DD274209A5 - Verfahren zur herstellung von aethylakrylat - Google Patents

Verfahren zur herstellung von aethylakrylat Download PDF

Info

Publication number: DD274209A5
Authority: DD; German Democratic Republic
Prior art keywords: acrylic acid; ethyl acrylate; acid; solvent; water
Prior art date: 1987-07-14

Application number

DD88317890A

Other languages

German (de)

English (en)

Inventor

Edward F Dougherty

James L Paul

Original Assignee

��@��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-07-14

Filing date

1988-07-13

Publication date

1989-12-13

1988-07-13 Application filed by ��@��@��k�� filed Critical ��@��@��k��

1989-12-13 Publication of DD274209A5 publication Critical patent/DD274209A5/de

Links

238000000034 method Methods 0.000 title claims description 17
230000008569 process Effects 0.000 title claims description 11
238000002360 preparation method Methods 0.000 title claims description 4
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title 1
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 37
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 35
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 35
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 33
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 33
238000006243 chemical reaction Methods 0.000 claims abstract description 13
239000002904 solvent Substances 0.000 claims abstract description 13
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 8
239000005977 Ethylene Substances 0.000 claims abstract description 8
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 27
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
238000004821 distillation Methods 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 14
KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 claims description 13
239000012298 atmosphere Substances 0.000 claims description 6
DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 claims description 5
229940008406 diethyl sulfate Drugs 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
150000002596 lactones Chemical class 0.000 claims description 4
229920000728 polyester Polymers 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 3
229920000642 polymer Polymers 0.000 claims description 2
239000002253 acid Substances 0.000 abstract description 23
238000011084 recovery Methods 0.000 abstract description 13
238000004519 manufacturing process Methods 0.000 abstract description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
150000002894 organic compounds Chemical class 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
239000003973 paint Substances 0.000 description 2
239000013049 sediment Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
230000008901 benefit Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000001311 chemical methods and process Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
-1 coatings Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
XHIOOWRNEXFQFM-UHFFFAOYSA-N ethyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(=O)C=C XHIOOWRNEXFQFM-UHFFFAOYSA-N 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
230000006872 improvement Effects 0.000 description 1
230000003993 interaction Effects 0.000 description 1
239000000463 material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000001577 simple distillation Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S203/00—Distillation: processes, separatory
- Y10S203/22—Accessories

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

DD88317890A 1987-07-14 1988-07-13 Verfahren zur herstellung von aethylakrylat DD274209A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/073,782 US5145989A (en)	1987-07-14	1987-07-14	Recovery of acrylic acid and/or ethyl acrylate from black acid

Publications (1)

Publication Number	Publication Date
DD274209A5 true DD274209A5 (de)	1989-12-13

Family

ID=22115768

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD88317890A DD274209A5 (de)	1987-07-14	1988-07-13	Verfahren zur herstellung von aethylakrylat

Country Status (13)

Country	Link
US (1)	US5145989A (ja)
EP (1)	EP0299743B1 (ja)
JP (1)	JP2602696B2 (ja)
CN (1)	CN1019970C (ja)
AT (1)	ATE64367T1 (ja)
AU (1)	AU602779B2 (ja)
BR (1)	BR8803496A (ja)
CA (1)	CA1307795C (ja)
DD (1)	DD274209A5 (ja)
DE (1)	DE3863244D1 (ja)
ES (1)	ES2022623B3 (ja)
GR (1)	GR3002122T3 (ja)
MX (1)	MX169580B (ja)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4968834A (en) *	1990-05-07	1990-11-06	Hoechst Celanese Corporation	Recovery of acrylic acid and/or ethyl acrylate from black acid
DE4019781A1 (de) *	1990-06-21	1992-01-02	Basf Ag	Verfahren zur herstellung von monoethylenisch ungesaettigten carbonsaeureestern
WO2002055472A1 (de) *	2000-12-18	2002-07-18	Basf Aktiengesellschaft	Verfahren zur herstellung von höheren (meth)acrylsäureestern
WO2003051813A1 (en) *	2001-12-18	2003-06-26	Metabolix, Inc.	Methods of making intermediates from polyhydroxyalkanoates
US9084467B2 (en)	2010-02-11	2015-07-21	Metabolix, Inc.	Process for gamma-butyrolactone production
CN110684470B (zh) *	2019-10-21	2022-03-01	江苏利田科技股份有限公司	一种利用uv单体废水制备丙烯酸酯粘合剂的方法以及一种丙烯酸酯粘合剂

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1668391A1 (de) *	1966-09-09	1972-03-30	Montedison Spa	Verfahren zur kontinuierlichen Herstellung von AEthylestern ungesaettigter Monocarbonsaeuren mit bis zu 4 Kohlenstoffatomen
US3894076A (en) *	1974-01-24	1975-07-08	Celanese Corp	Production of alkyl esters of unsaturated monocarboxylic acids
US3951756A (en) *	1974-11-08	1976-04-20	Celanese Corporation	Purification of alkyl esters
US4490553A (en) *	1980-08-29	1984-12-25	Celanese Corporation	Process for production of ethyl acrylate
FR2492369A1 (fr) *	1980-10-21	1982-04-23	Celanese Corp	Procede de production d'acrylate d'ethyle

1987
- 1987-07-14 US US07/073,782 patent/US5145989A/en not_active Expired - Fee Related
1988
- 1988-06-20 CA CA000569861A patent/CA1307795C/en not_active Expired - Lifetime
- 1988-07-08 JP JP63169134A patent/JP2602696B2/ja not_active Expired - Lifetime
- 1988-07-12 BR BR8803496A patent/BR8803496A/pt not_active Application Discontinuation
- 1988-07-13 EP EP88306416A patent/EP0299743B1/en not_active Expired - Lifetime
- 1988-07-13 ES ES88306416T patent/ES2022623B3/es not_active Expired - Lifetime
- 1988-07-13 AT AT88306416T patent/ATE64367T1/de not_active IP Right Cessation
- 1988-07-13 CN CN88104349A patent/CN1019970C/zh not_active Expired - Fee Related
- 1988-07-13 MX MX012239A patent/MX169580B/es unknown
- 1988-07-13 DD DD88317890A patent/DD274209A5/de not_active IP Right Cessation
- 1988-07-13 DE DE8888306416T patent/DE3863244D1/de not_active Expired - Fee Related
- 1988-07-14 AU AU19033/88A patent/AU602779B2/en not_active Ceased
1991
- 1991-06-13 GR GR91400019T patent/GR3002122T3/el unknown

Also Published As

Publication number	Publication date
GR3002122T3 (en)	1992-12-30
ES2022623B3 (es)	1991-12-01
AU602779B2 (en)	1990-10-25
CA1307795C (en)	1992-09-22
MX169580B (es)	1993-07-13
CN1030909A (zh)	1989-02-08
US5145989A (en)	1992-09-08
BR8803496A (pt)	1989-01-31
DE3863244D1 (de)	1991-07-18
JP2602696B2 (ja)	1997-04-23
EP0299743A1 (en)	1989-01-18
CN1019970C (zh)	1993-03-03
ATE64367T1 (de)	1991-06-15
AU1903388A (en)	1989-01-19
JPS6438046A (en)	1989-02-08
EP0299743B1 (en)	1991-06-12

Legal Events

Date	Code	Title	Description
1999-12-09	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
DE3225431C2 (de)	1990-01-04	Verfahren zur Herstellung von makrocyclischen Esterverbindungen
DE69501437T2 (de)	1998-06-04	Verfahren zur Herstellung von Methylmethacrylat ohne Diacethyl
DE69805799T2 (de)	2003-01-02	Behandlung von formaldehyd enthaltenden gemischen
EP0962444B1 (de)	2002-10-02	Verfahren zur Aufarbeitung von rohem, flüssigem Vinylacetat
DE2331722A1 (de)	1974-01-10	Verfahren zur reinigung von 1,3-dioxolan
DD274209A5 (de)	1989-12-13	Verfahren zur herstellung von aethylakrylat
DE1057086B (de)	1959-05-14	Verfahren zur Herstellung von wasserfreiem Formaldehyd
EP0127836B1 (de)	1986-08-13	Verfahren zur destillativen Gewinnung von Ameisensäure
DE69016195T2 (de)	1995-06-08	Gewinnung von Acrylsäure und/oder Äthylacrylat aus schwarzer Säure.
DE841505C (de)	1952-06-16	Verfahren zur Polymerisation eines ungesaettigten Alkohols, der ein ungesaettigtes Kohlenstoffatom direkt an die Carbinol-gruppe gebunden aufweist
DE4137846A1 (de)	1993-05-19	Verfahren zur herstellung von wasserfreiem und von verunreinigungen befreitem formaldehyd
DE1138752B (de)	1962-10-31	Verfahren zur Herstellung von reinem Formaldehyd
DE2028459C3 (de)	1974-10-03	Verfahren zur Herstellung von fluorhaltigen Alkoholen
DE837997C (de)	1952-05-05	Verfahren zur Herstellung von AEthergruppen enthaltenden organischen Verbindungen
AT397082B (de)	1994-01-25	Verfahren zur entfernung von säureresten aus (poly)esterifikationsprodukte enthaltenden reaktionsgemischen
DE4445825C2 (de)	2002-02-14	Monoalkylphosphin und Verfahren zur Herstellung desselben
DE3302127C2 (ja)	1991-02-14
EP0084674A1 (de)	1983-08-03	Verfahren zur Reinigung von Abfallschwefelsäure
CH395050A (de)	1965-07-15	Verfahren zur Gewinnung von Katalysatoren und Essigsäure aus einem Essigsäuresynthesegemisch
AT206880B (de)	1959-12-28	Verfahren zur Herstellung von Maleinsäureanhydrid
DE261642C (ja)
DE2326804C3 (de)	1979-12-20	Verfahren zur Herstellung von Wasserstoffperoxid
DE2012674A1 (en)	1971-12-02	Concentration of aq acetic acid solns
DD142184A1 (de)	1980-06-11	Gewinnung von trimethylolpropan
DE2310824C3 (de)	1977-12-22	Verfahren zur Gewinnung von Dimethylterephthalat und dessen Zwischenprodukten