DE2542230C2 - Verfahren zur Herstellung eines Phosphor enthaltenden Katalysators aus einem kristallinen Aluminosilicatzeolithen - Google Patents

Verfahren zur Herstellung eines Phosphor enthaltenden Katalysators aus einem kristallinen Aluminosilicatzeolithen

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Publication number
DE2542230C2
DE2542230C2 DE2542230A DE2542230A DE2542230C2 DE 2542230 C2 DE2542230 C2 DE 2542230C2 DE 2542230 A DE2542230 A DE 2542230A DE 2542230 A DE2542230 A DE 2542230A DE 2542230 C2 DE2542230 C2 DE 2542230C2
Authority
DE
Germany
Prior art keywords
phosphorus
zeolite
catalyst
weight
zeolites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE2542230A
Other languages
German (de)
English (en)
Other versions
DE2542230A1 (de
Inventor
Stephen Allan East Windsor N.J. Butter
Warren William Westfield N.J. Kaeding
Lewis Brewster Kendal Park N.J. Young
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/508,308 external-priority patent/US3972832A/en
Priority claimed from US508306A external-priority patent/US3906054A/en
Priority claimed from US508307A external-priority patent/US3911041A/en
Priority claimed from US05/538,666 external-priority patent/US3965208A/en
Priority claimed from US05/563,286 external-priority patent/US3962364A/en
Priority claimed from US05/605,968 external-priority patent/US4002698A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of DE2542230A1 publication Critical patent/DE2542230A1/de
Application granted granted Critical
Publication of DE2542230C2 publication Critical patent/DE2542230C2/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/868—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains sulfur as hetero-atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE2542230A 1974-09-23 1975-09-22 Verfahren zur Herstellung eines Phosphor enthaltenden Katalysators aus einem kristallinen Aluminosilicatzeolithen Expired DE2542230C2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US05/508,308 US3972832A (en) 1974-09-23 1974-09-23 Phosphorus-containing zeolite catalyst
US508306A US3906054A (en) 1974-09-23 1974-09-23 Alkylation of olefins
US508307A US3911041A (en) 1974-09-23 1974-09-23 Conversion of methanol and dimethyl ether
US05/538,666 US3965208A (en) 1975-01-06 1975-01-06 Methylation of toluene
US05/563,286 US3962364A (en) 1975-03-28 1975-03-28 Alkylation in presence of phosphorus-modified crystalline luminosilicate catalyst
US05/605,968 US4002698A (en) 1975-08-19 1975-08-19 Methylation of toluene in the presence of a phosphorus-modified activated crystalline aluminosilicate catalyst

Publications (2)

Publication Number Publication Date
DE2542230A1 DE2542230A1 (de) 1976-04-01
DE2542230C2 true DE2542230C2 (de) 1985-01-31

Family

ID=27560081

Family Applications (4)

Application Number Title Priority Date Filing Date
DE2542230A Expired DE2542230C2 (de) 1974-09-23 1975-09-22 Verfahren zur Herstellung eines Phosphor enthaltenden Katalysators aus einem kristallinen Aluminosilicatzeolithen
DE2560440A Expired DE2560440C2 (de) 1974-09-23 1975-09-22 Verfahren zur Herstellung von Kohlenwasserstoffen
DE2560442A Expired DE2560442C2 (de) 1974-09-23 1975-09-22 Verfahren zur Herstellung von Olefinen aus Olefinen mit kleinerer Anzahl an Kohlenstoffatomen
DE2560441A Expired DE2560441C2 (de) 1974-09-23 1975-09-22 Verfahren zur Umwandlung von Paraffinen zu einem Olefine enthaltenden Produkt

Family Applications After (3)

Application Number Title Priority Date Filing Date
DE2560440A Expired DE2560440C2 (de) 1974-09-23 1975-09-22 Verfahren zur Herstellung von Kohlenwasserstoffen
DE2560442A Expired DE2560442C2 (de) 1974-09-23 1975-09-22 Verfahren zur Herstellung von Olefinen aus Olefinen mit kleinerer Anzahl an Kohlenstoffatomen
DE2560441A Expired DE2560441C2 (de) 1974-09-23 1975-09-22 Verfahren zur Umwandlung von Paraffinen zu einem Olefine enthaltenden Produkt

Country Status (8)

Country Link
JP (1) JPS5815443B2 (2)
DD (1) DD123446A5 (2)
DE (4) DE2542230C2 (2)
FR (1) FR2285176A1 (2)
GB (1) GB1496181A (2)
IT (1) IT1042752B (2)
NL (1) NL7511167A (2)
NZ (1) NZ178543A (2)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ183608A (en) * 1976-03-31 1978-12-18 Mobil Oil Corp Aluminosilicate zeolite catalyst for selectine production of para-diakyl substituted benzenes
US4060568A (en) * 1976-03-31 1977-11-29 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4283306A (en) * 1979-04-20 1981-08-11 E. I. Du Pont De Nemours And Company Crystalline silica and use in alkylation of aromatics
JPS5643123U (2) * 1979-09-12 1981-04-20
US4274982A (en) * 1979-10-12 1981-06-23 Mobil Oil Corporation Method for maintaining para-selectivity of modified zeolite catalyst
EP0040015B1 (en) * 1980-05-13 1986-06-11 Imperial Chemical Industries Plc Process for making olefins
US4310440A (en) * 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
US4423269A (en) * 1981-09-25 1983-12-27 Chevron Research Company Oligomerization of gaseous olefins
US4417088A (en) * 1981-09-25 1983-11-22 Chevron Research Company Oligomerization of liquid olefins
US4511746A (en) * 1981-09-25 1985-04-16 Chevron Research Company Low activity catalyst oligomerization process
US4431527A (en) * 1981-11-13 1984-02-14 Standard Oil Company (Indiana) Process for hydrogen treating high nitrogen content hydrocarbon feeds
US4454241A (en) * 1982-05-24 1984-06-12 Exxon Research And Engineering Co. Phosphorus-containing catalyst
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4576805A (en) * 1982-08-27 1986-03-18 Mobil Oil Corporation Increasing lattice metal content of porous inorganic crystalline compositions
JPS6042220A (ja) * 1983-08-15 1985-03-06 モビル　オイル　コ−ポレ−シヨン ゼオライト処理法
JPS60103020A (ja) * 1983-11-08 1985-06-07 Agency Of Ind Science & Technol 結晶性アルミノホスホシリケ−トおよびそれを触媒として用いる炭化水素の製造方法
US4668837A (en) * 1983-11-21 1987-05-26 The Dow Chemical Company Phosphorus modified magnesium silicate
JPS60114042A (ja) * 1983-11-25 1985-06-20 Matsushita Electric Works Ltd 電力線搬送システム
EP0176150B2 (en) * 1984-09-25 1994-02-02 Catalysts & Chemicals Industries Co., Ltd. Catalytic cracking, process for heavy oil
JPS61126041A (ja) * 1984-11-22 1986-06-13 Res Assoc Util Of Light Oil ベンゼンのエチル化法
US4960504A (en) * 1984-12-18 1990-10-02 Uop Dewaxing catalysts and processes employing silicoaluminophosphate molecular sieves
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk Ｐ−キシレンの製造法
AU5645686A (en) * 1985-06-05 1986-12-18 Mobil Oil Corp. Cracking with molecular sieves containing aluminium, phosphorous and silicon
US4665251A (en) * 1985-06-12 1987-05-12 Mobil Oil Corporation Aromatization reactions with zeolites containing phosphorus oxide
IN167718B (2) * 1985-06-28 1990-12-08 Chevron Res
JPS6263528A (ja) * 1985-09-17 1987-03-20 Teijin Yuka Kk Ｐ−キシレンの製造法
JPS6450827A (en) * 1987-08-20 1989-02-27 Agency Ind Science Techn Production of lower olefin
JPH04316524A (ja) * 1991-04-12 1992-11-06 Nippon Oil Co Ltd アルキルビフエニル類の製造方法
IT1250435B (it) * 1991-07-01 1995-04-07 Mini Ricerca Scient Tecnolog Catalizzatore per l'alchilazione di composti aromatici e processo impiegante lo stesso
ES2076068B1 (es) * 1993-03-17 1996-06-16 Consejo Superior Investigacion Procedimiento de preparacion de catalizadores a base de zeolitas tratadas con acido fosforico, utiles para su aplicacion en unidades de craqueo catalitico.
US5925586A (en) * 1996-12-31 1999-07-20 Exxon Chemical Patents, Inc. Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
US6613951B1 (en) * 1999-09-23 2003-09-02 Mobil Oil Corporation Process for converting methanol to olefins
US7038100B2 (en) * 2001-04-30 2006-05-02 Exxonmobil Chemical Patents, Inc. Aromatics alkylation
CN1257769C (zh) * 2003-10-31 2006-05-31 中国石油化工股份有限公司 一种含磷和金属组分的mfi结构分子筛及其应用
RU2399414C2 (ru) * 2005-10-07 2010-09-20 ЭсКей ЭНЕРДЖИ КО., ЛТД. Гидротермически стабильный микропористый молекулярно-ситовый катализатор и метод его изготовления
JP4823655B2 (ja) * 2005-11-21 2011-11-24 出光興産株式会社 キシレン類の製造方法
JP5094506B2 (ja) * 2008-03-28 2012-12-12 出光興産株式会社 軽質オレフィンの製造方法
US8115041B2 (en) * 2008-04-02 2012-02-14 Saudi Basic Industries Corporation Pretreatment of a phosphorus-modified zeolite catalyst for an aromatic alkylation process
US8252967B2 (en) * 2009-04-14 2012-08-28 Exxonmobil Chemical Patents Inc. Process for the purification of paraxylene
FI124814B (fi) 2010-10-18 2015-01-30 Lappeenrannan Teknillinen Yliopisto Sähkökoneen staattori ja sähkökone
JP5798821B2 (ja) 2011-07-15 2015-10-21 三菱重工業株式会社 メタノールからガソリンを製造するともに発電する方法およびシステム
JP5812781B2 (ja) 2011-09-21 2015-11-17 三菱重工業株式会社 メタノールからガソリンと水素を製造する方法および装置
CN104114277B (zh) * 2011-10-17 2017-02-15 埃克森美孚研究工程公司 磷改性沸石催化剂
EP3433223A4 (en) * 2016-03-25 2019-12-25 ExxonMobil Chemical Patents Inc. CATALYST AND PROCESS FOR PRODUCING PARAXYLENE
CN114375288B (zh) * 2019-09-30 2024-08-23 陶氏环球技术有限责任公司 醚化方法
JP7737397B2 (ja) * 2020-04-13 2025-09-10 中国石油化工股▲ふん▼有限公司 リン改質ｍｆｉ構造分子篩、リン改質ｍｆｉ構造分子篩を含む接触分解助剤および接触分解触媒、ならびにその調製方法
CN117920324A (zh) * 2022-10-24 2024-04-26 中国石油化工股份有限公司 含磷zsm-5分子筛及其制备方法和应用
CN116477638B (zh) * 2023-03-23 2024-08-16 延长中科（大连）能源科技股份有限公司 一种高稳定性丝光沸石分子筛的制备方法及其应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3647682A (en) 1968-10-23 1972-03-07 Union Carbide Corp Olefin production by the catalytic treatment of hydrocarbons
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) * 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
GB1403329A (en) * 1972-04-28 1975-08-28 Mobil Oil Corp Vapour-phase alkylation in presence of crystalline alumino silicate catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
CS191916B2 (en) 1973-08-09 1979-07-31 Mobil Oil Corp Method of producing aromatic hydrocarbons

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JPS5157688A (en) 1976-05-20
FR2285176B1 (2) 1982-10-01
FR2285176A1 (fr) 1976-04-16
DE2560441C2 (de) 1986-05-22
JPS5815443B2 (ja) 1983-03-25
DE2560440C2 (de) 1986-11-13
IT1042752B (it) 1980-01-30
NL7511167A (nl) 1976-03-25
DE2542230A1 (de) 1976-04-01
DD123446A5 (2) 1976-12-20
NZ178543A (en) 1978-04-03
GB1496181A (en) 1977-12-30
DE2560442C2 (de) 1986-10-16
DE2560441A1 (2) 1982-08-26

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