CS277179B6 - Process for preparing homo- and copolymers substituted in positions alpha and omega by functional groups - Google Patents

Process for preparing homo- and copolymers substituted in positions alpha and omega by functional groups Download PDF

Info

Publication number: CS277179B6
Authority: CS; Czechoslovakia
Prior art keywords: mol; polymerization; initiator; temperature; activation energy
Prior art date: 1986-11-14

Application number

CS878155A

Other languages

Czech (cs)

English (en)

Other versions

CS815587A3 (en

Inventor

Tamara Ing Roz Berezsni Foldes

Gyorgyi Roz Fenyvesi Miketa

Andras Ing Nagy

Tibor Ing Pernecker

Arpad Rehak

Daniel Ing Szalay

Ferenc Tudos

Original Assignee

Mta Koezponti Kemiai Kutato In

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-11-14

Filing date

1987-11-13

Publication date

1992-12-16

1987-11-13 Application filed by Mta Koezponti Kemiai Kutato In filed Critical Mta Koezponti Kemiai Kutato In

1992-05-13 Publication of CS815587A3 publication Critical patent/CS815587A3/cs

1992-12-16 Publication of CS277179B6 publication Critical patent/CS277179B6/cs

Links

229920001577 copolymer Polymers 0.000 title claims description 13
125000000524 functional group Chemical group 0.000 title claims description 4
238000004519 manufacturing process Methods 0.000 title description 6
238000006116 polymerization reaction Methods 0.000 claims description 39
238000000034 method Methods 0.000 claims description 33
239000003999 initiator Substances 0.000 claims description 30
239000000178 monomer Substances 0.000 claims description 26
230000008569 process Effects 0.000 claims description 25
229920000642 polymer Polymers 0.000 claims description 17
230000004913 activation Effects 0.000 claims description 11
238000010526 radical polymerization reaction Methods 0.000 claims description 8
238000006243 chemical reaction Methods 0.000 claims description 6
238000000354 decomposition reaction Methods 0.000 claims description 6
239000000203 mixture Substances 0.000 claims description 4
239000011541 reaction mixture Substances 0.000 claims description 3
230000006798 recombination Effects 0.000 claims description 3
238000005215 recombination Methods 0.000 claims description 3
239000002904 solvent Substances 0.000 claims description 3
238000001816 cooling Methods 0.000 claims description 2
238000005485 electric heating Methods 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
238000003756 stirring Methods 0.000 claims description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 22
BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 14
IWTIJBANDVIHPX-UHFFFAOYSA-N 2-[(2-cyano-5-hydroxypentan-2-yl)diazenyl]-5-hydroxy-2-methylpentanenitrile Chemical compound OCCCC(C)(C#N)N=NC(C)(CCCO)C#N IWTIJBANDVIHPX-UHFFFAOYSA-N 0.000 description 9
230000035484 reaction time Effects 0.000 description 8
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
150000002009 diols Chemical class 0.000 description 6
239000005062 Polybutadiene Substances 0.000 description 5
229920002857 polybutadiene Polymers 0.000 description 5
238000007334 copolymerization reaction Methods 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
230000000977 initiatory effect Effects 0.000 description 3
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
230000008859 change Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
238000004088 simulation Methods 0.000 description 2
BJJVDFADUDDTQK-UHFFFAOYSA-N 5-hydroxy-2-methylpentanenitrile Chemical compound N#CC(C)CCCO BJJVDFADUDDTQK-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
241000755093 Gaidropsarus vulgaris Species 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000005094 computer simulation Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000007323 disproportionation reaction Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000010926 purge Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
230000002123 temporal effect Effects 0.000 description 1
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Polymerization Catalysts (AREA)

CS878155A 1986-11-14 1987-11-13 Process for preparing homo- and copolymers substituted in positions alpha and omega by functional groups CS277179B6 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
HU864693A HU201101B (en)	1986-11-14	1986-11-14	Process for producing by radical polymerization of polymers of polydispersity of 1,50 to 2,00, having functional groups in alpha, omega positions

Publications (2)

Publication Number	Publication Date
CS815587A3 CS815587A3 (en)	1992-05-13
CS277179B6 true CS277179B6 (en)	1992-12-16

Family

ID=10968689

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS878155A CS277179B6 (en)	1986-11-14	1987-11-13	Process for preparing homo- and copolymers substituted in positions alpha and omega by functional groups

Country Status (17)

Country	Link
US (1)	US5126415A (de)
JP (1)	JPH0762044B2 (de)
AT (1)	AT397506B (de)
BE (1)	BE1003753A4 (de)
CA (1)	CA1318437C (de)
CH (1)	CH675584A5 (de)
CS (1)	CS277179B6 (de)
DD (1)	DD262864A5 (de)
DE (1)	DE3738640C2 (de)
ES (1)	ES2005448A6 (de)
FI (1)	FI93844C (de)
FR (1)	FR2606774B1 (de)
HU (1)	HU201101B (de)
IT (1)	IT1232958B (de)
NL (1)	NL8702714A (de)
RU (1)	RU1780539C (de)
SE (1)	SE8704446L (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FI924730A7 (fi) *	1992-03-20	1993-09-21	Rohm & Haas	Menetelmä molekyylipainon jakautuman säätämiseksi polymeereissa
JP3320773B2 (ja) *	1992-06-05	2002-09-03	旭光学工業株式会社	成形複合光学部品の加熱重合方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1243197A (en) *	1968-01-18	1971-08-18	British Petroleum Co	Polymerisation process
US3817965A (en) *	1968-02-27	1974-06-18	Aquitaine Petrole	Polymerization of vinyl compounds in suspension
GB1252153A (de) *	1968-04-30	1971-11-03
JPS579368B2 (de) *	1973-06-01	1982-02-20
US4079074A (en) *	1977-01-06	1978-03-14	Pennwalt Corporation	Unsymmetrical diperoxides and processes of use in polymerizing unsaturated monomers
US4125696A (en) *	1977-01-06	1978-11-14	Pennwalt Corporation	Polymerization process using di-t-butyl diperoxycarbonate as a finishing catalyst
US4125695A (en) *	1977-01-06	1978-11-14	Pennwalt Corporation	Polymerization process with reduced cycle time employing polyfunctional free radical initiators
NL187487C (nl) *	1977-10-06	1991-10-16	Sumitomo Chemical Co	Werkwijze voor het doorlopend produceren van een voorpolymeerstroop.
JPS60112808A (ja) *	1983-11-25	1985-06-19	Idemitsu Petrochem Co Ltd	水酸基含有ジエン系重合体の製造方法
AT385040B (de) *	1985-03-15	1988-02-10	Lim Kunststoff Tech Gmbh	Verfahren zur herstellung von polyurethanen, insbesondere von polyurethanelastomeren, sowie verfahren zur radikalischen polymerisation

1986
- 1986-11-14 HU HU864693A patent/HU201101B/hu not_active IP Right Cessation
1987
- 1987-11-10 AT AT0296587A patent/AT397506B/de not_active IP Right Cessation
- 1987-11-13 BE BE8701284A patent/BE1003753A4/fr not_active IP Right Cessation
- 1987-11-13 CH CH4440/87A patent/CH675584A5/de not_active IP Right Cessation
- 1987-11-13 FI FI875042A patent/FI93844C/fi not_active IP Right Cessation
- 1987-11-13 DD DD87309020A patent/DD262864A5/de not_active IP Right Cessation
- 1987-11-13 ES ES8703252A patent/ES2005448A6/es not_active Expired
- 1987-11-13 SE SE8704446A patent/SE8704446L/ not_active Application Discontinuation
- 1987-11-13 CA CA000551844A patent/CA1318437C/en not_active Expired - Fee Related
- 1987-11-13 NL NL8702714A patent/NL8702714A/nl not_active Application Discontinuation
- 1987-11-13 IT IT8722632A patent/IT1232958B/it active
- 1987-11-13 CS CS878155A patent/CS277179B6/cs not_active IP Right Cessation
- 1987-11-13 FR FR8715680A patent/FR2606774B1/fr not_active Expired - Fee Related
- 1987-11-13 JP JP62285694A patent/JPH0762044B2/ja not_active Expired - Lifetime
- 1987-11-13 DE DE3738640A patent/DE3738640C2/de not_active Expired - Fee Related
- 1987-11-13 RU SU874203721A patent/RU1780539C/ru active
1990
- 1990-05-11 US US07/523,252 patent/US5126415A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
HU201101B (en)	1990-09-28
SE8704446D0 (sv)	1987-11-13
FI93844B (fi)	1995-02-28
DE3738640C2 (de)	1996-07-11
NL8702714A (nl)	1988-06-01
DD262864A5 (de)	1988-12-14
SE8704446L (sv)	1988-05-15
FI875042L (fi)	1988-05-15
FI875042A0 (fi)	1987-11-13
AT397506B (de)	1994-04-25
HUT47606A (en)	1989-03-28
US5126415A (en)	1992-06-30
RU1780539C (ru)	1992-12-07
IT1232958B (it)	1992-03-11
FI93844C (fi)	1995-06-12
DE3738640A1 (de)	1988-05-26
ATA296587A (de)	1993-09-15
FR2606774A1 (fr)	1988-05-20
CS815587A3 (en)	1992-05-13
BE1003753A4 (fr)	1992-06-09
IT8722632A0 (it)	1987-11-13
CA1318437C (en)	1993-05-25
JPH0762044B2 (ja)	1995-07-05
ES2005448A6 (es)	1989-03-01
FR2606774B1 (fr)	1993-02-19
JPS63264601A (ja)	1988-11-01
CH675584A5 (de)	1990-10-15

Legal Events

Date	Code	Title	Description
2000-07-12	MM4A	Patent lapsed due to non-payment of fee	Effective date: 19991113

Publication	Publication Date	Title
US4246382A (en)	1981-01-20	Solvent resistent acrylic resin and process for producing the same
Overberger et al.	1966	Copolymerization of styrene and methyl methacrylate with lithium as initiator
US2746943A (en)	1956-05-22	Polymer compositions and methods for producing the same
JPH08283315A (ja)	1996-10-29	スチレン−ブタジエンゴムの製造方法
US3839308A (en)	1974-10-01	Styrene-methacrylic acid copolymers and their preparation
US3676527A (en)	1972-07-11	Process for preparation of high impact polystyrene
US2907756A (en)	1959-10-06	Styrene polymerization process
Smets et al.	1957	Branching and graftcopolymerization of polyethyl‐α‐chloroacrylate
CS277179B6 (en)	1992-12-16	Process for preparing homo- and copolymers substituted in positions alpha and omega by functional groups
US3551523A (en)	1970-12-29	Polymerization process for preparing high impact polymers
MXPA02008381A (es)	2002-12-13	Procedimiento para la obtencion de particulas de caucho.
Fu et al.	2007	Semibatch atom transfer radical copolymerization of styrene and butyl acrylate
US3723575A (en)	1973-03-27	Method of producing graft polymers
US4713429A (en)	1987-12-15	Method for production of copolymer of vinyl cyanide compound and aromatic vinyl compound
US3629370A (en)	1971-12-21	Process for the production of thermoplastic-elastic moulding compositions of high impact and notched impact strength
KR100419230B1 (ko)	2004-06-30	백색도와내충격성이우수한열가소성수지의제조방법
KR100453875B1 (ko)	2004-10-20	내충격성과 유동성이 우수하고 자연색상이 향상된 높은고무함량을 갖는 신규의 그라프트 공중합체의 제조방법
WO2008090153A2 (de)	2008-07-31	Verfahren zur herstellung von homo- und copolymeren der vinylphosphonsäure
KR100188529B1 (ko)	1999-06-01	저온내충격성 및 광택도가 우수한 열가소성 수지조성물의제조방법
GB2050391A (en)	1981-01-07	Two-stage polymerisation
KR100215389B1 (ko)	1999-08-16	자연색상과 내충격성이 우수한 열가소성 수지 조성물의 제조방법
JPS6144912A (ja)	1986-03-04	改質されたｅｐｄｍゴム類、それらの製造、および　衝撃‐低抗性ビニル重合体類の製造用のそれの使用、並びにこの方法で得られるビニル重合体類
KR19990055608A (ko)	1999-07-15	내후성, 광택도 및 내충격성이 우수한 열가소성수지 조성물의 제조방법
US2559154A (en)	1951-07-03	Method of preparing copolymers of acrylonitrile
US4002811A (en)	1977-01-11	Production of uniform copolymer of acrylonitrile and aromatic olefines