidyl ether, propylene glycol diglycidylether etc. is non-formaldehyde resin, and the sulfone of BHES (two beta-hydroxy ethyl sulfone) etc. is a non-formaldehyde resin etc.Wherein, the low or variable color of preferred whiteness, the few glyoxal of feel sclerosis are the N of resin, N '-dimethyl dihydroxy ethylidene-urea.
The resin finishing agent is to the adhesion amount of cellulose fibre works, and with respect to the quality of the cellulose fibre works (being untreated) of implementing processing, preferably becoming the solid branch is 10-30 quality %, is more preferably 15-20 quality %.Adhesion amount can not be given full play to the effect of resin finishing very little the time sometimes, and when too many, sometimes along with resin finishing, the intensity of fiber structure reduces or obviously produces foreign odor.In order to obtain morphological stability, the concentration of the resin that expectation gives is to keep the maximum concentration of practical intensity.
The treatment fluid that uses among the present invention in order to improve resin finishing agent and cellulosic reactivity, promptly carries out resin finishing, so add the resin finishing catalyst.As this catalyst, so long as the catalyst that common resin finishing is used does not then have particular restriction, for example, can enumerate ammonium fluoroborate, sodium fluoborate, potassium fluoborate, zinc fluoroborate, the fluorine boronated compound of fluoboric acid magnesium etc., magnesium chloride, magnesium sulfate, the inorganic metal salt catalyst of magnesium nitrate etc., phosphoric acid, hydrochloric acid, sulfuric acid, sulfurous acid, hydrosulfurous acid, the inorganic acid of boric acid etc. etc.These catalyst can also and be used as the organic acid etc. of the citric acid, tartaric acid, malic acid, maleic acid etc. of co-catalyst as required.
Above-mentioned resin finishing is with the use amount of catalyst, and with respect to the resin finishing agent, preferred 1-6 quality % is more preferably 1-2 quality %.The use amount of catalyst is not carried out cross-linking reaction very little the time sometimes, and when too many, grey cloth produces aging sometimes.In order to obtain morphological stability, the catalyst concn that expectation gives is the maximum concentration that can keep practical intensity.
In addition, in the treatment fluid, as required, can add the auxiliary agent of the reaction that is used for carrying out smoothly cellulose and resin finishing agent.That is, auxiliary agent is to promote resin finishing agent and cellulosic reaction, also plays the reaction dissolvent that reacts equably in the generation cross-linking reaction, and the material that makes cellulose swelling action etc. is arranged again.
As above-mentioned auxiliary agent, for example, can enumerate glycerine, ethylene glycol, polyethylene glycol, the polyalcohols of polypropylene glycol etc., ethylene glycol monoethyl ether, diethylene glycol monoethyl ether, glycol monoethyl ether, diethylene glycol monomethyl ether, the ether alcohol class of diethylene glycol monobutyl ether etc., dimethyl formamide, morpholine, 2-Pyrrolidone, dimethylacetylamide, the nitrogen-containing solvent class of N-Methyl pyrrolidone etc., ethyl acetate, isopropyl acetate, butyl acetate, amyl acetate, acetic acid glycol monoethyl ether, the acetic acid ethylene glycol monoethyl ether, the ester class of gamma-butyrolacton etc. etc.
In addition, in the treatment fluid of the present invention, except that mentioned component, can also add the softener adjusting feel and use as required, as the surfactant of bleeding agent etc.
The method that the cellulose fibre works is given above-mentioned treatment fluid does not have particular restriction, can adopt the common baking method of rolling, rubbing method, spray-on process, known method such as method in the bath.Wherein especially consider, can preferably adopt the baking method of rolling of using stenter from the viewpoint of operation or good economy performance.
Roll in the baking method, be preferably in the treatment fluid of resinous processing agent and catalyst behind the impregnation of fibers works, for example press the pick-up rate jam of 50-120%, at baking temperature 80-130 ℃, preferred especially 90-110 ℃ processing time 1-10 minute, dry moisture under preferred 1-3 minute the condition makes resin finishing agent and catalyst become the adhesion amount of above-mentioned scope with respect to fiber structure especially.Baking temperature is a low temperature as far as possible preferably, but when being lower than 90 ℃, must be long-time dry, when surpassing 130 ℃, resin finishing agent is sometimes moved, and problems such as resin finishing agent uneven distribution occur, can not obtain desired morphological stability.
After rolling baking, in order to make resin and cellulose crosslinked, must heat treatment (baking), heat-treat condition is 140-170 ℃, preferred 150-160 ℃ temperature, 2-10 minute, preferably 2-6 minute.The baking machine that heat treatment is used does not have particular determination yet, can use stenter.But consider from operation or cost aspect, preferably after drying, then use stenter to heat-treat.Heat treatment temperature and time are depended on the kind of resin, the resin use amount, and the kind of catalyst, addition of catalyst etc., but heat treatment temperature is when being lower than 140 ℃, reaction is carried out slack-off, when surpassing 170 ℃, produces the improper problem of grey cloth flavescence etc. sometimes.
The fiber structure that heat treatment obtains preferably through washing the loose resin finishing agent of flush away etc., is regulated pH through using the washings that neutralize such as sodium carbonate.
Roll the baking back in case make, heat-treat this occasion after also can making, heat-treat condition can be roughly the same, but owing to making/wash after the heat treatment, and or give the photochemical catalyst difficulty, so can when preliminary treatment, adhere to photochemical catalyst in advance, carry out resin finishing.
The present invention can also use the processing (post processing) of the chemicals that contains photochemical catalyst after heat treatment except that above-mentioned method.The treatment conditions of this occasion can be same as described above.
In addition, in the chemicals that the present invention uses except that mentioned component, also can be as required, contain softener that the adjustment feel uses, deodorant, cloth hard finishing agent, Functional Chemicals etc.
At last, also can dye as required, napping, soft finish processing etc.
If adopt processing method of the present invention, not only be non-formaldehyde, and keep sufficient whiteness, and can give high wrinkle resistance to the cellulose fibre works.In addition, as described later, the cellulose fibre works that adopts the inventive method to make because washing resistance is good, can reach high W﹠amp; W, the amine that produces glyoxal hardly and be non-formaldehyde resin is smelly, so can claim that practical value is high.
The specific embodiment
Below, enumerate embodiment and comparative example is described more specifically the present invention, but the present invention is not limited by following embodiment.
Embodiment 1
Adopt usual method with cotton 100% through 40 yarn flat fabric of 50 * latitude (148 pieces/inch of warp counts, 70 pieces/inch of weft counts) bleaching ,-34 ℃ carry out 10 second the liquefied ammonia dipping, liquefied ammonia is removed in the mistake thermal evaporation then.
Use the multistage stenter to adopt to this fabric and roll the non-formaldehyde resin treatment fluid that baking method (100 ℃ * 120 seconds) gives prescription shown in the table 1, then use the multistage stenter to carry out baking in 160 ℃ * 2 minutes, after the washing, the chemicals of prescription shown in the use table 2 adopts and rolls baking method (120 ℃ * 1 minute) enforcement post processing, carries out wrinkle resistant processing.
Resin adhesion amount with respect to fabric is 18 quality %, and the adhesion amount of photochemical catalyst is 1.5 quality %.
Table 1
| Resin formula | Concentration | |
| Glyoxal is a resin | Off イ Network サ プ レ ッ ト NF (BASF system) | 280g/l |
| Acidic catalyst | Zn(BF 4) 2(gloomy field chemistry system) | 42g/l |
| Softener | Off ア イ Application テ ッ Network ス PE140 (big Japanese ink system) | 20g/l |
| Softener | エ ヴ ア Off ア ノ one Le N-7 (solar corona chemistry system) | 20g/l |
Table 2
| The post processing prescription | Concentration | |
| Photochemical catalyst * | FIS02FS (clear and electrician's system) | 20g/l |
| Softener | シ リ コ one ラ Application 810M-50 (a side society system) | 20g/l |
| Can make improving agent | Off ア イ Application テ ッ Network ス PE140 (big Japanese ink system) | 20g/l |
* contain silica composite titanium oxide slurry
Adopt following method to estimate W﹠amp to the fabric that makes; W, wrinkle resistance are carried out the foul smell sensory test.The results are shown in table 4.
W﹠amp; W evaluation method: JIS L 1096
Washing/drying method: JIS L217 103 methods/roller drying
Anti-opening: adopt JIS L1096 TENSILE STRENGTH and percentage elongation A method (mark the Schlieren method) to measure
Tear: adopt JIS L1096 tearing strength D method (pendulum method) to measure
The foul smell official can test method: grey cloth 10g is packed in the 200ml flask, and 48 hours solar radiations are carried out in sealing.
＜evaluation criterion〉zero: odorless roughly
△: foul smell slightly
*: the foul smell flavor is dense
Embodiment 2
Except making drying is 130 ℃ * 60 seconds, and making baking is that other are handled similarly to Example 1, similarly estimate outside 160 ℃ * 2 minutes the condition.The results are shown in table 4.
Embodiment 3
Except making baking is that other are handled similarly to Example 1, similarly estimate 145 ℃ * 4 minutes the condition.The results are shown in table 4.
Comparative example 1
Except do not add photochemical catalyst in the post processing prescription, other are handled similarly to Example 1, similarly estimate.The results are shown in table 4.
Comparative example 2
(Off レ ッ シ ュ シ ラ イ マ ッ FS-500M (loose tail medicine industry system) the replacement photochemical catalyst, other are handled similarly to Example 1, similarly estimate except add natural deodorant in the post processing prescription of following table 3.The results are shown in table 4.
Table 3
| The post processing prescription | Concentration | |
| Natural deodorant | Off レ ッ シ ュ シ ラ イ マ ッ FS-500M (loose tail medicine industry) | 50g/l |
| Softener | シ リ コ one ラ Application 810M-50 (a side society system) | 20g/l |
| Can make improving agent | Off ア イ Application テ ッ Network ス PE140 (big Japanese ink system) | 10g/l |
Table 4
| W﹠W (level) | Anti-open (kg) | Tear (g) | The foul smell official can test | |
| Embodiment 1 | 3.1 | 32.8 | 950 | ○ |
| Embodiment 2 | 2.9 | 38.0 | 1120 | ○ |
| Embodiment 3 | 3.1 | 24.0 | 650 | ○ |
| Comparative example 1 | 3.1 | 32.8 | 950 | × |
| Comparative example 2 | 3.1 | 33.2 | 960 | × |
Embodiment 4
Adopt usual method that cotton 100% is bleached through 40 yarn flat fabric of 50 * latitude (148 pieces/inch of warp counts, 70 pieces/inch of weft counts),, cross thermal evaporation then and remove liquefied ammonia at-34 ℃ of dipping liquefied ammonia in 10 second.
Using the employing of multistage stenter to roll baking method (120 ℃ * 60 seconds) to this fabric gives the pretreating agent shown in the table 5, then uses the multistage stenter to adopt and roll the non-formaldehyde resin treatment fluid that baking method (100 ℃ * 120 seconds) gives table 6.Then, after severing is made, use trolley conveyer formula apparatus for baking to carry out wrinkle resistant processing through baking (150 ℃ * 6 minutes).
Resin adhesion amount to fabric is 18 quality %, and the adhesion amount of photochemical catalyst is 1.5 quality %.
Table 5
| The preliminary treatment prescription | Concentration | |
| Photochemical catalyst | FIS02FS (clear and electrician's system) | 20g/l |
Table 6
| Resin formula | Concentration | |
| Glyoxal is a resin | Off イ Network サ プ レ ッ ト NF (BASF system) | 280g/l |
| Acidic catalyst | Zn(BF 4) 2(gloomy field chemistry system) | 28g/l |
| Softener | Off ア イ Application テ ッ Network ス PE140 (big Japanese ink system) | 20g/l |
| Softener | エ ヴ ア Off ア ノ one Le N-7 (solar corona chemistry system) | 10g/l |
| Softener | シ リ コ one ラ Application 810M-50 (a side society system) | 30g/l |
Adopt method similarly to Example 1 to estimate W﹠amp to the fabric that makes; W, wrinkle resistance is carried out the foul smell official and can be tested.The results are shown in table 9.
Comparative example 3
Except not carrying out preliminary treatment, handle similarly to Example 4, similarly estimate.The results are shown in table 9.
Comparative example 4
Except the pretreating agent of table 7 expression, handle similarly to Example 4, similarly estimate.The results are shown in table 9.
Table 7
| The preliminary treatment prescription | Concentration | |
| Natural deodorant | Off レ ッ シ ュ シ ラ イ マ ッ FS-500M (loose tail medicine industry system) | 50g/l |
Comparative example 5
Except the resin treatment liquid of not preliminary treatment and table 8, handle similarly to Example 4, similarly estimate.The results are shown in table 9.
Table 8
| Resin formula | Concentration | |
| Glyoxal is a resin | Off イ Network サ プ レ ッ ト NF (BASF system) | 280g/l |
| Acidic catalyst | Condensol N (BASF system) | 84g/l |
| Softener | Off ア イ Application テ ッ Network ス PE140 (big Japanese ink system) | 20g/l |
| Softener | エ ヴ ア Off ア ノ one Le N-7 (solar corona chemistry system) | 10g/l |
| Suction type softener | シ リ コ one ラ Application 810M-50 (a side society system) | 30g/l |
Table 9
| W﹠W (level) | Anti-open (kg) | Tear (g) | The foul smell official can test | |
| Embodiment 4 | 3.1 | 34.3 | 790 | ○ |
| Comparative example 3 | 3.1 | 36.0 | 980 | × |
| Comparative example 4 | 3.1 | 34.0 | 880 | × |
| Comparative example 5 | 2.3 | 34.0 | 870 | × |
Claims (9)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2005144193 | 2005-05-17 | ||
| JP2005144193A JP4081578B2 (en) | 2005-05-17 | 2005-05-17 | Method for removing amine odor from cellulosic fiber structure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1865590A true CN1865590A (en) | 2006-11-22 |
Family
ID=37424722
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006100824295A Pending CN1865590A (en) | 2005-05-17 | 2006-05-16 | Form stable cellulose series fiber structure and its processing method |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP4081578B2 (en) |
| KR (1) | KR100796673B1 (en) |
| CN (1) | CN1865590A (en) |
| TW (1) | TW200710303A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502969A (en) * | 2017-09-26 | 2017-12-22 | 成都新柯力化工科技有限公司 | A kind of textile fabric and preparation method with self-cleaning function |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PE20210519A1 (en) * | 2017-09-12 | 2021-03-17 | Cotton Inc | IMPROVING THE BALANCE OF PERMANENT IRONING PROPERTIES OF COTTON FABRICS USING FORMALDEHYDE-FREE TECHNOLOGY |
| KR102383575B1 (en) | 2021-10-19 | 2022-04-08 | (주)쿨베어스 | Treatment composition which is harmless to human body and eco-friendly for improving shape stability of fabrics |
| KR102445205B1 (en) | 2022-08-01 | 2022-09-20 | 주식회사 케이컴퍼니 | Textile coating composition for preventing crease, crease resistant textile and method for fabricating the same |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02139478A (en) * | 1988-08-10 | 1990-05-29 | Kanebo Ltd | Cellulosic textile product and production thereof |
| JP2000136484A (en) * | 1998-10-30 | 2000-05-16 | Asahi Chem Ind Co Ltd | Processing method of cellulose fabric |
-
2005
- 2005-05-17 JP JP2005144193A patent/JP4081578B2/en not_active Expired - Fee Related
-
2006
- 2006-04-25 TW TW095114762A patent/TW200710303A/en unknown
- 2006-04-25 KR KR1020060037127A patent/KR100796673B1/en not_active Expired - Fee Related
- 2006-05-16 CN CNA2006100824295A patent/CN1865590A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107502969A (en) * | 2017-09-26 | 2017-12-22 | 成都新柯力化工科技有限公司 | A kind of textile fabric and preparation method with self-cleaning function |
| CN107502969B (en) * | 2017-09-26 | 2019-05-10 | 常州市海格超细纺织品有限公司 | A kind of textile fiber with self-cleaning function and preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200710303A (en) | 2007-03-16 |
| KR20060119750A (en) | 2006-11-24 |
| JP2006322091A (en) | 2006-11-30 |
| KR100796673B1 (en) | 2008-01-21 |
| JP4081578B2 (en) | 2008-04-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106661131B (en) | Process for producing cellulose carbamate | |
| JP2020518713A (en) | Processing method for textile products | |
| FI77252C (en) | FOER FARING FOR FRAMSTAELLNING AV CELLULOSAKARBAMATER. | |
| CN1119030A (en) | Fiber treatment method | |
| CN1147281A (en) | Treatment method for reducing fibrillation tendency of lyocell fiber fabric | |
| EP0943027B1 (en) | Method for treating cellulosic shaped bodies | |
| EP1509548B1 (en) | Method for the production of cellulose carbamate moulded bodies | |
| CN1077184C (en) | Fabric treatment | |
| CN1865590A (en) | Form stable cellulose series fiber structure and its processing method | |
| JP6195896B2 (en) | Lignocellulose spinning solution, lignocellulose regenerated fiber and method for producing the same | |
| CN1106477C (en) | Shrink-proof treatment of celluosic fiber textile | |
| CN1148480C (en) | Process for processing fibrous cellulosic material | |
| CN1146684C (en) | Method for treating cellulose fibres and fibrous products made of such fibres | |
| JPH10168741A (en) | Resin processing of woven or knitted fabric containing cellulose fiber | |
| CN1734012A (en) | Method for processing cellulose-based fiber-containing fabric and cellulose-based fiber-containing fabric | |
| CN116856173A (en) | Fabric with anti-wrinkle and color-retaining functions and preparation method thereof | |
| DE69208311T2 (en) | Process for the creasing of cotton textiles without the use of formaldehyde | |
| CN1177094C (en) | Process for the production of cellulose-containing textile materials | |
| CN1730800A (en) | Method for Locating and Stripping Dyeing Defects of Silk Fabrics | |
| CN108866674A (en) | A kind of nanometer oil suction fibre of high oil absorption amount and preparation method thereof | |
| JPH11511764A (en) | Method for producing aqueous solution of N-methylmorpholine-N-oxide | |
| EP1713970B1 (en) | Method for treating textiles | |
| JP2893920B2 (en) | Fiber resin processing method | |
| CN1298770C (en) | Method for improving anti-sun factor of cellulose material | |
| CN105908553B (en) | A kind of non-cotton cellulosic method for bleaching |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20061122 |