DD151306A1 - Verfahren zum herstellen von erdoelsulfonaten - Google Patents

Verfahren zum herstellen von erdoelsulfonaten Download PDF

Info

Publication number: DD151306A1
Authority: DD; German Democratic Republic
Prior art keywords: hydrocarbons; product mixture; crude oil; sulfur trioxide; unreacted hydrocarbons
Prior art date: 1979-07-26

Application number

DD22158880A

Other languages

German (de)

English (en)

Inventor

Wayne E Luetzelschwab

Original Assignee

Marathon Oil Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-07-26

Filing date

1980-06-04

Publication date

1981-10-14

1980-06-04 Application filed by Marathon Oil Co filed Critical Marathon Oil Co

1981-10-14 Publication of DD151306A1 publication Critical patent/DD151306A1/de

Links

239000003208 petroleum Substances 0.000 title claims abstract description 32
238000004519 manufacturing process Methods 0.000 title claims description 5
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 title abstract description 44
229930195733 hydrocarbon Natural products 0.000 claims abstract description 110
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 107
239000000203 mixture Substances 0.000 claims abstract description 80
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims abstract description 70
238000000034 method Methods 0.000 claims abstract description 44
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 18
238000006243 chemical reaction Methods 0.000 claims abstract description 12
230000003472 neutralizing effect Effects 0.000 claims abstract description 9
150000003871 sulfonates Chemical class 0.000 claims abstract 7
239000010779 crude oil Substances 0.000 claims description 50
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 20
239000003085 diluting agent Substances 0.000 claims description 13
238000006386 neutralization reaction Methods 0.000 claims description 13
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
239000002904 solvent Substances 0.000 claims description 11
238000009835 boiling Methods 0.000 claims description 10
LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims description 10
239000003350 kerosene Substances 0.000 claims description 9
238000011084 recovery Methods 0.000 claims description 9
239000006185 dispersion Substances 0.000 claims description 8
229910052757 nitrogen Inorganic materials 0.000 claims description 6
239000003570 air Substances 0.000 claims description 5
238000002360 preparation method Methods 0.000 claims description 5
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 4
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims description 4
JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 claims description 4
229910052799 carbon Inorganic materials 0.000 claims description 4
239000007789 gas Substances 0.000 claims description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
230000035484 reaction time Effects 0.000 claims description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
239000005977 Ethylene Substances 0.000 claims description 2
239000003345 natural gas Substances 0.000 claims description 2
239000011541 reaction mixture Substances 0.000 claims description 2
229930195734 saturated hydrocarbon Natural products 0.000 claims 1
238000000926 separation method Methods 0.000 abstract description 41
239000002253 acid Substances 0.000 description 27
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 25
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 16
239000003921 oil Substances 0.000 description 15
239000012071 phase Substances 0.000 description 14
150000003460 sulfonic acids Chemical class 0.000 description 11
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
238000006277 sulfonation reaction Methods 0.000 description 10
229910021529 ammonia Inorganic materials 0.000 description 8
239000000654 additive Substances 0.000 description 7
238000000605 extraction Methods 0.000 description 7
239000007788 liquid Substances 0.000 description 7
230000002378 acidificating effect Effects 0.000 description 6
-1 hydrocarbon sulfonate Chemical class 0.000 description 5
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
239000013505 freshwater Substances 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
239000004435 Oxo alcohol Substances 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
238000005191 phase separation Methods 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000002411 adverse Effects 0.000 description 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
239000010730 cutting oil Substances 0.000 description 2
238000007865 diluting Methods 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
235000019441 ethanol Nutrition 0.000 description 2
238000005188 flotation Methods 0.000 description 2
239000002917 insecticide Substances 0.000 description 2
JOWRFSPJFXLGGY-UHFFFAOYSA-N rimazolium Chemical compound C1CCC(C)N2C(=O)C(C(=O)OCC)=C[N+](C)=C21 JOWRFSPJFXLGGY-UHFFFAOYSA-N 0.000 description 2
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 2
239000001993 wax Substances 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000007810 chemical reaction solvent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000003795 desorption Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000011552 falling film Substances 0.000 description 1
235000013312 flour Nutrition 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000003204 osmotic effect Effects 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/62—Sulfonated fats, oils or waxes of undetermined constitution

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

DD22158880A 1979-07-26 1980-06-04 Verfahren zum herstellen von erdoelsulfonaten DD151306A1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US6113079A	1979-07-26	1979-07-26

Publications (1)

Publication Number	Publication Date
DD151306A1 true DD151306A1 (de)	1981-10-14

Family

ID=22033785

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD22158880A DD151306A1 (de)	1979-07-26	1980-06-04	Verfahren zum herstellen von erdoelsulfonaten

Country Status (12)

Country	Link
JP (1)	JPS607979B2 (ja)
AR (1)	AR227152A1 (ja)
AT (1)	AT369419B (ja)
BR (1)	BR8003384A (ja)
CA (1)	CA1144177A (ja)
DD (1)	DD151306A1 (ja)
DE (1)	DE3018827A1 (ja)
FR (1)	FR2462422A1 (ja)
GB (1)	GB2054558B (ja)
IT (1)	IT1132140B (ja)
NL (1)	NL8003706A (ja)
RO (1)	RO79550A (ja)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6132532Y2 (ja) *	1981-01-19	1986-09-22

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2324198A7 (fr) *	1974-01-07	1977-04-08	Witco Chemical Corp	Procede de preparation d'acides sulfoniques de purete elevee
DD118083A1 (ja) *	1975-01-24	1976-02-12

1980
- 1980-05-14 DE DE19803018827 patent/DE3018827A1/de not_active Withdrawn
- 1980-05-20 GB GB8016609A patent/GB2054558B/en not_active Expired
- 1980-05-21 CA CA000352360A patent/CA1144177A/en not_active Expired
- 1980-05-29 BR BR8003384A patent/BR8003384A/pt unknown
- 1980-06-04 DD DD22158880A patent/DD151306A1/de unknown
- 1980-06-16 FR FR8013306A patent/FR2462422A1/fr active Granted
- 1980-06-23 JP JP55084110A patent/JPS607979B2/ja not_active Expired
- 1980-06-26 AR AR281550A patent/AR227152A1/es active
- 1980-06-26 NL NL8003706A patent/NL8003706A/nl not_active Application Discontinuation
- 1980-06-30 IT IT23135/80A patent/IT1132140B/it active
- 1980-07-24 RO RO80101798A patent/RO79550A/ro unknown
- 1980-07-25 AT AT0388980A patent/AT369419B/de not_active IP Right Cessation

Also Published As

Publication number	Publication date
DE3018827A1 (de)	1981-02-19
RO79550B (ro)	1983-01-30
AT369419B (de)	1982-12-27
RO79550A (ro)	1983-02-01
JPS5620563A (en)	1981-02-26
NL8003706A (nl)	1981-01-28
FR2462422A1 (fr)	1981-02-13
CA1144177A (en)	1983-04-05
BR8003384A (pt)	1981-03-31
JPS607979B2 (ja)	1985-02-28
IT8023135A0 (it)	1980-06-30
GB2054558B (en)	1983-09-21
IT1132140B (it)	1986-06-25
FR2462422B1 (ja)	1983-06-24
GB2054558A (en)	1981-02-18
ATA388980A (de)	1982-05-15
AR227152A1 (es)	1982-09-30

Publication	Publication Date	Title
DE848192C (de)	1952-09-01	Loesungsmittel-Extraktionsverfahren zum Trennen eines Gemisches organischer Verbindungen
DE2424274B2 (de)	1979-03-01	Verfahren zur Reduzierung des Gehaltes von Schwefel- und Stickstoffverbindungen in Erdölkohlenwasserstoff gemischen
US4147638A (en)	1979-04-03	Sulfonation of crude oils to produce petroleum sulfonates
DD254392A5 (de)	1988-02-24	Kontinuierliches verfahren zur behandlung eines mercaptan enthaltenden kohlenwasserstoff-versorgungsstromes
WO1990004586A1 (de)	1990-05-03	Verfahren zur herstellung hochsulfatierter fettsäuren und fettsäurederivate
DE2256758A1 (de)	1973-10-11	Verfahren zum herstellen von erdoelsulfonaten vermittels sulfonieren von rohoelen
DE1668781C3 (de)	1976-01-08	Verfahren zur Herstellung von Alkylaromaten
DE3018827A1 (de)	1981-02-19	Verfahren zur raffination von sulfonierten kohlenwasserstoffen
US4361520A (en)	1982-11-30	Refinement of sulfonated hydrocarbons
DE1134367B (de)	1962-08-09	Verfahren zur Herstellung von oelloeslichen Sulfonaten
DE2502254C2 (de)	1983-08-04	Verfahren zur Herstellung einwertige Kationen enthaltender Erdölsulfonate
DE2156087A1 (de)	1972-06-29	Sulfonierungsverfahren
US3149063A (en)	1964-09-15	Process of refining hydrocarbon mineral oils
US2252957A (en)	1941-08-19	Process for producing petroleum sulphonates
US3505367A (en)	1970-04-07	Process for purifying raw sulfonates
DE682195C (de)	1939-10-10	Verfahren zur Gewinnung von Sulfonierungsprodukten
US2203443A (en)	1940-06-04	Method of preparing detergent
DE831731C (de)	1952-02-18	Herstellung von oelloeslichen Sulfonaten
DE3014370A1 (de)	1980-10-30	Verfahren zur herstellung von petroleum-sulfonaten, die dadurch erhaltenen produkte und deren verwendung zur herstellung von mikro-emulsionen
US2723219A (en)	1955-11-08	Preparation of sulfonation feed stock
DE3242475T1 (de)	1983-12-15	Verfahren zum verbessern der eindrueckbarkeit von rohoel und erdoelsulfonat-stopfen vermittels zusatz eines alkylbenzolsulfonates
DE2428540A1 (de)	1975-01-30	Verfahren zur reinigung eines rohen olefingemischs
DE2603539A1 (de)	1976-09-30	Verfahren zum herstellen mizellarer dispersionen vermittels einer sulfonierung von rohoel oder rohoel, aus dem die leicht siedenden anteile entfernt worden sind, fuer die verdraengung von rohoel aus lagerstaetten
US3164547A (en)	1965-01-05	Process for refining hydrocarbon oils so as to obtain only refined oil and pure oil soluble sulphonates
DE860356C (de)	1952-12-22	Verfahren zur Abtrennung von Schwefelsaeureestern oder deren Salzen aus Sulfonierungsgemischen