CS261660B1 - Flux for welding with a high-alloyed band electricity - Google Patents

Flux for welding with a high-alloyed band electricity Download PDF

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CS261660B1
CS261660B1 CS874477A CS447787A CS261660B1 CS 261660 B1 CS261660 B1 CS 261660B1 CS 874477 A CS874477 A CS 874477A CS 447787 A CS447787 A CS 447787A CS 261660 B1 CS261660 B1 CS 261660B1
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oxide
flux
welding
alloyed
calcium
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CS874477A
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Czech (cs)
Slovak (sk)
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CS447787A1 (en
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Rudolf Ing Funk
Juraj Ing Kollarik
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Rudolf Ing Funk
Juraj Ing Kollarik
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Priority to CS874477A priority Critical patent/CS261660B1/en
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Publication of CS261660B1 publication Critical patent/CS261660B1/en

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Abstract

Riešenie sa týká zloženia taviva na naváranie vysokolegovanou pásovou elektrodou antikoróznych vrstlev na nelegované, nízkolegované a austenitické ocele. Podstata spočívá v chemickom zložení taviva, ktoré pozostáva z oxidu křemičitého od 4 do 12 pere. hmot., oxidu hlinitého od 24 do 33 % hmot., oxidu manganatého od 7,1 do 10 % hmot., oxidu vápenatého od 0,1 do 6 % hmot., oxidu barnatého od 8,1 do 12 % hmot., fluoridu vápenatého od 35 do 45 % hmot., ďalej oxid sodný a draselný, oxid horečnatýThe solution concerns the composition of the flux for welding anti-corrosion layers on unalloyed, low-alloyed and austenitic steels with a high-alloy strip electrode. The essence lies in the chemical composition of the flux, which consists of silicon dioxide from 4 to 12 wt. %, aluminum oxide from 24 to 33 wt. %, manganese oxide from 7.1 to 10 wt. %, calcium oxide from 0.1 to 6 wt. %, barium oxide from 8.1 to 12 wt. %, calcium fluoride from 35 to 45 wt. %, sodium and potassium oxide, magnesium oxide

Description

261658261658

Vynález sa týká taviva pře naváranie vy-sokolegovanou pásovou elektrodou antiko-róznych vrstiev na nelegované, nízkolego-vané a austenitlcké ocele. V procese navárania pásovou elektródoupod tavivom má tavivo rozhodujúci vplyvna formovanie húsenky, odstránitelnosť tros-ky a chemické zloženie návaru. Dobré for-movanie húsenky a samovolná odstránitel-nosť trosky sú nevyhnutné pre dosiahnutiebezchybného návaru. Tendencia zapekaniatrosky sa zvyšuje hlavně pri naváraní páso-vými elektrodami obsahujúcimi niób.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flux-welded, electrolytic strip electrode for non-alloyed low-alloy and austenitic steels. In the process of surfacing by electrode strip flux, the flux has a decisive influence on the mold formation, the slag removability and the chemical composition of the weld. Good mold formation and spontaneous slag removability are necessary to achieve a defective weld. The tendency of zapekaniatroska increases mainly when welding with niobium-containing tape electrodes.

Nepriaznivý metalurgický účinok taviva sapřejav! na chemickom zložení návaru, a tov nalegovaní kremíka a prepale chrómu aniobu. Zvýšenie obsahu kremíka sposobívznik horúcich trhlin v návare. Zníženie ob-sahu chrómu a niobu zhoršuje odolnost pro-ti medzikryštálovej korózii.Unfavorable metallurgical effect of the flux! on the chemical composition of the deposit, and on the alloying of the silicon and the chromium overcoat. Increasing the silicon content of hot cracks in the weld. Reducing the chromium and niobium content impairs the resistance to intercrystalline corrosion.

Je známe tavivo s nasledovným zložením:6 až 15 % hmot. oxidu křemičitého, 1 až 7pere. hmot. oxidu manganatého, 36,7 až 47pere. hmot. oxidu hlinitého, 1 až 4 % hmot.oxidu horečnatého, 10 až 17 % hmot. oxiduvápenatého, 1 až 3 % hmot. oxidu sodnéhoa draselného spolu, 16 až 26 % hmot. fluo-ridu vápenatého, 1 až 8 % hmot. fluoridubarnatého. Uvedené tavivo nemá dobré o-peratívne vlastnosti. Húsenka je hrbolatá av střede přepadnutá. Vyskytuje sa zapeka-nie trosky na povrchu húsenky.A flux of the following composition is known: 6 to 15 wt. of silica, 1 to 7. wt. manganese oxide, 36.7 to 47 ppm. wt. % alumina, 1 to 4% by weight of magnesium oxide, 10 to 17% by weight of magnesium oxide, % of calcium oxide, 1 to 3 wt. % sodium and potassium oxides together, 16 to 26 wt. calcium fluoride, 1 to 8 wt. fluoridubarate. Said flux does not have good opaque properties. The caterpillar is bumpy and mugged in the middle. The slag is sealed on the surface of the caterpillar.

Je známe tavené tavivo o nasledovnomchemickom zložení: 28 až 38 % hmot. oxi-du křemičitého, 15 až 29 % hmot. oxidu hli-nitého, 5 až 13 % hmot. oxidu vápenatého,10 až 18 % hmot. fluoridu vápenatého, 17až 30 % oxidu horečnatého, 0,2 až 2,5 %hmot. oxidu sodného a draselného spolu, 0,8až 8 % hmot. oxidu barnatého, 1 až 6 %hmot. oxidu manganatého. Toto tavivo mádobré formovanie húsenky vďaka vysokémuobsahu kysličníka křemičitého. Vysoký ob-sah kysličníka křemičitého sposobuje sílnúredukciu kremíka z taviva do návaru, čosposobuje náchylnost’ na praskanie za tep-la.A melted flux of the following chemical composition is known: 28 to 38 wt. % silicon dioxide, 15 to 29 wt. % of aluminum oxide, 5 to 13 wt. % calcium oxide, 10 to 18 wt. calcium fluoride, 17 to 30% magnesium oxide, 0.2 to 2.5 wt. sodium and potassium oxides together, 0.8 to 8 wt. % barium oxide, 1 to 6 wt. manganese oxide. This flux is a bead-forming blast due to the high content of silica. The high content of silicon dioxide causes the silicon to be reduced from the flux to the weld, causing susceptibility to heat cracking.

Uvedené nedostatky do značnej miery od-straňuje tavivo pre naváranie s vysokolego-vanou pásovou elektródou antikoróznychvrstiev na nelegované, nízkolegované a aus-tenitické ocele, ktoré obsahuje oxid sodnýa draselný, oxid horečnatý, podstata které-ho spočívá v tom, že ďalej pozostáva z oxi-du křemičitého od 4 do 12 % hmot., oxidu 4 hlinitého od 24 do 33 °/o hmot., oxidu man-ganatého od 7,1 do 10 % hmot., oxidu vá-penatého od 0,1 do 6 % hmot., oxidu barna-tého od 8,1 do 12 % hmot. a fluoridu vá-penatého od 35 do 45 % hmot.These drawbacks are largely removed by the flux for welding with a high-alloyed strip electrode of anticorrosive layers on unalloyed, low-alloyed and ausititic steels containing sodium and potassium oxides, magnesium oxide, the substance of which further consists of oxi. from 4 to 12% by weight silicon dioxide, from 24 to 33% by weight aluminum oxide, from 7.1 to 10% by weight manganese oxide, from 0.1 to 6% by weight of calcium oxide; of barium oxide from 8.1 to 12 wt. and calcium fluoride from 35 to 45 wt.

Pri naváraní pásovou elektródou s tavi-vom pódia vynálezu je stabilně horenie ob-lúka. Húsenka je rovnoměrně formovaná shladkým povrchom. Odstránitefnosť troskyje samovolná aj pri narábaní s pásovou e-lektródou obsahujúcou niób. Spotřeba ta-viva je nízká, asi 0,7 kg taviva na 1 kg na-vařeného kovu. Dobré formovanie a dobráodstránitelnosť trosky sa dosiahla optimál-nou kombináciou oxidov křemičitého, hli-nitého a horečnatého.In the welding of the strip electrode with the melting stage of the invention, the combustion of the arc is stable. The caterpillar is evenly formed by a smooth surface. Removal of slag also spontaneously when handling niobium-containing strip electrodes. Consumption is low, about 0.7 kg of flux per kg of boiled metal. Good slag formation and good removability has been achieved by an optimal combination of silica, alumina and magnesium oxide.

Tavivo podl'a vynálezu má velmi priaznivýmetalurgický vplyv na chemické zloženienávaru, vyznačuje sa nízkým nalegovanímkremíka, malým prepalom chrómu a niobu,čo sa dosiahlo optimálnou kombináciou fluo-ridu vápenatého, oxidu křemičitého a man-ganatého. Skúškami bolo overené tavivo'po-dlá vynálezu skladajúce sa z 6 °/o hmot. o-xidu křemičitého, 28,9 % hmot. oxidu hli-nitého, 7,1 °/o hmot. oxidu manganatého, 3 %hmot. oxidu vápenatého, 2 % hmot. oxiduhorečnatého, 10 % hmot. oxidu barnatého, 2,5 % hmot. oxidu sodného a draselného spo-lu, 40,4 % hmot, fluoridu vápenatého, zvy-šok taviva nečistoty, oxid železnatý, fosfora síra. Návar zhotovený s použitím tohoto tavi-va s vysokolegovanou pásovou elektródou ozložení 20,35 °/o hmot. chrómu, 2,75 % hmot.niobu, 0,13 % hmot. kremíka· mal velmidobré formovanú húsenku s hladkým po-vrchom a plynulými prechodmi medzí hú-senkaini, troska sa odděluje samovolné. Tiežsa dosiahol priaznivý metalurgický vplyv,obsah chrómu v návare bol 19,25 % hmot.,obsah niobu 2,66 °/o hmot. obsah kremíka0,35 % hmot. S tavivom o zložení 9 % hmot. oxidu kře-mičitého, 28 % hmot. oxidu hlinitého, 8,5pere. hmot. oxidu manganatého, 3 % hmot.oxidu vápenatého, 2 % hmot. oxidu horeč-natého, 9,5 % hmot. oxidu barnatého, 1 %hmot. oxidu sodného a draselného spolu,38,9 % hmot. fluoridu vápenatého, zvyšoktaviva nečistoty, oxid železnatý, fosfor, asíra sa dosiahli tiež velmi dobré formovacievlastnosti a priaznivý metalurgický vplyv nazloženie návaru.The flux according to the invention has a very favorable metallurgical effect on the chemical composition, characterized by a low alloying of silicon, a small amount of chromium and niobium, resulting from an optimum combination of calcium fluoride, silica and manganese. The fluxes of the invention consisting of 6% by weight were tested by tests. % silicon dioxide, 28.9 wt. of alumina, 7.1% by weight; % manganese oxide, 3 wt. % calcium oxide, 2 wt. % of magnesium oxide, 10 wt. % barium oxide, 2.5 wt. sodium and potassium oxides, 40.4 wt%, calcium fluoride, excess flux impurities, iron oxide, phosphorus sulfur. A weld made using this melter with a high-alloy strip electrode of 20.35% by weight. % chromium, 2.75% w / w, 0.13% w / w; the silicon had a very large molded caterpillar with a smooth surface and smooth passages of the huzenini, the slag separating itself spontaneously. Also, a favorable metallurgical effect was achieved, the chromium content of the weld was 19.25% by weight, the niobium content was 2.66% by weight. a silicon content of 0.35% by weight; With a flux of 9% by weight. % silica, 28 wt. alumina, 8.5p. wt. % manganese oxide, 3% calcium oxide, 2% wt. % magnesium oxide, 9.5 wt. % barium oxide, 1 wt. % sodium and potassium oxides together, 38.9 wt. calcium fluoride, dirt impurities, iron oxide, phosphorus, aspirate also have very good molding properties and a favorable metallurgical effect of depositing the weld.

PREDMETOBJECT

Tavivo pre naváranie vysokolegovanou pá-sovou elektródou antikoróznych vrstiev nanelegované, nízkolegované a austenitickéocele, ktoré obsahuje oxid sodný a drasel-ný, oxid horečnatý, vyznačujúci sa tým, žeďalej pozostáva zo 4,0 až 12,0 % hmot. o- ynAlezu xidu křemičitého, 24,0 až 33,0 % hmot. o-xidu hlinitého, 7,1 až 10,0 % hmot. oxidumanganatého, 0,1 až 6,0 % hmot. oxidu vá-penatého, 8,1 až 12,0 % hmot. oxidu bar-natého a 35,0 až 45,0 hmot. fluoridu vápe-natého.The flux for welding with a high alloyed anticorrosion layer electrode of a non-alloyed, low-alloyed, and austenitic steel comprising sodium and potassium oxide, magnesium oxide, further comprising 4.0 to 12.0% by weight. % silicon dioxide, 24.0 to 33.0 wt. aluminum oxide, 7.1 to 10.0 wt. % oxidumanganate, 0.1 to 6.0 wt. % of foamy oxide, 8.1 to 12.0 wt. % of barium oxide and 35.0 to 45.0 wt. calcium fluoride.

Claims (2)

PREDMET Tavivo pre naváranie vysokolegovanou pásovou elektródou antikoróznych vrstiev na nelegované, nízkolegované a austenitické ocele, ktoré obsahuje oxid sodný a draselný, oxid horečnatý, vyznačujúcl sa tým, že ďalej pozostáva zo 4,0 až 12,0 % hmot. oynAlezu xidu kremičitéh-o, 24,0 až 33,0 % hmot. oxidu hlinitého, 7,1 až 10,0 % hmot. oxidu manganatého, 0,1 až 6,0 % hmot. oxidu vápenatého, 8,1 až 12,0 % hmot. oxidu barnatého a 35,0 až 45,0 hmot. fluoridu vápenatého. ČESKOSLOVENSKA SOCIALISTICKÁ REPUBLIKA (1B) POPIS VYNALEZU K AUTORSKÉMU OSVEDÉEMU 261659 (11) (Bl) (51) Int. Cl.4 C 21 D 9/52 (22) Přihlášené 17 06 87 SUBJECT A flux for welding with a high-alloy strip electrode of anticorrosive layers to unalloyed, low-alloy and austenitic steels containing sodium and potassium oxide, magnesium oxide, characterized in that it further comprises 4.0 to 12.0 wt. % silicon dioxide oynAleze, 24.0 to 33.0 wt. % alumina, 7.1 to 10.0 wt. 0.1 to 6.0 wt. % calcium oxide, 8.1 to 12.0 wt. % barium oxide and 35.0 to 45.0 wt. calcium fluoride. CZECHOSLOVAK SOCIALIST REPUBLIC (1B) DESCRIPTION OF THE INVENTION CERTIFICATE 261659 (11) (Bl) (51) Int. Cl. 4 C 21 D 9/52 (22) Entries 17 06 87
CS874477A 1987-06-17 1987-06-17 Flux for welding with a high-alloyed band electricity CS261660B1 (en)

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