DD260071A5 - Verfahren zur herstellung von 0-alkyl-s,s-dialkyl-di-thiophosphaten - Google Patents

Verfahren zur herstellung von 0-alkyl-s,s-dialkyl-di-thiophosphaten Download PDF

Info

Publication number: DD260071A5
Authority: DD; German Democratic Republic
Prior art keywords: excess; thiol; ethyl; per mole; moles
Prior art date: 1986-02-11

Application number

DD87299818A

Other languages

German (de)

English (en)

Inventor

Jean-Michel Brochard

Francois Frisou

Roy Pierre Le

Original Assignee

��`��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-02-11

Filing date

1987-02-10

Publication date

1988-09-14

1987-02-10 Application filed by ��`��@��k�� filed Critical ��`��@��k��

1988-09-14 Publication of DD260071A5 publication Critical patent/DD260071A5/de

Links

238000000034 method Methods 0.000 title claims abstract description 29
238000002360 preparation method Methods 0.000 title claims abstract description 6
229910019142 PO4 Inorganic materials 0.000 claims abstract description 12
-1 alkyl phosphate Chemical compound 0.000 claims abstract description 12
239000010452 phosphate Substances 0.000 claims abstract description 12
239000002253 acid Substances 0.000 claims description 14
150000003573 thiols Chemical class 0.000 claims description 14
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 11
JASFTUXTUYZCBW-UHFFFAOYSA-N ethyl dihydrogen phosphate;dihydrochloride Chemical compound Cl.Cl.CCOP(O)(O)=O JASFTUXTUYZCBW-UHFFFAOYSA-N 0.000 claims description 11
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 10
150000007530 organic bases Chemical class 0.000 claims description 7
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
239000007864 aqueous solution Substances 0.000 claims description 5
239000002585 base Substances 0.000 claims description 5
239000000460 chlorine Substances 0.000 claims description 5
229910052801 chlorine Inorganic materials 0.000 claims description 5
150000007529 inorganic bases Chemical class 0.000 claims description 5
150000003512 tertiary amines Chemical class 0.000 claims description 4
229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
150000007522 mineralic acids Chemical group 0.000 claims description 2
150000007524 organic acids Chemical group 0.000 claims description 2
239000007787 solid Substances 0.000 claims description 2
125000005270 trialkylamine group Chemical group 0.000 claims description 2
125000001309 chloro group Chemical group Cl* 0.000 claims 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 4
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
239000003513 alkali Substances 0.000 claims 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims 1
125000005843 halogen group Chemical group 0.000 claims 1
VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 abstract description 3
239000005961 Ethoprophos Substances 0.000 abstract description 2
125000003396 thiol group Chemical class [H]S* 0.000 abstract 1
LOCHFZBWPCLPAN-UHFFFAOYSA-N butane-2-thiol Chemical compound CCC(C)S LOCHFZBWPCLPAN-UHFFFAOYSA-N 0.000 description 8
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
239000012429 reaction media Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 5
239000012074 organic phase Substances 0.000 description 5
SUVIGLJNEAMWEG-UHFFFAOYSA-N propane-1-thiol Chemical compound CCCS SUVIGLJNEAMWEG-UHFFFAOYSA-N 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
238000001816 cooling Methods 0.000 description 4
239000000203 mixture Substances 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
150000008044 alkali metal hydroxides Chemical class 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000012071 phase Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
238000005481 NMR spectroscopy Methods 0.000 description 1
241000244206 Nematoda Species 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical class OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000002917 insecticide Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000005645 nematicide Substances 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
- C07F9/165—Esters of thiophosphoric acids
- C07F9/17—Esters of thiophosphoric acids with hydroxyalkyl compounds without further substituents on alkyl

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Polyesters Or Polycarbonates (AREA)
Steroid Compounds (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

DD87299818A 1986-02-11 1987-02-10 Verfahren zur herstellung von 0-alkyl-s,s-dialkyl-di-thiophosphaten DD260071A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US82827286A	1986-02-11	1986-02-11

Publications (1)

Publication Number	Publication Date
DD260071A5 true DD260071A5 (de)	1988-09-14

Family

ID=25251343

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD87299818A DD260071A5 (de)	1986-02-11	1987-02-10	Verfahren zur herstellung von 0-alkyl-s,s-dialkyl-di-thiophosphaten

Country Status (21)

Country	Link
EP (1)	EP0235056B1 (fr)
JP (1)	JP2530142B2 (fr)
KR (1)	KR870007941A (fr)
CN (1)	CN1017432B (fr)
AT (1)	ATE53843T1 (fr)
AU (1)	AU600928B2 (fr)
BR (1)	BR8700588A (fr)
CA (1)	CA1292007C (fr)
DD (1)	DD260071A5 (fr)
DE (1)	DE3762516D1 (fr)
DK (1)	DK65487A (fr)
ES (1)	ES2015080B3 (fr)
FI (1)	FI86732C (fr)
GR (1)	GR3000483T3 (fr)
HU (1)	HUT45266A (fr)
IE (1)	IE60010B1 (fr)
IL (1)	IL81324A (fr)
PL (1)	PL264040A1 (fr)
PT (1)	PT84266B (fr)
YU (1)	YU19287A (fr)
ZA (1)	ZA87924B (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3263920A (en) *	1963-07-11	1966-08-02	Litton Industries Inc	Storage and transfer device
CN103059060B (zh) *	2013-01-15	2015-09-09	江苏丰山集团股份有限公司	丙线磷制品以及制备丙线磷的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1238013B (de) *	1965-07-08	1967-04-06	Bayer Ag	Verfahren zur Herstellung von Dithiolphosphorsaeureestern
BE786068A (fr) *	1971-07-12	1973-01-10	Bayer Ag	Nouveaux esters d'acides organophosphoriques, leur preparation et leur application comme insecticides et nematicides
JPS6058994A (ja) *	1983-09-12	1985-04-05	Sumitomo Chem Co Ltd	ジチオ−ルりん酸エステル，その製造法およびそれを有効成分とする土壌害虫防除剤

1987
- 1987-01-20 IL IL81324A patent/IL81324A/xx not_active IP Right Cessation
- 1987-01-27 CN CN87100525A patent/CN1017432B/zh not_active Expired
- 1987-01-27 KR KR870000638A patent/KR870007941A/ko not_active Ceased
- 1987-02-09 JP JP62027974A patent/JP2530142B2/ja not_active Expired - Fee Related
- 1987-02-09 AU AU68606/87A patent/AU600928B2/en not_active Ceased
- 1987-02-09 IE IE32987A patent/IE60010B1/en not_active IP Right Cessation
- 1987-02-09 ZA ZA87924A patent/ZA87924B/xx unknown
- 1987-02-09 CA CA000529304A patent/CA1292007C/fr not_active Expired - Lifetime
- 1987-02-10 DK DK065487A patent/DK65487A/da not_active Application Discontinuation
- 1987-02-10 AT AT87420040T patent/ATE53843T1/de not_active IP Right Cessation
- 1987-02-10 FI FI870544A patent/FI86732C/fi not_active IP Right Cessation
- 1987-02-10 DD DD87299818A patent/DD260071A5/de unknown
- 1987-02-10 BR BR8700588A patent/BR8700588A/pt not_active IP Right Cessation
- 1987-02-10 EP EP87420040A patent/EP0235056B1/fr not_active Expired - Lifetime
- 1987-02-10 PL PL1987264040A patent/PL264040A1/xx unknown
- 1987-02-10 ES ES87420040T patent/ES2015080B3/es not_active Expired - Lifetime
- 1987-02-10 DE DE8787420040T patent/DE3762516D1/de not_active Expired - Fee Related
- 1987-02-10 PT PT84266A patent/PT84266B/pt not_active IP Right Cessation
- 1987-02-10 YU YU00192/87A patent/YU19287A/xx unknown
- 1987-02-11 HU HU87534A patent/HUT45266A/hu unknown
1990
- 1990-05-14 GR GR89400277T patent/GR3000483T3/el unknown

Also Published As

Publication number	Publication date
ATE53843T1 (de)	1990-06-15
JP2530142B2 (ja)	1996-09-04
FI870544L (fi)	1987-08-12
HUT45266A (en)	1988-06-28
ZA87924B (en)	1987-09-30
JPS62195391A (ja)	1987-08-28
BR8700588A (pt)	1987-12-15
FI86732B (fi)	1992-06-30
PT84266B (pt)	1989-09-14
FI86732C (fi)	1992-10-12
CN87100525A (zh)	1987-08-26
CN1017432B (zh)	1992-07-15
EP0235056B1 (fr)	1990-05-02
GR3000483T3 (en)	1991-06-28
IL81324A0 (en)	1987-08-31
DK65487D0 (da)	1987-02-10
YU19287A (en)	1988-04-30
AU600928B2 (en)	1990-08-30
AU6860687A (en)	1987-08-13
EP0235056A1 (fr)	1987-09-02
IE870329L (en)	1987-08-11
DE3762516D1 (de)	1990-06-07
ES2015080B3 (es)	1990-08-01
IE60010B1 (en)	1994-05-18
DK65487A (da)	1987-08-12
IL81324A (en)	1991-03-10
CA1292007C (fr)	1991-11-12
FI870544A0 (fi)	1987-02-10
PL264040A1 (en)	1988-04-14
PT84266A (fr)	1987-03-01
KR870007941A (ko)	1987-09-23

Publication	Publication Date	Title
DE1201839B (de)	1965-09-30	Verfahren zur Herstellung aliphatischer Cyansaeureester, die durch elektronen-anziehende Atome oder Gruppen substituiert sind
DE2212604B2 (de)	1977-11-24	Verfahren zur herstellung von 2- halogenaethylphosphonsaeuren
DD260071A5 (de)	1988-09-14	Verfahren zur herstellung von 0-alkyl-s,s-dialkyl-di-thiophosphaten
DE1670711C3 (de)	1974-03-21	Verfahren zur Herstellung von Thionothiolphosphor-(-phosphon-, phosphin-)säuree stern
EP0008786B1 (fr)	1982-06-09	Procédé de préparation de sels d'amines d'esters acides O,S-dialcoyl thiophosphoriques
EP0015503B1 (fr)	1982-10-06	Procédé de préparation de diazinone
EP0708083B1 (fr)	1998-08-19	Procédé pour la préparation de l'ester méthoxycarbonylméthylémique de l'acide isopropylidèneaminooxyacétique
DE1238013B (de)	1967-04-06	Verfahren zur Herstellung von Dithiolphosphorsaeureestern
DE1668076C3 (de)	1975-05-28	Verfahren zur Herstellung von Isocyanatocarbonsäuretrialkylsilylestern
DE2137383C2 (de)	1982-12-09	Verfahren zur Herstellung substituierter Vinylester der Phosphorsäure
DE1932297A1 (de)	1971-01-07	Verfahren zur Herstellung von Benzimidazol-2-carbaminsaeureestern
DE1192202B (de)	1965-05-06	Verfahren zur Herstellung von (Thiono) Phosphor-(on, in)-saeureestern
DE1192647B (de)	1965-05-13	Verfahren zur Herstellung von Thiol- bzw. Thionothiolphosphonsaeureestern
DE1445659C (de)	1973-08-30	Pyndylphosphorverbindungen und Verfahren zu ihrer Herstellung
DE1768983A1 (de)	1971-04-29	N,N-Bis-halogenmethyl-carbaminsaeureester und Verfahren zu ihrer Herstellung
EP0122479A1 (fr)	1984-10-24	3-Chloro-1,1-dialkoxy-acétones et procédé de leur préparation
DE1768141C (de)	1973-04-05	Verfahren zur Herstellung von Salzen von Dithiophosphorsaure O,S diestern
DE1036846B (de)	1958-08-21	Verfahren zur Herstellung von Thiophosphorsaeureestern
DE1695808B2 (de)	1977-07-28	Verfahren zur herstellung von triglycidylisocyanurat
DE840684C (de)	1952-06-05	Verfahren zur Herstellung von im Isopropylrest chlorierten Isopropylarylverbindungen
DE1943712C3 (de)	1977-12-01	Verfahren zur Herstellung von Epoxy alkylphosphinoxiden
DE3147150A1 (de)	1983-06-01	Neues verfahren zur herstellung von epoxypropanderivaten
DE3425138A1 (de)	1986-01-16	Verfahren zur herstellung eines optisch aktiven phenoxypropionsaeure-ester-derivates
DE1196639B (de)	1965-07-15	Verfahren zur Herstellung von 1-Alkyl-1-alkoxy-3-aryl-harnstoffen
DE2040175A1 (de)	1972-02-17	Verfahren zur Herstellung von N-substituierten N-Chlormethylcarbamidsaeureestern