CS199214B2 - Insecticide and acaricide and method of producing active ingredient - Google Patents

Insecticide and acaricide and method of producing active ingredient Download PDF

Info

Publication number: CS199214B2
Authority: CS; Czechoslovakia
Prior art keywords: spec; active ingredient; formula; fluorophenoxy; chloride
Prior art date: 1977-07-06

Application number

CS784410A

Other languages

Czech (cs)

English (en)

Inventor

Rainer Fuchs

Ingeborg Hammann

Wilhelm Stendel

Original Assignee

Bayer Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-07-06

Filing date

1978-07-03

Publication date

1980-07-31

1978-07-03 Application filed by Bayer Ag filed Critical Bayer Ag

1980-07-31 Publication of CS199214B2 publication Critical patent/CS199214B2/cs

Links

239000004480 active ingredient Substances 0.000 title claims description 26
230000000895 acaricidal effect Effects 0.000 title claims description 7
238000000034 method Methods 0.000 title description 20
239000000642 acaricide Substances 0.000 title 1
239000002917 insecticide Substances 0.000 title 1
-1 phenoxybenzyl alcohols Chemical class 0.000 claims description 42
239000002904 solvent Substances 0.000 claims description 24
239000002253 acid Substances 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 12
YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical class OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 claims description 10
239000000460 chlorine Substances 0.000 claims description 9
239000001257 hydrogen Substances 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 9
229910052736 halogen Inorganic materials 0.000 claims description 8
150000002367 halogens Chemical class 0.000 claims description 8
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
229910052801 chlorine Inorganic materials 0.000 claims description 7
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
239000011737 fluorine Substances 0.000 claims description 6
229910052731 fluorine Inorganic materials 0.000 claims description 6
230000000749 insecticidal effect Effects 0.000 claims description 6
239000011230 binding agent Substances 0.000 claims description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
125000004093 cyano group Chemical group *C#N 0.000 claims description 3
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125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 2
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
238000004519 manufacturing process Methods 0.000 claims description 2
125000003545 alkoxy group Chemical group 0.000 claims 1
229910052740 iodine Inorganic materials 0.000 claims 1
125000001424 substituent group Chemical group 0.000 claims 1
239000013543 active substance Substances 0.000 description 21
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Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Landscapes

Life Sciences & Earth Sciences (AREA)
Dentistry (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Agronomy & Crop Science (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CS784410A 1977-07-06 1978-07-03 Insecticide and acaricide and method of producing active ingredient CS199214B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19772730515 DE2730515A1 (de)	1977-07-06	1977-07-06	Substituierte phenoxybenzyloxycarbonylderivate, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide

Publications (1)

Publication Number	Publication Date
CS199214B2 true CS199214B2 (en)	1980-07-31

Family

ID=6013281

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS784410A CS199214B2 (en)	1977-07-06	1978-07-03	Insecticide and acaricide and method of producing active ingredient

Country Status (22)

Country	Link
US (2)	US4276306A (fr)
EP (2)	EP0011695B1 (fr)
JP (2)	JPS5414946A (fr)
AR (1)	AR227617A1 (fr)
AT (1)	AT361251B (fr)
AU (1)	AU520095B2 (fr)
BR (1)	BR7804334A (fr)
CA (1)	CA1254227C (fr)
CS (1)	CS199214B2 (fr)
DD (2)	DD139991A5 (fr)
DE (3)	DE2730515A1 (fr)
DK (1)	DK160300C (fr)
EG (1)	EG13788A (fr)
ES (2)	ES471461A1 (fr)
GR (1)	GR71682B (fr)
HU (1)	HU176473B (fr)
IL (1)	IL55061A (fr)
IT (1)	IT1097465B (fr)
PH (1)	PH16779A (fr)
PT (1)	PT68252A (fr)
TR (1)	TR20790A (fr)
ZA (1)	ZA783869B (fr)

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US4200644A (en) *	1978-01-26	1980-04-29	Fmc Corporation	Arylthiovinylcyclopropanecarboxylate insecticides
DE2844271A1 (de) *	1978-10-11	1980-04-24	Bayer Ag	3-chlorostyryl-2,2-dimethyl-cyclopropancarbonsaeure-(4-fluoro-3-phenoxy- alpha -cyano-benzyl)-ester, verfahren zu ihrer herstellung und ihre verwendung als ektoparasitizide
DE2842542A1 (de) *	1978-09-29	1980-04-17	Bayer Ag	Substituierte bromostyryl-cyclopropancarbonsaeurephenoxybenzylester, verfahren zu ihrer herstellunnd ihre verwendung als insektizide und akarizide
DE2852028A1 (de) *	1978-12-01	1980-06-12	Bayer Ag	Mittel gegen keratinschaedlinge und verfahren zur behandlung von wolle mit diesen mitteln
IT1166681B (it) *	1979-03-09	1987-05-06	Montedison Spa	Piretroidi
CA1142953A (fr) *	1979-04-03	1983-03-15	Dale G. Brown	Methode de preparation d'esters pesticides a partir de certains acides carboxyliques a l'aide de catalyseurs a transfert de phase
DE2920947A1 (de) *	1979-05-23	1980-12-04	Bayer Ag	2-phenyl-alken-1-yl-cyclopropan- carbonsaeureester, verfahren zu ihrer herstellung sowie ihre verwendung als insektizide und akarizide und zwischenprodukte zu ihrer herstellung
DE2922481A1 (de) *	1979-06-01	1980-12-11	Bayer Ag	Elektroparasitizide mittel enthaltend substituierte phenoxybenzyloxycarbonylderivate, (ihio)phosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung als ektoparasitizide
FR2471187A1 (fr) *	1979-12-10	1981-06-19	Roussel Uclaf	Nouvelles compositions destinees a la lutte contre les parasites des animaux a sang chaud
FR2484256B1 (fr) *	1979-06-29	1986-10-24	Roussel Uclaf	Procede de lutte contre les parasites des animaux a sang chaud
DE2929645A1 (de) *	1979-07-21	1981-02-12	Bayer Ag	Verfahren zur herstellung von 1,1- dichloralkenen
US4296241A (en) *	1979-07-21	1981-10-20	Bayer Aktiengesellschaft	Preparation of 3-(2,2-dichlorovinyl)-2,2-dimethyl-cyclopropane-1-carboxylic acid derivatives
DE2936864A1 (de)	1979-09-12	1981-04-02	Bayer Ag, 5090 Leverkusen	(+-)-trans-3-(e, z-2-chlor-2-(4-chlorphenyl)-vinyl)-, 2,2-dimethyl-cyclopropan-carbonsaeure-(+-)-(alpha)-cyano-3-phenoxy-4-fluor-benzyl)-ester, die einzelnen e- und z-isomeren, verfahren zur herstellung dieser verbindungen und ihre verwendung als ektoparasitizide
DE3025218A1 (de) *	1980-07-03	1982-02-11	Bayer Ag, 5090 Leverkusen	1-aryl-cyclopropan-1-carbonsaeureester, verfahren zu deren herstellung und deren verwendung in schaedlingsbekaempfungsmitteln
DE3029426A1 (de) *	1980-08-02	1982-03-11	Bayer Ag, 5090 Leverkusen	Gegen zwecken wirksame pour-on-formulierungen
DE3033158A1 (de) *	1980-09-03	1982-04-01	Bayer Ag, 5090 Leverkusen	Optisch aktive isomere von trans-3-(2-chlor-2-(4-chlor-phenyl)-vinyl)-2,2-dimethyl-cyclopropan-1-carbonsaeure-((alpha)-cyano-4-fluor-3-phenoxy-benzyl)-ester, verfahren zu deren herstellung und deren verwendung als ektoparasitizide
JPS5786014A (en) *	1980-11-18	1982-05-28	Ishida Scales Mfg Co Ltd	Measuring or counting method by combination
US5286749A (en) *	1980-11-21	1994-02-15	Pitman-Moore Inc.	Control of sheep ectoparasites
DE3048021A1 (de) *	1980-12-19	1982-07-15	Bayer Ag, 5090 Leverkusen	Insektizide und akarizide mittel und ihre verwendung
JPS57169627A (en) *	1981-04-13	1982-10-19	Yamato Scale Co Ltd	Combination balance
JPS57175923A (en) *	1981-04-24	1982-10-29	Yamato Scale Co Ltd	Combined balance
DE3127752A1 (de) *	1981-07-14	1983-02-03	Bayer Ag, 5090 Leverkusen	Verfahren zur herstellung von permethrinsaeurementhylester
JPS5819516A (ja) *	1981-07-28	1983-02-04	Ishida Scales Mfg Co Ltd	複数の種類の品物の混合組合せ計量方法
JPS5892914A (ja) *	1981-11-30	1983-06-02	Ishida Scales Mfg Co Ltd	組合せ演算装置
DE3208334A1 (de) *	1982-03-09	1983-09-15	Bayer Ag, 5090 Leverkusen	Pestizide pour-on-formulierungen
JPS59622A (ja) *	1982-06-26	1984-01-05	Anritsu Corp	組合せ計量装置
DE3333657A1 (de) *	1983-09-17	1985-04-25	Bayer Ag, 5090 Leverkusen	Pyrethroide enthaltende formkoerper zur bekaempfung von ektoparasiten
DE3538688A1 (de) *	1985-10-31	1987-05-07	Bayer Ag	Verfahren zur bekaempfung von parasitosen bei bienen
AU615879B2 (en) *	1986-08-27	1991-10-17	Montedison S.P.A.	Derivatives of 2,2-dimethyl-cyclopropanecarboxylic acid
DE3629387A1 (de) *	1986-08-29	1988-03-03	Bayer Ag	Verfahren zur diastereomerentrennung von cyclopropancarbonsaeureestern
JPH02100028U (fr) *	1989-01-25	1990-08-09
DE3906556A1 (de) *	1989-03-02	1990-09-06	Desowag Materialschutz Gmbh	Mittel oder konzentrat zum konservieren von holz oder holzwerkstoffen
DE3907069A1 (de) *	1989-03-04	1990-09-06	Basf Ag	Substituierte 2-phenyl-alk(en)yl-1-yl-cyclopropancarbonsaeurebenzylester, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung von schaedlingen
CN107365252A (zh) *	2016-05-11	2017-11-21	江苏优士化学有限公司	3-(2-氯-2-(4-氯苯基)乙烯基)-2,2-二甲基环丙烷羧酸的合成方法

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FR1507192A (fr) *	1966-08-26	1967-12-29	Roussel Uclaf	Nouvelles aryl allylsulfones et procédé de préparation
US3786052A (en) *	1966-08-26	1974-01-15	J Martel	Novel cyclopropanecarboxylic acids and esters
NL133054C (fr) *	1967-11-10
SE386669B (sv) *	1968-07-12	1976-08-16	Roussel Uclaf	Sett att framstella inre hemiacylalen av cis-3,3-dimetyl-2-formylcyklopropan-1-karbonsyra
US3666789A (en) *	1969-05-21	1972-05-30	Sumitomo Chemical Co	Cyclopropanecarboxylic acid esters
FR2067854A5 (en) *	1969-11-19	1971-08-20	Roussel Uclaf	Subst vinyl cyclo-propane-1-carboxylic acids insecticidal prepn
JPS5220473B1 (fr) *	1970-06-29	1977-06-03
JPS515450B1 (fr) *	1971-06-29	1976-02-20
US4024163A (en) *	1972-05-25	1977-05-17	National Research Development Corporation	Insecticides
FR2248264B1 (fr) *	1973-10-22	1977-05-27	Roussel Uclaf
IN142702B (fr) *	1974-09-10	1977-08-20	Sagami Chem Res
JPS5813522B2 (ja) *	1974-10-24	1983-03-14	住友化学工業株式会社	新しいシクロプロパンカルボン酸エステルを含有する殺虫、殺ダニ剤
US3966959A (en) *	1975-02-13	1976-06-29	American Cyanamid Company	Insecticidal and acaricidal, pyrethroid compounds
CH602005A5 (en)	1976-02-17	1978-07-14	Ciba Geigy Ag	(3)-Phenoxy-benzyl styryl-cyclopropane carboxylates
NL7701321A (nl) *	1976-02-17	1977-08-19	Ciba Geigy	Werkwijze voor de bereiding van een ester.
JPS5828264B2 (ja) *	1976-03-26	1983-06-15	財団法人相模中央化学研究所	ビニルシクロプロパンカルボン酸エステルの製造方法
ZA775160B (en) *	1976-08-27	1978-07-26	Fmc Corp	Insecticidal styryl- and substituted-styrylcyclopropanecarboxylates
CA1260486A (fr) *	1976-08-27	1989-09-26	John F. Engel	Styrylcyclopropanecarboxylates et derive de substitution, insecticides
US4157397A (en) *	1976-08-27	1979-06-05	Fmc Corporation	Insecticidal (β-phenylvinyl)cyclopropanecarboxylates
DE2848495A1 (de) *	1977-11-11	1979-05-17	Ciba Geigy Ag	Cyclopropankarbonsaeureester, verfahren zu ihrer herstellung und ihre verwendung in der schaedlingsbekaempfung
DE2800922A1 (de) *	1978-01-10	1979-07-19	Bayer Ag	Verfahren zur trennung stereoisomerer vinylcyclopropancarbonsaeuren
US4200644A (en) *	1978-01-26	1980-04-29	Fmc Corporation	Arylthiovinylcyclopropanecarboxylate insecticides
DE2810634A1 (de) *	1978-03-11	1979-09-20	Bayer Ag	Pentafluorbenzyloxycarbonylderivate, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
US4358409A (en) *	1979-05-02	1982-11-09	Bayer Aktiengesellschaft	Preparation of styryl cyclopropane insecticide intermediates

1977
- 1977-07-06 DE DE19772730515 patent/DE2730515A1/de not_active Withdrawn
1978
- 1978-06-16 US US05/916,163 patent/US4276306A/en not_active Expired - Lifetime
- 1978-06-28 DE DE7878100252T patent/DE2860574D1/de not_active Expired
- 1978-06-28 DE DE7979103787T patent/DE2861686D1/de not_active Expired
- 1978-06-28 EP EP79103787A patent/EP0011695B1/fr not_active Expired
- 1978-06-28 EP EP78100252A patent/EP0000345B1/fr not_active Expired
- 1978-07-03 CS CS784410A patent/CS199214B2/cs unknown
- 1978-07-03 IL IL55061A patent/IL55061A/xx unknown
- 1978-07-04 AT AT484278A patent/AT361251B/de not_active IP Right Cessation
- 1978-07-04 CA CA 306758 patent/CA1254227C/fr not_active Expired
- 1978-07-04 DD DD78206509A patent/DD139991A5/de not_active IP Right Cessation
- 1978-07-04 DD DD78215933A patent/DD146286A5/de unknown
- 1978-07-04 IT IT25315/78A patent/IT1097465B/it active Protection Beyond IP Right Term
- 1978-07-04 PT PT68252A patent/PT68252A/pt unknown
- 1978-07-05 AU AU37787/78A patent/AU520095B2/en not_active Expired
- 1978-07-05 ES ES471461A patent/ES471461A1/es not_active Expired
- 1978-07-05 DK DK304178A patent/DK160300C/da not_active IP Right Cessation
- 1978-07-05 HU HU78BA3674A patent/HU176473B/hu not_active IP Right Cessation
- 1978-07-05 BR BR7804334A patent/BR7804334A/pt unknown
- 1978-07-05 GR GR56693A patent/GR71682B/el unknown
- 1978-07-05 JP JP8106878A patent/JPS5414946A/ja active Granted
- 1978-07-05 EG EG420/78A patent/EG13788A/xx active
- 1978-07-05 ZA ZA00783869A patent/ZA783869B/xx unknown
- 1978-07-05 AR AR272845A patent/AR227617A1/es active
- 1978-07-06 TR TR20790A patent/TR20790A/xx unknown
- 1978-07-06 PH PH21337A patent/PH16779A/en unknown
1979
- 1979-03-28 ES ES479021A patent/ES479021A1/es not_active Expired
1982
- 1982-06-24 US US06/391,732 patent/US4611009A/en not_active Expired - Lifetime
1986
- 1986-06-26 JP JP61148365A patent/JPS6248646A/ja active Granted

Also Published As

Publication number	Publication date
IL55061A (en)	1985-04-30
EG13788A (en)	1982-03-31
CA1254227C (fr)	1989-05-16
AU3778778A (en)	1980-01-10
ES471461A1 (es)	1979-09-16
ES479021A1 (es)	1979-07-01
DE2860574D1 (en)	1981-04-23
DD139991A5 (de)	1980-02-06
EP0011695A1 (fr)	1980-06-11
GR71682B (fr)	1983-06-21
JPS5414946A (en)	1979-02-03
PH16779A (en)	1984-02-22
EP0000345B1 (fr)	1981-04-01
AT361251B (de)	1981-02-25
DK160300B (da)	1991-02-25
DE2730515A1 (de)	1979-01-18
US4276306A (en)	1981-06-30
EP0000345A1 (fr)	1979-01-24
PT68252A (de)	1978-08-01
AR227617A1 (es)	1982-11-30
BR7804334A (pt)	1979-04-17
DK304178A (da)	1979-01-07
AU520095B2 (en)	1982-01-14
IT7825315A0 (it)	1978-07-04
JPS6248646A (ja)	1987-03-03
DE2861686D1 (en)	1982-04-29
JPH0127053B2 (fr)	1989-05-26
IT1097465B (it)	1985-08-31
DD146286A5 (de)	1981-02-04
IL55061A0 (en)	1978-09-29
TR20790A (tr)	1982-08-16
EP0011695B1 (fr)	1982-03-24
HU176473B (en)	1981-03-28
DK160300C (da)	1991-07-29
ATA484278A (de)	1980-07-15
ZA783869B (en)	1979-07-25
JPS6218538B2 (fr)	1987-04-23
US4611009A (en)	1986-09-09

Publication	Publication Date	Title
US4276306A (en)	1981-06-30	Combating arthropods with 3-phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates
US4252820A (en)	1981-02-24	Arthropodicidal 2,2-dimethyl-3-(2-perfluoroalkyl-2-perhaloalkyl-vinyl)-cyclopropanecarboxylic acid esters
HU176922B (hu)	1981-06-28	Insekticidnye i akaricidnye kompozicii soderzhahhie zamehhennye fenoksi-benzoil-oxsi-karbonil-soedinenija aktivnymi agentami,i sposob poluchenija aktivnykh agentov
US4485252A (en)	1984-11-27	2-Phenyl-alk-1-enyl-cyclopropane-carboxylic acid intermediates
US4271186A (en)	1981-06-02	Stilbene compounds and insecticidal/acaricidal compositions
CS196210B2 (en)	1980-03-31	Insecticide and acaricide and process for preparing effective compounds
US4199596A (en)	1980-04-22	Combating arthropods with fluorine-substituted phenoxybenzylcarbonyl derivatives
US4423066A (en)	1983-12-27	Combating arthropods with perfluorobenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates
DE2642981A1 (de)	1978-03-30	Alkoxysubstituierte pyrimidinylthionophosphonsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide und akarizide
US4582856A (en)	1986-04-15	Pesticidal 2,2-dimethyl-3-(2-halogeno-vinyl)-cyclopropanecarboxylic acid esters
EP0019090B1 (fr)	1983-05-18	Dérivés substitués de l'acide styrylcyclopropanecarboxylique, procédé pour leur préparation, leur utilisation, insecticides et acaricides, leur fabrication et procédé pour combattre les insectes
EP0206167B1 (fr)	1989-01-04	Esters de l'acide tétraméthylcyclopropanecarbonique
CS209820B2 (en)	1981-12-31	Insecticide and acaricide means and method of making the active substance
EP0007466B1 (fr)	1981-04-15	Esters 2-cyclopropyl-pyrimidin(4)yliques d'acides thionophosphoniques, procédé pour leur préparation, leur utilisation comme insecticides et acaricides, produits pesticides en contenant et procédé de préparation de ces produits pesticides
CS258478B2 (en)	1988-08-16	Insecticide and acaricide and method of efficient substances production
US4279920A (en)	1981-07-21	2,2-Dimethyl-3-(2-bromo-2-phenyl-vinyl)-cyclopropanecarboxylic acid 3-phenoxybenzyl esters and pesticidal use
US4297366A (en)	1981-10-27	Combating arthropods with 2,2-dimethyl-3-(2-fluoroalkyl-2-oxy-vinyl)-cyclopropane-carboxylic acid esters
CS217991B2 (en)	1983-02-25	Insecticide and acaricide means and method of making the active agent
CS227034B2 (en)	1984-04-16	Insecticide and acaricide
DE3126390A1 (de)	1983-01-13	S-azolyl-methyl-di(tri)-thiophosphorsaeureester, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel
US4215141A (en)	1980-07-29	Combating insects and acarids with 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters
EP0009709A1 (fr)	1980-04-16	Esters d'un acide cyclopropanecarboxylique substitués par un groupe fluoroalcényle (I), procédé pour leur préparation, produits intermédiaires obtenus, ainsi que leur préparation, compositions contenant les esters (I) et utilisation des esters (I) pour la lutte contre les insectes ou les araignées
CS264146B2 (en)	1989-06-13	Insecticide and process for preparing active component