DE69325552D1 - Manganoxide, ihre Herstellung und ihre Anwendung - Google Patents

Manganoxide, ihre Herstellung und ihre Anwendung

Info

Publication number
DE69325552D1
DE69325552D1 DE69325552T DE69325552T DE69325552D1 DE 69325552 D1 DE69325552 D1 DE 69325552D1 DE 69325552 T DE69325552 T DE 69325552T DE 69325552 T DE69325552 T DE 69325552T DE 69325552 D1 DE69325552 D1 DE 69325552D1
Authority
DE
Germany
Prior art keywords
production
application
manganese oxides
manganese
oxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69325552T
Other languages
English (en)
Other versions
DE69325552T2 (de
Inventor
Masaki Okada
Takashi Mouri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Publication of DE69325552D1 publication Critical patent/DE69325552D1/de
Application granted granted Critical
Publication of DE69325552T2 publication Critical patent/DE69325552T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Complex oxides containing cobalt and at least one other metal element
    • C01G51/42—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2
    • C01G51/44—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/52—Complex oxides containing cobalt and at least one other metal element containing alkali metals, e.g. LiCoO2 containing manganese of the type (Mn2O4)2-, e.g. Li2(CoxMn2-x)O4 or Li2(MyCoxMn2-x-y)O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/02—Amorphous compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/20—Two-dimensional structures
    • C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C01P2006/82—Compositional purity water content
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
DE69325552T 1992-07-29 1993-07-29 Manganoxide, ihre Herstellung und ihre Anwendung Expired - Fee Related DE69325552T2 (de)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP22089392 1992-07-29
JP32073392 1992-11-30
JP32073292 1992-11-30
JP32446992 1992-12-03
JP32446792 1992-12-03
JP32941192 1992-12-09

Publications (2)

Publication Number Publication Date
DE69325552D1 true DE69325552D1 (de) 1999-08-12
DE69325552T2 DE69325552T2 (de) 2000-03-23

Family

ID=27553966

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69325552T Expired - Fee Related DE69325552T2 (de) 1992-07-29 1993-07-29 Manganoxide, ihre Herstellung und ihre Anwendung

Country Status (3)

Country Link
US (1) US5672329A (de)
EP (1) EP0581290B1 (de)
DE (1) DE69325552T2 (de)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
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US5506077A (en) * 1993-06-14 1996-04-09 Koksbang; Rene Manganese oxide cathode active material
US5637545A (en) * 1994-12-21 1997-06-10 Uop Metallo manganese oxides
US5772898A (en) * 1994-12-21 1998-06-30 Uop Llc Hydrocarbon conversion process using novel metallo manganese oxides
GB9600772D0 (en) 1996-01-15 1996-03-20 Univ St Andrews Improvements in and relating to electrochemical cells
FR2751135A1 (fr) * 1996-07-12 1998-01-16 Accumulateurs Fixes Electrode de generateur electrochimique rechargeable au lithium
JP2990088B2 (ja) * 1997-02-28 1999-12-13 日本電気株式会社 マンガン含有複合酸化物，およびその複合酸化物を用いた複合ぺロブスカイト化合物組成物の製造方法
JP4326041B2 (ja) 1997-05-15 2009-09-02 エフエムシー・コーポレイション ドープされた層間化合物およびその作製方法
CA2240805C (en) 1997-06-19 2005-07-26 Tosoh Corporation Spinel-type lithium-manganese oxide containing heteroelements, preparation process and use thereof
US6506493B1 (en) * 1998-11-09 2003-01-14 Nanogram Corporation Metal oxide particles
US7384680B2 (en) 1997-07-21 2008-06-10 Nanogram Corporation Nanoparticle-based power coatings and corresponding structures
US6465129B1 (en) 1998-05-01 2002-10-15 Regents Of The University Of Minnesota Lithium batteries with new manganese oxide materials as lithium intercalation hosts
US6267943B1 (en) 1998-10-15 2001-07-31 Fmc Corporation Lithium manganese oxide spinel compound and method of preparing same
US6428766B1 (en) * 1998-10-27 2002-08-06 Toda Kogyo Corporation Manganese oxide, lithium manganese complex oxide and cobalt-coated lithium manganese complex oxide, and preparation processes thereof
DK1137598T3 (da) 1998-11-13 2003-08-18 Fmc Corp Lagdelte lithiummetaloxider, der er fri for lokale kubiske spinellignende struktuelle faser, og fremgangsmåder til fremstilling af samme
TW438721B (en) 1998-11-20 2001-06-07 Fmc Corp Multiple doped lithium manganese oxide compounds and methods of preparing same
US6579475B2 (en) 1999-12-10 2003-06-17 Fmc Corporation Lithium cobalt oxides and methods of making same
JP3611188B2 (ja) * 2000-03-03 2005-01-19 日産自動車株式会社 非水電解質二次電池用正極活物質および非水電解質二次電池
WO2003060019A1 (en) * 2002-01-04 2003-07-24 University Of Dayton Non-toxic corrosion protection pigments based on cobalt
US7235142B2 (en) * 2002-01-04 2007-06-26 University Of Dayton Non-toxic corrosion-protection rinses and seals based on cobalt
US7294211B2 (en) * 2002-01-04 2007-11-13 University Of Dayton Non-toxic corrosion-protection conversion coats based on cobalt
US6818313B2 (en) * 2002-07-24 2004-11-16 University Of Dayton Corrosion-inhibiting coating
US20040011252A1 (en) * 2003-01-13 2004-01-22 Sturgill Jeffrey A. Non-toxic corrosion-protection pigments based on manganese
US20030221590A1 (en) * 2003-01-13 2003-12-04 Sturgill Jeffrey A. Non-toxic corrosion-protection pigments based on permanganates and manganates
WO2012023357A1 (ja) * 2010-08-19 2012-02-23 三井金属鉱業株式会社 酸化マンガン粒子及びその製造方法
DE102012005015B4 (de) 2012-03-07 2025-02-13 Friedrich-Schiller-Universität Jena Verfahren zur einfachen Synthese von Birnessit
KR101339553B1 (ko) * 2012-03-22 2013-12-10 삼성전기주식회사 세라믹 전자부품용 비자성체 조성물, 이를 이용한 세라믹 전자부품 및 이의 제조방법
JP6067446B2 (ja) * 2012-04-02 2017-01-25 東レ・ファインケミカル株式会社 二酸化マンガンおよび硬化型組成物の製造方法
US9246170B2 (en) 2013-03-27 2016-01-26 Toyota Motor Engineering & Manufacturing North America, Inc. MgMn2O4 with a crystal structure analogue to CaFe2O4, CaMn2O4, or CaTi2O4 as rechargeable magnesium battery cathode
WO2016152141A1 (ja) * 2015-03-24 2016-09-29 クラリアント触媒株式会社 水溶液中のルテニウム吸着剤、及び水溶液中のルテニウムの吸着処理方法
CN107986335A (zh) * 2017-12-14 2018-05-04 上海第二工业大学 一种采用废旧三元动力锂电池正极材料制备二氧化锰颗粒的方法
CN108539172B (zh) * 2018-04-19 2020-05-29 吉首大学 高功率水系锌离子电池复合球形正极材料的制备方法
CN110391091B (zh) * 2019-08-22 2021-05-11 西北民族大学 Mn7O13·5H2O/α-Fe2O3复合材料的制备方法、制备产物及应用
CN114229907B (zh) * 2021-11-24 2024-03-12 广东邦普循环科技有限公司 一种锰酸锌负极材料的制备方法
CN115000394B (zh) * 2022-05-18 2024-04-12 安徽信息工程学院 一种电化学材料及其制备方法和应用
CN116565183B (zh) * 2023-07-06 2023-11-17 宁德时代新能源科技股份有限公司 正极活性材料及其制备方法、正极极片、电池和用电装置

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US4049790A (en) * 1976-06-03 1977-09-20 Exxon Research & Engineering Co. Layered manganese compound of the formula CA2 MN3 O8
US4246253A (en) * 1978-09-29 1981-01-20 Union Carbide Corporation MnO2 derived from LiMn2 O4
US4312930A (en) * 1978-09-29 1982-01-26 Union Carbide Corporation MnO2 Derived from LiMn2 O4
US4388294A (en) * 1981-07-31 1983-06-14 Exxon Research And Engineering Co. Oxygen deficient manganese perovskites
US4520005A (en) * 1983-11-02 1985-05-28 Ford Motor Company Method of making a compound
JPS62270420A (ja) * 1986-05-15 1987-11-24 Agency Of Ind Science & Technol 新規なマンガン化合物及びその製造方法
IN172479B (de) * 1988-03-08 1993-08-21 Elkem As
JPH0649577B2 (ja) * 1989-04-25 1994-06-29 工業技術院長 新規なマンガン化合物及びその製造方法
JPH03112816A (ja) * 1989-09-26 1991-05-14 Tosoh Corp ＺｎｘＭｎ↓３―ｘＯ↓４の合成方法
DE4025208A1 (de) * 1990-08-09 1992-02-13 Varta Batterie Elektrochemisches sekundaerelement

Also Published As

Publication number Publication date
US5672329A (en) 1997-09-30
DE69325552T2 (de) 2000-03-23
EP0581290B1 (de) 1999-07-07
EP0581290A1 (de) 1994-02-02

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