DD232912A5 - Verfahren zur herstellung von terephthalsaeure ueber terephtalsaeuredimethylester aus p-xylol und methanol - Google Patents

Verfahren zur herstellung von terephthalsaeure ueber terephtalsaeuredimethylester aus p-xylol und methanol Download PDF

Info

Publication number: DD232912A5
Authority: DD; German Democratic Republic
Prior art keywords: methanol; esterification; fraction; pressure; crude
Prior art date: 1984-03-03

Application number

DD85273522A

Other languages

German (de)

English (en)

Inventor

Rudolf Modic

Joerg Porschen

Anton Schoengen

Ralf Wirges

Original Assignee

Dynamit Nobel Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-03-03

Filing date

1985-02-25

Publication date

1986-02-12

1985-02-25 Application filed by Dynamit Nobel Ag filed Critical Dynamit Nobel Ag

1986-02-12 Publication of DD232912A5 publication Critical patent/DD232912A5/de

Links

OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 204
238000000034 method Methods 0.000 title claims abstract description 32
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical compound CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 title claims abstract 7
238000002360 preparation method Methods 0.000 title claims abstract 4
150000002148 esters Chemical class 0.000 title claims description 9
150000003504 terephthalic acids Chemical class 0.000 title 1
238000005886 esterification reaction Methods 0.000 claims abstract description 44
230000032050 esterification Effects 0.000 claims abstract description 41
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 14
230000006835 compression Effects 0.000 claims abstract description 11
238000007906 compression Methods 0.000 claims abstract description 11
239000000203 mixture Substances 0.000 claims abstract description 10
GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims abstract description 6
238000006243 chemical reaction Methods 0.000 claims description 11
238000006460 hydrolysis reaction Methods 0.000 claims description 8
230000007062 hydrolysis Effects 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 claims 8
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 claims 7
230000003647 oxidation Effects 0.000 claims 7
238000007254 oxidation reaction Methods 0.000 claims 7
LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 claims 6
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims 4
REIDAMBAPLIATC-UHFFFAOYSA-N 4-methoxycarbonylbenzoic acid Chemical compound COC(=O)C1=CC=C(C(O)=O)C=C1 REIDAMBAPLIATC-UHFFFAOYSA-N 0.000 claims 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
239000003054 catalyst Substances 0.000 claims 2
238000007700 distillative separation Methods 0.000 claims 2
229910001385 heavy metal Inorganic materials 0.000 claims 2
239000007788 liquid Substances 0.000 claims 2
239000007791 liquid phase Substances 0.000 claims 2
150000002736 metal compounds Chemical class 0.000 claims 2
229910052760 oxygen Inorganic materials 0.000 claims 2
239000001301 oxygen Substances 0.000 claims 2
238000011084 recovery Methods 0.000 claims 2
238000000926 separation method Methods 0.000 claims 2
239000004215 Carbon black (E152) Substances 0.000 claims 1
239000008346 aqueous phase Substances 0.000 claims 1
238000004821 distillation Methods 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 claims 1
150000002430 hydrocarbons Chemical class 0.000 claims 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
239000012452 mother liquor Substances 0.000 claims 1
239000012071 phase Substances 0.000 claims 1
238000001704 evaporation Methods 0.000 description 4
230000008020 evaporation Effects 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
230000000694 effects Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000013021 overheating Methods 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/14—Monocyclic dicarboxylic acids
- C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
- C07C63/26—1,4 - Benzenedicarboxylic acid
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

DD85273522A 1984-03-03 1985-02-25 Verfahren zur herstellung von terephthalsaeure ueber terephtalsaeuredimethylester aus p-xylol und methanol DD232912A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE3407912A DE3407912C1 (de)	1984-03-03	1984-03-03	Verfahren zur Herstellung von Terephthalsaeure ueber Terephthalsaeuredimethylester aus p-Xylol und Methanol

Publications (1)

Publication Number	Publication Date
DD232912A5 true DD232912A5 (de)	1986-02-12

Family

ID=6229529

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD85273522A DD232912A5 (de)	1984-03-03	1985-02-25	Verfahren zur herstellung von terephthalsaeure ueber terephtalsaeuredimethylester aus p-xylol und methanol

Country Status (20)

Country	Link
US (1)	US4642377A (cs)
EP (1)	EP0157122B1 (cs)
JP (1)	JPH0688937B2 (cs)
KR (1)	KR920003120B1 (cs)
BG (1)	BG45697A3 (cs)
BR (1)	BR8500935A (cs)
CS (1)	CS251095B2 (cs)
DD (1)	DD232912A5 (cs)
DE (2)	DE3407912C1 (cs)
EG (1)	EG17052A (cs)
ES (1)	ES8602590A1 (cs)
IN (1)	IN163350B (cs)
MX (1)	MX162239A (cs)
PL (1)	PL144915B1 (cs)
PT (1)	PT80041B (cs)
RO (1)	RO91879B (cs)
SU (1)	SU1581218A3 (cs)
TR (1)	TR22497A (cs)
YU (1)	YU44722B (cs)
ZA (1)	ZA851579B (cs)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4026732A1 (de) *	1990-08-24	1992-02-27	Huels Chemische Werke Ag	Verfahren zur reinigung eines oxidationsabgases mit energierueckgewinnung
US6472557B1 (en)	1999-02-10	2002-10-29	Eastman Chemical Company	Process for recycling polyesters
CN110078284B (zh) *	2019-04-25	2021-08-24	杭州多向流化学科技有限公司	用于制备对苯二甲酸的富水溶剂分级利用减排系统

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2653165A (en) *	1950-09-27	1953-09-22	California Research Corp	Oxidation process
DE1071688B (de) *	1958-06-14	1959-12-24	Basf Ag	Verfahren zur Verbesserung der Oxydationsgeschwindigkeit der bei Luftoxydation von xylol oder von gemischen aus xylol und p-toluylsaeuremethylestern anfallenden gemische
DE2916197C2 (de) *	1979-04-21	1982-01-28	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zur Herstellung von Terephthalsäure aus Dimethyltherephthalat als Zwischenprodukt

1984
- 1984-03-03 DE DE3407912A patent/DE3407912C1/de not_active Expired
- 1984-12-27 IN IN1039/MAS/84A patent/IN163350B/en unknown
1985
- 1985-02-07 EP EP85101271A patent/EP0157122B1/de not_active Expired
- 1985-02-07 DE DE8585101271T patent/DE3560053D1/de not_active Expired
- 1985-02-25 SU SU853857493A patent/SU1581218A3/ru active
- 1985-02-25 DD DD85273522A patent/DD232912A5/de unknown
- 1985-02-27 TR TR8624A patent/TR22497A/xx unknown
- 1985-02-27 RO RO117779A patent/RO91879B/ro unknown
- 1985-02-28 BG BG069044A patent/BG45697A3/xx unknown
- 1985-02-28 YU YU314/85A patent/YU44722B/xx unknown
- 1985-02-28 KR KR1019850001275A patent/KR920003120B1/ko not_active Expired
- 1985-02-28 MX MX204465A patent/MX162239A/es unknown
- 1985-03-01 ZA ZA851579A patent/ZA851579B/xx unknown
- 1985-03-01 PL PL1985252195A patent/PL144915B1/pl unknown
- 1985-03-01 PT PT80041A patent/PT80041B/pt not_active IP Right Cessation
- 1985-03-01 BR BR8500935A patent/BR8500935A/pt not_active IP Right Cessation
- 1985-03-01 ES ES540832A patent/ES8602590A1/es not_active Expired
- 1985-03-02 EG EG12585A patent/EG17052A/xx active
- 1985-03-04 JP JP60041377A patent/JPH0688937B2/ja not_active Expired - Fee Related
- 1985-03-04 CS CS851508A patent/CS251095B2/cs unknown
- 1985-03-04 US US06/707,579 patent/US4642377A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
DE3407912C1 (de)	1985-05-09
ZA851579B (en)	1985-10-30
ES540832A0 (es)	1985-12-01
TR22497A (tr)	1987-09-11
PL252195A1 (en)	1985-09-24
EP0157122B1 (de)	1987-01-14
EP0157122A1 (de)	1985-10-09
BG45697A3 (en)	1989-07-14
YU44722B (en)	1990-12-31
MX162239A (es)	1991-04-12
PL144915B1 (en)	1988-07-30
EG17052A (en)	1994-07-30
KR850007056A (ko)	1985-10-30
SU1581218A3 (ru)	1990-07-23
BR8500935A (pt)	1985-10-22
RO91879A (ro)	1987-06-30
JPS60202842A (ja)	1985-10-14
DE3560053D1 (en)	1987-02-19
PT80041A (de)	1985-04-01
RO91879B (ro)	1987-07-03
ES8602590A1 (es)	1985-12-01
YU31485A (en)	1987-10-31
PT80041B (pt)	1987-06-17
IN163350B (cs)	1988-09-10
JPH0688937B2 (ja)	1994-11-09
US4642377A (en)	1987-02-10
KR920003120B1 (ko)	1992-04-20
CS251095B2 (en)	1987-06-11

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DE60002950T2 (de)	2004-05-13	Verfahren zur Herstellung von Carbonsäure und Alkohol
DE2834140C2 (cs)	1987-12-10
DE3407925C1 (de)	1985-09-05	Verfahren zur Herstellung von Terephthalsaeuredimethylester aus p-Xylol und Methanol
DE69405138T2 (de)	1998-01-15	Verfahren zur Herstellung von Acryl- und Methacrylsäureestern
DE2252334C3 (de)	1985-02-07	Verfahren zur kontinuierlichen Herstellung von Methyl- oder Äthylacrylsäure- oder -methacrylsäureester
DE3143734A1 (de)	1983-05-11	Verfahren zur kontinuierlichen rektifikation eines alkohole enthaltenden fluessigkeitsgemisches"
DE3808427A1 (de)	1989-09-28	Verfahren zur kontinuierlichen umesterung von fettsaeure-niedrigalkyl-estern
DE1543174B2 (de)	1974-06-20	Kontinuierliches Verfahren zur Herstellung von Propylenoxyd
DE1919527B2 (de)	1975-01-23	Verfahren zur kontinuierlichen Herstellung von Carbonsäureestern
DE3407912C1 (de)	1985-05-09	Verfahren zur Herstellung von Terephthalsaeure ueber Terephthalsaeuredimethylester aus p-Xylol und Methanol
DE1618240C3 (de)	1974-10-17	Verfahren zur Gewinnung von Vinylacetat aus einem Gemisch von Vinylacetat, Äthylacetat und gegebenenfalls wenig
DE3120749A1 (de)	1982-02-11	Kontinuierliches verfahren zur entwaesserung der maleinsaeure und vorrichtung zu seiner durchfuehrung
DE19843654A1 (de)	2000-03-30	Verfahren zur Herstellung von Ethylenoxid durch Direktoxidation von Ethylen mit Luft oder Sauerstoff
DE2427875B2 (de)	1979-07-19	Verfahren zur Gewinnung von Dimethylterephthalat und von Zwischenprodukten der Dimethylterephthalat-Herstellung
DE102014108980A1 (de)	2015-12-31	Verfahren und Anlage zur Aufreinigung von Acrylsäure
DE69801654T2 (de)	2002-06-20	Verfahren zum herstellen von methacrylatestern
EP0002779B1 (de)	1980-07-23	Verfahren zur Vervollständigung der Veresterung von Carbonsäuren mit Alkoholen
DE824341C (de)	1951-12-10	Kontinuierliches Verfahren zur Herstellung niedermolekularer aliphatischer Ester
DE68903551T2 (de)	1993-04-01	Herstellungsverfahren von fettalkoholen und einrichtung zu dessen durchfuehrung.
DE2301208B2 (de)	1979-02-15	Verfahren zur Herstellung von Alkoholen durch Hydratisierung von Olefinen mit 2 - 3 C-Atomen
DE2128942A1 (cs)	1972-11-30
DE2301632C3 (de)	1976-10-21	Verfahren zur Herstellung von niederen Alkoholen
AT277952B (de)	1970-01-12	Verfahren zur Abtrennung der Mischung eiens Vinylesters mit der diesem Ester zugrundeliegenden Carbonsäure
EP0464037B1 (de)	1993-05-19	Anlage und verfahren zum kontinuierlichen herstellen von fettsäuremonoglyceriden
DE3214697A1 (de)	1983-10-27	Verfahren zur kontinuierlichen reinigung von milchsaeuremethylester