DD210289A5 - Polyveresterungskatalysator - Google Patents

Polyveresterungskatalysator Download PDF

Info

Publication number: DD210289A5
Authority: DD; German Democratic Republic
Prior art keywords: item; catalyst according; polyesterification; compound; polyesterification catalyst
Prior art date: 1981-12-31

Application number

DD82246831A

Other languages

German (de)

English (en)

Inventor

Kurt Weinberg

Gordon C Johnson

Original Assignee

Union Carbide Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-12-31

Filing date

1982-12-30

Publication date

1984-06-06

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23315439&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DD210289(A5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1982-12-30 Application filed by Union Carbide Corp filed Critical Union Carbide Corp

1984-06-06 Publication of DD210289A5 publication Critical patent/DD210289A5/de

Links

239000003054 catalyst Substances 0.000 title claims abstract description 55
-1 aliphatic glycols Chemical class 0.000 claims abstract description 44
150000001875 compounds Chemical class 0.000 claims abstract description 31
229920000728 polyester Polymers 0.000 claims abstract description 25
229920001296 polysiloxane Polymers 0.000 claims abstract description 17
229920001634 Copolyester Polymers 0.000 claims abstract description 8
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 22
150000004696 coordination complex Chemical class 0.000 claims description 12
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
239000010936 titanium Substances 0.000 claims description 9
229910052719 titanium Inorganic materials 0.000 claims description 9
229910052787 antimony Inorganic materials 0.000 claims description 7
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 7
229910052739 hydrogen Inorganic materials 0.000 claims description 7
125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 6
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
125000001188 haloalkyl group Chemical group 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 4
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
230000032050 esterification Effects 0.000 claims description 4
238000005886 esterification reaction Methods 0.000 claims description 4
229910052725 zinc Inorganic materials 0.000 claims description 4
239000011701 zinc Substances 0.000 claims description 4
125000002877 alkyl aryl group Chemical group 0.000 claims description 2
125000003710 aryl alkyl group Chemical group 0.000 claims description 2
125000003118 aryl group Chemical group 0.000 claims description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
239000007787 solid Substances 0.000 claims description 2
ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 claims 1
FOIVYJVLHYSTKR-UHFFFAOYSA-N 2-[diethoxy(methyl)silyl]ethylidyne-oxo-$l^{5}-phosphane Chemical compound CCO[Si](C)(OCC)CC#P=O FOIVYJVLHYSTKR-UHFFFAOYSA-N 0.000 claims 1
101100371682 Caenorhabditis elegans cyk-3 gene Proteins 0.000 claims 1
102000016938 Catalase Human genes 0.000 claims 1
108010053835 Catalase Proteins 0.000 claims 1
241001669680 Dormitator maculatus Species 0.000 claims 1
239000004793 Polystyrene Substances 0.000 claims 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims 1
ZXPDYFSTVHQQOI-UHFFFAOYSA-N diethoxysilane Chemical compound CCO[SiH2]OCC ZXPDYFSTVHQQOI-UHFFFAOYSA-N 0.000 claims 1
WKBFVGCODBSWLW-UHFFFAOYSA-N dimethoxy hydrogen phosphate Chemical compound COOP(O)(=O)OOC WKBFVGCODBSWLW-UHFFFAOYSA-N 0.000 claims 1
229920002223 polystyrene Polymers 0.000 claims 1
150000003212 purines Chemical class 0.000 claims 1
229910000077 silane Inorganic materials 0.000 claims 1
238000006068 polycondensation reaction Methods 0.000 abstract description 18
229910052751 metal Inorganic materials 0.000 abstract description 11
239000002184 metal Substances 0.000 abstract description 11
238000004519 manufacturing process Methods 0.000 abstract description 6
150000001991 dicarboxylic acids Chemical class 0.000 abstract description 5
239000002904 solvent Substances 0.000 abstract description 5
239000000835 fiber Substances 0.000 abstract 1
238000000465 moulding Methods 0.000 abstract 1
239000000203 mixture Substances 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 14
239000000047 product Substances 0.000 description 13
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
238000002360 preparation method Methods 0.000 description 8
239000011541 reaction mixture Substances 0.000 description 8
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 8
WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 7
239000012346 acetyl chloride Substances 0.000 description 7
229910052799 carbon Inorganic materials 0.000 description 7
239000003921 oil Substances 0.000 description 7
238000005809 transesterification reaction Methods 0.000 description 7
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
238000004452 microanalysis Methods 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
238000010992 reflux Methods 0.000 description 5
239000003381 stabilizer Substances 0.000 description 5
DORLLFMARXGILH-UHFFFAOYSA-N 2-di(propan-2-yloxy)phosphorylethyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(OCC)CCP(=O)(OC(C)C)OC(C)C DORLLFMARXGILH-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229910052801 chlorine Inorganic materials 0.000 description 4
229910052732 germanium Inorganic materials 0.000 description 4
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
229910052753 mercury Inorganic materials 0.000 description 4
238000002156 mixing Methods 0.000 description 4
229910052718 tin Inorganic materials 0.000 description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
FXXACINHVKSMDR-UHFFFAOYSA-N acetyl bromide Chemical compound CC(Br)=O FXXACINHVKSMDR-UHFFFAOYSA-N 0.000 description 3
150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000000126 substance Substances 0.000 description 3
229910052726 zirconium Inorganic materials 0.000 description 3
KSNNOYDBDGXZTI-UHFFFAOYSA-N 2-dimethoxyphosphorylethyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(OCC)CCP(=O)(OC)OC KSNNOYDBDGXZTI-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
239000012300 argon atmosphere Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052797 bismuth Inorganic materials 0.000 description 2
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
229940071125 manganese acetate Drugs 0.000 description 2
UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 2
239000003607 modifier Substances 0.000 description 2
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 2
AISBGJQOMJOFKM-UHFFFAOYSA-N 1-diethoxyphosphorylethoxy-diethoxy-propan-2-ylsilane Chemical compound CCO[Si](OCC)(C(C)C)OC(C)P(=O)(OCC)OCC AISBGJQOMJOFKM-UHFFFAOYSA-N 0.000 description 1
FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
VMAWODUEPLAHOE-UHFFFAOYSA-N 2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 VMAWODUEPLAHOE-UHFFFAOYSA-N 0.000 description 1
UOSRPXYNYMIRCO-UHFFFAOYSA-N 2-(2-diethoxyphosphorylethyl)-2,4,4,6,6,8,8-heptamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound CCOP(=O)(OCC)CC[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 UOSRPXYNYMIRCO-UHFFFAOYSA-N 0.000 description 1
ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
KKLQPWZZFDSXLD-UHFFFAOYSA-N 2-diethoxyphosphorylethyl-[2-diethoxyphosphorylethyl(dimethyl)silyl]oxy-dimethylsilane Chemical compound CCOP(=O)(OCC)CC[Si](C)(C)O[Si](C)(C)CCP(=O)(OCC)OCC KKLQPWZZFDSXLD-UHFFFAOYSA-N 0.000 description 1
TZPVQNXGICFWSH-UHFFFAOYSA-N 2-diethoxyphosphorylethyl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCOP(=O)(OCC)CC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C TZPVQNXGICFWSH-UHFFFAOYSA-N 0.000 description 1
GBQYMXVQHATSCC-UHFFFAOYSA-N 3-triethoxysilylpropanenitrile Chemical compound CCO[Si](OCC)(OCC)CCC#N GBQYMXVQHATSCC-UHFFFAOYSA-N 0.000 description 1
QLIQIXIBZLTPGQ-UHFFFAOYSA-N 4-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=C(C(O)=O)C=C1 QLIQIXIBZLTPGQ-UHFFFAOYSA-N 0.000 description 1
QULSFBUNRKJKEF-UHFFFAOYSA-M CC(=O)O[Co] Chemical compound CC(=O)O[Co] QULSFBUNRKJKEF-UHFFFAOYSA-M 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
102000004020 Oxygenases Human genes 0.000 description 1
108090000417 Oxygenases Proteins 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229910008329 Si-V Inorganic materials 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
229910006768 Si—V Inorganic materials 0.000 description 1
YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
150000004703 alkoxides Chemical class 0.000 description 1
230000029936 alkylation Effects 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
230000037007 arousal Effects 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
238000005282 brightening Methods 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000004040 coloring Methods 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
239000012967 coordination catalyst Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 1
125000003963 dichloro group Chemical group Cl* 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 description 1
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
239000011888 foil Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
239000012535 impurity Substances 0.000 description 1
238000002329 infrared spectrum Methods 0.000 description 1
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
CRGZYKWWYNQGEC-UHFFFAOYSA-N magnesium;methanolate Chemical compound [Mg+2].[O-]C.[O-]C CRGZYKWWYNQGEC-UHFFFAOYSA-N 0.000 description 1
239000006224 matting agent Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000000034 method Methods 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
VJUIXFPWWBZVIL-UHFFFAOYSA-N trimethyl-[prop-2-enyl(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[SiH](CC=C)O[Si](C)(C)C VJUIXFPWWBZVIL-UHFFFAOYSA-N 0.000 description 1
229940094989 trimethylsilane Drugs 0.000 description 1
BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
238000004383 yellowing Methods 0.000 description 1
239000004246 zinc acetate Substances 0.000 description 1
AGFGXVAAIXIOFZ-UHFFFAOYSA-L zinc;butanedioate Chemical compound [Zn+2].[O-]C(=O)CCC([O-])=O AGFGXVAAIXIOFZ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/87—Non-metals or inter-compounds thereof
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Polyesters Or Polycarbonates (AREA)
Artificial Filaments (AREA)

DD82246831A 1981-12-31 1982-12-30 Polyveresterungskatalysator DD210289A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/336,293 US4394295A (en)	1981-12-31	1981-12-31	Coordination complexes as polyesterification catalysts

Publications (1)

Publication Number	Publication Date
DD210289A5 true DD210289A5 (de)	1984-06-06

Family

ID=23315439

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD82246831A DD210289A5 (de)	1981-12-31	1982-12-30	Polyveresterungskatalysator

Country Status (8)

Country	Link
US (1)	US4394295A (fr)
EP (1)	EP0085192B1 (fr)
JP (1)	JPS58120633A (fr)
KR (1)	KR840002863A (fr)
BR (1)	BR8207507A (fr)
CA (1)	CA1190554A (fr)
DD (1)	DD210289A5 (fr)
DE (1)	DE3272644D1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE69820223T2 (de) *	1997-10-15	2004-09-16	Daicel Chemical Industries, Ltd., Sakai	Verfahren zur herstellung von monodispersen polymeren, verfahren zur kontinuierlichen polymerisation von cyclischen monomeren und daraus hergestellte polymere
US6346070B1 (en)	1998-12-25	2002-02-12	Mitsui Chemicals Inc	Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester
KR101026097B1 (ko) *	2003-06-03	2011-03-31	미쓰비시 가가꾸 가부시키가이샤	폴리에스테르 제조용 촉매, 이를 이용한 폴리에스테르의제조 방법, 및 티탄 함유 폴리에틸렌 테레프탈레이트
JP4855161B2 (ja) *	2006-07-13	2012-01-18	富士電機株式会社	変成器
GB0720579D0 (en) *	2007-10-20	2007-11-28	Phosphonics Ltd	Functionalised materials and uses thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DD85443A (fr) *
NL6606830A (fr) *	1965-05-19	1966-11-21
US3852247A (en) *	1970-11-02	1974-12-03	Fiber Industries Inc	Polymerization catalyst
USRE30554E (en)	1977-02-28	1981-03-24	Union Carbide Corporation	Coordination complexes as catalysts
US4143057A (en) *	1977-02-28	1979-03-06	Union Carbide Corporation	Coordination complexes as catalysts
US4254241A (en) *	1979-12-12	1981-03-03	Union Carbide Corporation	Process for producing polyoxyalkylene glycol modified polyesters

1981
- 1981-12-31 US US06/336,293 patent/US4394295A/en not_active Expired - Fee Related
1982
- 1982-12-02 CA CA000416854A patent/CA1190554A/fr not_active Expired
- 1982-12-27 BR BR8207507A patent/BR8207507A/pt unknown
- 1982-12-30 DD DD82246831A patent/DD210289A5/de unknown
- 1982-12-31 KR KR1019820005905A patent/KR840002863A/ko not_active Ceased
- 1982-12-31 DE DE8282112128T patent/DE3272644D1/de not_active Expired
- 1982-12-31 JP JP57235073A patent/JPS58120633A/ja active Pending
- 1982-12-31 EP EP82112128A patent/EP0085192B1/fr not_active Expired

Also Published As

Publication number	Publication date
KR840002863A (ko)	1984-07-21
EP0085192A1 (fr)	1983-08-10
EP0085192B1 (fr)	1986-08-13
JPS58120633A (ja)	1983-07-18
US4394295A (en)	1983-07-19
BR8207507A (pt)	1983-10-18
CA1190554A (fr)	1985-07-16
DE3272644D1 (en)	1986-09-18

Publication	Publication Date	Title
US4424140A (en)	1984-01-03	Stabilization of polycondensation catalysts
EP1202997B1 (fr)	2003-09-17	Silanes hydrolysables et polymerisables a faible viscosite et leur utilisation
DE3781886T2 (de)	1993-04-15	Verfahren zur herstellung eines acrylat- oder methacrylatgruppen enthaltenden polysiloxans.
DE69221283T2 (de)	1998-01-02	Verfahren zur Herstellung von Polysilanen
US4156072A (en)	1979-05-22	Coordination complexes as polyesterification catalysts
US4361694A (en)	1982-11-30	Coordination complexes as polyesterification catalysts
DD210289A5 (de)	1984-06-06	Polyveresterungskatalysator
DE2713679A1 (de)	1977-09-29	Verfahren zur herstellung eines polyesters
DE2342431A1 (de)	1974-03-07	Neue, lineare homo- und copolyester auf basis von terephthal- und/oder isophthalsaeure
Zeitler et al.	1957	Tetrakistriphenylsiloxytitanium and Some Related Compounds1
US4116942A (en)	1978-09-26	Process for catalytic production of polyesters
US2566957A (en)	1951-09-04	Tertiary-alkoxy chlorosilanes
GB1588782A (en)	1981-04-29	Catalytic production of polyesters
US2566956A (en)	1951-09-04	Tertiary-alkoxy chlorosilanes
DE2809875A1 (de)	1979-09-13	Verfahren zum anlagern von si-gebundenem wasserstoff an aliphatische mehrfachbindung
JP2666502B2 (ja)	1997-10-22	ポリエステルの製造方法
JPH0565339A (ja)	1993-03-19	難燃性ポリエステルの製法
US3123580A (en)	1964-03-03	Aromatic esters of chlorobenzene-
EP0096396A1 (fr)	1983-12-21	Stabilisation des catalyseurs de la polycondensation
DE4324674A1 (de)	1994-01-27	Verfahren zur Herstellung eines Polyethylennaphthalats
US2744088A (en)	1956-05-01	Linear polyesters from p, p'-sulfonyl dibenzoic acid plus aliphatic dibasic straightchain acids condensed with a glycol
JPS59164352A (ja)	1984-09-17	ハロゲン含有樹脂用安定剤
DE1291902B (de)	1969-04-03	Verfahren zur Herstellung von Polyestern
DE2533715A1 (de)	1976-02-12	Lineare polyester auf basis von s-triazindicarbonsaeuren
DE2418713C2 (de)	1982-10-28	Cyclolineare Polyorganosiloxane und Verfahren zu ihrer Herstellung