ZA96485B - Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins - Google Patents

Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins

Info

Publication number
ZA96485B
ZA96485B ZA96485A ZA96485A ZA96485B ZA 96485 B ZA96485 B ZA 96485B ZA 96485 A ZA96485 A ZA 96485A ZA 96485 A ZA96485 A ZA 96485A ZA 96485 B ZA96485 B ZA 96485B
Authority
ZA
South Africa
Prior art keywords
olefins
catalysts
polymerization
preparation
metallocene compounds
Prior art date
Application number
ZA96485A
Other languages
English (en)
Inventor
Luigi Resconi
Fabrizio Piemontesi
Ev Ilya E Nifant
Pavel V Ivchenko
Original Assignee
Montell Technology Company Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ZA96485(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv
Publication of ZA96485B publication Critical patent/ZA96485B/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
ZA96485A 1995-01-23 1996-01-22 Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins ZA96485B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Publications (1)

Publication Number Publication Date
ZA96485B true ZA96485B (en) 1996-08-13

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA96485A ZA96485B (en) 1995-01-23 1996-01-22 Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins

Country Status (24)

Country Link
US (3) US6051728A (de)
EP (1) EP0751946B2 (de)
JP (1) JP3838662B2 (de)
KR (2) KR100418106B1 (de)
CN (2) CN1075076C (de)
AR (1) AR000776A1 (de)
AU (1) AU700256B2 (de)
BG (1) BG100904A (de)
BR (1) BR9606373A (de)
CA (1) CA2186232A1 (de)
CZ (1) CZ309596A3 (de)
DE (1) DE69617543T3 (de)
ES (1) ES2167539T5 (de)
FI (1) FI963759A0 (de)
HU (1) HUP9602907A3 (de)
IL (1) IL116853A (de)
IT (1) IT1272923B (de)
MX (1) MX9604229A (de)
PL (1) PL185055B1 (de)
RU (1) RU2177948C2 (de)
TR (1) TR199600720T1 (de)
TW (1) TW319777B (de)
WO (1) WO1996022995A1 (de)
ZA (1) ZA96485B (de)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
PL188107B1 (pl) * 1996-11-15 2004-12-31 Montell Technology Company Bv Metalocen, układ katalityczny do polimeryzacji, kationowe metaloceny, ligand oraz sposób polimeryzacji
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
PL330222A1 (en) 1997-03-29 1999-05-10 Montell Technology Company Bv Metalocenes and catalysts for use in polymerisation of olefins
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
CN1272852A (zh) 1998-04-21 2000-11-08 蒙特尔技术有限公司 乙烯与α－烯烃共聚物的制备方法
WO2000001738A2 (en) * 1998-07-02 2000-01-13 Montell Technology Company Bv Process for the preparation of substantially amorphous alpha-olefin polymers, compositions containing them and process for the preparation of bridged ligand
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE60103702T2 (de) 2000-02-24 2005-06-23 Basell Polyolefine Gmbh Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist
PL353055A1 (en) 2000-03-22 2003-10-06 Basell Technology Company B.V. Thermoplastic compositions of isotactic propylene polymers and flexible propylene polymers having reduced isotacticity and a process for the preparation thereof
DE60108062T2 (de) * 2000-05-24 2005-06-02 Basell Polyolefine Gmbh Propylenpolymere und verfahren zur ihrer herstellung
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
DE60135311D1 (de) 2000-12-22 2008-09-25 Basell Polyolefine Gmbh Katalysatorkomponente fur die polymerisation von olefinen
JP2004516365A (ja) 2000-12-22 2004-06-03 バセル ポリオレフィン イタリア エス．ピー．エー． 多孔性ポリマーの製造方法およびそれから得られるポリマー
US7417006B2 (en) 2001-05-21 2008-08-26 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
CA2454060A1 (en) 2001-07-19 2003-01-30 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
AU2002320633B2 (en) 2001-07-19 2005-08-25 Univation Technologies, Llc Polyethylene films with improved physical properties
MXPA04000550A (es) * 2001-07-19 2005-02-17 Univation Tech Llc Sistemas catalizadores de metaloceno mixtos, conteniendo un incorporador de co-monomero pobre y un buen incorporador de co-monomero.
US7022793B2 (en) 2001-11-27 2006-04-04 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)
RU2308470C2 (ru) 2002-06-26 2007-10-20 Базелль Полиолефин Италия С.П.А. Ударопрочные полиолефиновые композиции
AU2003242663A1 (en) * 2002-06-26 2004-01-19 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
US7569647B2 (en) * 2002-10-10 2009-08-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
ES2394304T3 (es) * 2002-10-15 2013-01-30 Exxonmobil Chemical Patents, Inc. Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos
EP1613668B1 (de) 2003-04-17 2012-08-08 Basell Poliolefine Italia S.r.l. Verfahren zur olefin- gasphasenpolymerisation
CN101163723B (zh) 2003-07-04 2010-12-22 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
EP1564226A1 (de) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Katalysatorsystem auf Basis von Titanocene
EP1723184A1 (de) 2004-03-12 2006-11-22 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
EP1735355B1 (de) 2004-03-12 2010-09-29 Basell Polyolefine GmbH Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
BRPI0508155A (pt) 2004-03-12 2007-08-07 Basell Polyolefine Gmbh sistema catalìtico para a polimerização de olefinas
EP1655314A1 (de) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Polymerisationsverfahren von 1-buten mit propen
EP1814922A1 (de) 2004-11-22 2007-08-08 Basell Polyolefine GmbH Propylenbasierte terpolymere
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
JP2008523231A (ja) * 2004-12-13 2008-07-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィン繊維
CN101087905B (zh) * 2004-12-23 2010-12-15 巴塞尔聚烯烃意大利有限责任公司 具有弹性的纤维
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
US8084557B2 (en) 2007-12-18 2011-12-27 Basell Polyolefine Gmbh Gas-phase process for the polymerization of alpha-olefins
US20100280153A1 (en) * 2008-01-11 2010-11-04 Keita Itakura Modified propylene resin
BRPI0908411B1 (pt) * 2008-02-29 2018-10-30 Basell Poliolefine Italia Srl composições de poliolefinas
WO2010057841A1 (en) 2008-11-18 2010-05-27 Borealis Ag Propylene-butene random copolymer produced in the presence of a mettalocene catalyst
EP2341086A1 (de) † 2009-12-30 2011-07-06 Borealis AG BOPP-Folie
EP3848401A1 (de) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotaktische propylenpolymere
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
ES2703344T3 (es) 2013-07-17 2019-03-08 Exxonmobil Chemical Patents Inc Metalocenos y composiciones catalíticas derivadas de ellos
US9834628B2 (en) 2013-07-17 2017-12-05 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
EP3022238B1 (de) 2013-07-17 2017-09-20 ExxonMobil Chemical Patents Inc. Metallocene und katalysatorzusammensetzungen daraus
KR101599978B1 (ko) * 2013-09-30 2016-03-04 주식회사 엘지화학 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체
JP6440832B2 (ja) * 2014-12-15 2018-12-19 エルジー・ケム・リミテッド メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法
KR101826253B1 (ko) * 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
BR112019011558B1 (pt) * 2016-12-05 2023-01-17 Exxonmobil Chemical Patents Inc Polietilenos de metaloceno que compreende unidades derivadas de etileno, seu processo de formação e películas
EP3694811B1 (de) 2017-10-11 2024-04-03 Basell Polyolefine GmbH Unterstütztes katalysatorsystem

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
EP0284708B1 (de) * 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE68928696T2 (de) * 1988-12-26 1998-12-03 Mitsui Chemicals, Inc., Tokio/Tokyo Olefin-kopolymer und verfahren zur herstellung
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
EP0485821B1 (de) * 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
AU9159191A (en) * 1990-12-28 1992-08-17 Exxon Chemical Patents Inc. Syndiotactic polypropylene
DE59209897D1 (de) * 1991-05-27 2001-04-26 Targor Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
TW272985B (de) * 1992-09-11 1996-03-21 Hoechst Ag
EP0588208A3 (en) * 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
EP0629632B2 (de) 1993-06-07 2015-01-21 Mitsui Chemicals, Inc. Polypropylen
DE69434709T2 (de) * 1993-06-07 2006-10-19 Mitsui Chemicals, Inc. Propylenelastomere
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Also Published As

Publication number Publication date
US20030120015A1 (en) 2003-06-26
IT1272923B (it) 1997-07-01
DE69617543T3 (de) 2007-01-18
CN1196721C (zh) 2005-04-13
PL185055B1 (pl) 2003-02-28
IL116853A0 (en) 1996-07-23
KR100418106B1 (ko) 2004-04-30
CN1075076C (zh) 2001-11-21
PL316387A1 (en) 1997-01-06
EP0751946A1 (de) 1997-01-08
DE69617543T2 (de) 2002-08-01
JP3838662B2 (ja) 2006-10-25
JPH09510994A (ja) 1997-11-04
TW319777B (de) 1997-11-11
ITMI950099A0 (it) 1995-01-23
HUP9602907A2 (en) 1997-05-28
EP0751946B1 (de) 2001-12-05
DE69617543D1 (de) 2002-01-17
FI963759A7 (fi) 1996-09-20
US6518386B1 (en) 2003-02-11
ES2167539T3 (es) 2002-05-16
TR199600720T1 (tr) 1997-03-21
HUP9602907A3 (en) 1997-12-29
AU700256B2 (en) 1998-12-24
FI963759L (fi) 1996-09-20
ITMI950099A1 (it) 1996-07-23
US6051728A (en) 2000-04-18
IL116853A (en) 2000-09-28
BG100904A (bg) 1997-07-31
BR9606373A (pt) 2004-06-29
CZ309596A3 (en) 1997-04-16
CN1355256A (zh) 2002-06-26
KR970701723A (ko) 1997-04-12
WO1996022995A1 (en) 1996-08-01
MX9604229A (es) 1997-12-31
EP0751946B2 (de) 2006-08-09
AU4536696A (en) 1996-08-14
CA2186232A1 (en) 1996-08-01
AR000776A1 (es) 1997-08-06
FI963759A0 (fi) 1996-09-20
RU2177948C2 (ru) 2002-01-10
ES2167539T5 (es) 2007-04-01
CN1150430A (zh) 1997-05-21
KR100414759B1 (ko) 2004-01-13

Similar Documents

Publication Publication Date Title
ZA96485B (en) Metallocene compounds process for the preparation and their use in catalysts for the polymerization of olefins
ZA943595B (en) Supported metallocene catalyst systems for the polymerization of olefins preparation and use thereof
PL330222A1 (en) Metalocenes and catalysts for use in polymerisation of olefins
HUP0001325A3 (en) Catalysts and process for the polymerization of olefins
ZA9810179B (en) Metallocenes and catalysts for the polymerization of olefins containing them
IL117114A0 (en) Components and catalysts for the polymerization of olefins
ZA965078B (en) Catalyst and process for the preparation of hydrocarbons
PL349318A1 (en) Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
HUT60294A (en) Process for producing and applying catalyst component and catalyst usable in the polymerization of olefins
FI955822A0 (fi) Metalloseeniyhdisteitä ja niiden käyttö katalyytteihin olefiinien polymeroinnissa
AU5577290A (en) Syndio-isoblock olefin polymers and process for their preparation
SG65014A1 (en) Prepolymerized solid catalyst process for preparing the same and process for heterogeneous polymerization of olefins
IL118339A0 (en) Solid titanium catalyst component ethylene polymerization catalyst containing the same and ethylene polymerization process
ITMI950410A0 (it) Composti metallocenici bis-fluorenilici procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
HU9502707D0 (en) Compositions useful for olefin polymerization and process therefor and use thereof
HUT68128A (en) Process for the preparation of a ziegler-natta type catalyst and use thereof
AU3669295A (en) Catalyst system for olefin polymerization and process for the polymerization of at least one olefin in the presence of this catalyst system
HU9502334D0 (en) Catalyst and polymerization of olefins
ZA989699B (en) Catalysts for the polymerization of olefins and process for the preparation thereof
SI0684263T1 (en) Catalyst for the (co)polymerization of ethylene and process for its preparation
ZA956008B (en) Catalyst use thereof and process for preparation thereof
ZA984651B (en) Metallocene compounds and their use in catalysts for the polymerization of olefins
ZA949285B (en) Metallocenes,process for their preparation and their use as catalysts
GB8926800D0 (en) Process for the preparation of catalysts and for their use in the polymerisation of olefins
IL133921A0 (en) A process for polymerization of olefins in the presence of metallocenes