DD301192A7 - Elastomere propylencoplymere und Verfahren für deren Herstellung in derGasphase - Google Patents

Elastomere propylencoplymere und Verfahren für deren Herstellung in derGasphase Download PDF

Info

Publication number: DD301192A7
Authority: DD; German Democratic Republic
Prior art keywords: propylene; catalyst; ethylene; prepolymer; compound
Prior art date: 1989-07-17

Application number

DD342850A

Other languages

German (de)

English (en)

Original Assignee

Bp Chem Int Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-07-17

Filing date

1990-07-17

Publication date

1992-10-22

1990-07-17 Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd

1992-10-22 Publication of DD301192A7 publication Critical patent/DD301192A7/de

Links

QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 77
238000000034 method Methods 0.000 title claims abstract description 51
230000008569 process Effects 0.000 title claims abstract description 34
229920001577 copolymer Polymers 0.000 title claims description 60
238000002360 preparation method Methods 0.000 title claims description 37
239000003054 catalyst Substances 0.000 claims abstract description 87
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 61
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 46
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 45
239000005977 Ethylene Substances 0.000 claims abstract description 45
-1 aromatic carboxylic esters Chemical class 0.000 claims abstract description 36
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 32
239000007789 gas Substances 0.000 claims abstract description 31
239000001257 hydrogen Substances 0.000 claims abstract description 23
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
235000011147 magnesium chloride Nutrition 0.000 claims abstract description 23
239000004711 α-olefin Substances 0.000 claims abstract description 22
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 16
229920001198 elastomeric copolymer Polymers 0.000 claims abstract description 4
150000001875 compounds Chemical class 0.000 claims description 74
239000010936 titanium Substances 0.000 claims description 55
229910052719 titanium Inorganic materials 0.000 claims description 46
239000002245 particle Substances 0.000 claims description 45
239000007788 liquid Substances 0.000 claims description 37
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 35
238000007334 copolymerization reaction Methods 0.000 claims description 30
239000000725 suspension Substances 0.000 claims description 28
239000004215 Carbon black (E152) Substances 0.000 claims description 27
229930195733 hydrocarbon Natural products 0.000 claims description 27
150000002430 hydrocarbons Chemical class 0.000 claims description 27
239000000843 powder Substances 0.000 claims description 26
239000007787 solid Substances 0.000 claims description 26
238000009826 distribution Methods 0.000 claims description 24
125000004432 carbon atom Chemical group C* 0.000 claims description 15
239000000203 mixture Substances 0.000 claims description 15
150000001336 alkenes Chemical class 0.000 claims description 11
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 11
238000006116 polymerization reaction Methods 0.000 claims description 11
239000011949 solid catalyst Substances 0.000 claims description 11
229910052749 magnesium Inorganic materials 0.000 claims description 9
239000011777 magnesium Substances 0.000 claims description 9
239000012798 spherical particle Substances 0.000 claims description 9
239000004698 Polyethylene Substances 0.000 claims description 8
230000004913 activation Effects 0.000 claims description 8
150000002431 hydrogen Chemical class 0.000 claims description 8
238000005470 impregnation Methods 0.000 claims description 8
229920000573 polyethylene Polymers 0.000 claims description 8
229910052799 carbon Inorganic materials 0.000 claims description 7
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 6
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
239000004743 Polypropylene Substances 0.000 claims description 4
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 4
229920001155 polypropylene Polymers 0.000 claims description 4
150000003377 silicon compounds Chemical class 0.000 claims description 4
229940069096 dodecene Drugs 0.000 claims description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
150000002989 phenols Chemical class 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
150000001408 amides Chemical class 0.000 claims description 2
150000001412 amines Chemical class 0.000 claims description 2
150000002170 ethers Chemical class 0.000 claims description 2
150000004820 halides Chemical class 0.000 claims description 2
150000003003 phosphines Chemical class 0.000 claims description 2
150000003457 sulfones Chemical class 0.000 claims description 2
150000003462 sulfoxides Chemical class 0.000 claims description 2
150000003568 thioethers Chemical class 0.000 claims description 2
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 2
238000010907 mechanical stirring Methods 0.000 claims 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract description 14
238000004519 manufacturing process Methods 0.000 abstract description 8
230000003213 activating effect Effects 0.000 abstract description 5
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 47
238000006243 chemical reaction Methods 0.000 description 23
239000012071 phase Substances 0.000 description 23
238000003756 stirring Methods 0.000 description 23
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 10
229910001220 stainless steel Inorganic materials 0.000 description 10
239000010935 stainless steel Substances 0.000 description 10
239000012299 nitrogen atmosphere Substances 0.000 description 9
238000005406 washing Methods 0.000 description 9
239000008246 gaseous mixture Substances 0.000 description 8
QSSJZLPUHJDYKF-UHFFFAOYSA-N methyl 4-methylbenzoate Chemical compound COC(=O)C1=CC=C(C)C=C1 QSSJZLPUHJDYKF-UHFFFAOYSA-N 0.000 description 8
229920000642 polymer Polymers 0.000 description 8
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 8
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
229920005604 random copolymer Polymers 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 5
239000007791 liquid phase Substances 0.000 description 5
238000005259 measurement Methods 0.000 description 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
239000006228 supernatant Substances 0.000 description 5
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
125000004429 atom Chemical group 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
229920005606 polypropylene copolymer Polymers 0.000 description 4
238000001556 precipitation Methods 0.000 description 4
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 4
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000009835 boiling Methods 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
230000004927 fusion Effects 0.000 description 3
239000007792 gaseous phase Substances 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
229920001903 high density polyethylene Polymers 0.000 description 3
239000004700 high-density polyethylene Substances 0.000 description 3
239000000178 monomer Substances 0.000 description 3
230000000704 physical effect Effects 0.000 description 3
230000000379 polymerizing effect Effects 0.000 description 3
229920000098 polyolefin Polymers 0.000 description 3
229920005629 polypropylene homopolymer Polymers 0.000 description 3
229910000077 silane Inorganic materials 0.000 description 3
239000000243 solution Substances 0.000 description 3
230000000707 stereoselective effect Effects 0.000 description 3
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical class CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
238000000975 co-precipitation Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
150000004796 dialkyl magnesium compounds Chemical class 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000012685 gas phase polymerization Methods 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
229910001629 magnesium chloride Inorganic materials 0.000 description 2
150000004045 organic chlorine compounds Chemical class 0.000 description 2
239000000047 product Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
230000001603 reducing effect Effects 0.000 description 2
239000005060 rubber Substances 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
238000002791 soaking Methods 0.000 description 2
239000012265 solid product Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
230000008901 benefit Effects 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
238000012661 block copolymerization Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
ZZNQQQWFKKTOSD-UHFFFAOYSA-N diethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OCC)(OCC)C1=CC=CC=C1 ZZNQQQWFKKTOSD-UHFFFAOYSA-N 0.000 description 1
238000000113 differential scanning calorimetry Methods 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000000806 elastomer Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000012035 limiting reagent Substances 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
238000003801 milling Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
238000000399 optical microscopy Methods 0.000 description 1
230000008520 organization Effects 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000011555 saturated liquid Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000000758 substrate Substances 0.000 description 1
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
239000003643 water by type Substances 0.000 description 1
238000004804 winding Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)
Graft Or Block Polymers (AREA)

DD342850A 1989-07-17 1990-07-17 Elastomere propylencoplymere und Verfahren für deren Herstellung in derGasphase DD301192A7 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR8909823A FR2649708B1 (fr)	1989-07-17	1989-07-17	Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite

Publications (1)

Publication Number	Publication Date
DD301192A7 true DD301192A7 (de)	1992-10-22

Family

ID=9384002

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD342850A DD301192A7 (de)	1989-07-17	1990-07-17	Elastomere propylencoplymere und Verfahren für deren Herstellung in derGasphase

Country Status (18)

Country	Link
EP (1)	EP0409492B1 (ja)
JP (1)	JPH04500832A (ja)
CN (1)	CN1049357A (ja)
AT (1)	ATE110394T1 (ja)
AU (2)	AU631910B2 (ja)
BR (1)	BR9006856A (ja)
CA (1)	CA2030515A1 (ja)
DD (1)	DD301192A7 (ja)
DE (1)	DE69011776T2 (ja)
ES (1)	ES2057414T3 (ja)
FI (1)	FI99118B (ja)
FR (1)	FR2649708B1 (ja)
HU (1)	HUT56861A (ja)
MY (1)	MY108521A (ja)
NO (1)	NO178863C (ja)
NZ (1)	NZ234493A (ja)
PL (1)	PL286095A1 (ja)
WO (1)	WO1991001338A1 (ja)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2650827B1 (fr) *	1989-08-08	1993-03-05	Bp Chem Int Ltd	Procede de preparation d'un catalyseur de type ziegler - natta a base de vanadium
FR2651234B1 (fr) *	1989-08-29	1993-03-12	Bp Chem Int Ltd	Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite.
BR9005444A (pt) *	1989-10-31	1991-09-17	Union Carbide Chem Plastic	Processo para a preparacao de copolimeros aleatorios
DE69018372T2 (de) *	1989-10-31	1995-08-17	Union Carbide Chem Plastic	Verfahren zur Herstellung von statischen Copolymeren.
US5068489A (en) *	1989-12-28	1991-11-26	Union Carbide Chemicals And Plastics Technology Corporation	Preparation of very low molecular weight polyethylene in a fluidized bed
US5247032A (en) *	1989-12-29	1993-09-21	Mitsui Petrochemical Industries, Ltd.	Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same
FR2665451B1 (fr) *	1990-08-03	1994-04-08	Bp Chemicals Snc	Procede de fabrication en phase gazeuse de polymeres ou de copolymeres de l'ethylene a l'aide d'un systeme catalytique de haute activite et produits obtenus.
IT1246614B (it)	1991-06-03	1994-11-24	Himont Inc	Procedimento per la polimerizzazione in fase gas delle olefine
ES2106873T3 (es) *	1991-06-27	1997-11-16	Idemitsu Petrochemical Co	Resina de polipropileno y su composicion.
FR2697526B1 (fr) *	1992-10-30	1994-12-16	Bp Chemicals Snc	Procédé de préparation d'un catalyseur de type Ziegler-Natta pour la polymérisation des oléfines.
FR2689510B1 (fr) *	1992-04-03	1995-07-21	Bp Chemicals Snc	Procede de preparation d'un catalyseur de type ziegler natta pour la polymerisation des olefines.
EP0564211A3 (en) *	1992-04-03	1993-10-20	BP Chemicals Limited	Process for the preparation of a ziegler-natta catalyst
US5744555A (en) *	1994-11-25	1998-04-28	Eastman Chemical Company	Process for the synthesis of elastomeric polypropylene
CA2167983C (en) *	1995-01-25	2001-01-09	Toshiyuki Tsutsui	Dry prepolymerized catalyst for olefin polymerization, process for preparing the same and gas phase olefin polymerization process
FI963707A0 (fi) *	1996-09-19	1996-09-19	Borealis Polymers Oy	Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma
DE10259243A1 (de) *	2002-12-17	2004-07-01	Merck Patent Gmbh	Verfahren zur Herstellung von Co- und Terpolymeren aus Olefinen
EP2543684B1 (en) *	2011-07-07	2016-12-21	Borealis AG	Process for the manufacture of isotactic polypropylene
RU2015106531A (ru)	2012-08-07	2016-09-27	Бореалис Аг	Способ получения полипропилена, имеющий повышенную производительность

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS56811A (en) *	1979-06-18	1981-01-07	Mitsui Petrochem Ind Ltd	Preparation of olefin polymer or copolymer
DE3366573D1 (en) *	1982-06-24	1986-11-06	Bp Chimie Sa	Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
CA1306579C (en) *	1987-12-15	1992-08-18	Mamoru Kioka	Process for producing polypropylene and stretched polypropylene film
FR2628110B1 (fr) *	1988-03-03	1994-03-25	Bp Chimie	Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation
FR2629461B1 (fr) *	1988-03-31	1993-05-07	Bp Chimie Sa	Catalyseur de (co)polymerisation du propylene, supporte sur des particules spheriques de chlorure de magnesium et enrobe par du polypropylene, et procedes de preparation
FR2651234B1 (fr) *	1989-08-29	1993-03-12	Bp Chem Int Ltd	Procede de fabrication en phase gazeuse de copolymeres du propylene a l'aide d'un systeme catalytique de haute activite.

1989
- 1989-07-17 FR FR8909823A patent/FR2649708B1/fr not_active Expired - Lifetime
1990
- 1990-07-12 AU AU60441/90A patent/AU631910B2/en not_active Ceased
- 1990-07-12 EP EP90307662A patent/EP0409492B1/en not_active Expired - Lifetime
- 1990-07-12 BR BR909006856A patent/BR9006856A/pt not_active Application Discontinuation
- 1990-07-12 JP JP2510331A patent/JPH04500832A/ja active Pending
- 1990-07-12 DE DE69011776T patent/DE69011776T2/de not_active Expired - Fee Related
- 1990-07-12 AT AT90307662T patent/ATE110394T1/de not_active IP Right Cessation
- 1990-07-12 WO PCT/GB1990/001073 patent/WO1991001338A1/en not_active Ceased
- 1990-07-12 HU HU905513A patent/HUT56861A/hu unknown
- 1990-07-12 CA CA002030515A patent/CA2030515A1/en not_active Abandoned
- 1990-07-12 ES ES90307662T patent/ES2057414T3/es not_active Expired - Lifetime
- 1990-07-13 NZ NZ234493A patent/NZ234493A/xx unknown
- 1990-07-17 DD DD342850A patent/DD301192A7/de unknown
- 1990-07-17 MY MYPI90001192A patent/MY108521A/en unknown
- 1990-07-17 PL PL28609590A patent/PL286095A1/xx unknown
- 1990-07-17 CN CN90106929A patent/CN1049357A/zh active Pending
1991
- 1991-02-19 FI FI910789A patent/FI99118B/fi active
- 1991-03-12 NO NO910974A patent/NO178863C/no unknown
1992
- 1992-10-06 AU AU26244/92A patent/AU651006B2/en not_active Ceased

Also Published As

Publication number	Publication date
AU651006B2 (en)	1994-07-07
EP0409492A1 (en)	1991-01-23
PL286095A1 (en)	1991-09-23
FI910789A0 (fi)	1991-02-19
AU631910B2 (en)	1992-12-10
BR9006856A (pt)	1991-08-27
NO178863B (no)	1996-03-11
WO1991001338A1 (en)	1991-02-07
HU905513D0 (en)	1991-07-29
FR2649708B1 (fr)	1991-10-25
NO910974D0 (no)	1991-03-12
DE69011776D1 (de)	1994-09-29
ES2057414T3 (es)	1994-10-16
MY108521A (en)	1996-10-31
CA2030515A1 (en)	1991-01-18
DE69011776T2 (de)	1994-12-15
ATE110394T1 (de)	1994-09-15
NO910974L (no)	1991-03-12
NZ234493A (en)	1991-08-27
CN1049357A (zh)	1991-02-20
EP0409492B1 (en)	1994-08-24
HUT56861A (en)	1991-10-28
AU6044190A (en)	1991-02-22
AU2624492A (en)	1992-12-03
FI99118B (fi)	1997-06-30
NO178863C (no)	1996-06-19
JPH04500832A (ja)	1992-02-13
FR2649708A1 (fr)	1991-01-18

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DE68922335T2 (de)	1995-08-31	Ziegler-Natta-Katalysator.
DE69028509T2 (de)	1997-02-06	Katalysator und Prepolymer für Herstellung von Polyolefinen
DD301192A7 (de)	1992-10-22	Elastomere propylencoplymere und Verfahren für deren Herstellung in derGasphase
DE69501526T2 (de)	1998-08-20	Verfahren zur gasphasenpolymerisation von alpha-olefinen
DE69314826T2 (de)	1998-04-30	Verfahren für Gasphase-Polymerisation von Alpha-Olefinen
DE69006141T2 (de)	1994-05-05	Verfahren zur Herstellung von Elastomer-Propylencopolymeren in der Gasphase.
DE68928212T2 (de)	1997-11-13	Modifiziertes Polypropylen, Verfahren zur Herstellung von Produkten daraus
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DE69112466T2 (de)	1996-04-11	Magnesiumchloridteilchen mit einer kegelstumpfartigen Struktur, katalytische Komponenten auf diesen Teilchen, damit hergestellte Polyolefine und Verfahren zur Herstellung dieser Produkte.
DE69428409T2 (de)	2002-06-06	Verfahren zur Herstellung von Polyethylen mit breiter Molekulargewichtsverteilung
DE60203707T2 (de)	2006-03-02	Verfahren zur Herstellung einer Lldpe Zusammensetzung
DE69205960T3 (de)	2000-07-27	Verfahren zur Herstellung von linearen Polyäthylenen mit niedriger Dichte.
DE69028503T2 (de)	1997-01-30	Katalysator und Prepolymer für Polyolefinherstellung
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DD274230A5 (de)	1989-12-13	Verfahren zur herstellung von polymeren
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JPS6025444B2 (ja)	1985-06-18	低密度ポリエチレンの製造方法
DE69123164T2 (de)	1997-03-13	Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer
DD224854A5 (de)	1985-07-17	Ethylenpolymerisation unter verwendung von vanadintraegerkatalysatoren
DE69317324T2 (de)	1998-09-10	Olefinpolymerisationskatalysatorsystem; Verfahren zu dieser Polymerisation und gewonnene Polymere
DE68901679T2 (de)	1992-12-10	Ziegler-natta-katalysator.
DE69914076T2 (de)	2004-08-26	Polymermaterialen hergestellt durch die verwendung von elektronendonormischungen