DD154990A5 - Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einer metallverbindung und einem organoperoxid - Google Patents

Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einer metallverbindung und einem organoperoxid Download PDF

Info

Publication number: DD154990A5
Authority: DD; German Democratic Republic
Prior art keywords: units; parts; general formula; polymer; mercaptoorganopolysiloxanmasse
Prior art date: 1979-12-03

Application number

DD80225681A

Other languages

German (de)

English (en)

Inventor

Gary R Homan

Chi-Long Lee

Original Assignee

Dow Corning

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-12-03

Filing date

1980-12-03

Publication date

1982-05-05

1980-12-03 Application filed by Dow Corning filed Critical Dow Corning

1982-05-05 Publication of DD154990A5 publication Critical patent/DD154990A5/de

Links

150000002736 metal compounds Chemical class 0.000 title description 8
150000003623 transition metal compounds Chemical class 0.000 claims abstract description 20
229920001971 elastomer Polymers 0.000 claims abstract description 19
239000000945 filler Substances 0.000 claims abstract description 19
239000000806 elastomer Substances 0.000 claims abstract description 18
238000002156 mixing Methods 0.000 claims abstract description 8
-1 dimethylsiloxane units Chemical group 0.000 claims description 50
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 32
150000002978 peroxides Chemical class 0.000 claims description 26
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 17
125000003396 thiol group Chemical group [H]S* 0.000 claims description 13
229910052742 iron Inorganic materials 0.000 claims description 11
150000001875 compounds Chemical class 0.000 claims description 9
229910017052 cobalt Inorganic materials 0.000 claims description 8
239000010941 cobalt Substances 0.000 claims description 8
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
229910052759 nickel Inorganic materials 0.000 claims description 8
238000006243 chemical reaction Methods 0.000 claims description 5
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 5
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
229910052802 copper Inorganic materials 0.000 claims description 4
239000010949 copper Substances 0.000 claims description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
229910021645 metal ion Inorganic materials 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
229910052723 transition metal Inorganic materials 0.000 claims description 4
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
229920002554 vinyl polymer Chemical group 0.000 claims description 4
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
239000011572 manganese Substances 0.000 claims description 3
150000003624 transition metals Chemical class 0.000 claims description 3
125000006273 (C1-C3) alkyl group Chemical group 0.000 claims description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 2
PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
229910017053 inorganic salt Inorganic materials 0.000 claims 1
229910052748 manganese Inorganic materials 0.000 claims 1
239000000203 mixture Substances 0.000 abstract description 111
239000000463 material Substances 0.000 abstract description 16
229920000642 polymer Polymers 0.000 description 75
230000000704 physical effect Effects 0.000 description 23
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 19
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 17
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 17
238000000034 method Methods 0.000 description 14
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 11
238000009472 formulation Methods 0.000 description 10
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 9
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
238000004132 cross linking Methods 0.000 description 7
239000003431 cross linking reagent Substances 0.000 description 7
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
229910052740 iodine Inorganic materials 0.000 description 6
239000000395 magnesium oxide Substances 0.000 description 6
239000002480 mineral oil Substances 0.000 description 6
235000010446 mineral oil Nutrition 0.000 description 6
239000000377 silicon dioxide Substances 0.000 description 6
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 5
238000004458 analytical method Methods 0.000 description 5
235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
239000011630 iodine Substances 0.000 description 5
230000006855 networking Effects 0.000 description 5
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
238000004448 titration Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
229910021591 Copper(I) chloride Inorganic materials 0.000 description 4
239000003054 catalyst Substances 0.000 description 4
230000008859 change Effects 0.000 description 4
OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 4
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
239000004205 dimethyl polysiloxane Substances 0.000 description 4
SGLXWMAOOWXVAM-UHFFFAOYSA-L manganese(2+);octanoate Chemical compound [Mn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O SGLXWMAOOWXVAM-UHFFFAOYSA-L 0.000 description 4
229920001296 polysiloxane Polymers 0.000 description 4
230000008569 process Effects 0.000 description 4
239000000047 product Substances 0.000 description 4
WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000007423 decrease Effects 0.000 description 3
229960005191 ferric oxide Drugs 0.000 description 3
KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 3
229910021485 fumed silica Inorganic materials 0.000 description 3
238000005227 gel permeation chromatography Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
235000012239 silicon dioxide Nutrition 0.000 description 3
DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 2
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
229910021577 Iron(II) chloride Inorganic materials 0.000 description 2
239000005909 Kieselgur Substances 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
235000019400 benzoyl peroxide Nutrition 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
ILZSSCVGGYJLOG-UHFFFAOYSA-N cobaltocene Chemical compound [Co+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 ILZSSCVGGYJLOG-UHFFFAOYSA-N 0.000 description 2
125000004989 dicarbonyl group Chemical group 0.000 description 2
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
230000005764 inhibitory process Effects 0.000 description 2
ORTRPLABQKAPKJ-UHFFFAOYSA-K iron(3+);octanoate Chemical compound [Fe+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O ORTRPLABQKAPKJ-UHFFFAOYSA-K 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229910017464 nitrogen compound Inorganic materials 0.000 description 2
150000002830 nitrogen compounds Chemical class 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
IALUUOKJPBOFJL-UHFFFAOYSA-N potassium oxidosilane Chemical compound [K+].[SiH3][O-] IALUUOKJPBOFJL-UHFFFAOYSA-N 0.000 description 2
239000010453 quartz Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
239000000565 sealant Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 2
OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
CWPKTBMRVATCBL-UHFFFAOYSA-N 3-[1-[1-[(2-methylphenyl)methyl]piperidin-4-yl]piperidin-4-yl]-1h-benzimidazol-2-one Chemical compound CC1=CC=CC=C1CN1CCC(N2CCC(CC2)N2C(NC3=CC=CC=C32)=O)CC1 CWPKTBMRVATCBL-UHFFFAOYSA-N 0.000 description 1
RMMOPSSZEHDFBL-UHFFFAOYSA-N 3-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]propane-1-thiol Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)CCCS RMMOPSSZEHDFBL-UHFFFAOYSA-N 0.000 description 1
KKMXCXAACAJOPB-UHFFFAOYSA-N 3-[dimethylsilyloxy(dimethyl)silyl]propane-1,1-dithiol Chemical compound C[SiH](O[Si](CCC(S)S)(C)C)C KKMXCXAACAJOPB-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical class [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
ZBFZBSPHMMXVMQ-UHFFFAOYSA-L O.O.O.O.O.O.N.S(=O)(=O)([O-])[O-].[Fe+2] Chemical compound O.O.O.O.O.O.N.S(=O)(=O)([O-])[O-].[Fe+2] ZBFZBSPHMMXVMQ-UHFFFAOYSA-L 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229910020175 SiOH Inorganic materials 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
208000000260 Warts Diseases 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
239000006229 carbon black Substances 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
GFHNAMRJFCEERV-UHFFFAOYSA-L cobalt chloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].[Cl-].[Co+2] GFHNAMRJFCEERV-UHFFFAOYSA-L 0.000 description 1
150000001869 cobalt compounds Chemical class 0.000 description 1
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
HWVKIRQMNIWOLT-UHFFFAOYSA-L cobalt(2+);octanoate Chemical compound [Co+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O HWVKIRQMNIWOLT-UHFFFAOYSA-L 0.000 description 1
238000001816 cooling Methods 0.000 description 1
CAMXOLUXKJMDSB-UHFFFAOYSA-L copper;naphthalene-1-carboxylate Chemical compound [Cu+2].C1=CC=C2C(C(=O)[O-])=CC=CC2=C1.C1=CC=C2C(C(=O)[O-])=CC=CC2=C1 CAMXOLUXKJMDSB-UHFFFAOYSA-L 0.000 description 1
239000004148 curcumin Substances 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
MKZHAQVVAPWKID-UHFFFAOYSA-N dimethoxy(3-methylsulfanylpropyl)silane Chemical compound CO[SiH](OC)CCCSC MKZHAQVVAPWKID-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000005670 electromagnetic radiation Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
MQLVWQSVRZVNIP-UHFFFAOYSA-L ferrous ammonium sulfate hexahydrate Chemical compound [NH4+].[NH4+].O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O MQLVWQSVRZVNIP-UHFFFAOYSA-L 0.000 description 1
238000011049 filling Methods 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000011874 heated mixture Substances 0.000 description 1
UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
239000011346 highly viscous material Substances 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002669 linoleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000011068 loading method Methods 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
230000000873 masking effect Effects 0.000 description 1
125000001038 naphthoyl group Chemical group C1(=CC=CC2=CC=CC=C12)C(=O)* 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
DVTHIMLUHWEZOM-UHFFFAOYSA-L nickel(2+);octanoate Chemical compound [Ni+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O DVTHIMLUHWEZOM-UHFFFAOYSA-L 0.000 description 1
HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
QUPCNWFFTANZPX-UHFFFAOYSA-M paramenthane hydroperoxide Chemical compound [O-]O.CC(C)C1CCC(C)CC1 QUPCNWFFTANZPX-UHFFFAOYSA-M 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
RIZGKEIRSQLIBK-UHFFFAOYSA-N prop-1-ene-1-thiol Chemical group CC=CS RIZGKEIRSQLIBK-UHFFFAOYSA-N 0.000 description 1
125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
239000003566 sealing material Substances 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
229920002379 silicone rubber Polymers 0.000 description 1
239000004945 silicone rubber Substances 0.000 description 1
201000010153 skin papilloma Diseases 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000005496 tempering Methods 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

DD80225681A 1979-12-03 1980-12-03 Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einer metallverbindung und einem organoperoxid DD154990A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/099,298 US4272623A (en)	1979-12-03	1979-12-03	Mercaptoorganopolysiloxane elastomers catalyzed by metallic compounds in the presence of peroxides

Publications (1)

Publication Number	Publication Date
DD154990A5 true DD154990A5 (de)	1982-05-05

Family

ID=22274315

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD80225681A DD154990A5 (de)	1979-12-03	1980-12-03	Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einer metallverbindung und einem organoperoxid

Country Status (10)

Country	Link
US (1)	US4272623A (fr)
EP (1)	EP0041556A4 (fr)
BE (1)	BE886456A (fr)
BR (1)	BR8008951A (fr)
CA (1)	CA1155994A (fr)
DD (1)	DD154990A5 (fr)
ES (1)	ES8205250A1 (fr)
IT (1)	IT1134412B (fr)
WO (1)	WO1981001559A1 (fr)
ZA (1)	ZA807225B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4526954A (en) *	1983-12-28	1985-07-02	Union Carbide Corporation	Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen
US5994456A (en) *	1998-04-09	1999-11-30	Dow Corning Corporation	Compositions comprising mercapto-functional organosilicon compounds

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3445419A (en) *	1966-01-21	1969-05-20	Dow Corning	Room temperature vulcanizable silicones
DE2008426A1 (fr)	1969-02-27	1970-09-10
US3655713A (en) *	1970-07-13	1972-04-11	Dow Corning	Silacyclopentane thiols and thiolates
US3816282A (en) *	1971-04-15	1974-06-11	Gen Electric	Radiation induced polymerization of polysiloxanes
US4064027A (en) *	1973-09-28	1977-12-20	Dow Corning Corporation	UV curable composition
US3873499A (en) *	1973-11-29	1975-03-25	Dow Corning	Fast curing mercaptoalkyl vinyl siloxane resins
US4039505A (en) *	1976-03-03	1977-08-02	Dow Corning Corporation	Siloxane elastomers containing sulfur and method of preparation
US4039504A (en) *	1976-03-03	1977-08-02	Dow Corning Corporation	Mercaptosiloxane elastomer and method of preparation
US4066603A (en) *	1976-03-03	1978-01-03	Dow Corning Corporation	Sulfur containing silicone elastomer and method of preparation
US4070329A (en) *	1977-01-03	1978-01-24	Dow Corning Corporation	Siloxane elastomer prepared from mercaptoorg anopolysiloxanes
US4070328A (en) *	1977-01-03	1978-01-24	Dow Corning Corporation	Mercaptoorganopolysiloxanes cured to elastomers with peroxides and nitrogen compounds

1979
- 1979-12-03 US US06/099,298 patent/US4272623A/en not_active Expired - Lifetime
1980
- 1980-11-06 BR BR8008951A patent/BR8008951A/pt unknown
- 1980-11-06 EP EP19810900160 patent/EP0041556A4/fr not_active Withdrawn
- 1980-11-06 WO PCT/US1980/001500 patent/WO1981001559A1/fr not_active Ceased
- 1980-11-12 CA CA000364509A patent/CA1155994A/fr not_active Expired
- 1980-11-20 ZA ZA00807225A patent/ZA807225B/xx unknown
- 1980-11-21 IT IT26162/80A patent/IT1134412B/it active
- 1980-12-02 ES ES497376A patent/ES8205250A1/es not_active Expired
- 1980-12-02 BE BE0/203014A patent/BE886456A/fr not_active IP Right Cessation
- 1980-12-03 DD DD80225681A patent/DD154990A5/de unknown

Also Published As

Publication number	Publication date
BR8008951A (pt)	1981-10-20
CA1155994A (fr)	1983-10-25
JPS56501612A (fr)	1981-11-05
IT1134412B (it)	1986-08-13
IT8026162A0 (it)	1980-11-21
ES497376A0 (es)	1982-06-01
US4272623A (en)	1981-06-09
BE886456A (fr)	1981-06-02
EP0041556A1 (fr)	1981-12-16
ZA807225B (en)	1981-12-30
EP0041556A4 (fr)	1982-05-10
ES8205250A1 (es)	1982-06-01
WO1981001559A1 (fr)	1981-06-11

Publication	Publication Date	Title
DE68904637T2 (de)	1993-06-03	Silikon-dichtungsmaterialien mit verminderter farbe.
DE4010281C2 (de)	2002-06-13	Abdruckzusammensetzung
DE2661091C2 (fr)	1989-03-30
DE2856229C2 (fr)	1987-07-23
DE68911260T2 (de)	1994-07-07	Helle und fliessfähige Silikondichtungsmasse.
DE2350369C2 (de)	1982-12-30	Verfahren zum Herstellen von Diorganopolysiloxanen
DE2502936C3 (de)	1980-02-21	Warmehartbare Organopoiysiloxanformmassen
EP0158141B1 (fr)	1989-10-18	Pâtes contenant du platine, des organopolysiloxanes et des charges
DE2535334B2 (de)	1978-09-28	Verfahren zur homogenen Verteilung hochdisperser aktiver Füllstoffe in Poly organosiloxanen
DE2308595C2 (de)	1982-04-15	Hitzehärtbare Polysiloxanformmassen mit verbesserter Feuerbeständigkeit
DE1904588B2 (de)	1970-12-03	Verzögerung und/oder Verhinderung der Härtung bei Raumtemperatur in Formmassen auf Grundlage von Organosiliciumverbir.dungen
DE3226228C2 (fr)	1987-06-04
DE2754702A1 (de)	1978-07-06	Zu einem elastomer haertbare mercaptoorganopolysiloxanmasse
DE1902086B2 (de)	1970-10-15	Stabilisierung der Lagerfähigkeit hitzehärtbarer Formmassen auf Grundlage von Qrganosiliciumverbindungen
DE2933247A1 (de)	1980-03-06	Kautschukmischung
DE2638452A1 (de)	1978-03-02	Zweikomponenten-siliconkautschuk
DE3912877A1 (de)	1989-11-02	Feines pulver aus einem siliconharz, enthaltend quaternaere ammoniumgruppen
DE1944367A1 (de)	1970-05-06	Organopolysiloxanelastomere
EP0010708B1 (fr)	1982-08-04	Procédé pour la préparation de masses d'organosiloxanes présentant une faible rémanence à la compression et qui sont durcissables en élastomères
DE69016298T2 (de)	1995-05-24	Härtbare Organopolysiloxanzusammensetzungen.
DD154993A5 (de)	1982-05-05	Sauerstoffhaertbare mercaptoorganosiloxanmasse und ihre verwendung zur herstellung hoehermolekularer produkte
DE2362954C2 (de)	1986-07-17	Cer(III)-diorganosiloxanolate enthaltende flüssige Reaktionsprodukte und deren Verwendung
DE69905542T2 (de)	2003-12-11	Additionshärtbare Silikonelastomermischung
DD154991A5 (de)	1982-05-05	Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einem aliphatisch ungesaettigten polydorganosiloxan und einem metallsalz einer carbonsaeure
DE2618418A1 (de)	1976-11-04	Siloxancopolymer