NO177389C - Katalysator og prepolymer, fremstilling av slike og polymerisasjon av etylen - Google Patents

Katalysator og prepolymer, fremstilling av slike og polymerisasjon av etylen

Info

Publication number: NO177389C
Authority: NO; Norway
Prior art keywords: prepolymer; ethylene; catalyst; solid catalyst; contacting
Prior art date: 1990-03-12

Application number

NO910954A

Other languages

English (en)

Norwegian (no)

Other versions

NO910954D0 (no

NO177389B (no

NO910954L (no

Inventor

Jean-Claude Andre Bailly

Christine Jacqueline Chabrand

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-03-12

Filing date

1991-03-11

Publication date

1995-09-06

1991-03-11 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

1991-03-11 Publication of NO910954D0 publication Critical patent/NO910954D0/no

1991-09-13 Publication of NO910954L publication Critical patent/NO910954L/no

1995-05-29 Publication of NO177389B publication Critical patent/NO177389B/no

1995-09-06 Publication of NO177389C publication Critical patent/NO177389C/no

Links

VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 3
239000005977 Ethylene Substances 0.000 title abstract 3
239000003054 catalyst Substances 0.000 title abstract 2
238000006116 polymerization reaction Methods 0.000 title 1
239000011949 solid catalyst Substances 0.000 abstract 4
-1 alcohol Chemical class 0.000 abstract 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
150000001336 alkenes Chemical class 0.000 abstract 2
229910052739 hydrogen Inorganic materials 0.000 abstract 2
239000001257 hydrogen Substances 0.000 abstract 2
125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
150000002899 organoaluminium compounds Chemical class 0.000 abstract 2
239000002245 particle Substances 0.000 abstract 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
239000000203 mixture Substances 0.000 abstract 1
239000010936 titanium Substances 0.000 abstract 1
229910052719 titanium Inorganic materials 0.000 abstract 1
229910052720 vanadium Inorganic materials 0.000 abstract 1
229910052726 zirconium Inorganic materials 0.000 abstract 1
239000004711 α-olefin Substances 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
- C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerization Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Graft Or Block Polymers (AREA)

NO910954A 1990-03-12 1991-03-11 Katalysator og prepolymer, fremstilling av slike og polymerisasjon av etylen NO177389C (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9003368A FR2659337B1 (fr)	1990-03-12	1990-03-12	Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.

Publications (4)

Publication Number	Publication Date
NO910954D0 NO910954D0 (no)	1991-03-11
NO910954L NO910954L (no)	1991-09-13
NO177389B NO177389B (no)	1995-05-29
NO177389C true NO177389C (no)	1995-09-06

Family

ID=9394799

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO910954A NO177389C (no)	1990-03-12	1991-03-11	Katalysator og prepolymer, fremstilling av slike og polymerisasjon av etylen

Country Status (17)

Country	Link
EP (1)	EP0447070B1 (fr)
JP (1)	JPH04220406A (fr)
KR (1)	KR910016782A (fr)
CN (1)	CN1054776A (fr)
AT (1)	ATE121758T1 (fr)
AU (1)	AU640452B2 (fr)
CA (1)	CA2036767A1 (fr)
CS (1)	CS63391A2 (fr)
DE (1)	DE69109161T2 (fr)
ES (1)	ES2071211T3 (fr)
FI (1)	FI911215A7 (fr)
FR (1)	FR2659337B1 (fr)
HU (1)	HUT60296A (fr)
NO (1)	NO177389C (fr)
PL (1)	PL289376A1 (fr)
PT (1)	PT97007B (fr)
ZA (1)	ZA911294B (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2659336B1 (fr) *	1990-03-12	1993-05-07	Bp Chemicals Snc	Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
EP0578838A1 (fr) *	1992-04-29	1994-01-19	Hoechst Aktiengesellschaft	Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation
US6143845A (en) *	1992-05-28	2000-11-07	Idemitsu Petrochemical Co., Ltd.	Process for producing polyolefin
TW298593B (fr) *	1993-02-12	1997-02-21	Hoechst Ag
WO1995011264A1 (fr) *	1993-10-21	1995-04-27	Mobil Oil Corporation	Melanges de polyolefines a repartition bimodale de poids moleculaires
IT1269931B (it) *	1994-03-29	1997-04-16	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
EP0676418B1 (fr) *	1994-04-07	2000-07-26	BP Chemicals Limited	Procédé de polymérisation
IT1270070B (it) *	1994-07-08	1997-04-28	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
US5622906A (en) *	1994-09-16	1997-04-22	Phillips Petroleum Company	Compositions useful for olefin polymerization and processes therefor and therewith
US5529965A (en) *	1994-10-28	1996-06-25	Exxon Chemical Patents Inc.	Polymerization catalyst systems, their production and use
US5714424A (en) *	1995-01-09	1998-02-03	W. R. Grace & Co.-Conn.	Multi-component polyolefin catalysts
US5882750A (en) *	1995-07-03	1999-03-16	Mobil Oil Corporation	Single reactor bimodal HMW-HDPE film resin with improved bubble stability
FR2738829B1 (fr)	1995-09-19	1997-10-17	Atochem Elf Sa	Prepolymere pour la polymerisation des olefines, associant plusieurs composantes catalytiques solides
ES2129323B1 (es)	1996-04-18	2000-09-16	Repsol Quimica Sa	Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
WO1997042237A1 (fr) *	1996-05-03	1997-11-13	Dsm N.V.	Procede pour fabriquer des polyolefines ayant des repartitions larges des poids moleculaires
US6136747A (en) *	1998-06-19	2000-10-24	Union Carbide Chemicals & Plastics Technology Corporation	Mixed catalyst composition for the production of olefin polymers
CN1096474C (zh) *	1998-12-30	2002-12-18	化学工业部北京化工研究院	用于合成宽分布乙烯聚合物的复合催化剂及其制法和应用
US6265037B1 (en)	1999-04-16	2001-07-24	Andersen Corporation	Polyolefin wood fiber composite
DE19962129A1 (de)	1999-12-21	2001-06-28	Targor Gmbh	Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
JP2004516363A (ja) *	2000-12-22	2004-06-03	バセルポリオレフィンジーエムビーエイチ	オレフィンの重合用触媒成分
CA2874344C (fr)	2014-12-15	2021-08-31	Nova Chemicals Corporation	Catalyseur spheroide de polymerisation d'olefines
CA2890606C (fr)	2015-05-07	2022-07-19	Nova Chemicals Corporation	Procede de polymerisation au moyen de catalyseur de type ziegler-natta spherique dense
JP7518642B2 (ja) *	2020-03-17	2024-07-18	三井化学株式会社	エチレン系重合体粒子の製造方法および延伸成形体の製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1268754A (fr) *	1985-06-21	1990-05-08	Howard Curtis Welborn, Jr.	Catalyseur de polymerisation sur support
US4659685A (en) *	1986-03-17	1987-04-21	The Dow Chemical Company	Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IT1221654B (it) *	1987-11-27	1990-07-12	Ausimont Spa	Catalizzatori per la polimerizzazione delle olefine
FR2656314B1 (fr) *	1989-12-22	1992-04-17	Bp Chemicals Snc	Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2656315B1 (fr) *	1989-12-22	1992-04-17	Bp Chemicals Snc	Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2659336B1 (fr) *	1990-03-12	1993-05-07	Bp Chemicals Snc	Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

1990
- 1990-03-12 FR FR9003368A patent/FR2659337B1/fr not_active Expired - Lifetime
1991
- 1991-02-20 CA CA002036767A patent/CA2036767A1/fr not_active Abandoned
- 1991-02-21 ZA ZA911294A patent/ZA911294B/xx unknown
- 1991-02-25 AU AU71345/91A patent/AU640452B2/en not_active Ceased
- 1991-02-28 EP EP91301672A patent/EP0447070B1/fr not_active Expired - Lifetime
- 1991-02-28 AT AT91301672T patent/ATE121758T1/de not_active IP Right Cessation
- 1991-02-28 ES ES91301672T patent/ES2071211T3/es not_active Expired - Lifetime
- 1991-02-28 DE DE69109161T patent/DE69109161T2/de not_active Expired - Fee Related
- 1991-03-11 PT PT97007A patent/PT97007B/pt not_active IP Right Cessation
- 1991-03-11 JP JP3044933A patent/JPH04220406A/ja active Pending
- 1991-03-11 HU HU91791A patent/HUT60296A/hu unknown
- 1991-03-11 CS CS91633A patent/CS63391A2/cs unknown
- 1991-03-11 PL PL28937691A patent/PL289376A1/xx unknown
- 1991-03-11 NO NO910954A patent/NO177389C/no unknown
- 1991-03-12 KR KR1019910003943A patent/KR910016782A/ko not_active Ceased
- 1991-03-12 FI FI911215A patent/FI911215A7/fi not_active Application Discontinuation
- 1991-03-12 CN CN91101482A patent/CN1054776A/zh active Pending

Also Published As

Publication number	Publication date
PL289376A1 (en)	1992-03-09
EP0447070B1 (fr)	1995-04-26
AU7134591A (en)	1991-09-12
DE69109161D1 (de)	1995-06-01
FI911215A0 (fi)	1991-03-12
KR910016782A (ko)	1991-11-05
FR2659337B1 (fr)	1992-06-05
HUT60296A (en)	1992-08-28
JPH04220406A (ja)	1992-08-11
ZA911294B (en)	1992-10-28
NO910954D0 (no)	1991-03-11
FI911215L (fi)	1991-09-13
ES2071211T3 (es)	1995-06-16
DE69109161T2 (de)	1995-08-31
HU910791D0 (en)	1991-09-30
NO177389B (no)	1995-05-29
FR2659337A1 (fr)	1991-09-13
CN1054776A (zh)	1991-09-25
FI911215A7 (fi)	1991-09-13
CS63391A2 (en)	1991-10-15
PT97007B (pt)	1998-07-31
ATE121758T1 (de)	1995-05-15
NO910954L (no)	1991-09-13
CA2036767A1 (fr)	1991-09-13
AU640452B2 (en)	1993-08-26
PT97007A (pt)	1991-10-31
EP0447070A1 (fr)	1991-09-18

Publication	Publication Date	Title
NO177389C (no)	1995-09-06	Katalysator og prepolymer, fremstilling av slike og polymerisasjon av etylen
US5422325A (en)	1995-06-06	Supported polymerization catalysts, their production and use
CA2077744C (fr)	2003-04-15	Systeme catalytique a catalyseurs homogenes et heterogenes pour la production de polyolefines
FR2656315B1 (fr)	1992-04-17	Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
FR2656314B1 (fr)	1992-04-17	Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
WO1992000333A3 (fr)	1992-03-19	Catalyseurs en alliage organometallique de monocyclopentadienyle depourvu d'aluminium destines a la polymerisation d'olefines
FI963759A7 (fi)	1996-09-20	Metalloseeniyhdisteitä, menetelmä niiden valmistamiseksi ja niiden käyttö olefiinien polymerointiin tarkoitetuissa katalyyteissä
FI911214A0 (fi)	1991-03-12	Katalysator och prepolymer foer anvaendning vid polymerisation av olefiner och fraon dessa framstaellbar (ko) polymer av eten.
AU622573B2 (en)	1992-04-09	Process for preparing in gas phase elastomeric copolymers of propylene
ATE44036T1 (de)	1989-06-15	Herstellung koerniger stereoregulaerer 1-butenpolymere in einem fliessbett.
FI893621A0 (fi)	1989-07-28	Foerfarande foer framstaellning av katalysatorkomponenter foer polymerisation av polyeten med relativt smal molekylviktsfoerdelning.
KR102547232B1 (ko)	2023-06-26	올레핀 중합용 촉매의 제조방법
JPS565806A (en)	1981-01-21	Polymerization of olefin
WO1994012547A3 (fr)	1994-07-21	Polymerisation de monomeres fonctionnalises a l'aide de catalyseurs de ziegler-natta