DD160454A5 - Verfahren zur herstellung eines katalysatortraegers - Google Patents

Verfahren zur herstellung eines katalysatortraegers Download PDF

Info

Publication number: DD160454A5
Authority: DD; German Democratic Republic
Prior art keywords: catalyst; titanium; solid; compound; electron donor
Prior art date: 1981-04-22

Application number

DD23095281A

Other languages

German (de)

English (en)

Inventor

Nemesio D Miro

Malcolm J Kaus

Original Assignee

Dart Ind Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-04-22

Filing date

1981-06-19

Publication date

1983-08-03

1981-04-22 Priority claimed from US06/252,661 external-priority patent/US4425257A/en

1981-06-19 Application filed by Dart Ind Inc filed Critical Dart Ind Inc

1983-08-03 Publication of DD160454A5 publication Critical patent/DD160454A5/de

Links

239000003054 catalyst Substances 0.000 title claims abstract description 256
238000004519 manufacturing process Methods 0.000 title claims description 16
150000001875 compounds Chemical class 0.000 claims abstract description 62
239000007787 solid Substances 0.000 claims abstract description 51
238000000034 method Methods 0.000 claims abstract description 47
238000006116 polymerization reaction Methods 0.000 claims abstract description 38
239000000203 mixture Substances 0.000 claims abstract description 23
239000004711 α-olefin Substances 0.000 claims abstract description 20
238000002360 preparation method Methods 0.000 claims abstract description 19
230000008569 process Effects 0.000 claims abstract description 17
239000000126 substance Substances 0.000 claims abstract description 13
229920000098 polyolefin Polymers 0.000 claims abstract description 6
230000035515 penetration Effects 0.000 claims abstract description 4
-1 arylalkyl ethers Chemical class 0.000 claims description 115
239000004743 Polypropylene Substances 0.000 claims description 101
229920001155 polypropylene Polymers 0.000 claims description 97
239000010936 titanium Substances 0.000 claims description 70
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 65
229910052719 titanium Inorganic materials 0.000 claims description 65
229920000642 polymer Polymers 0.000 claims description 60
RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 claims description 59
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 58
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 35
150000003623 transition metal compounds Chemical class 0.000 claims description 34
UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 29
239000007788 liquid Substances 0.000 claims description 21
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 19
239000011777 magnesium Substances 0.000 claims description 19
235000011147 magnesium chloride Nutrition 0.000 claims description 17
239000007795 chemical reaction product Substances 0.000 claims description 16
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 15
229910052749 magnesium Inorganic materials 0.000 claims description 15
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
238000006243 chemical reaction Methods 0.000 claims description 14
239000000463 material Substances 0.000 claims description 12
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 12
229910052782 aluminium Inorganic materials 0.000 claims description 11
239000011572 manganese Substances 0.000 claims description 10
239000000047 product Substances 0.000 claims description 10
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 9
229910052757 nitrogen Inorganic materials 0.000 claims description 9
239000012024 dehydrating agents‎ Substances 0.000 claims description 8
229910052751 metal Inorganic materials 0.000 claims description 8
239000002184 metal Substances 0.000 claims description 8
239000011949 solid catalyst Substances 0.000 claims description 8
229910052723 transition metal Inorganic materials 0.000 claims description 8
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 7
241000607479 Yersinia pestis Species 0.000 claims description 7
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
230000000694 effects Effects 0.000 claims description 7
229910052748 manganese Inorganic materials 0.000 claims description 7
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
239000005977 Ethylene Substances 0.000 claims description 6
239000003795 chemical substances by application Substances 0.000 claims description 6
239000000575 pesticide Substances 0.000 claims description 6
239000006104 solid solution Substances 0.000 claims description 6
150000003624 transition metals Chemical class 0.000 claims description 6
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical group C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 5
125000004429 atom Chemical group 0.000 claims description 5
239000000178 monomer Substances 0.000 claims description 5
150000002902 organometallic compounds Chemical class 0.000 claims description 5
239000011236 particulate material Substances 0.000 claims description 5
229910052698 phosphorus Inorganic materials 0.000 claims description 5
239000005049 silicon tetrachloride Substances 0.000 claims description 5
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 5
229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
229910052760 oxygen Inorganic materials 0.000 claims description 4
239000001301 oxygen Substances 0.000 claims description 4
239000000243 solution Substances 0.000 claims description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
238000011065 in-situ storage Methods 0.000 claims description 3
150000002894 organic compounds Chemical class 0.000 claims description 3
229920001296 polysiloxane Polymers 0.000 claims description 3
229910052717 sulfur Inorganic materials 0.000 claims description 3
239000011593 sulfur Substances 0.000 claims description 3
CSDQQAQKBAQLLE-UHFFFAOYSA-N 4-(4-chlorophenyl)-4,5,6,7-tetrahydrothieno[3,2-c]pyridine Chemical compound C1=CC(Cl)=CC=C1C1C(C=CS2)=C2CCN1 CSDQQAQKBAQLLE-UHFFFAOYSA-N 0.000 claims description 2
239000005997 Calcium carbide Substances 0.000 claims description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 claims description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 2
150000004678 hydrides Chemical class 0.000 claims description 2
125000004437 phosphorous atom Chemical group 0.000 claims description 2
CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims description 2
150000003609 titanium compounds Chemical class 0.000 claims 10
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
206010061926 Purulence Diseases 0.000 claims 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
239000004744 fabric Substances 0.000 claims 2
125000000524 functional group Chemical group 0.000 claims 2
206010067482 No adverse event Diseases 0.000 claims 1
239000000470 constituent Substances 0.000 claims 1
230000001627 detrimental effect Effects 0.000 claims 1
230000002708 enhancing effect Effects 0.000 claims 1
229910052759 nickel Inorganic materials 0.000 claims 1
239000013618 particulate matter Substances 0.000 claims 1
239000012466 permeate Substances 0.000 claims 1
239000002685 polymerization catalyst Substances 0.000 claims 1
229920005862 polyol Polymers 0.000 claims 1
150000003077 polyols Chemical class 0.000 claims 1
239000011343 solid material Substances 0.000 claims 1
238000005265 energy consumption Methods 0.000 abstract description 3
238000003912 environmental pollution Methods 0.000 abstract description 2
238000003801 milling Methods 0.000 description 16
238000000227 grinding Methods 0.000 description 14
239000001257 hydrogen Substances 0.000 description 13
229910052739 hydrogen Inorganic materials 0.000 description 13
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 13
238000002156 mixing Methods 0.000 description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 12
238000000605 extraction Methods 0.000 description 11
239000002904 solvent Substances 0.000 description 11
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
239000004698 Polyethylene Substances 0.000 description 8
239000012298 atmosphere Substances 0.000 description 8
229920000573 polyethylene Polymers 0.000 description 8
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
239000012876 carrier material Substances 0.000 description 6
230000009467 reduction Effects 0.000 description 6
238000005070 sampling Methods 0.000 description 5
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
230000008901 benefit Effects 0.000 description 4
150000001735 carboxylic acids Chemical class 0.000 description 4
238000009826 distribution Methods 0.000 description 4
150000002148 esters Chemical class 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
239000007789 gas Substances 0.000 description 4
239000004615 ingredient Substances 0.000 description 4
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
125000005907 alkyl ester group Chemical group 0.000 description 3
238000001035 drying Methods 0.000 description 3
150000004820 halides Chemical group 0.000 description 3
239000000155 melt Substances 0.000 description 3
230000004048 modification Effects 0.000 description 3
238000012986 modification Methods 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920001083 polybutene Polymers 0.000 description 3
239000000843 powder Substances 0.000 description 3
IJJWOSAXNHWBPR-HUBLWGQQSA-N 5-[(3as,4s,6ar)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]-n-(6-hydrazinyl-6-oxohexyl)pentanamide Chemical compound N1C(=O)N[C@@H]2[C@H](CCCCC(=O)NCCCCCC(=O)NN)SC[C@@H]21 IJJWOSAXNHWBPR-HUBLWGQQSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
230000000903 blocking effect Effects 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000000969 carrier Substances 0.000 description 2
RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 2
NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000008030 elimination Effects 0.000 description 2
238000003379 elimination reaction Methods 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
230000006872 improvement Effects 0.000 description 2
230000001965 increasing effect Effects 0.000 description 2
239000001282 iso-butane Substances 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
229910052743 krypton Inorganic materials 0.000 description 2
DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
230000007704 transition Effects 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
238000005406 washing Methods 0.000 description 2
KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
WZFUQSJFWNHZHM-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)CC(=O)N1CC2=C(CC1)NN=N2 WZFUQSJFWNHZHM-UHFFFAOYSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
229910016467 AlCl 4 Inorganic materials 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
229910003902 SiCl 4 Inorganic materials 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
238000000944 Soxhlet extraction Methods 0.000 description 1
229910010062 TiCl3 Inorganic materials 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001346 alkyl aryl ethers Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000008378 aryl ethers Chemical class 0.000 description 1
230000003416 augmentation Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
229960002903 benzyl benzoate Drugs 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
150000001805 chlorine compounds Chemical group 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
229910001873 dinitrogen Inorganic materials 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
230000004907 flux Effects 0.000 description 1
239000011888 foil Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000005556 hormone Substances 0.000 description 1
229940088597 hormone Drugs 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
230000001939 inductive effect Effects 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
238000006317 isomerization reaction Methods 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
230000007774 longterm Effects 0.000 description 1
150000002696 manganese Chemical class 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
229940050176 methyl chloride Drugs 0.000 description 1
IYZQOALZCXGJIJ-UHFFFAOYSA-N methylsulfanyloxybenzene Chemical compound CSOC1=CC=CC=C1 IYZQOALZCXGJIJ-UHFFFAOYSA-N 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
238000004184 polymer manufacturing process Methods 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000007970 thio esters Chemical class 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
125000005323 thioketone group Chemical group 0.000 description 1
RFRNCCDBLKNKEQ-UHFFFAOYSA-N triethylalumane;tris(2-methylpropyl)alumane Chemical compound CC[Al](CC)CC.CC(C)C[Al](CC(C)C)CC(C)C RFRNCCDBLKNKEQ-UHFFFAOYSA-N 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000002699 waste material Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

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Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

DD23095281A 1981-04-22 1981-06-19 Verfahren zur herstellung eines katalysatortraegers DD160454A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/252,661 US4425257A (en)	1980-05-02	1981-04-22	Supported high efficiency polyolefin catalyst component and methods of making and using the same

Publications (1)

Publication Number	Publication Date
DD160454A5 true DD160454A5 (de)	1983-08-03

Family

ID=22956977

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD23095281A DD160454A5 (de)	1981-04-22	1981-06-19	Verfahren zur herstellung eines katalysatortraegers

Country Status (3)

Country	Link
DD (1)	DD160454A5 (fr)
RO (1)	RO82203A (fr)
ZA (1)	ZA814852B (fr)

1981
- 1981-05-19 RO RO81104331A patent/RO82203A/fr unknown
- 1981-06-19 DD DD23095281A patent/DD160454A5/de unknown
- 1981-07-15 ZA ZA814852A patent/ZA814852B/xx unknown

Also Published As

Publication number	Publication date
ZA814852B (en)	1982-07-28
RO82203B (ro)	1983-07-30
RO82203A (fr)	1983-08-03

Publication	Publication Date	Title
DE2735672C2 (fr)	1991-09-26
DE2739608C2 (fr)	1987-08-27
DE2110380C2 (fr)	1988-02-18
DE2660216C2 (de)	1982-02-25	Feste Katalysatorkomponente zur Polymerisation von &alpha;-Olefinen
DE3228065C2 (fr)	1987-09-03
DE2515211C2 (fr)	1987-10-01
DE2153520A1 (de)	1972-05-04	Verfahren zur selektiven Polymerisation von alpha-Olefinen
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