CS259535B2 - Macroemulsion and method of its production - Google Patents

Macroemulsion and method of its production Download PDF

Info

Publication number: CS259535B2
Authority: CS; Czechoslovakia
Prior art keywords: weight; optionally; polyvinyl alcohol; average molecular; molecular weight
Prior art date: 1985-04-11

Application number

CS166286A

Other languages

Czech (cs)

English (en)

Inventor

Wolfgang Wirth

Heinz J Niessen

Bernd Klinksiek

Original Assignee

Bayer Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-04-11

Filing date

1986-03-11

Publication date

1988-10-14

1986-03-11 Application filed by Bayer Ag filed Critical Bayer Ag

1988-10-14 Publication of CS259535B2 publication Critical patent/CS259535B2/cs

Links

239000004907 Macro-emulsion Substances 0.000 title claims abstract description 56
238000000034 method Methods 0.000 title claims abstract description 9
238000004519 manufacturing process Methods 0.000 title description 3
229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 32
239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 31
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
239000000654 additive Substances 0.000 claims abstract description 11
239000002728 pyrethroid Substances 0.000 claims abstract description 9
239000007787 solid Substances 0.000 claims abstract description 9
239000002245 particle Substances 0.000 claims abstract description 8
239000002253 acid Substances 0.000 claims abstract description 7
239000000839 emulsion Substances 0.000 claims description 19
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 16
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
239000003921 oil Substances 0.000 claims description 10
239000012071 phase Substances 0.000 claims description 10
239000007864 aqueous solution Substances 0.000 claims description 9
239000008346 aqueous phase Substances 0.000 claims description 8
239000003849 aromatic solvent Substances 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 7
239000000243 solution Substances 0.000 claims description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
238000009835 boiling Methods 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 6
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 5
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
238000002425 crystallisation Methods 0.000 claims description 4
125000004093 cyano group Chemical group *C#N 0.000 claims description 4
229910052731 fluorine Inorganic materials 0.000 claims description 4
125000001153 fluoro group Chemical group F* 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
239000003755 preservative agent Substances 0.000 claims description 4
239000002904 solvent Substances 0.000 claims description 4
239000011877 solvent mixture Substances 0.000 claims description 4
XGOIGQAZIPSVGC-UHFFFAOYSA-N 3-(2,2-dichloroethenyl)-2,2-dimethyl-1-[(2,3,4,5,6-pentafluorophenyl)methyl]cyclopropane-1-carboxylic acid Chemical compound CC1(C)C(C=C(Cl)Cl)C1(C(O)=O)CC1=C(F)C(F)=C(F)C(F)=C1F XGOIGQAZIPSVGC-UHFFFAOYSA-N 0.000 claims description 3
239000005711 Benzoic acid Substances 0.000 claims description 3
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 3
239000007798 antifreeze agent Substances 0.000 claims description 3
235000010233 benzoic acid Nutrition 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
230000008025 crystallization Effects 0.000 claims description 3
230000002401 inhibitory effect Effects 0.000 claims description 3
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
239000002518 antifoaming agent Substances 0.000 claims description 2
150000001555 benzenes Chemical class 0.000 claims description 2
239000003086 colorant Substances 0.000 claims description 2
230000002708 enhancing effect Effects 0.000 claims description 2
239000008096 xylene Substances 0.000 claims description 2
150000003738 xylenes Chemical class 0.000 claims description 2
238000002360 preparation method Methods 0.000 abstract description 6
241000607479 Yersinia pestis Species 0.000 abstract description 3
125000003118 aryl group Chemical group 0.000 abstract description 3
239000003085 diluting agent Substances 0.000 abstract description 3
235000019422 polyvinyl alcohol Nutrition 0.000 description 25
238000004128 high performance liquid chromatography Methods 0.000 description 16
238000003860 storage Methods 0.000 description 12
239000003995 emulsifying agent Substances 0.000 description 5
239000003960 organic solvent Substances 0.000 description 5
239000004480 active ingredient Substances 0.000 description 4
239000013543 active substance Substances 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
239000012141 concentrate Substances 0.000 description 4
230000002110 toxicologic effect Effects 0.000 description 4
231100000723 toxicological property Toxicity 0.000 description 4
LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 3
230000002349 favourable effect Effects 0.000 description 3
239000004530 micro-emulsion Substances 0.000 description 3
239000002562 thickening agent Substances 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000012868 active agrochemical ingredient Substances 0.000 description 2
239000003905 agrochemical Substances 0.000 description 2
HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
239000000975 dye Substances 0.000 description 2
238000009472 formulation Methods 0.000 description 2
230000000622 irritating effect Effects 0.000 description 2
LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
210000004877 mucosa Anatomy 0.000 description 2
239000004476 plant protection product Substances 0.000 description 2
QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
241001454295 Tetranychidae Species 0.000 description 1
230000000895 acaricidal effect Effects 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000001000 anthraquinone dye Substances 0.000 description 1
239000000987 azo dye Substances 0.000 description 1
229940095076 benzaldehyde Drugs 0.000 description 1
229960004365 benzoic acid Drugs 0.000 description 1
229960002836 biphenylol Drugs 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005100 correlation spectroscopy Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
238000003898 horticulture Methods 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000000749 insecticidal effect Effects 0.000 description 1
229960002216 methylparaben Drugs 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002790 naphthalenes Chemical class 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
235000010292 orthophenyl phenol Nutrition 0.000 description 1
QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
238000004382 potting Methods 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
235000010199 sorbic acid Nutrition 0.000 description 1
239000004334 sorbic acid Substances 0.000 description 1
229940075582 sorbic acid Drugs 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

Landscapes

Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Dispersion Chemistry (AREA)
Chemical & Material Sciences (AREA)
Toxicology (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

CS166286A 1985-04-11 1986-03-11 Macroemulsion and method of its production CS259535B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19853512917 DE3512917A1 (de)	1985-04-11	1985-04-11	Makroemulsionen

Publications (1)

Publication Number	Publication Date
CS259535B2 true CS259535B2 (en)	1988-10-14

Family

ID=6267680

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS166286A CS259535B2 (en)	1985-04-11	1986-03-11	Macroemulsion and method of its production

Country Status (3)

Country	Link
CS (1)	CS259535B2 (pl)
DE (1)	DE3512917A1 (pl)
PL (1)	PL147429B1 (pl)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DK220987A (da) *	1987-04-30	1988-10-31	Cheminova As	Olie-i-vand-praeparat til anvendelse som pesticidt middel, og fremgangsmaade til bekaempelse af skadeli-ge organismer hermed

1985
- 1985-04-11 DE DE19853512917 patent/DE3512917A1/de not_active Withdrawn
1986
- 1986-03-11 PL PL25836386A patent/PL147429B1/pl unknown
- 1986-03-11 CS CS166286A patent/CS259535B2/cs unknown

Also Published As

Publication number	Publication date
DE3512917A1 (de)	1986-10-16
PL147429B1 (en)	1989-06-30

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