CS270808B1 - Low-alloy low-carbon welding steel - Google Patents

Low-alloy low-carbon welding steel Download PDF

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CS270808B1
CS270808B1 CS876165A CS616587A CS270808B1 CS 270808 B1 CS270808 B1 CS 270808B1 CS 876165 A CS876165 A CS 876165A CS 616587 A CS616587 A CS 616587A CS 270808 B1 CS270808 B1 CS 270808B1
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Czechoslovakia
Prior art keywords
low
weight
cold
rolled
silicon
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CS876165A
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Czech (cs)
Slovak (sk)
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CS616587A1 (en
Inventor
Arpad Ing Csc Simon
Frantisek Ing Jasovsky
Jan Ing Janok
Ondrej Ing Csc Kozar
Ludovit Ing Furman
Milan Ing Csc Ondas
Milan Ing Csc Alexy
Original Assignee
Simon Arpad
Jasovsky Frantisek
Janok Jan
Kozar Ondrej
Furman Ludovit
Ondas Milan
Alexy Milan
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Application filed by Simon Arpad, Jasovsky Frantisek, Janok Jan, Kozar Ondrej, Furman Ludovit, Ondas Milan, Alexy Milan filed Critical Simon Arpad
Priority to CS876165A priority Critical patent/CS270808B1/en
Publication of CS616587A1 publication Critical patent/CS616587A1/en
Publication of CS270808B1 publication Critical patent/CS270808B1/en

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Abstract

Low-alloyed,low-carbon weldable steel is designated for two-sided and/or one-sided zinc metal-coated strips primarily for the automotive industry and bent profiles with a basic carbon content of up to 0.06%, sulphur from 0.002 up to 0.025%, phosphorus between 0.005 and 0.035%, manganese from 0.1 up to 0.3%, silicon between 0.05 and 0.2% and aluminum from 0.03 up to 0.08% of weight. This steel contains alloying compounds in the extent of 0.05 up to 0.25% of molybdenum and 0.05 up to 0.15% of zirconium provided that the total share of the alloying compounds does not exceed 0.50% of the weight.

Description

(57) Nízkolegovaná nízkouhlikatá zvaritel'ná ocet určená pre obojstranně alebo jednostranné pokovované pásy plechu zinkom alebo jeho zliatinami najma pre automobilový priemysel a ohýbané profily o základnom zlo žení uhlíka do 0,06 %, siry od 0,002 do 0,025 fosforu od 0,005 do 0,035 manganu od 0,1 do 0,3 kremíka od 0,05 do 0,2 % a hlinika od 0,03 do 0^08 % hmotnosti. Táto ocel’ obsahuje legujuce zložky v rozsahu 0,05 až 0^25 % molybdénu a 0,05 až 0,15 % zirkonia, pričom celkový podiel legujúcich zložiek nepřesahuje 0,50 % hmotnosti.(57) Low-alloy low-carbon weldable vinegar for double-sided or one-sided coated strips of zinc or its alloys, in particular for the automotive industry and bent sections with a basic carbon composition of 0,06%, sulfur of 0,002 to 0,025 phosphorus of 0,005 to 0,035 manganese from 0.1 to 0.3 silicon from 0.05 to 0.2% and aluminum from 0.03 to 0.088% by weight. This steel obsahuje contains alloying ingredients in the range of 0.05 to 0 ^ 25% molybdenum and 0.05 to 0.15% zirconium, with a total proportion of alloying ingredients not exceeding 0.50% by weight.

0 8080 808

(11) (11) (13) (13) B1 B1 (51) (51) Int. Cl. 5 C 22 C 38/00Int. Cl. 5 C 22 C 38/00

Vynález sa týká nízkolegovanej ní zkouhlí kovej zvaretelnej ocele určenej pře pokovované pásy plechu válcované za tepla a za studená najma pře automobilový priemy8Θ1 a pře ohýbané profily všeobecného použitia rieSi zvýSenie koróznej odolnosti voči tepelnej a atmosférickéj erózii samotného Jlechu, při zníženej hmotnosti pokovovacích povlakov a zvýšení leh vzájomnej přilnavosti.The present invention relates to low alloy steels for hot-rolled and cold-rolled metallized sheet metal sheets, in particular for automotive industry and general purpose bent profiles, to increase corrosion resistance to thermal and atmospheric erosion of flutter alone, while reducing the weight of plating coatings mutual adhesion.

Pre uvedené účely použitia plechov například na ohýbané profily a najma na ka- t rosérie a výfuky v áutomobilovom priemysle, sa používájú nízkouhlíkaté hlbokoťažné, připadne konStrukčné ocele válcované za studená. Tieto ocele, okrem nevýhodných mechanických vlastností, vykazujú nedo sta točnu ко rožnu odolnosti voči atmosferickým * vplyvom a zvlášť za pSsobenia tepelného vplyvu například na výfuky automobilov. Aj při nutnom pokovovaní pře uvedené účely, je nutné nanášať povlaky o vyšSej hmotnosti, okolo 275 g.m2 a to obojstranne, při poměrně velkej drsnosti povrchu po studenom válcování. Nedostatočná korózna odolnost! týchto ocelí obmedzuje možnost! jednostranného pokovovania plechov riešiaceho problémy lisovánia pri spracování napřiklad karosériových plechov. Nevhodná Struktura materiálov, najma na povrchu plechov v tzv. intermetalickej fáze, neumožňuje přitom potrebnú priínavosť a vazbu pokovovacieho povlaku na povrch plechu. Uvedené klasické ocele svojimi nevhodnými pevnostnými vlastnosťami a bez osobitnej povrchovej a tepelnej úpravy před alebo po pokovovaní plechov, vyžadajú přitom poměrně veiké hrubky plechov na uvedené výrobky s vysokou ich hmotnosťou ako aj eťažené zváranie plechov takto pokovovaných. Problém sa čiaetočne rieSi vývojom materiálov a technologií pokovovania.For the aforementioned purposes of using sheet metal, for example, for bent profiles, and in particular for rosettes and exhausts in the automotive industry, low-carbon, deep-drawn or cold-rolled structural steels are used. These steels, in addition to the disadvantageous mechanical properties, exhibit an insufficient degree of resistance to atmospheric influences and, in particular, to thermal effects on, for example, car exhausts. Even with the necessary plating for the above purposes, it is necessary to apply coatings with a higher weight, about 275 gm 2 , on both sides, with relatively high surface roughness after cold rolling. Insufficient corrosion resistance! These steels limits the possibility! One-sided plating of sheet metal solving pressing problems during processing of body panels, for example. Unsuitable Structure of materials, especially on the surface of sheets in the so-called. intermetallic phase, while not allowing the necessary adhesion and binding of the metallization coating to the sheet surface. The above-mentioned conventional steels, due to their unsuitable strength properties and without special surface and heat treatment before or after the metal plating of the sheets, require relatively large sheet thicknesses for the said high-weight products as well as difficult welding of the sheets so coated. The problem is solved in many cases by the development of plating materials and technologies.

Uvedené nedostatky odstraňuje a vytýčený problém rieSi nízkolegovaná nízkouhlíkatá zvaritelná ocel' podlá vynálezu. Podstata vynálezu spočívá v tom, že nízkolegovaná nízkouhlíkatá zvaritelná ocel' o základnom zložení uhlíka do 0,06 %, mangánu od 0,1 do 0,3 %, kremíka od 0,05 do 0,2 %, hliníka od 0,03 do 0,08 % a s obsahom síry od 0,002 do 0,025 % a fosforu od 0,005 do 0,035 obsahuje dalej legujúce zložky v rozsahu 0,05 až 0,25 % molybdénu a 0,05 až 0,15 % hmotnosti titanu. S výhodou je ocel ďalej legovaná zirkoniom v rozsahu 0,05 až 0,15 % hmotnosti pričom celkový podiel všetkých legujúcich zložiek nepřesahuje 0,50 % hmotnosti.The low-alloy low-carbon weldable steel according to the invention solves these problems. SUMMARY OF THE INVENTION The low-alloy low-carbon weldable steel having a basic carbon composition of up to 0.06%, a manganese of 0.1 to 0.3%, a silicon of 0.05 to 0.2%, an aluminum of 0.03 to 0.3% 0.08% and with a sulfur content of 0.002 to 0.025% and a phosphorus of 0.005 to 0.035 contains further alloying components in the range of 0.05-0.25% molybdenum and 0.05-0.15% by weight of titanium. Preferably, the steel is further alloyed with zirconium in the range of 0.05 to 0.15% by weight, the total proportion of all alloying components not exceeding 0.50% by weight.

Výhody ocele podlá vynálezu sú hlavně v tom, že vytvořená nová nízkouhlíkatá ocel vykazuje podstatné vyšSiu koróznu odolnost! voči atmosferickým, ako aj kombinovaným tepelným vplyvom, a to jednak bez pokovovania a jednak po pokovovaní, čo umožňuje pokovovanie s nižSou hmotnosťou povlaku, resp. jednostranné pokovovanie výhodné pre náročné lisovanie, např. karosérií automobilov. Vhodné legovanie ocelí » zlepšuje pevnostně vlastnosti plechov 8 možnosíou zníženia hmotnosti výrobkov z nich. Hlavně však kombinácia protikoróznych zložiek a to kremíka s uvedenými legujúcimi prvkami, súčasne vytvárajú v povrchovej intermeralickej vrstvě kvarternár- nu fázu spojenia s pokovovacím zinkom ale aj jeho zliatinami, včítane vyvinutéj zliatiny zinku a hliníka, Co podstatné zvyšuje přilnavost’ povlaku к základnému materiálu a v konečnom dSsledku zvýšenu zvaritelnosť pokovaných plechov bez narušenia ich koróznej odolnosti. Ocel umožňuje aj účelnejšie a racioualne využiť dalšie technologie epracovania před a po pokovovaní plechov.The advantages of the steel according to the invention are mainly that the new low carbon steel formed exhibits a significantly higher corrosion resistance! against atmospheric as well as combined thermal influences, both without plating and after plating, which enables plating with a lower coating weight and / or coating. one-sided plating advantageous for demanding stamping, e.g. car bodies. Appropriate alloying of the steels improves the strength properties of the sheets 8 by reducing the weight of the steel products. In particular, however, the combination of the anticorrosive components, namely silicon with the above-mentioned alloying elements, at the same time form a quaternary phase of bonding with the zinc plating as well as its alloys, including the zinc-aluminum alloy developed in the surface intermeralic layer. d As a result, the weldability of the plated sheets is increased without compromising their corrosion resistance. Steel also enables more effective and rational use of other technologies of pre-treatment before and after metal plating.

Příklad nízkolegovanej ocele podlá vynálezu:An example of low alloy steel according to the invention:

Ocel obsahuje 0,04 % uhlíka, 0,21 % mangánu, 0,15 % kremíka, 0,012 % síry, 0,015 % fosforu, 0,095 % zirkónia, 0,045 % hliníka, 0,090 % molybdénu a 0,11 % titanu, zvyšok železo.The steel contains 0.04% carbon, 0.21% manganese, 0.15% silicon, 0.012% sulfur, 0.015% phosphorus, 0.095% zirconium, 0.045% aluminum, 0.090% molybdenum and 0.11% titanium, the rest iron.

Claims (2)

PREDMET VYNÁLEZUOBJECT OF THE INVENTION 1· Nízkolegovaná ní zkouhlí katá zvaritelná ocel pre oboj stranně alebo jednostranné pokovované pásy plechu válcované za tepla aj za studená najma pre automobilový priemysel například na výfuky a karosérie a pre ohýbané profily váeobecného použitia, u pri pokovovaní zinkom alebo jeho zliatinami a/alebo zliatinou zinku a hliníka s přísadou kremíka a titanu alebo horčíka, o základnom zložení uhlíka do 0,06 %, síry od 0,002 do 0,025 fosforu od 0,005 do 0,035 mangánu od 0,1 do 0,3 kremíka od 0,05 do 0,2 % a hliníka od 0,03 do 0,08 % hmotnosti vyznaSujúca sa tým, že obsahuje ďalej legujúce zložky v rozsahu 0,05 až 0,25 % molybdenu a 0,05 až 0,15 % hmotnosti titanu.1 · Low-alloyed cast steel for cold-rolled and cold-rolled cold-rolled and cold-rolled metal sheets, especially for the automotive industry, for example, exhaust pipes and bodywork and bent general purpose profiles, zinc plating or zinc alloys and / or zinc alloys and aluminum with the addition of silicon and titanium or magnesium, with a basic carbon composition of up to 0,06%, a sulfur of 0,002 to 0,025 of phosphorus of 0,005 to 0,035 of manganese of 0,1 to 0,3 of silicon of 0,05 to 0,2% and % aluminum, from 0.03 to 0.08% by weight, further comprising alloying components in the range of 0.05 to 0.25% molybdenum and 0.05 to 0.15% by weight of titanium. 2. Nízkolegovená ocel podlá bodu 1 vyznačujúca sa tým, že je legovaná ďalej 0,05 až 0,15 $ hmotnosti zirkonia, pričom celkový podiel všetkých uvedených legujucích zložiek nepřesahuje 0,50 % hmotnosti.2. Low-alloy steel according to claim 1, characterized in that it is further alloyed with 0.05 to 0.15% by weight of zirconium, the total proportion of all said alloying components not exceeding 0.50% by weight.
CS876165A 1987-08-21 1987-08-21 Low-alloy low-carbon welding steel CS270808B1 (en)

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CS270808B1 true CS270808B1 (en) 1990-08-14

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