DD294245A5 - Verfahren zur oligomerisierung von olefinen - Google Patents

Verfahren zur oligomerisierung von olefinen Download PDF

Info

Publication number: DD294245A5
Authority: DD; German Democratic Republic
Prior art keywords: oligomerization; molecular sieve; catalyst; olefins; nickel
Prior art date: 1989-05-05

Application number

DD90340335A

Other languages

German (de)

English (en)

Inventor

Franz Nierlich

Joachim Neumeister

Thomas Wildt

Wilhelm Droste

Fritz Obenaus

Original Assignee

��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-05-05

Filing date

1990-05-03

Publication date

1991-09-26

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6380139&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DD294245(A5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1990-05-03 Application filed by ��@��k�� filed Critical ��@��k��

1991-09-26 Publication of DD294245A5 publication Critical patent/DD294245A5/de

Links

238000000034 method Methods 0.000 title claims abstract description 20
230000003606 oligomerizing effect Effects 0.000 title 1
239000003054 catalyst Substances 0.000 claims abstract description 52
229930195733 hydrocarbon Natural products 0.000 claims abstract description 45
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 44
239000002808 molecular sieve Substances 0.000 claims abstract description 44
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 44
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 42
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 41
239000000203 mixture Substances 0.000 claims abstract description 41
238000006384 oligomerization reaction Methods 0.000 claims abstract description 38
150000001336 alkenes Chemical class 0.000 claims abstract description 28
229910052759 nickel Inorganic materials 0.000 claims abstract description 19
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
239000011593 sulfur Substances 0.000 claims description 7
229910052717 sulfur Inorganic materials 0.000 claims description 7
238000005984 hydrogenation reaction Methods 0.000 claims description 4
239000007791 liquid phase Substances 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
150000001298 alcohols Chemical class 0.000 claims description 3
150000002366 halogen compounds Chemical class 0.000 claims description 3
229910052710 silicon Inorganic materials 0.000 claims description 3
239000010703 silicon Substances 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 2
239000011148 porous material Substances 0.000 abstract description 16
230000003197 catalytic effect Effects 0.000 abstract description 2
239000002574 poison Substances 0.000 description 14
231100000614 poison Toxicity 0.000 description 14
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
239000010457 zeolite Substances 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 9
239000003795 chemical substances by application Substances 0.000 description 9
QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
239000000243 solution Substances 0.000 description 8
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 6
-1 ethylene, propylene Chemical group 0.000 description 6
BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 5
229910021536 Zeolite Inorganic materials 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
239000010949 copper Substances 0.000 description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
239000007789 gas Substances 0.000 description 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
229910052802 copper Inorganic materials 0.000 description 4
239000012071 phase Substances 0.000 description 4
150000003464 sulfur compounds Chemical class 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
238000009835 boiling Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
238000004821 distillation Methods 0.000 description 3
150000002927 oxygen compounds Chemical class 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
229940002612 prodrug Drugs 0.000 description 3
239000000651 prodrug Substances 0.000 description 3
239000001294 propane Substances 0.000 description 3
238000000926 separation method Methods 0.000 description 3
230000007306 turnover Effects 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
229910004298 SiO 2 Inorganic materials 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
238000010533 azeotropic distillation Methods 0.000 description 2
229910052796 boron Inorganic materials 0.000 description 2
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
238000000975 co-precipitation Methods 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
239000000470 constituent Substances 0.000 description 2
239000003599 detergent Substances 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
239000012299 nitrogen atmosphere Substances 0.000 description 2
229910017464 nitrogen compound Inorganic materials 0.000 description 2
150000002830 nitrogen compounds Chemical class 0.000 description 2
WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical class [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
239000008037 PVC plasticizer Substances 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
KMWBBMXGHHLDKL-UHFFFAOYSA-N [AlH3].[Si] Chemical compound [AlH3].[Si] KMWBBMXGHHLDKL-UHFFFAOYSA-N 0.000 description 1
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
239000003513 alkali Substances 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
229910001570 bauxite Inorganic materials 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
CDNBBXKOCUDMCC-UHFFFAOYSA-N but-1-ene;2-methylpropane Chemical compound CCC=C.CC(C)C CDNBBXKOCUDMCC-UHFFFAOYSA-N 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
239000002283 diesel fuel Substances 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
WQABCVAJNWAXTE-UHFFFAOYSA-N dimercaprol Chemical compound OCC(S)CS WQABCVAJNWAXTE-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
239000002815 homogeneous catalyst Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052746 lanthanum Inorganic materials 0.000 description 1
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
229910052680 mordenite Inorganic materials 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
150000004291 polyenes Chemical class 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
HVZJRWJGKQPSFL-UHFFFAOYSA-N tert-Amyl methyl ether Chemical compound CCC(C)(C)OC HVZJRWJGKQPSFL-UHFFFAOYSA-N 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Analytical Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Water Supply & Treatment (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

DD90340335A 1989-05-05 1990-05-03 Verfahren zur oligomerisierung von olefinen DD294245A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE3914817A DE3914817C2 (de)	1989-05-05	1989-05-05	Verfahren zur Oligomerisierung von Olefinen

Publications (1)

Publication Number	Publication Date
DD294245A5 true DD294245A5 (de)	1991-09-26

Family

ID=6380139

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD90340335A DD294245A5 (de)	1989-05-05	1990-05-03	Verfahren zur oligomerisierung von olefinen

Country Status (20)

Country	Link
US (1)	US5177282A (cs)
EP (1)	EP0395857B2 (cs)
JP (1)	JP2726138B2 (cs)
KR (1)	KR970006883B1 (cs)
AR (1)	AR244190A1 (cs)
AT (1)	ATE110047T1 (cs)
AU (1)	AU620987B2 (cs)
BG (1)	BG60554B1 (cs)
BR (1)	BR9002090A (cs)
CA (1)	CA2015789C (cs)
CS (1)	CS275062B2 (cs)
DD (1)	DD294245A5 (cs)
DE (2)	DE3914817C2 (cs)
ES (1)	ES2058640T5 (cs)
FI (1)	FI94623C (cs)
HU (1)	HU207698B (cs)
NO (1)	NO178297C (cs)
PT (1)	PT93819B (cs)
RU (1)	RU2058976C1 (cs)
ZA (1)	ZA903391B (cs)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5120881A (en) *	1988-11-22	1992-06-09	Exxon Chemical Patents Inc	Removal of nitrogenous components of a hydrocarbon feedstream
US5336827A (en) *	1992-07-09	1994-08-09	Idemitsu Kosan Co., Ltd.	Process for producing an oligomer
AU681948B2 (en) *	1994-02-22	1997-09-11	Exxon Chemical Patents Inc.	Oligomerization and catalysts therefor
GB9502342D0 (en)	1995-02-07	1995-03-29	Exxon Chemical Patents Inc	Hydrocarbon treatment and catalyst therefor
DE19629906A1 (de) *	1996-07-24	1998-01-29	Huels Chemische Werke Ag	Verfahren zur Herstellung von Butenoligomeren aus Fischer-Tropsch-Olefinen
DE19629903A1 (de) *	1996-07-24	1998-01-29	Huels Chemische Werke Ag	Verfahren zur Herstellung von Buten-Oligomeren aus Feldbutanen
DE19629904A1 (de) *	1996-07-24	1998-01-29	Huels Chemische Werke Ag	Verfahren zur Herstellung von Alkyl-tert.butylethern und Di-n-buten aus Feldbutanen
DE19629905A1 (de) *	1996-07-24	1998-01-29	Huels Chemische Werke Ag	Verfahren zur Herstellung von Alkly-tert.butylethern und Di-n-buten aus Feldbutanen
DE19910103A1 (de)	1999-03-08	2000-09-14	Basf Ag	Verfahren zur Oligomerisierung von C¶6¶-Olefinen
DE19915357A1 (de) *	1999-04-06	2000-10-12	Basf Ag	Verfahren zur Oligomerisierung von C¶2¶- bis C¶8¶-Olefinen
DE19922038A1 (de) *	1999-05-12	2000-11-16	Basf Ag	Verfahren zur Oligomerisierung von C2- bis C8-Olefinen
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1990
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- 1990-03-09 ES ES90104478T patent/ES2058640T5/es not_active Expired - Lifetime
- 1990-03-09 DE DE59006810T patent/DE59006810D1/de not_active Expired - Lifetime
- 1990-03-09 AT AT90104478T patent/ATE110047T1/de not_active IP Right Cessation
- 1990-04-04 US US07/503,951 patent/US5177282A/en not_active Expired - Lifetime
- 1990-04-19 AR AR90316664A patent/AR244190A1/es active
- 1990-04-20 PT PT93819A patent/PT93819B/pt not_active IP Right Cessation
- 1990-05-01 JP JP2111902A patent/JP2726138B2/ja not_active Expired - Lifetime
- 1990-05-02 FI FI902188A patent/FI94623C/fi not_active IP Right Cessation
- 1990-05-03 KR KR1019900006230A patent/KR970006883B1/ko not_active Expired - Lifetime
- 1990-05-03 DD DD90340335A patent/DD294245A5/de not_active IP Right Cessation
- 1990-05-03 BG BG91917A patent/BG60554B1/bg unknown
- 1990-05-03 CA CA002015789A patent/CA2015789C/en not_active Expired - Fee Related
- 1990-05-04 RU SU904743813A patent/RU2058976C1/ru not_active IP Right Cessation
- 1990-05-04 NO NO901996A patent/NO178297C/no not_active IP Right Cessation
- 1990-05-04 CS CS902220A patent/CS275062B2/cs not_active IP Right Cessation
- 1990-05-04 AU AU54735/90A patent/AU620987B2/en not_active Ceased
- 1990-05-04 HU HU902673A patent/HU207698B/hu not_active IP Right Cessation
- 1990-05-04 BR BR909002090A patent/BR9002090A/pt not_active IP Right Cessation
- 1990-05-04 ZA ZA903391A patent/ZA903391B/xx unknown

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Publication number	Publication date
KR900018338A (ko)	1990-12-21
CA2015789A1 (en)	1990-11-05
ZA903391B (en)	1991-02-27
BG60554B1 (bg)	1995-08-28
BR9002090A (pt)	1991-08-13
ES2058640T5 (es)	1999-03-16
PT93819A (pt)	1991-01-08
NO901996D0 (no)	1990-05-04
BG91917A (bg)	1993-12-24
HU902673D0 (en)	1990-09-28
PT93819B (pt)	1999-06-30
JP2726138B2 (ja)	1998-03-11
HU207698B (en)	1993-05-28
CS9002220A3 (en)	1992-01-15
ES2058640T3 (es)	1994-11-01
JPH02306926A (ja)	1990-12-20
DE3914817C2 (de)	1995-09-07
NO901996L (no)	1990-11-06
AU5473590A (en)	1990-11-08
CA2015789C (en)	1999-11-23
FI902188A0 (fi)	1990-05-02
AR244190A1 (es)	1993-10-29
US5177282A (en)	1993-01-05
RU2058976C1 (ru)	1996-04-27
EP0395857B2 (de)	1998-12-16
KR970006883B1 (ko)	1997-04-30
NO178297C (no)	1996-02-28
HUT54332A (en)	1991-02-28
FI94623C (fi)	1995-10-10
FI94623B (fi)	1995-06-30
EP0395857A1 (de)	1990-11-07
AU620987B2 (en)	1992-02-27
ATE110047T1 (de)	1994-09-15
DE59006810D1 (de)	1994-09-22
DE3914817A1 (de)	1990-11-08
NO178297B (no)	1995-11-20
CS275062B2 (en)	1992-01-15
EP0395857B1 (de)	1994-08-17

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EP0395857B2 (de)	1998-12-16	Verfahren zur Oligomerisierung von Olefinen
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