CS233708B2 - Catalytic mixture for polymerization of propylene or for mixture of propylene and copolymerizable alpha-olefines - Google Patents

Catalytic mixture for polymerization of propylene or for mixture of propylene and copolymerizable alpha-olefines Download PDF

Info

Publication number: CS233708B2
Authority: CS; Czechoslovakia
Prior art keywords: deac; ticl; catalyst; titanium tetrachloride; polymerization
Prior art date: 1978-02-27

Application number

CS791314A

Other languages

Czech (cs)

English (en)

Inventor

Nikolaus K Balint

Original Assignee

Standard Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-02-27

Filing date

1979-02-27

Publication date

1985-03-14

1979-02-27 Application filed by Standard Oil Co filed Critical Standard Oil Co

1985-03-14 Publication of CS233708B2 publication Critical patent/CS233708B2/cs

Links

239000000203 mixture Substances 0.000 title claims abstract description 31
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 23
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title claims abstract description 23
230000003197 catalytic effect Effects 0.000 title claims abstract description 6
238000006116 polymerization reaction Methods 0.000 title claims description 39
239000002253 acid Substances 0.000 claims abstract description 19
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 102
239000003054 catalyst Substances 0.000 claims description 58
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 39
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 35
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 29
239000003607 modifier Substances 0.000 claims description 19
229910052723 transition metal Inorganic materials 0.000 claims description 8
150000003624 transition metals Chemical class 0.000 claims description 8
239000004711 α-olefin Substances 0.000 claims description 7
229910052782 aluminium Inorganic materials 0.000 claims description 6
XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims description 5
KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 4
241000795633 Olea <sea slug> Species 0.000 claims description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
229910052500 inorganic mineral Inorganic materials 0.000 abstract description 13
239000011707 mineral Substances 0.000 abstract description 13
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 12
239000011593 sulfur Substances 0.000 abstract description 12
229910052717 sulfur Inorganic materials 0.000 abstract description 12
150000001875 compounds Chemical class 0.000 abstract description 11
150000003623 transition metal compounds Chemical class 0.000 abstract description 10
150000008064 anhydrides Chemical class 0.000 abstract description 4
239000002685 polymerization catalyst Substances 0.000 abstract description 4
230000003247 decreasing effect Effects 0.000 abstract 1
238000010348 incorporation Methods 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 87
239000000126 substance Substances 0.000 description 29
229920000642 polymer Polymers 0.000 description 23
235000019645 odor Nutrition 0.000 description 21
239000000047 product Substances 0.000 description 17
238000000034 method Methods 0.000 description 13
150000007513 acids Chemical class 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
238000002474 experimental method Methods 0.000 description 9
-1 tetraalysylsilanes Chemical class 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
229910010062 TiCl3 Inorganic materials 0.000 description 8
239000010936 titanium Substances 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
239000002904 solvent Substances 0.000 description 7
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 7
HOPRXXXSABQWAV-UHFFFAOYSA-N anhydrous collidine Natural products CC1=CC=NC(C)=C1C HOPRXXXSABQWAV-UHFFFAOYSA-N 0.000 description 6
UTBIMNXEDGNJFE-UHFFFAOYSA-N collidine Natural products CC1=CC=C(C)C(C)=N1 UTBIMNXEDGNJFE-UHFFFAOYSA-N 0.000 description 6
239000007788 liquid Substances 0.000 description 6
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
239000007787 solid Substances 0.000 description 6
GFYHSKONPJXCDE-UHFFFAOYSA-N sym-collidine Natural products CC1=CN=C(C)C(C)=C1 GFYHSKONPJXCDE-UHFFFAOYSA-N 0.000 description 6
229910052719 titanium Inorganic materials 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
150000001336 alkenes Chemical class 0.000 description 5
230000007423 decrease Effects 0.000 description 5
239000008188 pellet Substances 0.000 description 5
238000003756 stirring Methods 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
125000005234 alkyl aluminium group Chemical group 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
150000004820 halides Chemical class 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
239000000463 material Substances 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
229920001155 polypropylene Polymers 0.000 description 4
239000002002 slurry Substances 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
229910010061 TiC13 Inorganic materials 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000000178 monomer Substances 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 3
RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
OISVCGZHLKNMSJ-UHFFFAOYSA-N 2,6-dimethylpyridine Chemical compound CC1=CC=CC(C)=N1 OISVCGZHLKNMSJ-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
QPJVMBTYPHYUOC-UHFFFAOYSA-N Methyl benzoate Natural products COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
150000004982 aromatic amines Chemical class 0.000 description 2
238000010923 batch production Methods 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
238000000605 extraction Methods 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000011521 glass Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
229910000041 hydrogen chloride Inorganic materials 0.000 description 2
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910000372 mercury(II) sulfate Inorganic materials 0.000 description 2
229940095102 methyl benzoate Drugs 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
230000000737 periodic effect Effects 0.000 description 2
150000003003 phosphines Chemical class 0.000 description 2
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
229920000098 polyolefin Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 description 2
239000002195 soluble material Substances 0.000 description 2
241000894007 species Species 0.000 description 2
HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 2
235000011149 sulphuric acid Nutrition 0.000 description 2
239000000725 suspension Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 description 2
238000005406 washing Methods 0.000 description 2
JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
LIDGFHXPUOJZMK-UHFFFAOYSA-N 2,6-dimethyl-1-oxidopyridin-1-ium Chemical compound CC1=CC=CC(C)=[N+]1[O-] LIDGFHXPUOJZMK-UHFFFAOYSA-N 0.000 description 1
244000291564 Allium cepa Species 0.000 description 1
235000002732 Allium cepa var. cepa Nutrition 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
235000005979 Citrus limon Nutrition 0.000 description 1
244000131522 Citrus pyriformis Species 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
206010012374 Depressed mood Diseases 0.000 description 1
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical class Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000005233 alkylalcohol group Chemical group 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical class [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
208000007502 anemia Diseases 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
238000000429 assembly Methods 0.000 description 1
230000000712 assembly Effects 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000013590 bulk material Substances 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000005266 casting Methods 0.000 description 1
238000010538 cationic polymerization reaction Methods 0.000 description 1
150000004770 chalcogenides Chemical class 0.000 description 1
239000012295 chemical reaction liquid Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
150000001924 cycloalkanes Chemical class 0.000 description 1
230000002950 deficient Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
150000005195 diethylbenzenes Chemical class 0.000 description 1
238000007865 diluting Methods 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
HPYNZHMRTTWQTB-UHFFFAOYSA-N dimethylpyridine Natural products CC1=CC=CN=C1C HPYNZHMRTTWQTB-UHFFFAOYSA-N 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical compound OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
KEXAJKYAHMNIIT-UHFFFAOYSA-N ethene molybdenum Chemical group [Mo].C=C KEXAJKYAHMNIIT-UHFFFAOYSA-N 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical group OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
150000002483 hydrogen compounds Chemical class 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000005923 long-lasting effect Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
230000036651 mood Effects 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
235000015097 nutrients Nutrition 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002901 organomagnesium compounds Chemical class 0.000 description 1
230000001151 other effect Effects 0.000 description 1
210000001672 ovary Anatomy 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
150000002926 oxygen Chemical class 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
238000000059 patterning Methods 0.000 description 1
230000037048 polymerization activity Effects 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
VBMHLJHEUUUOEG-UHFFFAOYSA-N sulfuric acid sulfur trioxide Chemical compound S(O)(O)(=O)=O.S(=O)(=O)=O.S(O)(O)(=O)=O VBMHLJHEUUUOEG-UHFFFAOYSA-N 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
210000004233 talus Anatomy 0.000 description 1
150000003510 tertiary aliphatic amines Chemical class 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
230000004580 weight loss Effects 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CS791314A 1978-02-27 1979-02-27 Catalytic mixture for polymerization of propylene or for mixture of propylene and copolymerizable alpha-olefines CS233708B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US05/881,828 US4171284A (en)	1978-02-27	1978-02-27	Catalyst system

Publications (1)

Publication Number	Publication Date
CS233708B2 true CS233708B2 (en)	1985-03-14

Family

ID=25379303

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS791314A CS233708B2 (en)	1978-02-27	1979-02-27	Catalytic mixture for polymerization of propylene or for mixture of propylene and copolymerizable alpha-olefines

Country Status (10)

Country	Link
US (1)	US4171284A (fr)
JP (1)	JPS54129080A (fr)
BE (1)	BE874499A (fr)
CA (1)	CA1132131A (fr)
CS (1)	CS233708B2 (fr)
DE (1)	DE2907466A1 (fr)
FR (1)	FR2418244A1 (fr)
GB (1)	GB2015544B (fr)
IT (1)	IT1116842B (fr)
NL (1)	NL7901491A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4324690A (en) *	1979-02-15	1982-04-13	Standard Oil Company (Indiana)	Alpha-olefin polymerization catalyst
US4277370A (en) *	1979-02-15	1981-07-07	Standard Oil Company (Indiana)	Alpha-olefin polymerization catalyst

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3072630A (en) *	1955-03-08	1963-01-08	Du Pont	Polymerization of ethylene using coordination catalyst system with a halide promotor
BE552578A (fr) *	1955-11-14
BE557561A (fr) *	1956-08-02
US2971950A (en) *	1957-08-05	1961-02-14	Montedison Spa	Production of isotactic poly (alpha-olefins) having regulated molecular weight
US3121064A (en) *	1958-01-31	1964-02-11	Hoechst Ag	Hydrogen halide activation of ticl4-alkyl aluminum halide catalysts
US3271381A (en) *	1958-09-15	1966-09-06	Monsanto Co	Polymerization of olefins by use of modified catalysts
US3129256A (en) *	1959-12-01	1964-04-14	Gulf Research Development Co	Alkylation of benzene with propylene in the presence of a catalyst containing titanium tetrachloride, alkyl aluminum sesquichloride, and oxygen
FR1299311A (fr) *	1960-09-03	1962-07-20	Scholven Chemie Ag	Procédé de fabrication de produits de polymérisation à poids moléculaire élevé à partir d'oléfines
US3328366A (en) *	1963-05-23	1967-06-27	Sumitomo Chemical Co	Polymerization of ethylene and an alpha-olefin in the presence of an alkyl aluminum halide, a vanadium compound and an organic compound containing sulfur, oxygen and a halogen
US3627797A (en) *	1965-10-07	1971-12-14	Gen Tire & Rubber Co	Titanium halide-mercaptan and preparation thereof
US3692712A (en) *	1967-07-28	1972-09-19	Ici Ltd	Alpha-olefin polymer composition and process for preparing same
GB1257221A (fr) *	1968-02-28	1971-12-15
DE1770688A1 (de) *	1968-06-21	1971-11-04	Bayer Ag	Verfahren zur Polymerisation von Cyclopenten
JPS4820542B1 (fr) *	1969-07-09	1973-06-21
US3670043A (en) *	1970-03-23	1972-06-13	Donald H Kubicek	OLEFIN CONVERSION PROCESS USING COMPLEXES OF Ti, Zr AND Hf WITH ORGANOALUMINUM AS OLEFIN REACTION CATALYSTS
BE765033R (fr) *	1970-04-06	1971-09-30	Inst Francais Du Petrole	Nouveau procede d'hydrogenation et catalyseurs d'hydrogenation correspondants
US4029866A (en) *	1972-01-28	1977-06-14	Exxon Research And Engineering Company	Cationic polymerization catalyst
US3985677A (en) *	1972-10-27	1976-10-12	The Goodyear Tire & Rubber Company	Preparation of polymerization catalyst and polymerization therewith
CA1039448A (fr) *	1973-12-27	1978-09-26	Mituji Miyoshi	Mode de preparation des polyolefines
JPS5634977A (en) *	1979-08-27	1981-04-07	Kiyotatsu Fukai	Rotary hydraulic machinery

1978
- 1978-02-27 US US05/881,828 patent/US4171284A/en not_active Expired - Lifetime
1979
- 1979-02-15 GB GB7905440A patent/GB2015544B/en not_active Expired
- 1979-02-26 CA CA322,305A patent/CA1132131A/fr not_active Expired
- 1979-02-26 DE DE19792907466 patent/DE2907466A1/de not_active Withdrawn
- 1979-02-26 IT IT48134/79A patent/IT1116842B/it active
- 1979-02-26 NL NL7901491A patent/NL7901491A/xx not_active Application Discontinuation
- 1979-02-27 FR FR7905043A patent/FR2418244A1/fr not_active Withdrawn
- 1979-02-27 CS CS791314A patent/CS233708B2/cs unknown
- 1979-02-27 BE BE0/193739A patent/BE874499A/fr not_active IP Right Cessation
- 1979-02-27 JP JP2247479A patent/JPS54129080A/ja active Granted

Also Published As

Publication number	Publication date
DE2907466A1 (de)	1979-09-06
BE874499A (fr)	1979-08-27
FR2418244A1 (fr)	1979-09-21
CA1132131A (fr)	1982-09-21
IT1116842B (it)	1986-02-10
IT7948134A0 (it)	1979-02-26
JPS54129080A (en)	1979-10-06
JPS6259130B2 (fr)	1987-12-09
US4171284A (en)	1979-10-16
NL7901491A (nl)	1979-08-29
GB2015544A (en)	1979-09-12
GB2015544B (en)	1982-11-10

Publication	Publication Date	Title
FI90248B (fi)	1993-09-30	Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten
ITMI971348A1 (it)	1998-12-09	Componenti e catalizzatori per la polimerizzazione di olefine
US20030008769A1 (en)	2003-01-09	Catalyst
ITMI971350A1 (it)	1998-12-09	Componenti e catalizzatori per la polimerizzazione di olefine
MXPA01010260A (es)	2002-03-27	Productos de adicion de dicloruro de magnesio y alcohol, procedimiento para su preparacion y componentes catalizadores obtenidos de los mismos.
PL106503B1 (pl)	1979-12-31	Katalizator do polimeryzacji i kopolimeryzacji olefin,oraz sposob wytwarzania katalizatora do polimeryzacji i kopolimeryzacji olefin
PL139915B1 (en)	1987-03-31	Method of obtaining a catalyst for polymerisation of alpha olefines
JPS5896613A (ja)	1983-06-08	固型触媒コンプレクス
JPS606962B2 (ja)	1985-02-21	重合触媒および方法
EP0159736A2 (fr)	1985-10-30	Composition de catalyseur pour la polymérisation d'oléfines
PL80658B1 (fr)	1975-08-30
CA1225080A (fr)	1987-08-04	Procede et catalyseur de polymerisation de polyolefines
DE2504597A1 (de)	1975-08-14	Katalysatorsystem zur polymerisation von olefinen, verfahren zu seiner herstellung und seine verwendung
KR100323784B1 (ko)	2002-06-20	프로필렌-에틸렌블럭공중합체의연속제조법
CS233708B2 (en)	1985-03-14	Catalytic mixture for polymerization of propylene or for mixture of propylene and copolymerizable alpha-olefines
DE69030404T2 (de)	1997-11-06	Fester Katalysatorbestandteil für die Olefinpolymerisation
BR112018017259B1 (pt)	2022-11-16	Método para formar uma composição precursora modificada de um catalisador de ziegler-natta (zn)
DE69600487T2 (de)	1998-12-03	Verfahren zur Herstellung eines Ziegler-Natta-Katalysators
JPS585312A (ja)	1983-01-12	ポリオレフインの製造方法
ES2625904T3 (es)	2017-07-20	Proceso para la preparación de un componente catalizador y componentes que se obtienen de este
US3109822A (en)	1963-11-05	catalyst composition
RU2126804C1 (ru)	1999-02-27	Способ получения гомополимеров и сополимеров этилена
JPS60112614A (ja)	1985-06-19	マグネシウムジハライド水和物を使用したオレフィン重合触媒の製造方法
US3031440A (en)	1962-04-24	Polymerization of olefins with a catalyst of a grignard reagent and an aluminum containing titanium composition
SU1135427A3 (ru)	1985-01-15	Способ получени каталитической композиции дл полимеризации этилена и сополимеризации его с бутеном-1