DD208960A5 - Verfahren und vorrichtung zur behandlung eines schwefel enthaltenden gasstroms - Google Patents
Verfahren und vorrichtung zur behandlung eines schwefel enthaltenden gasstroms Download PDFInfo
- Publication number
- DD208960A5 DD208960A5 DD23782982A DD23782982A DD208960A5 DD 208960 A5 DD208960 A5 DD 208960A5 DD 23782982 A DD23782982 A DD 23782982A DD 23782982 A DD23782982 A DD 23782982A DD 208960 A5 DD208960 A5 DD 208960A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- stream
- sulfur
- temperature
- water
- dried
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 113
- 238000010408 sweeping Methods 0.000 title 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 168
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 157
- 239000011593 sulfur Substances 0.000 claims abstract description 157
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 141
- 229910001868 water Inorganic materials 0.000 claims abstract description 137
- 239000007789 gas Substances 0.000 claims abstract description 122
- 239000003054 catalyst Substances 0.000 claims abstract description 50
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000011541 reaction mixture Substances 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 230000008569 process Effects 0.000 claims description 76
- 238000006243 chemical reaction Methods 0.000 claims description 65
- 238000007254 oxidation reaction Methods 0.000 claims description 64
- 230000003647 oxidation Effects 0.000 claims description 62
- 150000003464 sulfur compounds Chemical class 0.000 claims description 37
- 238000010791 quenching Methods 0.000 claims description 29
- 230000003197 catalytic effect Effects 0.000 claims description 22
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 230000009467 reduction Effects 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 8
- 230000000171 quenching effect Effects 0.000 claims description 5
- 230000008014 freezing Effects 0.000 claims description 4
- 238000007710 freezing Methods 0.000 claims description 4
- 230000007257 malfunction Effects 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 2
- -1 H2S and SO_ Chemical class 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract description 24
- 230000005611 electricity Effects 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 238000010574 gas phase reaction Methods 0.000 abstract 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 46
- 238000001816 cooling Methods 0.000 description 27
- 238000011084 recovery Methods 0.000 description 25
- 241000196324 Embryophyta Species 0.000 description 20
- 241000894007 species Species 0.000 description 17
- 238000006722 reduction reaction Methods 0.000 description 13
- 238000005984 hydrogenation reaction Methods 0.000 description 12
- 230000008929 regeneration Effects 0.000 description 12
- 238000011069 regeneration method Methods 0.000 description 12
- 238000001179 sorption measurement Methods 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 238000004364 calculation method Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000004064 recycling Methods 0.000 description 6
- 238000013459 approach Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- NINIDFKCEFEMDL-OUBTZVSYSA-N sulfur-33 atom Chemical compound [33S] NINIDFKCEFEMDL-OUBTZVSYSA-N 0.000 description 3
- 101000588924 Anthopleura elegantissima Delta-actitoxin-Ael1a Proteins 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229940123973 Oxygen scavenger Drugs 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241000533867 Fordia Species 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 238000011021 bench scale process Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000004064 dysfunction Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000036515 potency Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Treating Waste Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23977281A | 1981-03-02 | 1981-03-02 | |
| US23973081A | 1981-03-02 | 1981-03-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD208960A5 true DD208960A5 (de) | 1984-04-18 |
Family
ID=26932808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD23782982A DD208960A5 (de) | 1981-03-02 | 1982-03-02 | Verfahren und vorrichtung zur behandlung eines schwefel enthaltenden gasstroms |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0059548A1 (fr) |
| AU (1) | AU8103382A (fr) |
| DD (1) | DD208960A5 (fr) |
| ES (1) | ES510056A0 (fr) |
| PL (1) | PL235288A1 (fr) |
| RO (1) | RO84468B (fr) |
| YU (1) | YU44982A (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3310710C1 (de) * | 1983-03-24 | 1984-07-05 | Davy McKee AG, 6000 Frankfurt | Verfahren zur Reinigung von Claus-Abgas |
| US4507275A (en) * | 1983-08-30 | 1985-03-26 | Standard Oil Company (Indiana) | Process for producing and recovering elemental sulfur from acid gas |
| CA1218219A (fr) * | 1983-09-29 | 1987-02-24 | John W. Palm | Procede et appareil pour l'elimination de l'ammoniac dans des circuits de gaz acides |
| FR2589082B1 (fr) * | 1985-10-25 | 1989-12-01 | Elf Aquitaine | Procede d'elimination des composes soufres contenus dans un gaz residuaire, notamment issu d'une usine a soufre claus, avec recuperation desdits composes sous la forme de soufre |
| GB2215323B (en) * | 1988-03-09 | 1991-12-18 | Exxon Research Engineering Co | Process for removing sulfur moieties from a sulfurous gas such as claus tail-gas |
| DE3901600C2 (de) * | 1989-01-20 | 1998-12-24 | Krupp Koppers Gmbh | Verfahren zur Behandlung der Vakuumabluft von Teerdestillationsanlagen |
| US20100303700A1 (en) * | 2009-05-29 | 2010-12-02 | Nagaraju Palla | Process for treating a gas stream or effluent |
| CN114515509B (zh) * | 2020-11-19 | 2023-10-31 | 中国石油天然气股份有限公司 | 用于硫磺回收系统的停工除硫装置及除硫方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1097306A (en) * | 1964-03-19 | 1968-01-03 | Peter Spence & Sons Ltd | Improvements in or relating to waste gas purification |
| US3752877A (en) * | 1969-08-27 | 1973-08-14 | Parsons Co Ralph M | Recovery of sulfur compounds from tail gases |
| NL7310929A (fr) * | 1973-08-08 | 1974-01-25 | ||
| DE2648190C3 (de) * | 1976-10-25 | 1980-02-21 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Schwefel nach dem Claus-Verfahren |
| US4113849A (en) * | 1977-03-25 | 1978-09-12 | Union Carbide Corporation | Recovering sulfur from gas streams containing hydrogen sulfide |
| US4255408A (en) * | 1977-11-11 | 1981-03-10 | Thermo-Mist Company | Process for removing sulfur and sulfur compounds from the effluent of industrial processes |
-
1982
- 1982-02-15 EP EP19820300754 patent/EP0059548A1/fr not_active Ceased
- 1982-03-02 RO RO106786A patent/RO84468B/ro unknown
- 1982-03-02 AU AU81033/82A patent/AU8103382A/en not_active Abandoned
- 1982-03-02 DD DD23782982A patent/DD208960A5/de unknown
- 1982-03-02 YU YU44982A patent/YU44982A/xx unknown
- 1982-03-02 PL PL23528882A patent/PL235288A1/xx unknown
- 1982-03-02 ES ES510056A patent/ES510056A0/es active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| YU44982A (en) | 1985-03-20 |
| ES8303244A1 (es) | 1983-02-01 |
| ES510056A0 (es) | 1983-02-01 |
| RO84468B (ro) | 1984-10-30 |
| PL235288A1 (fr) | 1982-10-25 |
| RO84468A (fr) | 1984-09-29 |
| AU8103382A (en) | 1982-09-09 |
| EP0059548A1 (fr) | 1982-09-08 |
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