DE683024C - Process for the production of flooring materials - Google Patents
Process for the production of flooring materialsInfo
- Publication number
- DE683024C DE683024C DEI60116D DEI0060116D DE683024C DE 683024 C DE683024 C DE 683024C DE I60116 D DEI60116 D DE I60116D DE I0060116 D DEI0060116 D DE I0060116D DE 683024 C DE683024 C DE 683024C
- Authority
- DE
- Germany
- Prior art keywords
- condensation products
- production
- adipic acid
- adipic
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 6
- 239000000463 material Substances 0.000 title claims description 5
- 238000009408 flooring Methods 0.000 title 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 16
- 239000007859 condensation product Substances 0.000 claims description 16
- 235000011037 adipic acid Nutrition 0.000 claims description 9
- 239000001361 adipic acid Substances 0.000 claims description 8
- 150000001279 adipic acids Chemical class 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000001294 propane Substances 0.000 claims description 4
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WDBZEBXYXWWDPJ-UHFFFAOYSA-N 3-(2-methylphenoxy)propanoic acid Chemical compound CC1=CC=CC=C1OCCC(O)=O WDBZEBXYXWWDPJ-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/121—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N1/00—Linoleum, e.g. linoxyn, polymerised or oxidised resin
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
Verfahren zur Herstellung von Bodenbelagstoffen Im Hauptpatent 679 472 ist ein Verfahren zur Herstellung von Bodenbelagstoffen beschrieben, bei dem man Kondensationsprodukte aus Adipinsäure und mehrwertigen Alkoholen, insbesondere Trimethyloläthan und bzw. oder -propan, mit Füllstoffen auf Unterlagen aufwalzt oder aufpreßt oder die Massen, ohne auf eine Unterlage aufzubringen, auszieht.Process for the production of floor coverings In the main patent 679 472 describes a process for the production of floor coverings in which condensation products of adipic acid and polyhydric alcohols, in particular Trimethylolethane and / or -propane, rolled on with fillers on substrates or presses on or pulls the masses out without applying to a base.
In dem Zusatzpatent 682 017 ist beschrieben, daß an Stelle der im Hauptpatent genannten Kondensationsprodukte mit Vorteil auch solche aus alkylierten Adipinsäuren und mehrwertigen Alkoholen verwendet werden können. Nach dem Zusatzpatent 682 o16 können auch noch Linoxyn und bzw. oder Polyvinylverbindungen mitverwendet werden. Es wurde nun gefunden, daß man gleichfalls Bodenbelagstoffe mit ausgezeichneten Eigenschaften erhält, wenn man bei dem Verfahren des Hauptpatentes als Bindemittel Kondensationsprodukte aus Adipinsäure oder alkylierten Adipinsäuren und anderen mehrbasischen Carbonsäuren und mehrwertigen Alkoholen, insbesondere Trimethyloläthan und bzw. oder -propan, verwendet.In the additional patent 682 017 it is described that in place of the im Condensation products mentioned in the main patent advantageously also include those from alkylated ones Adipic acids and polyhydric alcohols can be used. According to the additional patent 682 o16 can also use Linoxyn and / or polyvinyl compounds will. It has now been found that you can also use floor coverings with excellent Properties obtained when using the method of the main patent as a binder Condensation products from adipic acid or alkylated adipic acids and others polybasic carboxylic acids and polyhydric alcohols, especially trimethylol ethane and or or propane, is used.
Diese Kondensationsprodukte können in gleicher Weise wie die im Hauptpatent genannten Kondensationsprodukte auch in Gegenwart von Natur- oder Kunstharzen, Bitumen, Asphalt, Stearinpech, Glycerinpech oder Rückständen der Fettsäuredestillation hergestellt sein, oder diese Stoffe können ihnen nachträglich zugemischt werden. Die Bindemittel können auch noch Linoxyn und bzw. oder Polyvinylverbindungen, insbesondere dis, im Patent 679 607 beschriebenen Misch merisate aus Vinyläthern mit einer @i". '@ gruppe und Vinyläthern mit mehreren Vix," gruppen, enthalten.These condensation products can be used in the same way as those in the main patent named condensation products also in the presence of natural or synthetic resins, bitumen, Asphalt, stearic pitch, glycerine pitch or residues of fatty acid distillation are produced be, or these substances can be them can be added subsequently. The binders can also be linoxyn and / or polyvinyl compounds, in particular dis, in the patent 679 607 described mixed merisate of vinyl ethers with an @i ". '@ group and vinyl ethers with multiple vix, "groups, included.
Geeignete mehrbasische Säuren, die mit der Adipinsäure oder deren Homologen gemeinsam bei -der Kondensation verwendet werden sollen, sind beispielsweise Bernsteinsäure, Maleinsäure, Fumarsäure, Sebacinsäure sowie Phthalsäure. Die Phthalsäure wendet man zweckmäßig nicht in großen Mengen an, da sonst die Kondensationsprodukte zu hart und zu schwer verarbeitbar werden.Suitable polybasic acids with adipic acid or its Homologues to be used together in the condensation are, for example Succinic acid, maleic acid, fumaric acid, sebacic acid and phthalic acid. The phthalic acid it is advisable not to use large amounts, otherwise the condensation products become too hard and difficult to process.
Die Herstellung der Kondensationsprodukte geschieht in an sich bekannter Weise, und ihre Verarbeitung zu Belagstoffen erfolgt in dergleichen Weise, wie im Hauptpatent beschrieben. Beispiel Ein zähes, gummiartiges Kondensationsprodukt aus 73 Teilen Adipinsäure, 98 Teilen Maleinsäureanhydrid und i34Teilen Trimethylolpropan wird in der im Beispiel i des Hauptpatents 679 47- beschriebenen -Weise zu Belagsto -ften verarbeitet.The condensation products are produced in a manner known per se Way, and their processing into coverings is carried out in the same way as in Main patent described. Example A tough, rubbery condensation product from 73 parts of adipic acid, 98 parts of maleic anhydride and i34 parts of trimethylolpropane becomes in the manner described in example i of the main patent 679 47- to covering material -ften processed.
Die erhaltenen Belagstoffe zeichnen sich durch höhe Elastizität, gute mechanische Festigkeit und Beständigkeit gegen Wasser und Benzin aus.The covering materials obtained are characterized by high elasticity, good mechanical strength and resistance to water and gasoline.
In gleicher Weise kann man auch ein Kondensationsprodukt aus 74 Teilen Methyladipinsäure, 34 Teilen Phthalsäureanhydrid und i34Teilen Trimethylolpropan verwenden.In the same way you can also use a condensation product of 74 parts Methyl adipic acid, 34 parts of phthalic anhydride and i34 parts of trimethylolpropane use.
Man hat bereits vorgeschlagen, die vorstehend beschriebenen Kondensationsprodukte oder ähnliche Verbindungen als Imprägnier-, Klebe- und Bindemittel, z. B. für Lacke oder auch für Druckwalzen, zu verwenden. Daraus konnte aber die vorzügliche Eignung der Kondensationsprodukte aus Adipinsäure oder alkylierter Adipinsäure und anderen mehrbasischen Carbonsäuren und mehrwertigen Ikoholen zur Herstellung von Bodenbelägen cht hergeleitet werden, weil an Bodenbeläge .Wanz besonders hohe Anforderungen bezüg--lich Wasser- und Benzinfestigkeit, Elastizität, Widerstand gegen das Eindrücken irgendwelcher Gegenstände, hoher Alterungsbeständigkeit und insbesondere leichter Verarbeitbarkeit gestellt werden und die meisten Kondensationsprodukte aus mehrbasischen Säuren und mehrwertigen Alkoholen nicht befriedigen, während die Kondensationsprodukte aus Adipinsäure oder alkylierter Adipinsäure und anderen mehrbasischen Carbonsäuren und mehrwertigen Alkoholen, insbesondere aus Trimethyloläthan und bzw. oder -propan, die an Bindemittel für Bodenbeläge gestellten Forderungen vollständig erfüllen und ausgezeichnete Bodenbeläge ergeben.The condensation products described above have already been proposed or similar compounds as impregnating agents, adhesives and binders, e.g. B. for paints or also for pressure rollers to be used. From this, however, could the excellent suitability the condensation products of adipic acid or alkylated adipic acid and others polybasic carboxylic acids and polyvalent alcohols for the production of floor coverings cannot be derived because .Wanz has particularly high requirements in terms of floor coverings Water and gasoline resistance, elasticity, resistance to indentation of any Objects, high resistance to aging and, in particular, easy processability and most condensation products from polybasic acids and polyhydric alcohols do not satisfy while the condensation products are off Adipic acid or alkylated adipic acid and other polybasic carboxylic acids and polyhydric alcohols, in particular from trimethylolethane and / or -propane, fully meet the requirements placed on binders for floor coverings and excellent floor coverings.
Gegenüber den bekannten linoleumähnlichen Massen aus Köndensationsprodukten aus Acelainsäure und Glycerin zeichnen sich die neuen Bodenbeläge durch erheblich bessere mechanische Festigkeit und Elastizität aus.Compared to the known linoleum-like masses made from condensation products made of azelaic acid and glycerine, the new floor coverings are characterized by a considerable amount better mechanical strength and elasticity.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI60116D DE683024C (en) | 1937-10-10 | 1937-12-30 | Process for the production of flooring materials |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEI59263D DE679472C (en) | 1937-10-10 | 1937-10-10 | Process for the production of flooring materials |
| DEI60116D DE683024C (en) | 1937-10-10 | 1937-12-30 | Process for the production of flooring materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE683024C true DE683024C (en) | 1939-10-27 |
Family
ID=25982026
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEI60116D Expired DE683024C (en) | 1937-10-10 | 1937-12-30 | Process for the production of flooring materials |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE683024C (en) |
-
1937
- 1937-12-30 DE DEI60116D patent/DE683024C/en not_active Expired
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE683024C (en) | Process for the production of flooring materials | |
| DE682017C (en) | Process for the production of flooring materials | |
| DE3688242T2 (en) | RESIN COMPOSITION AND METHOD FOR THEIR PRODUCTION. | |
| DE861609C (en) | Process for the production of high molecular weight condensation products | |
| DE1544619A1 (en) | Urethane compositions provided with extenders | |
| DE1469890B1 (en) | Polyester molding compound | |
| DE739000C (en) | Plasticizers | |
| DE705210C (en) | vinyl record | |
| DE684017C (en) | Process for the production of condensation products | |
| DE600582C (en) | Process for impregnating fabrics and paper | |
| DE536666C (en) | Spinneret, especially for the manufacture of rayon | |
| DE893585C (en) | Process for the production of floor, table, wall and other covering materials | |
| DE545780C (en) | Process for the production of resinous condensation products | |
| DE565481C (en) | Process for the preparation of unsaturated fatty acids | |
| DE905771C (en) | Process for the preparation of a primer from coal tar pitch and organic solvents | |
| AT114880B (en) | Insulating compound for electrical purposes. | |
| DE749564C (en) | Rubber-like mass for electrical purposes, in particular for insulation and cable sheathing | |
| DE538831C (en) | Process for the production of condensation products | |
| DE924897C (en) | Process for the production of plastic masses from mixtures of dicarboxylic acid esters | |
| DE601323C (en) | Process for the production of synthetic compositions from polyvinyl chloride | |
| DE889072C (en) | Process for the production of flooring materials | |
| DE929577C (en) | Process for the production of urea-formaldehyde condensation products modified with alcohol and fatty acid amide | |
| DE611056C (en) | Process for the production of resinous condensation products from polybasic organic acids and saturated aliphatic polyoxymonocarboxylic acids | |
| DE902553C (en) | Plasticizers | |
| DE682016C (en) | Process for the production of flooring materials |