CS250214B2 - Method of simultaneous production of fuel gas and process heat from carbonaceous materials - Google Patents

Method of simultaneous production of fuel gas and process heat from carbonaceous materials Download PDF

Info

Publication number: CS250214B2
Authority: CS; Czechoslovakia
Prior art keywords: gas; fluidized bed; combustion; gasification; reactor
Prior art date: 1981-04-07

Application number

CS822441A

Other languages

Czech (cs)

English (en)

Inventor

Hans Beisswenger

Georg Daradimos

Martin Hirsch

Ludolf Plass

Harry Serbent

Original Assignee

Metallgesellschaft Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-04-07

Filing date

1982-04-05

Publication date

1987-04-16

1982-04-05 Application filed by Metallgesellschaft Ag filed Critical Metallgesellschaft Ag

1987-04-16 Publication of CS250214B2 publication Critical patent/CS250214B2/cs

Links

238000000034 method Methods 0.000 title claims description 52
239000002737 fuel gas Substances 0.000 title claims description 19
239000003575 carbonaceous material Substances 0.000 title claims description 18
238000004519 manufacturing process Methods 0.000 title claims description 14
239000007789 gas Substances 0.000 claims description 112
238000002485 combustion reaction Methods 0.000 claims description 53
239000007787 solid Substances 0.000 claims description 40
238000002309 gasification Methods 0.000 claims description 31
239000003795 chemical substances by application Substances 0.000 claims description 24
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 23
229910052760 oxygen Inorganic materials 0.000 claims description 23
239000001301 oxygen Substances 0.000 claims description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
239000003546 flue gas Substances 0.000 claims description 19
239000000428 dust Substances 0.000 claims description 18
238000006477 desulfuration reaction Methods 0.000 claims description 17
230000023556 desulfurization Effects 0.000 claims description 17
238000012546 transfer Methods 0.000 claims description 17
230000003009 desulfurizing effect Effects 0.000 claims description 16
239000002002 slurry Substances 0.000 claims description 16
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 15
239000003245 coal Substances 0.000 claims description 15
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 13
229910001882 dioxygen Inorganic materials 0.000 claims description 12
150000003839 salts Chemical class 0.000 claims description 11
238000001816 cooling Methods 0.000 claims description 10
239000002245 particle Substances 0.000 claims description 10
229920006395 saturated elastomer Polymers 0.000 claims description 9
239000000047 product Substances 0.000 claims description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
235000019738 Limestone Nutrition 0.000 claims description 5
239000006227 byproduct Substances 0.000 claims description 5
229910052799 carbon Inorganic materials 0.000 claims description 5
239000006028 limestone Substances 0.000 claims description 5
239000007858 starting material Substances 0.000 claims description 5
239000010459 dolomite Substances 0.000 claims description 4
229910000514 dolomite Inorganic materials 0.000 claims description 4
150000003464 sulfur compounds Chemical class 0.000 claims description 3
235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
235000011941 Tilia x europaea Nutrition 0.000 claims 1
239000004571 lime Substances 0.000 claims 1
238000010438 heat treatment Methods 0.000 description 9
239000007788 liquid Substances 0.000 description 9
239000002918 waste heat Substances 0.000 description 5
238000000746 purification Methods 0.000 description 4
238000005201 scrubbing Methods 0.000 description 4
239000004449 solid propellant Substances 0.000 description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
238000007664 blowing Methods 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
238000009833 condensation Methods 0.000 description 3
230000005494 condensation Effects 0.000 description 3
239000002826 coolant Substances 0.000 description 3
MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
238000005406 washing Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
230000007423 decrease Effects 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
239000011261 inert gas Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000010802 sludge Substances 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
235000010216 calcium carbonate Nutrition 0.000 description 1
JGIATAMCQXIDNZ-UHFFFAOYSA-N calcium sulfide Chemical compound [Ca]=S JGIATAMCQXIDNZ-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000003763 carbonization Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000010276 construction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000011043 electrofiltration Methods 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000010304 firing Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
238000005243 fluidization Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
230000017525 heat dissipation Effects 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
239000003077 lignite Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
238000011017 operating method Methods 0.000 description 1
238000013021 overheating Methods 0.000 description 1
230000036284 oxygen consumption Effects 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000003134 recirculating effect Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
239000010454 slate Substances 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
239000008400 supply water Substances 0.000 description 1
125000000101 thioether group Chemical group 0.000 description 1
239000002912 waste gas Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/463—Gasification of granular or pulverulent flues in suspension in stationary fluidised beds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/86—Other features combined with waste-heat boilers
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/005—Fluidised bed combustion apparatus comprising two or more beds
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C10/00—Fluidised bed combustion apparatus
- F23C10/02—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed
- F23C10/04—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone
- F23C10/08—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases
- F23C10/10—Fluidised bed combustion apparatus with means specially adapted for achieving or promoting a circulating movement of particles within the bed or for a recirculation of particles entrained from the bed the particles being circulated to a section, e.g. a heat-exchange section or a return duct, at least partially shielded from the combustion zone, before being reintroduced into the combustion zone characterised by the arrangement of separation apparatus, e.g. cyclones, for separating particles from the flue gases the separation apparatus being located outside the combustion chamber
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2206/00—Fluidised bed combustion
- F23C2206/10—Circulating fluidised bed
- F23C2206/101—Entrained or fast fluidised bed

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Combustion & Propulsion (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Mechanical Engineering (AREA)
General Engineering & Computer Science (AREA)
Fluidized-Bed Combustion And Resonant Combustion (AREA)
Carbon And Carbon Compounds (AREA)

CS822441A 1981-04-07 1982-04-05 Method of simultaneous production of fuel gas and process heat from carbonaceous materials CS250214B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE3113993A DE3113993A1 (de)	1981-04-07	1981-04-07	Verfahren zur gleichzeitigen erzeugung von brenngas und prozesswaerme aus kohlenstoffhaltigen materialien

Publications (1)

Publication Number	Publication Date
CS250214B2 true CS250214B2 (en)	1987-04-16

Family

ID=6129565

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS822441A CS250214B2 (en)	1981-04-07	1982-04-05	Method of simultaneous production of fuel gas and process heat from carbonaceous materials

Country Status (19)

Country	Link
US (1)	US4444568A (fr)
EP (1)	EP0062363B1 (fr)
JP (1)	JPS57179290A (fr)
AR (1)	AR227714A1 (fr)
AT (1)	ATE17866T1 (fr)
AU (1)	AU545446B2 (fr)
BR (1)	BR8201974A (fr)
CA (1)	CA1179846A (fr)
CS (1)	CS250214B2 (fr)
DE (2)	DE3113993A1 (fr)
ES (1)	ES8306785A1 (fr)
FI (1)	FI73724C (fr)
GR (1)	GR75461B (fr)
IE (1)	IE52546B1 (fr)
IN (1)	IN152949B (fr)
MX (1)	MX159901A (fr)
NO (1)	NO155545C (fr)
NZ (1)	NZ199930A (fr)
ZA (1)	ZA822345B (fr)

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DE3428782A1 (de) *	1984-08-04	1986-02-13	Metallgesellschaft Ag, 6000 Frankfurt	Verfahren zur erzeugung von eisenschwamm
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EP0220342A1 (fr) *	1985-11-01	1987-05-06	Metallgesellschaft Ag	Procédé pour traiter un condensat aqueux
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CN101896581B (zh)	2007-12-12	2014-08-27	奥图泰有限公司	生产焦炭和燃料气的方法和装置
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1981
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- 1981-06-17 IN IN657/CAL/81A patent/IN152949B/en unknown
1982
- 1982-03-02 EP EP82200261A patent/EP0062363B1/fr not_active Expired
- 1982-03-02 DE DE8282200261T patent/DE3268909D1/de not_active Expired
- 1982-03-02 AT AT82200261T patent/ATE17866T1/de not_active IP Right Cessation
- 1982-03-05 NZ NZ199930A patent/NZ199930A/en unknown
- 1982-03-21 AR AR288971A patent/AR227714A1/es active
- 1982-03-26 US US06/362,266 patent/US4444568A/en not_active Expired - Lifetime
- 1982-03-30 FI FI821104A patent/FI73724C/fi not_active IP Right Cessation
- 1982-03-30 NO NO821072A patent/NO155545C/no unknown
- 1982-04-02 IE IE796/82A patent/IE52546B1/en unknown
- 1982-04-05 ZA ZA822345A patent/ZA822345B/xx unknown
- 1982-04-05 CS CS822441A patent/CS250214B2/cs unknown
- 1982-04-05 GR GR67820A patent/GR75461B/el unknown
- 1982-04-06 AU AU82389/82A patent/AU545446B2/en not_active Ceased
- 1982-04-06 ES ES511221A patent/ES8306785A1/es not_active Expired
- 1982-04-06 MX MX192185A patent/MX159901A/es unknown
- 1982-04-06 BR BR8201974A patent/BR8201974A/pt not_active IP Right Cessation
- 1982-04-06 CA CA000400511A patent/CA1179846A/fr not_active Expired
- 1982-04-07 JP JP57057960A patent/JPS57179290A/ja active Granted

Also Published As

Publication number	Publication date
JPS57179290A (en)	1982-11-04
AU8238982A (en)	1982-10-14
IN152949B (fr)	1984-05-05
EP0062363B1 (fr)	1986-02-05
ATE17866T1 (de)	1986-02-15
NO821072L (no)	1982-10-08
FI821104A0 (fi)	1982-03-30
NO155545C (no)	1987-04-15
NZ199930A (en)	1985-07-31
CA1179846A (fr)	1984-12-27
FI73724B (fi)	1987-07-31
FI821104L (fi)	1982-10-08
ZA822345B (en)	1983-11-30
EP0062363A1 (fr)	1982-10-13
AR227714A1 (es)	1982-11-30
IE820796L (en)	1982-10-07
DE3113993A1 (de)	1982-11-11
DE3268909D1 (en)	1986-03-20
GR75461B (fr)	1984-07-20
ES511221A0 (es)	1983-06-01
JPH0466919B2 (fr)	1992-10-26
FI73724C (fi)	1987-11-09
AU545446B2 (en)	1985-07-11
IE52546B1 (en)	1987-12-09
US4444568A (en)	1984-04-24
MX159901A (es)	1989-09-29
NO155545B (no)	1987-01-05
ES8306785A1 (es)	1983-06-01
BR8201974A (pt)	1983-03-15

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