CS271345B2 - Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath - Google Patents

Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath Download PDF

Info

Publication number: CS271345B2
Authority: CS; Czechoslovakia
Prior art keywords: pickling; bath; scale; alloys; pickled
Prior art date: 1987-01-19

Application number

CS88287A

Other languages

Czech (cs)

English (en)

Other versions

CS28788A2 (en

Inventor

Zoltan Bordas

Jozsef Mihaleczku

Ernoe Toereki

Pal Humenyanszky

Barnabas Ersek

Istvan Nyitray

Original Assignee

Borsodi Vegyi Komb

Borsodnadasdi Lemezgyar

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-01-19

Filing date

1988-01-15

Publication date

1990-09-12

1988-01-15 Application filed by Borsodi Vegyi Komb, Borsodnadasdi Lemezgyar filed Critical Borsodi Vegyi Komb

1989-12-13 Publication of CS28788A2 publication Critical patent/CS28788A2/cs

1990-09-12 Publication of CS271345B2 publication Critical patent/CS271345B2/cs

Links

238000005554 pickling Methods 0.000 title claims description 73
238000000034 method Methods 0.000 title claims description 19
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 18
229910045601 alloy Inorganic materials 0.000 title claims description 13
239000000956 alloy Substances 0.000 title claims description 13
229910052742 iron Inorganic materials 0.000 title claims description 4
229910044991 metal oxide Inorganic materials 0.000 title claims description 4
150000004706 metal oxides Chemical class 0.000 title claims description 4
239000000243 solution Substances 0.000 claims description 22
239000002253 acid Substances 0.000 claims description 16
229910052751 metal Inorganic materials 0.000 claims description 14
239000002184 metal Substances 0.000 claims description 14
229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 10
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 10
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 8
229910021653 sulphate ion Inorganic materials 0.000 claims description 5
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 4
229910001447 ferric ion Inorganic materials 0.000 claims description 4
229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
-1 iron ion Chemical class 0.000 claims description 3
239000011707 mineral Substances 0.000 claims description 3
239000007864 aqueous solution Substances 0.000 claims description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 22
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 20
150000002500 ions Chemical class 0.000 description 14
229910000831 Steel Inorganic materials 0.000 description 12
239000010959 steel Substances 0.000 description 12
239000000155 melt Substances 0.000 description 8
150000003839 salts Chemical class 0.000 description 7
150000007513 acids Chemical class 0.000 description 6
229910000360 iron(III) sulfate Inorganic materials 0.000 description 6
238000010438 heat treatment Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
229910000975 Carbon steel Inorganic materials 0.000 description 4
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000010949 copper Substances 0.000 description 4
238000010186 staining Methods 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 3
229910001092 metal group alloy Inorganic materials 0.000 description 3
229910017604 nitric acid Inorganic materials 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000003518 caustics Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000003595 mist Substances 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
229910000881 Cu alloy Inorganic materials 0.000 description 1
YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
IGUSRGSVTUAUKM-UHFFFAOYSA-N [N+][O-].O[N+]([O-])=O Chemical class [N+][O-].O[N+]([O-])=O IGUSRGSVTUAUKM-UHFFFAOYSA-N 0.000 description 1
238000007792 addition Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
239000003517 fume Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
231100001261 hazardous Toxicity 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
230000027939 micturition Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000012312 sodium hydride Substances 0.000 description 1
229910000104 sodium hydride Inorganic materials 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000004317 sodium nitrate Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/103—Other heavy metals copper or alloys of copper
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

CS88287A 1987-01-19 1988-01-15 Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath CS271345B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
HU87135A HUT53398A (en)	1987-01-19	1987-01-19	Process for descaling and deoxidating metals and metal alloys, particularly alloyed steels, high-alloyed steels and carbon steels, in pickling bath containing iron(iii)ion active ingredient

Publications (2)

Publication Number	Publication Date
CS28788A2 CS28788A2 (en)	1989-12-13
CS271345B2 true CS271345B2 (en)	1990-09-12

Family

ID=10948099

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS88287A CS271345B2 (en)	1987-01-19	1988-01-15	Method of scale and metal oxides and their alloys removal of trivalent iron pickling bath

Country Status (8)

Country	Link
CN (1)	CN1039850A (de)
CS (1)	CS271345B2 (de)
DD (1)	DD267265A5 (de)
DE (1)	DE3801018A1 (de)
FR (1)	FR2633946A1 (de)
HU (1)	HUT53398A (de)
NO (1)	NO882844L (de)
PL (1)	PL270198A1 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
HUT53398A (en) *	1987-01-19	1990-10-28	Borsodi Vegyi Komb	Process for descaling and deoxidating metals and metal alloys, particularly alloyed steels, high-alloyed steels and carbon steels, in pickling bath containing iron(iii)ion active ingredient
EP0346510A1 (de) *	1988-06-15	1989-12-20	Chema Chemiemaschinen Gmbh	Beizen von Halbzeugen
AT406486B (de) *	1998-12-22	2000-05-25	Andritz Patentverwaltung	Verfahren zum beizen von edelstahl
CN102660747A (zh) *	2012-04-13	2012-09-12	中国文化遗产研究院	用于银器与鎏金银器保护的硫脲类复配除锈剂和除锈膏
CN103498164A (zh) *	2013-09-04	2014-01-08	大连理工大学	一种热轧钢板氧化层的环保清洗液及清洗方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS545829A (en) *	1977-06-15	1979-01-17	Nishiyama Sutenresu Kemikaru K	Acid cleaning agent for marageing steel
DE2736255A1 (de) *	1977-08-11	1979-03-01	Beugin Procedes Sa	Verfahren zum beizen von staehlen
JPS6043920B2 (ja) *	1978-09-13	1985-10-01	旭電化工業株式会社	新規な酸洗剤
JPS5550468A (en) *	1978-10-11	1980-04-12	Kawasaki Steel Corp	Pickling method for cr base stainless steel
JPS5920752B2 (ja) *	1980-08-07	1984-05-15	川崎製鉄株式会社	オ−ステナイト系ステンレス鋼板の酸洗方法
HUT53398A (en) *	1987-01-19	1990-10-28	Borsodi Vegyi Komb	Process for descaling and deoxidating metals and metal alloys, particularly alloyed steels, high-alloyed steels and carbon steels, in pickling bath containing iron(iii)ion active ingredient

1987
- 1987-01-19 HU HU87135A patent/HUT53398A/hu unknown
1988
- 1988-01-15 DE DE3801018A patent/DE3801018A1/de not_active Withdrawn
- 1988-01-15 CS CS88287A patent/CS271345B2/cs unknown
- 1988-01-18 DD DD88312282A patent/DD267265A5/de unknown
- 1988-01-18 PL PL27019888A patent/PL270198A1/xx unknown
- 1988-06-27 NO NO88882844A patent/NO882844L/no unknown
- 1988-07-07 FR FR8809226A patent/FR2633946A1/fr active Pending
- 1988-07-22 CN CN88104461A patent/CN1039850A/zh active Pending

Also Published As

Publication number	Publication date
DD267265A5 (de)	1989-04-26
FR2633946A1 (fr)	1990-01-12
CS28788A2 (en)	1989-12-13
NO882844L (no)	1990-01-22
HUT53398A (en)	1990-10-28
PL270198A1 (en)	1988-12-08
DE3801018A1 (de)	1988-07-28
NO882844D0 (no)	1988-06-27
CN1039850A (zh)	1990-02-21

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