CS63391A2 - Catalyst and prepolymer applicable for olefins' polymerization and ethylene (co)polymer that can be prepared from them - Google Patents

Catalyst and prepolymer applicable for olefins' polymerization and ethylene (co)polymer that can be prepared from them Download PDF

Info

Publication number: CS63391A2
Authority: CS; Czechoslovakia
Prior art keywords: ethylene; compound; carrier; prepolymer; catalyst
Prior art date: 1990-03-12

Application number

CS91633A

Other languages

Czech (cs)

English (en)

Inventor

Jean-Claude Andre Bailly

Christine Jacqueline Chabrand

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-03-12

Filing date

1991-03-11

Publication date

1991-10-15

1991-03-11 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

1991-10-15 Publication of CS63391A2 publication Critical patent/CS63391A2/cs

Links

239000003054 catalyst Substances 0.000 title claims abstract description 47
150000001336 alkenes Chemical class 0.000 title claims abstract description 18
238000006116 polymerization reaction Methods 0.000 title claims description 25
229920001038 ethylene copolymer Polymers 0.000 title description 6
-1 alcohol Chemical class 0.000 claims abstract description 61
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 58
229910052726 zirconium Inorganic materials 0.000 claims abstract description 57
239000002245 particle Substances 0.000 claims abstract description 55
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 45
239000005977 Ethylene Substances 0.000 claims abstract description 28
239000011949 solid catalyst Substances 0.000 claims abstract description 28
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 27
229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 22
239000010936 titanium Substances 0.000 claims abstract description 22
238000009826 distribution Methods 0.000 claims abstract description 21
238000000034 method Methods 0.000 claims abstract description 20
239000000203 mixture Substances 0.000 claims abstract description 19
229910052719 titanium Inorganic materials 0.000 claims abstract description 18
229910052720 vanadium Inorganic materials 0.000 claims abstract description 17
239000001257 hydrogen Substances 0.000 claims abstract description 16
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 16
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
239000004711 α-olefin Substances 0.000 claims abstract description 8
150000002899 organoaluminium compounds Chemical class 0.000 claims abstract description 5
125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 5
150000001875 compounds Chemical class 0.000 claims description 65
150000003624 transition metals Chemical class 0.000 claims description 31
229910052723 transition metal Inorganic materials 0.000 claims description 30
239000011777 magnesium Substances 0.000 claims description 21
150000004820 halides Chemical class 0.000 claims description 18
229920000573 polyethylene Polymers 0.000 claims description 17
238000002360 preparation method Methods 0.000 claims description 17
239000004698 Polyethylene Substances 0.000 claims description 16
229930195733 hydrocarbon Natural products 0.000 claims description 16
239000004215 Carbon black (E152) Substances 0.000 claims description 15
150000002430 hydrocarbons Chemical class 0.000 claims description 15
229920001577 copolymer Polymers 0.000 claims description 11
239000007788 liquid Substances 0.000 claims description 11
229910052749 magnesium Inorganic materials 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 10
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
239000007789 gas Substances 0.000 claims description 5
150000001298 alcohols Chemical class 0.000 claims description 3
150000002148 esters Chemical class 0.000 claims description 3
150000002170 ethers Chemical class 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 3
150000002989 phenols Chemical class 0.000 claims description 3
150000001408 amides Chemical class 0.000 claims description 2
150000008039 phosphoramides Chemical group 0.000 claims description 2
150000003141 primary amines Chemical class 0.000 claims description 2
150000003462 sulfoxides Chemical class 0.000 claims description 2
150000003512 tertiary amines Chemical class 0.000 claims description 2
150000003568 thioethers Chemical class 0.000 claims description 2
150000003003 phosphines Chemical group 0.000 claims 2
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 2
229910052845 zircon Inorganic materials 0.000 claims 2
MKPXGEVFQSIKGE-UHFFFAOYSA-N [Mg].[Si] Chemical compound [Mg].[Si] MKPXGEVFQSIKGE-UHFFFAOYSA-N 0.000 claims 1
DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical group [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 claims 1
150000001735 carboxylic acids Chemical group 0.000 claims 1
230000000379 polymerizing effect Effects 0.000 claims 1
150000003140 primary amides Chemical class 0.000 claims 1
150000003335 secondary amines Chemical class 0.000 claims 1
150000003457 sulfones Chemical class 0.000 claims 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 4
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 56
239000000243 solution Substances 0.000 description 40
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
125000004432 carbon atom Chemical group C* 0.000 description 22
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 13
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
229910052782 aluminium Inorganic materials 0.000 description 12
239000000843 powder Substances 0.000 description 10
239000000460 chlorine Substances 0.000 description 9
239000002904 solvent Substances 0.000 description 9
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 8
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
229910052801 chlorine Inorganic materials 0.000 description 8
238000001816 cooling Methods 0.000 description 8
239000012071 phase Substances 0.000 description 8
239000000725 suspension Substances 0.000 description 8
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 7
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 7
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
150000002431 hydrogen Chemical class 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
238000003756 stirring Methods 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
238000007792 addition Methods 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
239000002002 slurry Substances 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
229910021550 Vanadium Chloride Inorganic materials 0.000 description 3
230000002902 bimodal effect Effects 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
125000001485 cycloalkadienyl group Chemical group 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 3
XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 3
229920000098 polyolefin Polymers 0.000 description 3
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
229910007926 ZrCl Inorganic materials 0.000 description 2
125000005234 alkyl aluminium group Chemical group 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003426 co-catalyst Substances 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
238000012685 gas phase polymerization Methods 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
229920001903 high density polyethylene Polymers 0.000 description 2
239000004700 high-density polyethylene Substances 0.000 description 2
125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 2
238000005259 measurement Methods 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
150000002902 organometallic compounds Chemical class 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
239000000376 reactant Substances 0.000 description 2
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
TUPMGGHTDIFOMI-UHFFFAOYSA-J 2-methylprop-2-enoate;zirconium(4+) Chemical compound [Zr+4].CC(=C)C([O-])=O.CC(=C)C([O-])=O.CC(=C)C([O-])=O.CC(=C)C([O-])=O TUPMGGHTDIFOMI-UHFFFAOYSA-J 0.000 description 1
QMYGFTJCQFEDST-UHFFFAOYSA-N 3-methoxybutyl acetate Chemical group COC(C)CCOC(C)=O QMYGFTJCQFEDST-UHFFFAOYSA-N 0.000 description 1
XJONFIGVOQMBIP-UHFFFAOYSA-L Cl[Zr](Cl)C1C=CC=C1 Chemical compound Cl[Zr](Cl)C1C=CC=C1 XJONFIGVOQMBIP-UHFFFAOYSA-L 0.000 description 1
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
229920001730 Moisture cure polyurethane Polymers 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
ZGUGWUXLJSTTMA-UHFFFAOYSA-N Promazinum Chemical compound C1=CC=C2N(CCCN(C)C)C3=CC=CC=C3SC2=C1 ZGUGWUXLJSTTMA-UHFFFAOYSA-N 0.000 description 1
JZRWCGZRTZMZEH-UHFFFAOYSA-N Thiamine Natural products CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N JZRWCGZRTZMZEH-UHFFFAOYSA-N 0.000 description 1
229910010068 TiCl2 Inorganic materials 0.000 description 1
229910003074 TiCl4 Inorganic materials 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
238000010668 complexation reaction Methods 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical compound [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 1
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 1
238000001514 detection method Methods 0.000 description 1
150000004796 dialkyl magnesium compounds Chemical class 0.000 description 1
125000002897 diene group Chemical group 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000012674 dispersion polymerization Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000005243 fluidization Methods 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
125000001475 halogen functional group Chemical group 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
238000010191 image analysis Methods 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
OHZZTXYKLXZFSZ-UHFFFAOYSA-I manganese(3+) 5,10,15-tris(1-methylpyridin-1-ium-4-yl)-20-(1-methylpyridin-4-ylidene)porphyrin-22-ide pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mn+3].C1=CN(C)C=CC1=C1C(C=C2)=NC2=C(C=2C=C[N+](C)=CC=2)C([N-]2)=CC=C2C(C=2C=C[N+](C)=CC=2)=C(C=C2)N=C2C(C=2C=C[N+](C)=CC=2)=C2N=C1C=C2 OHZZTXYKLXZFSZ-UHFFFAOYSA-I 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
239000012968 metallocene catalyst Substances 0.000 description 1
CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
238000007814 microscopic assay Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
KUVXJBSVPBXHEK-UHFFFAOYSA-N octylaluminum Chemical compound CCCCCCCC[Al] KUVXJBSVPBXHEK-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000002901 organomagnesium compounds Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
150000003334 secondary amides Chemical class 0.000 description 1
125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
UIIMBOGNXHQVGW-UHFFFAOYSA-N sodium;hydron;carbonate Chemical compound [Na+].OC(O)=O UIIMBOGNXHQVGW-UHFFFAOYSA-N 0.000 description 1
239000012265 solid product Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
KYMBYSLLVAOCFI-UHFFFAOYSA-N thiamine Chemical compound CC1=C(CCO)SCN1CC1=CN=C(C)N=C1N KYMBYSLLVAOCFI-UHFFFAOYSA-N 0.000 description 1
229960003495 thiamine Drugs 0.000 description 1
235000019157 thiamine Nutrition 0.000 description 1
239000011721 thiamine Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
230000001131 transforming effect Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)

CS91633A 1990-03-12 1991-03-11 Catalyst and prepolymer applicable for olefins' polymerization and ethylene (co)polymer that can be prepared from them CS63391A2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9003368A FR2659337B1 (fr)	1990-03-12	1990-03-12	Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Publications (1)

Publication Number	Publication Date
CS63391A2 true CS63391A2 (en)	1991-10-15

Family

ID=9394799

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS91633A CS63391A2 (en)	1990-03-12	1991-03-11	Catalyst and prepolymer applicable for olefins' polymerization and ethylene (co)polymer that can be prepared from them

Country Status (17)

Country	Link
EP (1)	EP0447070B1 (fr)
JP (1)	JPH04220406A (fr)
KR (1)	KR910016782A (fr)
CN (1)	CN1054776A (fr)
AT (1)	ATE121758T1 (fr)
AU (1)	AU640452B2 (fr)
CA (1)	CA2036767A1 (fr)
CS (1)	CS63391A2 (fr)
DE (1)	DE69109161T2 (fr)
ES (1)	ES2071211T3 (fr)
FI (1)	FI911215L (fr)
FR (1)	FR2659337B1 (fr)
HU (1)	HUT60296A (fr)
NO (1)	NO177389C (fr)
PL (1)	PL289376A1 (fr)
PT (1)	PT97007B (fr)
ZA (1)	ZA911294B (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2659336B1 (fr) *	1990-03-12	1993-05-07	Bp Chemicals Snc	Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
EP0578838A1 (fr) *	1992-04-29	1994-01-19	Hoechst Aktiengesellschaft	Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation
EP0609439B1 (fr) *	1992-05-28	1996-11-27	Idemitsu Petrochemical Co., Ltd.	Procede de production de polyolefine
TW298593B (fr) *	1993-02-12	1997-02-21	Hoechst Ag
JP3390446B2 (ja) *	1993-10-21	2003-03-24	モービル・オイル・コーポレーション	高分子量成分及び低分子量成分を含む樹脂組成物
IT1269931B (it) *	1994-03-29	1997-04-16	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
ES2150529T3 (es) *	1994-04-07	2000-12-01	Bp Chem Int Ltd	Procedimiento de polimerizacion.
IT1270070B (it)	1994-07-08	1997-04-28	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
US5622906A (en) *	1994-09-16	1997-04-22	Phillips Petroleum Company	Compositions useful for olefin polymerization and processes therefor and therewith
US5529965A (en) *	1994-10-28	1996-06-25	Exxon Chemical Patents Inc.	Polymerization catalyst systems, their production and use
US5714424A (en) *	1995-01-09	1998-02-03	W. R. Grace & Co.-Conn.	Multi-component polyolefin catalysts
US5882750A (en) *	1995-07-03	1999-03-16	Mobil Oil Corporation	Single reactor bimodal HMW-HDPE film resin with improved bubble stability
FR2738829B1 (fr)	1995-09-19	1997-10-17	Atochem Elf Sa	Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides
ES2129323B1 (es) *	1996-04-18	2000-09-16	Repsol Quimica Sa	Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
AU2411797A (en) *	1996-05-03	1997-11-26	Dsm N.V.	A process for making polyolefins having broad molecular weight distributions
US6136747A (en) *	1998-06-19	2000-10-24	Union Carbide Chemicals & Plastics Technology Corporation	Mixed catalyst composition for the production of olefin polymers
CN1096474C (zh)	1998-12-30	2002-12-18	化学工业部北京化工研究院	用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6265037B1 (en)	1999-04-16	2001-07-24	Andersen Corporation	Polyolefin wood fiber composite
DE19962129A1 (de)	1999-12-21	2001-06-28	Targor Gmbh	Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
EP1265933B1 (fr)	2000-12-22	2008-08-13	Basell Polyolefine GmbH	Composes catalytiques pour la polymerisation d'olefines
CA2874344C (fr)	2014-12-15	2021-08-31	Nova Chemicals Corporation	Catalyseur spheroide de polymerisation d'olefines
CA2890606C (fr)	2015-05-07	2022-07-19	Nova Chemicals Corporation	Procede de polymerisation au moyen de catalyseur de type ziegler-natta spherique dense
JP7518642B2 (ja) *	2020-03-17	2024-07-18	三井化学株式会社	エチレン系重合体粒子の製造方法および延伸成形体の製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1268754A (fr) *	1985-06-21	1990-05-08	Howard Curtis Welborn, Jr.	Catalyseur de polymerisation sur support
US4659685A (en) *	1986-03-17	1987-04-21	The Dow Chemical Company	Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IT1221654B (it) *	1987-11-27	1990-07-12	Ausimont Spa	Catalizzatori per la polimerizzazione delle olefine
FR2656314B1 (fr) *	1989-12-22	1992-04-17	Bp Chemicals Snc	Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2656315B1 (fr) *	1989-12-22	1992-04-17	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2659336B1 (fr) *	1990-03-12	1993-05-07	Bp Chemicals Snc	Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

1990
- 1990-03-12 FR FR9003368A patent/FR2659337B1/fr not_active Expired - Lifetime
1991
- 1991-02-20 CA CA002036767A patent/CA2036767A1/fr not_active Abandoned
- 1991-02-21 ZA ZA911294A patent/ZA911294B/xx unknown
- 1991-02-25 AU AU71345/91A patent/AU640452B2/en not_active Ceased
- 1991-02-28 AT AT91301672T patent/ATE121758T1/de not_active IP Right Cessation
- 1991-02-28 EP EP91301672A patent/EP0447070B1/fr not_active Expired - Lifetime
- 1991-02-28 DE DE69109161T patent/DE69109161T2/de not_active Expired - Fee Related
- 1991-02-28 ES ES91301672T patent/ES2071211T3/es not_active Expired - Lifetime
- 1991-03-11 CS CS91633A patent/CS63391A2/cs unknown
- 1991-03-11 PT PT97007A patent/PT97007B/pt not_active IP Right Cessation
- 1991-03-11 PL PL28937691A patent/PL289376A1/xx unknown
- 1991-03-11 NO NO910954A patent/NO177389C/no unknown
- 1991-03-11 JP JP3044933A patent/JPH04220406A/ja active Pending
- 1991-03-11 HU HU91791A patent/HUT60296A/hu unknown
- 1991-03-12 FI FI911215A patent/FI911215L/fi not_active Application Discontinuation
- 1991-03-12 KR KR1019910003943A patent/KR910016782A/ko not_active Ceased
- 1991-03-12 CN CN91101482A patent/CN1054776A/zh active Pending

Also Published As

Publication number	Publication date
EP0447070A1 (fr)	1991-09-18
FI911215A0 (fi)	1991-03-12
HUT60296A (en)	1992-08-28
CN1054776A (zh)	1991-09-25
PT97007B (pt)	1998-07-31
JPH04220406A (ja)	1992-08-11
PL289376A1 (en)	1992-03-09
AU7134591A (en)	1991-09-12
EP0447070B1 (fr)	1995-04-26
FR2659337A1 (fr)	1991-09-13
FI911215A7 (fi)	1991-09-13
HU910791D0 (en)	1991-09-30
FR2659337B1 (fr)	1992-06-05
PT97007A (pt)	1991-10-31
KR910016782A (ko)	1991-11-05
NO177389B (no)	1995-05-29
DE69109161D1 (de)	1995-06-01
NO910954L (no)	1991-09-13
AU640452B2 (en)	1993-08-26
FI911215L (fi)	1991-09-13
ES2071211T3 (es)	1995-06-16
DE69109161T2 (de)	1995-08-31
ATE121758T1 (de)	1995-05-15
CA2036767A1 (fr)	1991-09-13
NO910954D0 (no)	1991-03-11
NO177389C (no)	1995-09-06
ZA911294B (en)	1992-10-28

Publication	Publication Date	Title
EP0436326B1 (fr)	1996-09-11	Catalyseur et prépolymère à utiliser dans la préparation de polyoléfines
CS63391A2 (en)	1991-10-15	Catalyst and prepolymer applicable for olefins' polymerization and ethylene (co)polymer that can be prepared from them
EP0435514B1 (fr)	1996-09-11	Catalyseur et prépolymère utilisées dans la préparation de polyoléfines
EP0767184B1 (fr)	1999-08-18	Support pour catalyseur de polymérisation d'oléfines, catalyseur de polymérisation d'oléfines et procédé de préparation de polymère d'oléfines
US8835577B2 (en)	2014-09-16	Catalyst systems having a tailored hydrogen response
WO2008075202A2 (fr)	2008-06-26	Composition de catalyse aux métallocènes sur support de polymère pour polymériser les oléfines
EP0447071B1 (fr)	1996-11-20	Catalyseur et prépolymère utilisés pour la polymérisation d'oléfines et (co)polymère d'éthylène ainsi obtenu
EP1216261B1 (fr)	2004-06-09	Compositions de catalyseur de polymerisation d'olefines en polymere possedant une repartition diverse du poids moleculaire, et procedes associes de production et d'utilisation de ce catalyseur
EP0437080A1 (fr)	1991-07-17	Procédé de préparation d'un catalyseur de type Ziegler-Natta
AU650814B2 (en)	1994-06-30	Vanadium-containing copolymer
EP0436325B1 (fr)	1995-06-14	Procédé de préparation d'un catalyseur du type Ziegler-Natta
JP2004035893A (ja)	2004-02-05	新規の触媒組成物およびそれを用いたオレフィン重合およびアルファオレフィンとのオレフィン共重合のための方法
JP3910651B2 (ja)	2007-04-25	有機アルミニウムオキシ組成物の製造方法
JP2618386B2 (ja)	1997-06-11	オレフインの重合方法
JP3230763B2 (ja)	2001-11-19	オレフィン重合用触媒およびオレフィンの重合方法
JP2001048912A (ja)	2001-02-20	オレフィン重合用予備重合触媒の製造方法
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JPH0819183B2 (ja)	1996-02-28	オレフイン重合用固体触媒の製法