DE69617543D1 - Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung - Google Patents

Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung

Info

Publication number
DE69617543D1
DE69617543D1 DE69617543T DE69617543T DE69617543D1 DE 69617543 D1 DE69617543 D1 DE 69617543D1 DE 69617543 T DE69617543 T DE 69617543T DE 69617543 T DE69617543 T DE 69617543T DE 69617543 D1 DE69617543 D1 DE 69617543D1
Authority
DE
Germany
Prior art keywords
catalysts
production
olefin polymerization
metallocene compounds
metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69617543T
Other languages
English (en)
Other versions
DE69617543T3 (de
DE69617543T2 (de
Inventor
Luigi Resconi
Fabrizio Piemontesi
Ev Ilya E Nifant
Pavel V Ivchenko
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69617543(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Technology Co BV filed Critical Basell Technology Co BV
Publication of DE69617543D1 publication Critical patent/DE69617543D1/de
Application granted granted Critical
Publication of DE69617543T2 publication Critical patent/DE69617543T2/de
Publication of DE69617543T3 publication Critical patent/DE69617543T3/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69617543T 1995-01-23 1996-01-17 Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung Expired - Lifetime DE69617543T3 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
ITMI950099 1995-01-23
PCT/EP1996/000171 WO1996022995A1 (en) 1995-01-23 1996-01-17 Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins

Publications (3)

Publication Number Publication Date
DE69617543D1 true DE69617543D1 (de) 2002-01-17
DE69617543T2 DE69617543T2 (de) 2002-08-01
DE69617543T3 DE69617543T3 (de) 2007-01-18

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69617543T Expired - Lifetime DE69617543T3 (de) 1995-01-23 1996-01-17 Metallocenverbindungen, verfahren zu ihrer herstellung und ihre verwendung in katalysatoren für die olefinpolymerisierung

Country Status (24)

Country Link
US (3) US6051728A (de)
EP (1) EP0751946B2 (de)
JP (1) JP3838662B2 (de)
KR (2) KR100418106B1 (de)
CN (2) CN1075076C (de)
AR (1) AR000776A1 (de)
AU (1) AU700256B2 (de)
BG (1) BG100904A (de)
BR (1) BR9606373A (de)
CA (1) CA2186232A1 (de)
CZ (1) CZ309596A3 (de)
DE (1) DE69617543T3 (de)
ES (1) ES2167539T5 (de)
FI (1) FI963759A7 (de)
HU (1) HUP9602907A3 (de)
IL (1) IL116853A (de)
IT (1) IT1272923B (de)
MX (1) MX9604229A (de)
PL (1) PL185055B1 (de)
RU (1) RU2177948C2 (de)
TR (1) TR199600720T1 (de)
TW (1) TW319777B (de)
WO (1) WO1996022995A1 (de)
ZA (1) ZA96485B (de)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
BR9715006B1 (pt) * 1996-11-15 2011-06-28 metalocenos heterocìclicos, ligantes, sistema catalìtico e processo para a polimerização de monÈmeros polimerizáveis por adição.
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
CZ434598A3 (cs) 1997-03-29 1999-08-11 Montell Technology Company B. V. Metalocenové sloučeniny
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
DE69918013T2 (de) 1998-04-21 2005-07-14 Basell Polyolefine Gmbh Verfahren zur herstellung von copolymeren aus ethylen und alpha-olefinen
HUP0100215A3 (en) * 1998-07-02 2001-12-28 Montell Technology Company Bv Process for the preparation of substantially amorphous alpha-ol
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
WO2001062764A1 (en) 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
AU5620301A (en) 2000-03-22 2001-10-03 Basell Technology Company B.V. Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof
EP1222216B1 (de) 2000-05-24 2004-12-29 Basell Polyolefine GmbH Propylenpolymere und verfahren zur ihrer herstellung
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
US7183332B2 (en) 2000-12-22 2007-02-27 Basell Poliolefine Italia S.P.A. Process for the preparation of porous polymers and polymers obtainable thereof
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
US7417006B2 (en) 2001-05-21 2008-08-26 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
CN1315919C (zh) * 2001-07-19 2007-05-16 尤尼威蒂恩技术有限责任公司 具有改进物理性能的聚乙烯薄膜
AU2002354949B2 (en) 2001-07-19 2005-06-23 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
CA2454521A1 (en) * 2001-07-19 2003-01-30 Univation Technologies, Llc Mixed metallocene catalyst systems containing a poor comonomer incorporator and a good comonomer incorporator
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
JP2005510590A (ja) 2001-11-27 2005-04-21 バセル ポリオレフィン ジーエムビーエイチ ポリマー組成物の処理の方法
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)
AU2003279668A1 (en) 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
US7700690B2 (en) * 2002-06-26 2010-04-20 Basell Poliolefine Italia S.R.L. Impact-resistant polyolefin compositions
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
AU2003273400A1 (en) * 2002-10-10 2004-05-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
ES2394304T3 (es) 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
WO2004092228A1 (en) 2003-04-17 2004-10-28 Basell Poliolefine Italia S.R.L. Gas-phase olefin polymerization process
JP4709748B2 (ja) 2003-07-04 2011-06-22 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン重合方法
EP1564226A1 (de) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Katalysatorsystem auf Basis von Titanocene
WO2005095468A2 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefin
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
WO2005095473A1 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
EP1655314A1 (de) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Polymerisationsverfahren von 1-buten mit propen
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
WO2006053911A1 (en) 2004-11-22 2006-05-26 Basell Polyolefine Gmbh Propylene based terpolymers
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
WO2006067214A1 (en) * 2004-12-23 2006-06-29 Basell Poliolefine Italia S.R.L. Fibres having elastic properties
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
EP2231724B1 (de) 2007-12-18 2011-08-10 Basell Polyolefine GmbH Gasphasenverfahren zur polymerisation von alpha-olefinen
WO2009088033A1 (ja) * 2008-01-11 2009-07-16 Mitsui Chemicals, Inc. 変性プロピレン樹脂
EP2247424B1 (de) * 2008-02-29 2012-07-04 Basell Poliolefine Italia S.r.l. Polyolefinzusammensetzungen
CN102216349A (zh) * 2008-11-18 2011-10-12 北欧化工公司 在茂金属催化剂存在下所生产的丙烯-丁烯无规共聚物
EP2341086A1 (de) † 2009-12-30 2011-07-06 Borealis AG BOPP-Folie
EP3301119B1 (de) 2013-07-17 2021-03-17 ExxonMobil Chemical Patents Inc. Isotaktische propylenpolymere
CN105358586A (zh) * 2013-07-17 2016-02-24 埃克森美孚化学专利公司 环丙基取代的茂金属催化剂
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
EP3022235B1 (de) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocene und katalysatorzusammensetzungen daraus
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022234B1 (de) 2013-07-17 2018-12-26 ExxonMobil Chemical Patents Inc. Substituierte metallocenkatalysatoren
KR101599978B1 (ko) * 2013-09-30 2016-03-04 주식회사 엘지화학 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체
CN107075008B (zh) * 2014-12-15 2020-01-21 Lg化学株式会社 金属茂化合物、负载金属茂的催化剂以及使用该负载金属茂的催化剂制备聚烯烃的方法
KR101826253B1 (ko) 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
EP3548525A1 (de) * 2016-12-05 2019-10-09 ExxonMobil Chemical Patents Inc. Metallocenpolyethylene mit breiter orthogonaler verteilung für filme
EP3694811B1 (de) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Unterstütztes katalysatorsystem

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
EP0284708B1 (de) * 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
WO1990007526A1 (fr) * 1988-12-26 1990-07-12 Mitsui Petrochemical Industries, Ltd. Copolymeres olefines et leur production
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
ES2155492T3 (es) * 1991-05-27 2001-05-16 Basell Polyolefine Gmbh Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares.
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
DE59309424D1 (de) * 1992-08-15 1999-04-15 Targor Gmbh Verfahren zur Herstellung von Polyolefinen
TW272985B (de) * 1992-09-11 1996-03-21 Hoechst Ag
EP0588208A3 (en) * 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
DE69434709T2 (de) * 1993-06-07 2006-10-19 Mitsui Chemicals, Inc. Propylenelastomere
DE69427999T3 (de) * 1993-06-07 2012-09-27 Mitsui Chemicals, Inc. Übergangsmetallverbindung, diese enthaltende Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit und Homo- und Copolymere des Propylens
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Also Published As

Publication number Publication date
MX9604229A (es) 1997-12-31
CN1150430A (zh) 1997-05-21
ES2167539T3 (es) 2002-05-16
IL116853A (en) 2000-09-28
ZA96485B (en) 1996-08-13
IT1272923B (it) 1997-07-01
JPH09510994A (ja) 1997-11-04
AU700256B2 (en) 1998-12-24
IL116853A0 (en) 1996-07-23
KR100414759B1 (ko) 2004-01-13
DE69617543T3 (de) 2007-01-18
CN1075076C (zh) 2001-11-21
BR9606373A (pt) 2004-06-29
FI963759A0 (fi) 1996-09-20
PL185055B1 (pl) 2003-02-28
TW319777B (de) 1997-11-11
CN1355256A (zh) 2002-06-26
US6051728A (en) 2000-04-18
EP0751946B2 (de) 2006-08-09
KR100418106B1 (ko) 2004-04-30
ITMI950099A1 (it) 1996-07-23
EP0751946B1 (de) 2001-12-05
US6518386B1 (en) 2003-02-11
AU4536696A (en) 1996-08-14
PL316387A1 (en) 1997-01-06
FI963759L (fi) 1996-09-20
HUP9602907A3 (en) 1997-12-29
FI963759A7 (fi) 1996-09-20
RU2177948C2 (ru) 2002-01-10
BG100904A (bg) 1997-07-31
CA2186232A1 (en) 1996-08-01
ES2167539T5 (es) 2007-04-01
JP3838662B2 (ja) 2006-10-25
AR000776A1 (es) 1997-08-06
CN1196721C (zh) 2005-04-13
KR970701723A (ko) 1997-04-12
EP0751946A1 (de) 1997-01-08
ITMI950099A0 (it) 1995-01-23
CZ309596A3 (en) 1997-04-16
HUP9602907A2 (en) 1997-05-28
TR199600720T1 (tr) 1997-03-21
WO1996022995A1 (en) 1996-08-01
DE69617543T2 (de) 2002-08-01
US20030120015A1 (en) 2003-06-26

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