DD297980A5 - Verfahren zur herstellung eines geschlossen-zelligen auf polyisocyanat basierenden hartschaums - Google Patents

Verfahren zur herstellung eines geschlossen-zelligen auf polyisocyanat basierenden hartschaums Download PDF

Info

Publication number: DD297980A5
Authority: DD; German Democratic Republic
Prior art keywords: polyisocyanate; boiling point; foam; closed; halohydrocarbon
Prior art date: 1989-05-10

Application number

DD90340466A

Other languages

German (de)

English (en)

Inventor

Henri J M Gruenbauer

Guido F Smits

Original Assignee

��@��@��@��k��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-05-10

Filing date

1990-05-08

Publication date

1992-01-30

1990-05-08 Application filed by ��@��@��@��k�� filed Critical ��@��@��@��k��

1992-01-30 Publication of DD297980A5 publication Critical patent/DD297980A5/de

Links

238000004519 manufacturing process Methods 0.000 title abstract description 14
239000006260 foam Substances 0.000 claims abstract description 54
229920001228 polyisocyanate Polymers 0.000 claims abstract description 48
239000005056 polyisocyanate Substances 0.000 claims abstract description 48
238000009835 boiling Methods 0.000 claims abstract description 31
150000002894 organic compounds Chemical class 0.000 claims abstract description 27
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
239000003380 propellant Substances 0.000 claims abstract description 20
238000000034 method Methods 0.000 claims abstract description 17
150000005826 halohydrocarbons Chemical class 0.000 claims abstract description 9
230000008569 process Effects 0.000 claims abstract description 9
UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical class CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims abstract description 8
ATEBGNALLCMSGS-UHFFFAOYSA-N 2-chloro-1,1-difluoroethane Chemical compound FC(F)CCl ATEBGNALLCMSGS-UHFFFAOYSA-N 0.000 claims abstract description 6
YACLCMMBHTUQON-UHFFFAOYSA-N 1-chloro-1-fluoroethane Chemical class CC(F)Cl YACLCMMBHTUQON-UHFFFAOYSA-N 0.000 claims abstract description 4
-1 halohydrocarbon compounds Chemical class 0.000 claims description 26
150000001875 compounds Chemical class 0.000 claims description 24
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
239000001257 hydrogen Substances 0.000 claims description 22
229910052739 hydrogen Inorganic materials 0.000 claims description 22
239000000203 mixture Substances 0.000 claims description 22
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 12
LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical group FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 10
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 10
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 8
BOUGCJDAQLKBQH-UHFFFAOYSA-N 1-chloro-1,2,2,2-tetrafluoroethane Chemical compound FC(Cl)C(F)(F)F BOUGCJDAQLKBQH-UHFFFAOYSA-N 0.000 claims description 7
NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims description 6
239000001569 carbon dioxide Substances 0.000 claims description 6
229910002092 carbon dioxide Inorganic materials 0.000 claims description 6
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 5
239000001294 propane Substances 0.000 claims description 5
UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims description 4
239000008246 gaseous mixture Substances 0.000 claims description 4
229930195733 hydrocarbon Natural products 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 4
RFCAUADVODFSLZ-UHFFFAOYSA-N 1-Chloro-1,1,2,2,2-pentafluoroethane Chemical compound FC(F)(F)C(F)(F)Cl RFCAUADVODFSLZ-UHFFFAOYSA-N 0.000 claims description 3
235000019406 chloropentafluoroethane Nutrition 0.000 claims description 3
239000004215 Carbon black (E152) Substances 0.000 claims description 2
150000008280 chlorinated hydrocarbons Chemical class 0.000 claims description 2
150000001924 cycloalkanes Chemical class 0.000 claims description 2
ZJCFOZHHYJVNNP-UHFFFAOYSA-N F[C]Br Chemical compound F[C]Br ZJCFOZHHYJVNNP-UHFFFAOYSA-N 0.000 claims 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
229910052794 bromium Inorganic materials 0.000 claims 1
150000005827 chlorofluoro hydrocarbons Chemical class 0.000 claims 1
239000004604 Blowing Agent Substances 0.000 abstract description 26
150000008282 halocarbons Chemical class 0.000 abstract description 8
BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 abstract description 5
229920005862 polyol Polymers 0.000 description 26
150000003077 polyols Chemical class 0.000 description 26
239000003054 catalyst Substances 0.000 description 13
210000004027 cell Anatomy 0.000 description 13
239000007789 gas Substances 0.000 description 9
229920013701 VORANOL™ Polymers 0.000 description 8
239000004094 surface-active agent Substances 0.000 description 8
239000012948 isocyanate Substances 0.000 description 7
229920005830 Polyurethane Foam Polymers 0.000 description 6
150000002513 isocyanates Chemical class 0.000 description 6
239000011496 polyurethane foam Substances 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
238000009413 insulation Methods 0.000 description 5
239000000463 material Substances 0.000 description 5
XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical class FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
239000007788 liquid Substances 0.000 description 4
UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 4
VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 description 3
SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000005187 foaming Methods 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000002243 precursor Substances 0.000 description 3
GQUXQQYWQKRCPL-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluorocyclopropane Chemical compound FC1(F)C(F)(F)C1(F)F GQUXQQYWQKRCPL-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
230000008859 change Effects 0.000 description 2
230000009194 climbing Effects 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
235000019404 dichlorodifluoromethane Nutrition 0.000 description 2
150000002009 diols Chemical class 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
230000006872 improvement Effects 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
239000013518 molded foam Substances 0.000 description 2
QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 description 2
150000002902 organometallic compounds Chemical class 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920000570 polyether Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
229920006389 polyphenyl polymer Polymers 0.000 description 2
239000004814 polyurethane Substances 0.000 description 2
229920002635 polyurethane Polymers 0.000 description 2
239000000047 product Substances 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
239000003507 refrigerant Substances 0.000 description 2
239000000600 sorbitol Substances 0.000 description 2
239000007921 spray Substances 0.000 description 2
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
229940029284 trichlorofluoromethane Drugs 0.000 description 2
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
SBSFLEWISJSSHL-UHFFFAOYSA-N (3-methyl-2-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C(C)C)C1=CC=CC=C1 SBSFLEWISJSSHL-UHFFFAOYSA-N 0.000 description 1
NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical group FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 1
YHLIEGBCOUQKHU-UHFFFAOYSA-N 1,1-difluoroprop-1-ene Chemical group CC=C(F)F YHLIEGBCOUQKHU-UHFFFAOYSA-N 0.000 description 1
WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 description 1
VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
XXSZLFRJEKKBDJ-UHFFFAOYSA-N 1-chloro-1,1,2,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)Cl XXSZLFRJEKKBDJ-UHFFFAOYSA-N 0.000 description 1
CJENPNUXCMYXPT-UHFFFAOYSA-N 1-chloro-1,2-difluoroethene Chemical group FC=C(F)Cl CJENPNUXCMYXPT-UHFFFAOYSA-N 0.000 description 1
LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
HZAWPPRBCALFRN-UHFFFAOYSA-N 1-methyl-4-[(4-methylphenyl)methyl]benzene Chemical compound C1=CC(C)=CC=C1CC1=CC=C(C)C=C1 HZAWPPRBCALFRN-UHFFFAOYSA-N 0.000 description 1
OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
VZDIRINETBAVAV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylcyclohexane Chemical compound CC1CCC(N=C=O)CC1N=C=O VZDIRINETBAVAV-UHFFFAOYSA-N 0.000 description 1
BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
TZBVWTQFTPARSX-UHFFFAOYSA-N 2-n,2-n,3-n,3-n,4-pentamethylpentane-2,3-diamine Chemical compound CC(C)C(N(C)C)C(C)N(C)C TZBVWTQFTPARSX-UHFFFAOYSA-N 0.000 description 1
QZWKEPYTBWZJJA-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine-4,4'-diisocyanate Chemical compound C1=C(N=C=O)C(OC)=CC(C=2C=C(OC)C(N=C=O)=CC=2)=C1 QZWKEPYTBWZJJA-UHFFFAOYSA-N 0.000 description 1
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
239000004340 Chloropentafluoroethane Substances 0.000 description 1
239000004338 Dichlorodifluoromethane Substances 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
239000004341 Octafluorocyclobutane Substances 0.000 description 1
229920002176 Pluracol® Polymers 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
GPDWNEFHGANACG-UHFFFAOYSA-L [dibutyl(2-ethylhexanoyloxy)stannyl] 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)O[Sn](CCCC)(CCCC)OC(=O)C(CC)CCCC GPDWNEFHGANACG-UHFFFAOYSA-L 0.000 description 1
230000035508 accumulation Effects 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000011354 acetal resin Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000032683 aging Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
MEXUFEQDCXZEON-UHFFFAOYSA-N bromochlorodifluoromethane Chemical compound FC(F)(Cl)Br MEXUFEQDCXZEON-UHFFFAOYSA-N 0.000 description 1
GRCDJFHYVYUNHM-UHFFFAOYSA-N bromodifluoromethane Chemical compound FC(F)Br GRCDJFHYVYUNHM-UHFFFAOYSA-N 0.000 description 1
LHMHCLYDBQOYTO-UHFFFAOYSA-N bromofluoromethane Chemical class FCBr LHMHCLYDBQOYTO-UHFFFAOYSA-N 0.000 description 1
RJCQBQGAPKAMLL-UHFFFAOYSA-N bromotrifluoromethane Chemical compound FC(F)(F)Br RJCQBQGAPKAMLL-UHFFFAOYSA-N 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
230000001413 cellular effect Effects 0.000 description 1
210000003850 cellular structure Anatomy 0.000 description 1
UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000006071 cream Substances 0.000 description 1
239000012043 crude product Substances 0.000 description 1
150000001925 cycloalkenes Chemical class 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
125000005442 diisocyanate group Chemical group 0.000 description 1
XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
UKACHOXRXFQJFN-UHFFFAOYSA-N heptafluoropropane Chemical compound FC(F)C(F)(F)C(F)(F)F UKACHOXRXFQJFN-UHFFFAOYSA-N 0.000 description 1
HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
239000003999 initiator Substances 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
238000000465 moulding Methods 0.000 description 1
RCZLVPFECJNLMZ-UHFFFAOYSA-N n,n,n',n'-tetraethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN(CC)CC RCZLVPFECJNLMZ-UHFFFAOYSA-N 0.000 description 1
XFLSMWXCZBIXLV-UHFFFAOYSA-N n,n-dimethyl-2-(4-methylpiperazin-1-yl)ethanamine Chemical compound CN(C)CCN1CCN(C)CC1 XFLSMWXCZBIXLV-UHFFFAOYSA-N 0.000 description 1
BCCOBQSFUDVTJQ-UHFFFAOYSA-N octafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(F)C1(F)F BCCOBQSFUDVTJQ-UHFFFAOYSA-N 0.000 description 1
235000019407 octafluorocyclobutane Nutrition 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
239000002245 particle Substances 0.000 description 1
MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
229960004065 perflutren Drugs 0.000 description 1
239000012071 phase Substances 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920005906 polyester polyol Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920003226 polyurethane urea Polymers 0.000 description 1
239000003755 preservative agent Substances 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
239000012763 reinforcing filler Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
125000003396 thiol group Chemical group [H]S* 0.000 description 1
239000012974 tin catalyst Substances 0.000 description 1
RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
150000004998 toluenediamines Chemical class 0.000 description 1
238000005829 trimerization reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyurethanes Or Polyureas (AREA)
Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

DD90340466A 1989-05-10 1990-05-08 Verfahren zur herstellung eines geschlossen-zelligen auf polyisocyanat basierenden hartschaums DD297980A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/350,174 US4972003A (en)	1989-05-10	1989-05-10	Foaming system for rigid urethane and isocyanurate foams

Publications (1)

Publication Number	Publication Date
DD297980A5 true DD297980A5 (de)	1992-01-30

Family

ID=23375523

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD90340466A DD297980A5 (de)	1989-05-10	1990-05-08	Verfahren zur herstellung eines geschlossen-zelligen auf polyisocyanat basierenden hartschaums

Country Status (18)

Country	Link
US (1)	US4972003A (fr)
EP (1)	EP0398148B1 (fr)
JP (2)	JPH037738A (fr)
KR (1)	KR0155948B1 (fr)
AR (1)	AR244726A1 (fr)
AT (1)	ATE164608T1 (fr)
AU (1)	AU622023B2 (fr)
BR (1)	BR9002194A (fr)
CA (1)	CA2016328C (fr)
DD (1)	DD297980A5 (fr)
DE (1)	DE69032188T2 (fr)
DK (1)	DK0398148T3 (fr)
ES (1)	ES2113850T3 (fr)
GR (1)	GR3026714T3 (fr)
MX (1)	MX166373B (fr)
NO (1)	NO179178C (fr)
NZ (1)	NZ233595A (fr)
TW (1)	TW203620B (fr)

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US5539008A (en) *	1993-12-29	1996-07-23	Minnesota Mining And Manufacturing Company	Foamable composition containing unsaturated perfluorochemical blowing agent
US5409961A (en) *	1994-07-08	1995-04-25	Basf Corporation	Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft
US5488072A (en) *	1995-02-06	1996-01-30	Basf Corporation	Rigid closed cell polyisocyanate based foams for use as positive flotation materials in watercraft
US5470891A (en) *	1995-04-10	1995-11-28	Basf Corporation	Dimensionally stable closed cell rigid polyisocyanate based foam prepared from a froth foaming mixture
US5840212A (en) *	1996-10-23	1998-11-24	Bayer Corporation	Rigid foams with improved insulation properties and a process for the production of such foams
EP0882760B1 (fr) *	1997-06-03	2003-11-05	Asahi Glass Company Ltd.	Méthode de production d'une résine synthetique expansée
EP1123341B1 (fr)	1998-09-10	2005-04-27	Dow Global Technologies Inc.	Polyols convenant a l'elaboration de mousse rigide de polyuretane soufflee a l'eau
US5958992A (en) *	1998-11-24	1999-09-28	Elf Atochem North America, Inc.	Blowing agent blends
US6136877A (en) *	1999-03-26	2000-10-24	Elf Atochem North America, Inc.	142b/124 blowing agent blends
US6117917A (en) *	1999-04-12	2000-09-12	Elf Atochem North America, Inc.	Blowing agent blends and use thereof
US6262136B1 (en)	1999-05-26	2001-07-17	Bayer Corporation	Storage stable foam-forming system
US6866923B2 (en) *	2000-11-15	2005-03-15	Atlas Roofing Corporation	Thermosetting plastic foams and methods of production thereof using adhesion additives
US20040126564A1 (en) *	2000-11-15	2004-07-01	Atlas Roofing Corporation	Thermosetting plastic foams and methods of production thereof using adhesion additives
US6534556B2 (en)	2001-02-20	2003-03-18	Basf Corporation	Sprayable autofrothing polyisocyanate foam and delivery system
US6753357B2 (en) *	2001-12-18	2004-06-22	Foam Supplies, Inc.	Rigid foam compositions and method employing methyl formate as a blowing agent
JP5286953B2 (ja) *	2002-01-16	2013-09-11	旭硝子株式会社	硬質ポリウレタンフォームの製造方法
US20030213189A1 (en) *	2002-05-16	2003-11-20	Goldman Arthur S.	Thermoplastic polymer extrusion bending
KR20140066210A (ko) *	2004-08-04	2014-05-30	포움 서플라이즈 인코포레이션	폴리우레탄 폼에서의 반응도 변동 및 촉매 분해
US20060052468A1 (en) *	2004-09-08	2006-03-09	Chris Janzen	Resin composition for use in a froth spraying system
US8895635B2 (en)	2007-03-29	2014-11-25	Arkema Inc.	Blowing agent compositions of hydrochlorofluoroolefins
US9206297B2 (en)	2007-03-29	2015-12-08	Arkema Inc.	Blowing agent compositions of hydrochlorofluoroolefins
US11091602B2 (en)	2007-03-29	2021-08-17	Arkema Inc.	Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins
US11208536B2 (en)	2007-03-29	2021-12-28	Arkema Inc.	Blowing agent compositions of hydrofluoroolefins and hydrochlorofluoroolefins
BRPI1007524A2 (pt)	2009-01-29	2017-03-01	Arkema Inc	composições de agente de expansão à base de tetrafluoropropeno
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BR8900726A (pt) *	1988-02-22	1989-10-17	Du Pont	Processo para preparacao de uma mistura util na fabricacao de espuma de poliuretano,e espuma de poliuretano
DE3824354A1 (de) *	1988-07-19	1990-01-25	Basf Ag, 67063 Ludwigshafen	Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren mittels lagerstabiler, treibmittelhaltiger emulsionen und diese emulsionen
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1989
- 1989-05-10 US US07/350,174 patent/US4972003A/en not_active Expired - Lifetime
1990
- 1990-05-05 TW TW079103675A patent/TW203620B/zh active
- 1990-05-07 JP JP2115926A patent/JPH037738A/ja active Pending
- 1990-05-08 BR BR909002194A patent/BR9002194A/pt not_active IP Right Cessation
- 1990-05-08 NZ NZ233595A patent/NZ233595A/xx unknown
- 1990-05-08 DD DD90340466A patent/DD297980A5/de unknown
- 1990-05-09 AU AU54826/90A patent/AU622023B2/en not_active Expired
- 1990-05-09 DE DE69032188T patent/DE69032188T2/de not_active Expired - Lifetime
- 1990-05-09 MX MX020647A patent/MX166373B/es unknown
- 1990-05-09 KR KR1019900006514A patent/KR0155948B1/ko not_active Expired - Fee Related
- 1990-05-09 ES ES90108749T patent/ES2113850T3/es not_active Expired - Lifetime
- 1990-05-09 AR AR90316810A patent/AR244726A1/es active
- 1990-05-09 EP EP90108749A patent/EP0398148B1/fr not_active Expired - Lifetime
- 1990-05-09 DK DK90108749T patent/DK0398148T3/da active
- 1990-05-09 AT AT90108749T patent/ATE164608T1/de not_active IP Right Cessation
- 1990-05-09 NO NO902046A patent/NO179178C/no not_active IP Right Cessation
- 1990-05-09 CA CA002016328A patent/CA2016328C/fr not_active Expired - Lifetime
1998
- 1998-04-23 GR GR980400902T patent/GR3026714T3/el unknown
2002
- 2002-02-04 JP JP2002027192A patent/JP2002234927A/ja active Pending

Also Published As

Publication number	Publication date
TW203620B (fr)	1993-04-11
KR900018190A (ko)	1990-12-20
JPH037738A (ja)	1991-01-14
GR3026714T3 (en)	1998-07-31
AU5482690A (en)	1990-11-15
NO902046L (no)	1990-11-12
CA2016328C (fr)	2000-06-27
MX166373B (es)	1993-01-05
ATE164608T1 (de)	1998-04-15
AU622023B2 (en)	1992-03-26
EP0398148A2 (fr)	1990-11-22
KR0155948B1 (ko)	1998-12-01
US4972003A (en)	1990-11-20
DK0398148T3 (da)	1999-01-11
CA2016328A1 (fr)	1990-11-10
NO179178B (no)	1996-05-13
EP0398148B1 (fr)	1998-04-01
AR244726A1 (es)	1993-11-30
NO902046D0 (no)	1990-05-09
DE69032188T2 (de)	1998-07-30
ES2113850T3 (es)	1998-05-16
EP0398148A3 (fr)	1991-03-27
NZ233595A (en)	1993-04-28
DE69032188D1 (de)	1998-05-07
BR9002194A (pt)	1991-08-13
JP2002234927A (ja)	2002-08-23
NO179178C (no)	1996-08-21

Legal Events

Date	Code	Title	Description
2004-04-28	IF04	In force in the year 2004	Expiry date: 20100509

Publication	Publication Date	Title
DE69032188T2 (de)	1998-07-30	Herstellung von Urethan und Isocyanurat-Schäumen in Anwesenheit von niedrig siedenden Treibmitteln
DE69013975T2 (de)	1995-03-16	Treibmittel für feste Urethan- und Isocyanurat-Schäume.
US4997706A (en)	1991-03-05	Foaming system for closed-cell rigid polymer foam
CA2109627C (fr)	2002-08-13	Agent de soufflage et methode de preparation de mousse de polyurethane
EP0946630B1 (fr)	2001-05-09	Melanges contenant du 1,1,1,3,3-pentafluorobutane
DE69803669T2 (de)	2002-08-14	Isocyanatzusammensetzungen für aufgeschäumte polyurethanschaumstoffe
DE69100834T2 (de)	1994-04-07	Barriereschicht zum verhindern eines solvensangriffs auf kunststoffe.
DE69412601T2 (de)	1999-01-28	Verfahren zur herstellung von polyurethanhartschaumstoffen
DE68921564T2 (de)	1995-07-13	Polyolzusammensetzung, daraus hergestellte, auf Polyisocyanat basierende Schäume und Verfahren zu deren Herstellung.
DE69408875T2 (de)	1998-06-25	Verfahren zur herstellung eines polyurethanschaumstoffs in gegenwart von kohlenwasserstoffen als treibmittelgemisch
DE69801835T2 (de)	2002-04-11	Verfahren zur herstellung von polyurethan-hartschaumstoffen
DE69910627T3 (de)	2006-12-21	Auf polyurethan basierender und expandierbaren graphit enthaltender schaum sowie verfahren zu dessen herstellung
DE68906218T2 (de)	1993-08-05	Polyurethanschaum, der mit verminderten verhaeltnissen aus harten halogenkohlenwasserstofftreibmitteln praepariert ist.
EP3592791B1 (fr)	2022-08-17	Mousse de polyuréthane et son procédé de fabrication
DE69804952T2 (de)	2002-10-17	Verfahren zur herstellung von polyurethanhartschäumen
DE60319689T2 (de)	2009-04-23	Mit teilfluorierten fluorkohlenwasserstoffen und kohlendioixd getriebene polyurethan- oder polyisocyanatschaumstoffe
CA2217988C (fr)	2006-05-23	Mousses rigides ayant des proprietes insolantes ameliorees et procede pour leur production
DE69229051T2 (de)	1999-09-23	Treibmittel und verfahren zur herstellung von polyurethanschaum
DE60108526T2 (de)	2005-08-18	Verfahren zur herstellung von strukturschaumstoffen aus polyurethan
DE19822944A1 (de)	1999-11-25	Herstellung von Polyurethanschäumen
US5539006A (en)	1996-07-23	Rigid foams with improved insulation and physical properties
DE19725360C2 (de)	1999-12-23	Gemische mit 1,1,1,3,3-Pentafluorbutan
DE69721997T2 (de)	2004-02-26	Verwendung von treibmittelmischungen zur herstellung von schaumstoffen auf polyisocyanatbasis
DE69615828T2 (de)	2002-04-04	Azeotropische zusammensetzungen von perfluorohexan, oder 1,1,1,4,4-hexafluorobutan, oder 1,3 dioxolan und kohlenwasserstoffe mit 5 oder 6 kohlenstoffatomen
EP0864602B1 (fr)	2004-09-15	Procédé de préparation de mousses rigides de polyuréthane de faible densité apparente