CZ101595A3 - Granular detergents with protease and bleaching activity - Google Patents

Granular detergents with protease and bleaching activity Download PDF

Info

Publication number: CZ101595A3
Authority: CZ; Czechia
Prior art keywords: composition; group; protease; acid; weight
Prior art date: 1992-10-23

Application number

CZ951015A

Other languages

Czech (cs)

English (en)

Inventor

Giulio David Neil Di

Edward Eugene Getty

Chanchal Kumar Ghosh

Original Assignee

Procter & Gamble

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-10-23

Filing date

1993-10-18

Publication date

1996-04-17

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25510025&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CZ101595(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1993-10-18 Application filed by Procter & Gamble filed Critical Procter & Gamble

1996-04-17 Publication of CZ101595A3 publication Critical patent/CZ101595A3/cs

Links

108091005804 Peptidases Proteins 0.000 title claims abstract description 77
239000003599 detergent Substances 0.000 title claims abstract description 76
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 title claims abstract 10
239000004365 Protease Substances 0.000 title claims description 73
238000004061 bleaching Methods 0.000 title abstract description 18
230000000694 effects Effects 0.000 title description 9
239000000203 mixture Substances 0.000 claims abstract description 116
239000007844 bleaching agent Substances 0.000 claims abstract description 112
239000012190 activator Substances 0.000 claims abstract description 52
239000004094 surface-active agent Substances 0.000 claims abstract description 20
150000004967 organic peroxy acids Chemical class 0.000 claims abstract description 12
125000004432 carbon atom Chemical group C* 0.000 claims description 65
125000000217 alkyl group Chemical group 0.000 claims description 51
-1 heptyl- Chemical group 0.000 claims description 48
150000004965 peroxy acids Chemical class 0.000 claims description 36
239000011734 sodium Substances 0.000 claims description 32
239000004744 fabric Substances 0.000 claims description 31
229910052708 sodium Inorganic materials 0.000 claims description 30
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 24
108010042388 protease C Proteins 0.000 claims description 24
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 23
238000004140 cleaning Methods 0.000 claims description 23
239000002253 acid Substances 0.000 claims description 21
150000003839 salts Chemical class 0.000 claims description 20
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 17
229910052783 alkali metal Inorganic materials 0.000 claims description 15
239000003945 anionic surfactant Substances 0.000 claims description 14
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
238000000034 method Methods 0.000 claims description 10
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
239000002736 nonionic surfactant Substances 0.000 claims description 9
229910052760 oxygen Inorganic materials 0.000 claims description 9
239000001301 oxygen Substances 0.000 claims description 9
125000002947 alkylene group Chemical group 0.000 claims description 8
238000011065 in-situ storage Methods 0.000 claims description 8
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125000000129 anionic group Chemical group 0.000 claims description 7
230000001580 bacterial effect Effects 0.000 claims description 7
239000008187 granular material Substances 0.000 claims description 7
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229910019142 PO4 Inorganic materials 0.000 claims description 6
108010022999 Serine Proteases Proteins 0.000 claims description 6
102000012479 Serine Proteases Human genes 0.000 claims description 6
150000001340 alkali metals Chemical class 0.000 claims description 6
229960001922 sodium perborate Drugs 0.000 claims description 6
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 6
AVLQNPBLHZMWFC-UHFFFAOYSA-N 6-(nonylamino)-6-oxohexaneperoxoic acid Chemical compound CCCCCCCCCNC(=O)CCCCC(=O)OO AVLQNPBLHZMWFC-UHFFFAOYSA-N 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 5
235000021317 phosphate Nutrition 0.000 claims description 5
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125000002877 alkyl aryl group Chemical group 0.000 claims description 4
150000008051 alkyl sulfates Chemical class 0.000 claims description 4
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 4
239000002563 ionic surfactant Substances 0.000 claims description 4
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QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical group [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 claims description 4
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 4
239000002888 zwitterionic surfactant Substances 0.000 claims description 4
HGJOCYGWJRYXCF-UHFFFAOYSA-N 2-decylsulfonylpropaneperoxoic acid Chemical compound CCCCCCCCCCS(=O)(=O)C(C)C(=O)OO HGJOCYGWJRYXCF-UHFFFAOYSA-N 0.000 claims description 3
BDJSVGWWOVGVFS-UHFFFAOYSA-N 2-heptylsulfonylpropaneperoxoic acid Chemical compound CCCCCCCS(=O)(=O)C(C)C(=O)OO BDJSVGWWOVGVFS-UHFFFAOYSA-N 0.000 claims description 3
KOEDSBONUVRKAF-UHFFFAOYSA-N 4-(nonylamino)-4-oxobutaneperoxoic acid Chemical compound CCCCCCCCCNC(=O)CCC(=O)OO KOEDSBONUVRKAF-UHFFFAOYSA-N 0.000 claims description 3
244000063299 Bacillus subtilis Species 0.000 claims description 3
235000014469 Bacillus subtilis Nutrition 0.000 claims description 3
150000001450 anions Chemical group 0.000 claims description 3
150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
MIKSWWHQLZYKGU-UHFFFAOYSA-M sodium;2-benzoyloxybenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 MIKSWWHQLZYKGU-UHFFFAOYSA-M 0.000 claims description 3
125000005192 alkyl ethylene group Chemical group 0.000 claims description 2
125000000732 arylene group Chemical group 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
241000194108 Bacillus licheniformis Species 0.000 claims 2
150000004702 methyl esters Chemical class 0.000 claims 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
150000001860 citric acid derivatives Chemical class 0.000 claims 1
150000001875 compounds Chemical class 0.000 abstract description 7
102000035195 Peptidases Human genes 0.000 description 67
229940088598 enzyme Drugs 0.000 description 33
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108090000790 Enzymes Proteins 0.000 description 32
239000000945 filler Substances 0.000 description 17
150000002978 peroxides Chemical class 0.000 description 14
238000005406 washing Methods 0.000 description 14
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
239000003795 chemical substances by application Substances 0.000 description 11
229910052700 potassium Inorganic materials 0.000 description 11
239000011591 potassium Substances 0.000 description 11
239000000463 material Substances 0.000 description 10
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 8
125000001931 aliphatic group Chemical group 0.000 description 7
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 7
108010054213 protease C1 Proteins 0.000 description 7
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
150000007513 acids Chemical class 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000008363 phosphate buffer Substances 0.000 description 6
239000000344 soap Substances 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
150000007942 carboxylates Chemical class 0.000 description 5
239000003153 chemical reaction reagent Substances 0.000 description 5
235000019864 coconut oil Nutrition 0.000 description 5
239000003240 coconut oil Substances 0.000 description 5
230000002209 hydrophobic effect Effects 0.000 description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
101000581940 Homo sapiens Napsin-A Proteins 0.000 description 4
102100027343 Napsin-A Human genes 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
150000001735 carboxylic acids Chemical class 0.000 description 4
239000003925 fat Substances 0.000 description 4
235000019197 fats Nutrition 0.000 description 4
150000002430 hydrocarbons Chemical group 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000003760 tallow Substances 0.000 description 4
241000193830 Bacillus <bacterium> Species 0.000 description 3
101710180012 Protease 7 Proteins 0.000 description 3
229910021536 Zeolite Inorganic materials 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
150000004996 alkyl benzenes Chemical class 0.000 description 3
OENHQHLEOONYIE-UKMVMLAPSA-N beta-Carotene Chemical compound CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
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235000014113 dietary fatty acids Nutrition 0.000 description 3
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150000004665 fatty acids Chemical class 0.000 description 3
239000003205 fragrance Substances 0.000 description 3
125000001165 hydrophobic group Chemical group 0.000 description 3
125000002768 hydroxyalkyl group Chemical group 0.000 description 3
230000000269 nucleophilic effect Effects 0.000 description 3
239000012766 organic filler Substances 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
159000000001 potassium salts Chemical class 0.000 description 3
235000018102 proteins Nutrition 0.000 description 3
102000004169 proteins and genes Human genes 0.000 description 3
108090000623 proteins and genes Proteins 0.000 description 3
235000015067 sauces Nutrition 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
235000019832 sodium triphosphate Nutrition 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 2
KYVZSRPVPDAAKQ-UHFFFAOYSA-N 2-benzoyloxybenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 KYVZSRPVPDAAKQ-UHFFFAOYSA-N 0.000 description 2
LTALJGSZILUUQA-UHFFFAOYSA-N 2-nonanoyloxybenzenesulfonic acid Chemical compound CCCCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O LTALJGSZILUUQA-UHFFFAOYSA-N 0.000 description 2
DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 2
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
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WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 2
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 2
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KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
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150000001408 amides Chemical group 0.000 description 2
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238000011109 contamination Methods 0.000 description 2
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XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 2
108010020132 microbial serine proteinases Proteins 0.000 description 2
238000002156 mixing Methods 0.000 description 2
FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 2
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101710184263 Alkaline serine protease Proteins 0.000 description 1
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244000025254 Cannabis sativa Species 0.000 description 1
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KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
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IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical class OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
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102100038360 N-acylethanolamine-hydrolyzing acid amidase Human genes 0.000 description 1
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ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
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VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
108090000787 Subtilisin Proteins 0.000 description 1
CPZRYQJPVUJHOS-UHFFFAOYSA-N [2-(2-phenylethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CCC1=CC=CC=C1 CPZRYQJPVUJHOS-UHFFFAOYSA-N 0.000 description 1
OFQGYBUACFYNQF-UHFFFAOYSA-L [Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-].[Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-] Chemical compound [Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-].[Na+].C(CCCCCCCC)(=O)OC1=C(C=CC=C1)S(=O)(=O)[O-] OFQGYBUACFYNQF-UHFFFAOYSA-L 0.000 description 1
125000005354 acylalkyl group Chemical group 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001334 alicyclic compounds Chemical class 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
238000003556 assay Methods 0.000 description 1
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
239000011648 beta-carotene Substances 0.000 description 1
TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 description 1
235000013734 beta-carotene Nutrition 0.000 description 1
229960002747 betacarotene Drugs 0.000 description 1
ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
238000005282 brightening Methods 0.000 description 1
239000000872 buffer Substances 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
OKYDTGSQPZBYTF-UHFFFAOYSA-J calcium;magnesium;disulfate Chemical compound [Mg+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OKYDTGSQPZBYTF-UHFFFAOYSA-J 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000002301 combined effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000013078 crystal Substances 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
OOVHDTPLMCQXTA-UHFFFAOYSA-L disodium phosphono dihydrogen phosphate carbonate Chemical compound C([O-])([O-])=O.[Na+].OP(O)(=O)OP(=O)(O)O.[Na+] OOVHDTPLMCQXTA-UHFFFAOYSA-L 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000002255 enzymatic effect Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
125000005313 fatty acid group Chemical group 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000006081 fluorescent whitening agent Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000005457 ice water Substances 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910003475 inorganic filler Inorganic materials 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
238000010412 laundry washing Methods 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
125000005341 metaphosphate group Chemical group 0.000 description 1
LOTBYPQQWICYBB-UHFFFAOYSA-N methyl n-hexyl-n-[2-(hexylamino)ethyl]carbamate Chemical compound CCCCCCNCCN(C(=O)OC)CCCCCC LOTBYPQQWICYBB-UHFFFAOYSA-N 0.000 description 1
244000005700 microbiome Species 0.000 description 1
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
108040007629 peroxidase activity proteins Proteins 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical class [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
238000010186 staining Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
150000003462 sulfoxides Chemical class 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
238000003828 vacuum filtration Methods 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

CZ951015A 1992-10-23 1993-10-18 Granular detergents with protease and bleaching activity CZ101595A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US96547892A	1992-10-23	1992-10-23

Publications (1)

Publication Number	Publication Date
CZ101595A3 true CZ101595A3 (en)	1996-04-17

Family

ID=25510025

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CZ951015A CZ101595A3 (en)	1992-10-23	1993-10-18	Granular detergents with protease and bleaching activity

Country Status (19)

Country	Link
EP (1)	EP0665876B1 (de)
JP (1)	JPH08502546A (de)
KR (1)	KR950704466A (de)
CN (1)	CN1090599A (de)
AT (1)	ATE178352T1 (de)
AU (1)	AU5406394A (de)
BR (1)	BR9307300A (de)
CA (1)	CA2147658A1 (de)
CZ (1)	CZ101595A3 (de)
DE (1)	DE69324261T2 (de)
DK (1)	DK0665876T3 (de)
EG (1)	EG20573A (de)
ES (1)	ES2131125T3 (de)
GR (1)	GR3029922T3 (de)
HU (1)	HU217918B (de)
MA (1)	MA23011A1 (de)
MX (1)	MX9306634A (de)
PL (1)	PL175424B1 (de)
WO (1)	WO1994010284A1 (de)

Families Citing this family (27)

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DE69413028T2 (de) *	1993-05-20	1999-05-06	The Procter & Gamble Co., Cincinnati, Ohio	Bleichmethoden mit peroxysäurenaktivatoren zusammen mit enzymen
AU7244594A (en) *	1993-06-25	1995-01-17	Procter & Gamble Company, The	Granular laundry detergent compositions containing lipase and sodium nonanoyloxybenzene sulfonate
EP0723580B1 (de) *	1993-10-14	2003-07-16	The Procter & Gamble Company	Proteasen enthaltende bleichmittelzusammensetzungen
DE69434962T2 (de) *	1993-10-14	2008-01-17	The Procter & Gamble Company, Cincinnati	Proteasehaltige reinigungsmittel
ES2139891T3 (es) *	1994-04-22	2000-02-16	Procter & Gamble	Composiciones de blanqueo que comprenden una enzima proteasa.
US6066611A (en) *	1994-10-13	2000-05-23	The Procter & Gamble Company	Bleaching compositions comprising protease enzymes
EP0791046B1 (de) *	1994-11-18	2000-04-05	THE PROCTER & GAMBLE COMPANY	Lipase- und proteasehaltige waschmittelzusammensetzungen
EP0792342B1 (de) *	1994-11-18	2001-09-05	The Procter & Gamble Company	Verwendung von spezifische lipolytische enzyme in reinigungsmitteln
CN1048279C (zh) *	1995-12-20	2000-01-12	北京洛娃新型化工材料技术开发有限公司	含氧漂白剂的皂粉及其制造方法
US6369250B1 (en)	1997-08-20	2002-04-09	Procter & Gamble Company	Process for preparing and/or purifying amido acid phenyl ester sulfonates
GB2329187A (en) *	1997-09-11	1999-03-17	Procter & Gamble	Detergent composition containing an anionic surfactant system and a hydrophobic peroxy bleach
WO1999033946A1 (en) *	1997-12-29	1999-07-08	Colgate-Palmolive Company	Enzyme-containing compositions having improved cleaning power
US8871807B2 (en)	2008-03-28	2014-10-28	Ecolab Usa Inc.	Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids
US12203056B2 (en)	2008-03-28	2025-01-21	Ecolab Usa Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
NZ587218A (en)	2008-03-28	2012-04-27	Ecolab Inc	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US8809392B2 (en)	2008-03-28	2014-08-19	Ecolab Usa Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US8846107B2 (en)	2010-12-29	2014-09-30	Ecolab Usa Inc.	In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof
EP2687094B1 (de)	2010-12-29	2018-05-02	Ecolab USA Inc.	Erzeugung von Peroxycarboxylsäuren mit alkalischem pH-Wert und deren Verwendung als Textilienbleichmittel und antimikrobielle Wirkstoffe
US9321664B2 (en)	2011-12-20	2016-04-26	Ecolab Usa Inc.	Stable percarboxylic acid compositions and uses thereof
EP2831000A4 (de)	2012-03-30	2016-03-30	Ecolab Usa Inc	Verwendung von peressigsäure/wasserstoffperoxid und peroxidreduzierungsmitteln zur behandlung von bohrflüssigkeiten, fracking-flüssigkeiten, rückflusswasser und entsorgungswasser
US20140256811A1 (en)	2013-03-05	2014-09-11	Ecolab Usa Inc.	Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
US10165774B2 (en)	2013-03-05	2019-01-01	Ecolab Usa Inc.	Defoamer useful in a peracid composition with anionic surfactants
US8822719B1 (en)	2013-03-05	2014-09-02	Ecolab Usa Inc.	Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
CN103196857A (zh) *	2013-04-19	2013-07-10	陈军	洗涤评估用人工污渍样本的制备方法
EP3841059A1 (de)	2018-08-22	2021-06-30	Ecolab USA Inc.	Wasserstoffperoxid- und persäurestabilisierung mit molekülen auf basis einer pyridincarbonsäure an c-3, -4 oder -5
CN113811762A (zh)	2019-05-31	2021-12-17	埃科莱布美国股份有限公司	通过电导率测量和过酸组合物监测过酸浓度的方法
WO2021026410A1 (en)	2019-08-07	2021-02-11	Ecolab Usa Inc.	Polymeric and solid-supported chelators for stabilization of peracid-containing compositions

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GB1349650A (en) *	1970-11-27	1974-04-10	Pegg S & Son Ltd	Textile processing
FR2232590A1 (en) *	1973-06-07	1975-01-03	Procter & Gamble Europ	Washing compsn. contg. org. peracids - with surface active agents and enzymes for better stain removal
US4634551A (en) *	1985-06-03	1987-01-06	Procter & Gamble Company	Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain
DE3682443D1 (de) *	1985-06-28	1991-12-19	Procter & Gamble	Granulierte zusammensetzung enthaltend ein trockenes bleichmittel und ein stabiles enzym.
DE3683882D1 (de) *	1985-08-21	1992-03-26	Clorox Co	Stabiles persaeurebleichmittel.

1993
- 1993-10-18 EP EP93924343A patent/EP0665876B1/de not_active Revoked
- 1993-10-18 AT AT93924343T patent/ATE178352T1/de not_active IP Right Cessation
- 1993-10-18 CZ CZ951015A patent/CZ101595A3/cs unknown
- 1993-10-18 ES ES93924343T patent/ES2131125T3/es not_active Expired - Lifetime
- 1993-10-18 BR BR9307300A patent/BR9307300A/pt not_active Application Discontinuation
- 1993-10-18 JP JP6511119A patent/JPH08502546A/ja active Pending
- 1993-10-18 PL PL93308475A patent/PL175424B1/pl unknown
- 1993-10-18 AU AU54063/94A patent/AU5406394A/en not_active Abandoned
- 1993-10-18 HU HU9501144A patent/HU217918B/hu not_active IP Right Cessation
- 1993-10-18 DE DE69324261T patent/DE69324261T2/de not_active Expired - Fee Related
- 1993-10-18 KR KR1019950701554A patent/KR950704466A/ko not_active Withdrawn
- 1993-10-18 DK DK93924343T patent/DK0665876T3/da active
- 1993-10-18 CA CA002147658A patent/CA2147658A1/en not_active Abandoned
- 1993-10-18 WO PCT/US1993/009930 patent/WO1994010284A1/en not_active Ceased
- 1993-10-20 EG EG67193A patent/EG20573A/xx active
- 1993-10-21 MA MA23317A patent/MA23011A1/fr unknown
- 1993-10-22 CN CN93120507A patent/CN1090599A/zh active Pending
- 1993-10-25 MX MX9306634A patent/MX9306634A/es unknown
1999
- 1999-04-07 GR GR990401014T patent/GR3029922T3/el unknown

Also Published As

Publication number	Publication date
KR950704466A (ko)	1995-11-20
AU5406394A (en)	1994-05-24
WO1994010284A1 (en)	1994-05-11
HU217918B (hu)	2000-05-28
EP0665876A1 (de)	1995-08-09
MA23011A1 (fr)	1994-07-01
PL308475A1 (en)	1995-08-07
ES2131125T3 (es)	1999-07-16
CA2147658A1 (en)	1994-05-11
DE69324261D1 (de)	1999-05-06
PL175424B1 (pl)	1998-12-31
DK0665876T3 (da)	1999-06-21
CN1090599A (zh)	1994-08-10
ATE178352T1 (de)	1999-04-15
EG20573A (en)	1999-08-30
JPH08502546A (ja)	1996-03-19
HU9501144D0 (en)	1995-06-28
HUT71729A (en)	1996-01-29
BR9307300A (pt)	1999-06-01
DE69324261T2 (de)	1999-10-14
EP0665876B1 (de)	1999-03-31
GR3029922T3 (en)	1999-07-30
MX9306634A (es)	1994-04-29

Publication	Publication Date	Title
CZ101595A3 (en)	1996-04-17	Granular detergents with protease and bleaching activity
KR920010476B1 (ko)	1992-11-28	표백활성제 및 표백조성물
ES2397718T3 (es)	2013-03-11	Catalizador orgánico con mayor compatibilidad enzimática
EP0098021A2 (de)	1984-01-11	Zusammensetzungen für das Bleichen
JPH0813984B2 (ja)	1996-02-14	洗剤組成物
FI64639C (fi)	1983-12-12	Bleknings- och rengoeringskomposition
US4455249A (en)	1984-06-19	Stabilized bleach and laundering composition
CA2262892A1 (en)	1998-02-26	N-acylimines as bleach catalysts
EP0163331A1 (de)	1985-12-04	Körnige Detergens-Bleichmittelzusammensetzungen
GB2172300A (en)	1986-09-17	Laundry bars
US5914305A (en)	1999-06-22	Peroxynitrite based bleaching systems
MXPA00003514A (es)	2005-08-16	Composicion detergente.
MXPA02000057A (es)	2002-07-02	Composiciones blanqueadoras.
JPS6021720B2 (ja)	1985-05-29	標白洗浄剤
EP1038946A2 (de)	2000-09-27	N-Acylimine als Bleichkatalysatoren
EP0693116A1 (de)	1996-01-24	Zusammensetzung und verfahren zur verbinderung der farbstoffübertragung
KR960007394B1 (ko)	1996-05-31	표백제 함유세제 조성물
US5755991A (en)	1998-05-26	N-acyl oxaziridines as bleach agents
CA1208852A (en)	1986-08-05	Low temperature bleaching composition
KR100493457B1 (ko)	2005-06-07	벤젠디올(Ｂｅｎｚｅｎｄｉｏｌ) 이탈기를 포함하는표백활성화 화합물 및 이를 함유하는 표백 조성물
JP3194610B2 (ja)	2001-07-30	高嵩密度粒状漂白洗剤組成物
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