DD242661A1 - Verfahren zur herstellung lithiumhaltiger polymerisationsinitiatoren - Google Patents

Verfahren zur herstellung lithiumhaltiger polymerisationsinitiatoren Download PDF

Info

Publication number: DD242661A1
Authority: DD; German Democratic Republic
Prior art keywords: divinylbenzene; ether; dilithium; polymerization initiators; lithium
Prior art date: 1982-07-23

Application number

DD24190282A

Other languages

German (de)

English (en)

Inventor

Volker Griehl

Elisabeth Anton

Original Assignee

Buna Chem Werke Veb

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-07-23

Filing date

1982-07-23

Publication date

1987-02-04

1982-07-23 Application filed by Buna Chem Werke Veb filed Critical Buna Chem Werke Veb

1982-07-23 Priority to DD24190282A priority Critical patent/DD242661A1/de

1983-03-18 Priority to DE19833309748 priority patent/DE3309748A1/de

1983-04-07 Priority to FR8305709A priority patent/FR2530642B1/fr

1983-07-15 Priority to CS534783A priority patent/CS237518B1/cs

1983-07-15 Priority to GB08319201A priority patent/GB2124228B/en

1987-02-04 Publication of DD242661A1 publication Critical patent/DD242661A1/de

Links

239000003505 polymerization initiator Substances 0.000 title claims abstract description 7
238000004519 manufacturing process Methods 0.000 title claims abstract description 4
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims abstract description 43
238000000034 method Methods 0.000 claims abstract description 11
229910052744 lithium Inorganic materials 0.000 claims abstract description 10
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 8
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 20
239000000203 mixture Substances 0.000 claims description 16
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
239000004215 Carbon black (E152) Substances 0.000 claims description 10
229930195733 hydrocarbon Natural products 0.000 claims description 10
150000002430 hydrocarbons Chemical class 0.000 claims description 10
-1 lithium organo compound Chemical class 0.000 claims description 8
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 6
239000002904 solvent Substances 0.000 claims description 6
KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 claims description 4
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 4
RXGDGBFPBCUIMS-UHFFFAOYSA-N dilithium;butane Chemical compound [Li+].[Li+].[CH2-]CC[CH2-] RXGDGBFPBCUIMS-UHFFFAOYSA-N 0.000 claims description 4
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 3
WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 claims description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
125000000962 organic group Chemical group 0.000 claims 1
238000002360 preparation method Methods 0.000 abstract description 9
230000015572 biosynthetic process Effects 0.000 abstract description 7
238000003786 synthesis reaction Methods 0.000 abstract description 7
229920006250 telechelic polymer Polymers 0.000 abstract description 3
238000005580 one pot reaction Methods 0.000 abstract description 2
150000002894 organic compounds Chemical class 0.000 abstract description 2
239000003999 initiator Substances 0.000 description 16
150000001875 compounds Chemical class 0.000 description 11
238000006243 chemical reaction Methods 0.000 description 9
229920000642 polymer Polymers 0.000 description 5
SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical class [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
239000000178 monomer Substances 0.000 description 3
239000002244 precipitate Substances 0.000 description 3
HIACAHMKXQESOV-UHFFFAOYSA-N 1,2-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC=C1C(C)=C HIACAHMKXQESOV-UHFFFAOYSA-N 0.000 description 2
PRJNEUBECVAVAG-UHFFFAOYSA-N 1,3-bis(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1 PRJNEUBECVAVAG-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
238000010539 anionic addition polymerization reaction Methods 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
229920001002 functional polymer Polymers 0.000 description 2
238000006263 metalation reaction Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000725 suspension Substances 0.000 description 2
WEERVPDNCOGWJF-UHFFFAOYSA-N 1,4-bis(ethenyl)benzene Chemical compound C=CC1=CC=C(C=C)C=C1 WEERVPDNCOGWJF-UHFFFAOYSA-N 0.000 description 1
239000004970 Chain extender Substances 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000004210 ether based solvent Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001914 filtration Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
150000002900 organolithium compounds Chemical class 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
150000003384 small molecules Chemical class 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Polymerization Catalysts (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DD24190282A 1982-07-23 1982-07-23 Verfahren zur herstellung lithiumhaltiger polymerisationsinitiatoren DD242661A1 (de)

Priority Applications (5)

Application Number	Priority Date	Filing Date	Title
DD24190282A DD242661A1 (de)	1982-07-23	1982-07-23	Verfahren zur herstellung lithiumhaltiger polymerisationsinitiatoren
DE19833309748 DE3309748A1 (de)	1982-07-23	1983-03-18	Verfahren zur herstellung mehrfunktioneller polymerisationsinitiatoren
FR8305709A FR2530642B1 (fr)	1982-07-23	1983-04-07	Procede pour la preparation d'initiateurs de polymerisation multifonctionnels
CS534783A CS237518B1 (en)	1982-07-23	1983-07-15	Process for preparation of polymerization starters comprising lithium
GB08319201A GB2124228B (en)	1982-07-23	1983-07-15	Organo-lithium polymerization initiator

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DD24190282A DD242661A1 (de)	1982-07-23	1982-07-23	Verfahren zur herstellung lithiumhaltiger polymerisationsinitiatoren

Publications (1)

Publication Number	Publication Date
DD242661A1 true DD242661A1 (de)	1987-02-04

Family

ID=5540166

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD24190282A DD242661A1 (de)	1982-07-23	1982-07-23	Verfahren zur herstellung lithiumhaltiger polymerisationsinitiatoren

Country Status (2)

Country	Link
CS (1)	CS237518B1 (cs)
DD (1)	DD242661A1 (cs)

1982
- 1982-07-23 DD DD24190282A patent/DD242661A1/de not_active IP Right Cessation
1983
- 1983-07-15 CS CS534783A patent/CS237518B1/cs unknown

Also Published As

Publication number	Publication date
CS237518B1 (en)	1985-08-15

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Date	Code	Title	Description
1998-07-02	ENJ	Ceased due to non-payment of renewal fee