DD240022A5 - Vernetzbare organische polymerzusammensetzung und verfahren zur herstellung derselben - Google Patents

Vernetzbare organische polymerzusammensetzung und verfahren zur herstellung derselben Download PDF

Info

Publication number: DD240022A5
Authority: DD; German Democratic Republic
Prior art keywords: compound; condensation catalyst; copolymer; crosslinkable; silyl
Prior art date: 1984-07-20

Application number

DD85278781A

Other languages

German (de)

English (en)

Inventor

Jeffrey D Umpleby

Original Assignee

��@��@��@��@��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-07-20

Filing date

1985-07-19

Publication date

1986-10-15

1985-07-19 Application filed by ��@��@��@��@��@��k�� filed Critical ��@��@��@��@��@��k��

1986-10-15 Publication of DD240022A5 publication Critical patent/DD240022A5/de

Links

239000000203 mixture Substances 0.000 title claims abstract description 38
238000004519 manufacturing process Methods 0.000 title claims description 4
229920001577 copolymer Polymers 0.000 claims abstract description 42
-1 unsaturated silane compound Chemical class 0.000 claims abstract description 34
150000003606 tin compounds Chemical class 0.000 claims abstract description 20
239000003054 catalyst Substances 0.000 claims abstract description 19
238000009833 condensation Methods 0.000 claims abstract description 18
230000005494 condensation Effects 0.000 claims abstract description 18
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims abstract description 15
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 14
239000005977 Ethylene Substances 0.000 claims abstract description 13
238000000034 method Methods 0.000 claims description 16
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical group CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 claims description 12
239000000178 monomer Substances 0.000 claims description 12
239000000654 additive Substances 0.000 claims description 8
238000002156 mixing Methods 0.000 claims description 8
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
150000007942 carboxylates Chemical group 0.000 claims description 7
229910000077 silane Inorganic materials 0.000 claims description 7
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
239000004594 Masterbatch (MB) Substances 0.000 claims description 5
229920000620 organic polymer Polymers 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
239000012141 concentrate Substances 0.000 claims description 3
239000004615 ingredient Substances 0.000 claims description 3
125000000962 organic group Chemical group 0.000 claims description 3
229920001169 thermoplastic Polymers 0.000 claims description 3
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical compound O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 claims description 2
ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 abstract 1
238000004132 cross linking Methods 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
150000001875 compounds Chemical class 0.000 description 8
238000007334 copolymerization reaction Methods 0.000 description 7
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 6
238000012360 testing method Methods 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
238000001125 extrusion Methods 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
230000002028 premature Effects 0.000 description 5
229910052718 tin Inorganic materials 0.000 description 5
125000001183 hydrocarbyl group Chemical group 0.000 description 4
229910052698 phosphorus Inorganic materials 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
238000000071 blow moulding Methods 0.000 description 3
239000011248 coating agent Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
150000003018 phosphorus compounds Chemical class 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
238000003856 thermoforming Methods 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
125000002843 carboxylic acid group Chemical group 0.000 description 2
150000001991 dicarboxylic acids Chemical class 0.000 description 2
229920000578 graft copolymer Polymers 0.000 description 2
229920001684 low density polyethylene Polymers 0.000 description 2
239000004702 low-density polyethylene Substances 0.000 description 2
150000002689 maleic acids Chemical class 0.000 description 2
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 2
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
239000011343 solid material Substances 0.000 description 2
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
150000001260 acyclic compounds Chemical class 0.000 description 1
150000001279 adipic acids Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
125000001769 aryl amino group Chemical group 0.000 description 1
125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
238000003490 calendering Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000007547 defect Effects 0.000 description 1
125000001142 dicarboxylic acid group Chemical group 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 description 1
NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
150000002238 fumaric acids Chemical class 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
238000009413 insulation Methods 0.000 description 1
125000000555 isopropenyl group Chemical group [H]\C([H])=C(\*)C([H])([H])[H] 0.000 description 1
229920000092 linear low density polyethylene Polymers 0.000 description 1
239000004707 linear low-density polyethylene Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
239000006078 metal deactivator Substances 0.000 description 1
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000005515 organic divalent group Chemical group 0.000 description 1
SMQUZDBALVYZAC-UHFFFAOYSA-N ortho-hydroxybenzaldehyde Natural products OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 1
150000002913 oxalic acids Chemical class 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
239000002245 particle Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
150000003003 phosphines Chemical class 0.000 description 1
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
150000003022 phthalic acids Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000008262 pumice Substances 0.000 description 1
239000007870 radical polymerization initiator Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
238000001175 rotational moulding Methods 0.000 description 1
150000003330 sebacic acids Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000003707 silyl modified polymer Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000001721 transfer moulding Methods 0.000 description 1
XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
DSKYTPNZLCVELA-UHFFFAOYSA-N trihexyl phosphite Chemical compound CCCCCCOP(OCCCCCC)OCCCCCC DSKYTPNZLCVELA-UHFFFAOYSA-N 0.000 description 1
QUTZUATVZPXUJR-UHFFFAOYSA-N trinonyl phosphite Chemical compound CCCCCCCCCOP(OCCCCCCCCC)OCCCCCCCCC QUTZUATVZPXUJR-UHFFFAOYSA-N 0.000 description 1
DECPGQLXYYCNEZ-UHFFFAOYSA-N tris(6-methylheptyl) phosphite Chemical compound CC(C)CCCCCOP(OCCCCCC(C)C)OCCCCCC(C)C DECPGQLXYYCNEZ-UHFFFAOYSA-N 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000011179 visual inspection Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Biological Depolymerization Polymers (AREA)
Insulated Conductors (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Silicon Polymers (AREA)
Organic Insulating Materials (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Medicinal Preparation (AREA)
Graft Or Block Polymers (AREA)
Paints Or Removers (AREA)
Extrusion Moulding Of Plastics Or The Like (AREA)

DD85278781A 1984-07-20 1985-07-19 Vernetzbare organische polymerzusammensetzung und verfahren zur herstellung derselben DD240022A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB848418592A GB8418592D0 (en)	1984-07-20	1984-07-20	Polymer composition

Publications (1)

Publication Number	Publication Date
DD240022A5 true DD240022A5 (de)	1986-10-15

Family

ID=10564218

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD85278781A DD240022A5 (de)	1984-07-20	1985-07-19	Vernetzbare organische polymerzusammensetzung und verfahren zur herstellung derselben

Country Status (23)

Country	Link
US (1)	US4795786A (no)
EP (1)	EP0169070B1 (no)
JP (1)	JPH0774293B2 (no)
KR (1)	KR930009332B1 (no)
AT (1)	ATE62703T1 (no)
AU (1)	AU579385B2 (no)
BG (1)	BG48216A3 (no)
BR (1)	BR8503459A (no)
CA (1)	CA1254693A (no)
DD (1)	DD240022A5 (no)
DE (1)	DE3582524D1 (no)
ES (1)	ES8800320A1 (no)
FI (1)	FI84613C (no)
GB (1)	GB8418592D0 (no)
GR (1)	GR851786B (no)
IE (1)	IE60526B1 (no)
IN (1)	IN165802B (no)
NO (1)	NO176322C (no)
NZ (1)	NZ212772A (no)
PT (1)	PT80827B (no)
SG (1)	SG66891G (no)
SU (1)	SU1545944A3 (no)
ZA (1)	ZA855474B (no)

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GB8816657D0 (en) *	1988-07-13	1988-08-17	Bp Chem Int Ltd	Crosslinkable silyl polymer composition
EP0365289A3 (en) *	1988-10-21	1991-10-09	Neste Oy	Method for producing a filled water-crosslinkable silane copolymer composition
SE462752B (sv) *	1988-12-23	1990-08-27	Neste Oy	Silanfoernaetningsbar polymerkomposition innehaallande en silanfoerening som motverkar foer tidig haerdning
US5047476A (en) *	1989-05-12	1991-09-10	Union Carbide Chemicals And Plastics Company Inc.	Process for crosslinking hydrolyzable copolymers
GB9103802D0 (en) *	1991-02-23	1991-04-10	Bp Chem Int Ltd	Crosslinkable polymeric composition
US5266627A (en) *	1991-02-25	1993-11-30	Quantum Chemical Corporation	Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process
CA2061465A1 (en) *	1991-02-25	1992-08-26	Craig C. Meverden	Filled hydrolyzable copolymer compositions resistant to premature crosslinking
CA2156816A1 (en)	1994-09-07	1996-03-08	Jeffrey S. Borke	Flame retardant insulation compositions having enhanced curability
US5492760A (en) *	1994-12-05	1996-02-20	At Plastics Inc.	Water tree resistant, moisture curable insulation composition for power cables
KR100318889B1 (ko) *	1995-12-18	2002-04-22	잭퀴즈 스컴부르크	이중 결합 중합체의 가교결합용의, 실란, 자유라디칼 생성제 및아민 혼합물
US6288184B1 (en) *	1999-09-29	2001-09-11	Sri International	Hydrolytically degradable olefin copolymers
US7037992B2 (en) *	1999-09-29	2006-05-02	Sri International	Olefin copolymers containing hydrolytically cleavable linkages and use thereof in degradable products
FR2864096B1 (fr) *	2003-12-23	2007-02-23	Rhodia Chimie Sa	Composition polyorganosiloxane monocomposante reticulant en elastomere silicone
CN101802072B (zh) *	2007-07-13	2012-09-05	陶氏环球技术有限责任公司	通过有机化合物的闭环脱水反应产生的水用于湿交联聚烯烃的原位方法
KR101329678B1 (ko)	2009-06-22	2013-11-14	보레알리스 아게	이산화염소 내성 폴리에틸렌 파이프, 그의 제조 및 용도
CN106687520B (zh)	2014-09-18	2018-07-27	北欧化工公司	适度交联的薄膜

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US3225018A (en) *	1961-12-15	1965-12-21	Union Carbide Corp	Heat curing of ethylene/vinylsilane copolymers
US3392156A (en) *	1964-07-10	1968-07-09	Nat Distillers Chem Corp	Copolymers of ethylene and vinyl triethoxysilanes and mechanically worked products thereof
BE794718Q (fr) *	1968-12-20	1973-05-16	Dow Corning Ltd	Procede de reticulation d'olefines
GB1357549A (en) *	1971-11-12	1974-06-26	Dow Corning Ltd	Cross-linking of polymers
GB1526398A (en) *	1974-12-06	1978-09-27	Maillefer Sa	Manufacture of extruded products
JPS559611A (en) *	1978-07-05	1980-01-23	Mitsubishi Petrochem Co Ltd	Cross-linkable polyethylene resin composition
JPS5566809A (en) *	1978-11-13	1980-05-20	Mitsubishi Petrochemical Co	Method of manufacturing crosslinked polyethylene resinncoated wire
JPS55128441A (en) *	1979-03-27	1980-10-04	Mitsubishi Petrochem Co Ltd	Preparing method for cross-linked polyethylene extrudate
CH631289A5 (fr) *	1979-04-03	1982-07-30	Maillefer Sa	Procede de fabrication d'un conducteur electrique, isole par un revetement en matiere plastique reticulee, et conducteur electrique isole obtenu selon le procede.
JPS55155040A (en) *	1979-05-22	1980-12-03	Mitsubishi Petrochem Co Ltd	Cross-linking ethylene copolymer composition
JPS568447A (en) *	1979-07-03	1981-01-28	Mitsubishi Petrochem Co Ltd	Crosslinkable ethylene copolymer composition
JPS5695940A (en) *	1979-12-28	1981-08-03	Mitsubishi Petrochem Co Ltd	Ethylene polymer composition
JPS5721410A (en) *	1980-07-11	1982-02-04	Kanegafuchi Chem Ind Co Ltd	Silyl group-containing vinyl resin and its production
JPS5763351A (en) *	1980-10-03	1982-04-16	Kanegafuchi Chem Ind Co Ltd	Composition having improved pot life
JPS5763352A (en) *	1980-10-04	1982-04-16	Kanegafuchi Chem Ind Co Ltd	Composition having improved storage stability
JPS57105446A (en) *	1980-12-19	1982-06-30	Kanegafuchi Chem Ind Co Ltd	Curable composition
JPS5819361A (ja) *	1981-07-27	1983-02-04	Kanegafuchi Chem Ind Co Ltd	１液型室温硬化性組成物
JPS61141761A (ja) *	1984-12-12	1986-06-28	Kanegafuchi Chem Ind Co Ltd	硬化性組成物

1984
- 1984-07-20 GB GB848418592A patent/GB8418592D0/en active Pending
1985
- 1985-07-12 IE IE175585A patent/IE60526B1/en not_active IP Right Cessation
- 1985-07-16 CA CA000486879A patent/CA1254693A/en not_active Expired
- 1985-07-17 NZ NZ212772A patent/NZ212772A/en unknown
- 1985-07-17 IN IN563/DEL/85A patent/IN165802B/en unknown
- 1985-07-17 AU AU45110/85A patent/AU579385B2/en not_active Ceased
- 1985-07-18 AT AT85305118T patent/ATE62703T1/de not_active IP Right Cessation
- 1985-07-18 GR GR851786A patent/GR851786B/el unknown
- 1985-07-18 EP EP85305118A patent/EP0169070B1/en not_active Expired - Lifetime
- 1985-07-18 PT PT80827A patent/PT80827B/pt not_active IP Right Cessation
- 1985-07-18 DE DE8585305118T patent/DE3582524D1/de not_active Expired - Lifetime
- 1985-07-19 SU SU853929247A patent/SU1545944A3/ru active
- 1985-07-19 JP JP60160020A patent/JPH0774293B2/ja not_active Expired - Fee Related
- 1985-07-19 BR BR8503459A patent/BR8503459A/pt not_active IP Right Cessation
- 1985-07-19 NO NO852892A patent/NO176322C/no unknown
- 1985-07-19 BG BG071161A patent/BG48216A3/xx unknown
- 1985-07-19 ES ES545410A patent/ES8800320A1/es not_active Expired
- 1985-07-19 FI FI852837A patent/FI84613C/fi not_active IP Right Cessation
- 1985-07-19 ZA ZA855474A patent/ZA855474B/xx unknown
- 1985-07-19 DD DD85278781A patent/DD240022A5/de not_active IP Right Cessation
- 1985-07-20 KR KR1019850005179A patent/KR930009332B1/ko not_active Expired - Fee Related
1987
- 1987-12-24 US US07/140,943 patent/US4795786A/en not_active Expired - Lifetime
1991
- 1991-08-16 SG SG668/91A patent/SG66891G/en unknown

Also Published As

Publication number	Publication date
CA1254693A (en)	1989-05-23
SG66891G (en)	1991-09-13
NO176322B (no)	1994-12-05
ATE62703T1 (de)	1991-05-15
GB8418592D0 (en)	1984-08-22
DE3582524D1 (de)	1991-05-23
FI852837L (fi)	1986-01-21
ZA855474B (en)	1987-03-25
AU579385B2 (en)	1988-11-24
NO852892L (no)	1986-01-21
KR930009332B1 (ko)	1993-09-27
PT80827A (en)	1985-08-01
AU4511085A (en)	1986-01-23
EP0169070A3 (en)	1988-12-07
EP0169070A2 (en)	1986-01-22
NO176322C (no)	1995-03-15
JPH0774293B2 (ja)	1995-08-09
EP0169070B1 (en)	1991-04-17
SU1545944A3 (ru)	1990-02-23
PT80827B (pt)	1987-10-20
KR860001150A (ko)	1986-02-22
US4795786A (en)	1989-01-03
GR851786B (no)	1985-11-26
ES8800320A1 (es)	1987-11-01
FI852837A0 (fi)	1985-07-19
BR8503459A (pt)	1986-04-15
FI84613B (fi)	1991-09-13
BG48216A3 (en)	1990-12-14
JPS6153346A (ja)	1986-03-17
IE60526B1 (en)	1994-07-27
FI84613C (fi)	1991-12-27
NZ212772A (en)	1988-02-29
IE851755L (en)	1986-01-20
ES545410A0 (es)	1987-11-01
IN165802B (no)	1990-01-13

Legal Events

Date	Code	Title	Description
1986-10-15	A5	Published as prov. exclusive patent
1998-07-30	ENJ	Ceased due to non-payment of renewal fee

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