DE735096C - Verfahren zur Herstellung von Sulfonsaeuren - Google Patents

Verfahren zur Herstellung von Sulfonsaeuren

Info

Publication number: DE735096C
Authority: DE; Germany
Prior art keywords: hydrocarbons; sulfur dioxide; production; acids; oil
Prior art date: 1940-12-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DEI68390D

Other languages

German (de)

English (en)

Inventor

Aktiengesellsc Farbenindustrie

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

IG Farbenindustrie AG

Original Assignee

IG Farbenindustrie AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1940-12-09

Filing date

1940-12-10

Publication date

1943-05-06

1940-12-10 Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG

1943-05-06 Application granted granted Critical

1943-05-06 Publication of DE735096C publication Critical patent/DE735096C/de

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 7
238000004519 manufacturing process Methods 0.000 title claims description 3
239000002253 acid Substances 0.000 title description 8
150000007513 acids Chemical class 0.000 title description 6
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 22
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
238000006243 chemical reaction Methods 0.000 claims description 9
239000001301 oxygen Substances 0.000 claims description 9
229910052760 oxygen Inorganic materials 0.000 claims description 9
150000003460 sulfonic acids Chemical class 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
229930195733 hydrocarbon Natural products 0.000 description 15
150000002430 hydrocarbons Chemical class 0.000 description 14
239000000203 mixture Substances 0.000 description 12
239000003921 oil Substances 0.000 description 11
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 10
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 7
229910052938 sodium sulfate Inorganic materials 0.000 description 7
235000011152 sodium sulphate Nutrition 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000007789 gas Substances 0.000 description 6
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
239000002904 solvent Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000010453 quartz Substances 0.000 description 3
238000000926 separation method Methods 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
239000001273 butane Substances 0.000 description 2
239000003245 coal Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
-1 hydrocarbons salts Chemical class 0.000 description 2
239000001282 iso-butane Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
229910052753 mercury Inorganic materials 0.000 description 2
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000007787 solid Substances 0.000 description 2
238000010626 work up procedure Methods 0.000 description 2
FKOZPUORKCHONH-UHFFFAOYSA-N 2-methylpropane-1-sulfonic acid Chemical compound CC(C)CS(O)(=O)=O FKOZPUORKCHONH-UHFFFAOYSA-N 0.000 description 1
RUOIPBUNBYUZCK-UHFFFAOYSA-N 2-methylpropane-1-sulfonic acid;sodium Chemical compound [Na].CC(C)CS(O)(=O)=O RUOIPBUNBYUZCK-UHFFFAOYSA-N 0.000 description 1
YDOBHSAXRNUOFX-UHFFFAOYSA-N 3-ethylheptane-1-sulfonic acid Chemical class CCCCC(CC)CCS(O)(=O)=O YDOBHSAXRNUOFX-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
238000007664 blowing Methods 0.000 description 1
238000009835 boiling Methods 0.000 description 1
QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical class CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000003518 caustics Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000012230 colorless oil Substances 0.000 description 1
ZHGASCUQXLPSDT-UHFFFAOYSA-N cyclohexanesulfonic acid Chemical compound OS(=O)(=O)C1CCCCC1 ZHGASCUQXLPSDT-UHFFFAOYSA-N 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000000284 extract Substances 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
238000007654 immersion Methods 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
239000001294 propane Substances 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000011833 salt mixture Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical class OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/14—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by sulfoxidation, i.e. by reaction with sulfur dioxide and oxygen with formation of sulfo or halosulfonyl groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/28—Tubular capacitors
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/30—Stacked capacitors
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G5/00—Capacitors in which the capacitance is varied by mechanical means, e.g. by turning a shaft; Processes of their manufacture
- H01G5/38—Multiple capacitors, e.g. ganged
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H—ELECTRICITY
- H03—ELECTRONIC CIRCUITRY
- H03J—TUNING RESONANT CIRCUITS; SELECTING RESONANT CIRCUITS
- H03J3/00—Continuous tuning
- H03J3/20—Continuous tuning of single resonant circuit by varying inductance only or capacitance only

Landscapes

Engineering & Computer Science (AREA)
Power Engineering (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Microelectronics & Electronic Packaging (AREA)
Chemical Kinetics & Catalysis (AREA)
Manufacturing & Machinery (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

DEI68390D 1940-12-09 1940-12-10 Verfahren zur Herstellung von Sulfonsaeuren Expired DE735096C (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DEI0068390		1940-12-09

Publications (1)

Publication Number	Publication Date
DE735096C true DE735096C (de)	1943-05-06

Family

ID=7196871

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DEI68390D Expired DE735096C (de)	1940-12-09	1940-12-10	Verfahren zur Herstellung von Sulfonsaeuren

Country Status (4)

Country	Link
BE (8)	BE443658A (fr)
CH (1)	CH228209A (fr)
DE (1)	DE735096C (fr)
FR (1)	FR877672A (fr)

Cited By (54)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2503280A (en) *	1947-10-24	1950-04-11	Du Pont	Azo catalysts in preparation of sulfonic acids
US2507088A (en) *	1948-01-08	1950-05-09	Du Pont	Sulfoxidation process
DE1014067B (de) *	1953-07-29	1957-08-22	Basf Ag	Netzmittel fuer Merzerisier- und Laugierbaeder
DE967238C (de) *	1953-02-06	1957-10-24	Basf Ag	Leicht emulgierbare oder kolloidal loesliche Wachsprodukte
DE1139116B (de) *	1956-02-03	1962-11-08	Exxon Research Engineering Co	Verfahren zur Herstellung von aliphatischen und cycloaliphatischen Sulfonsaeuren
US3507909A (en) *	1968-01-22	1970-04-21	Phillips Petroleum Co	Production of sulfonate salts of lighter color
US4518537A (en) *	1983-02-07	1985-05-21	Hoechst Aktiengesellschaft	Process for isolating paraffinsulfonate from the reaction mixture obtained on sulfoxidating paraffins
US5075026A (en) *	1986-05-21	1991-12-24	Colgate-Palmolive Company	Microemulsion all purpose liquid cleaning composition
EP0478086A2 (fr)	1990-09-25	1992-04-01	Colgate-Palmolive Company	Composition détergente désinfectante en microémulsion stable
WO2007123566A1 (fr)	2006-04-21	2007-11-01	Colgate-Palmolive Company	Formule pour visibilité et impact de matériaux suspendus
DE102007020697A1 (de)	2007-05-03	2008-11-06	Clariant International Ltd.	Verfahren zur Isolierung konzentrierter Paraffinsulfonsäuren
EP2014755A2 (fr)	2007-05-29	2009-01-14	The Procter and Gamble Company	Méthode pour laver la vaisselle
EP2083066A1 (fr)	2008-01-22	2009-07-29	The Procter and Gamble Company	Composition de détergent liquide
WO2009143091A1 (fr)	2008-05-23	2009-11-26	Colgate-Palmolive Company	Compositions nettoyantes liquides et procédés et fabrication
DE102008032723A1 (de)	2008-07-11	2010-01-14	Clariant International Limited	Verfahren zur Isolierung von Paraffinsulfonsäuren
EP2264136A1 (fr)	2009-06-19	2010-12-22	The Procter & Gamble Company	Composition de détergent liquide pour lavage de la vaisselle à la main
EP2264138A1 (fr)	2009-06-19	2010-12-22	The Procter & Gamble Company	Composition de détergent liquide pour lavage de la vaisselle à la main
EP2308957A1 (fr)	2006-12-15	2011-04-13	Colgate-Palmolive Company	Composition liquide détergente
WO2011084569A1 (fr)	2009-12-17	2011-07-14	The Procter & Gamble Company	Composition détergente permettant de laver la vaisselle et renfermant un composant de neutralisation des mauvaises odeurs et procédés de nettoyage de vaisselle
WO2011087754A1 (fr)	2009-12-22	2011-07-21	The Procter & Gamble Company	Composition detergente de liquide alcalin pour laver la vaisselle a la main
US8030268B2 (en)	2005-02-15	2011-10-04	Colgate-Palmolive Company	Cleaning compositions that provide grease removal and fragrance delivery
EP2420557A1 (fr)	2010-08-17	2012-02-22	The Procter & Gamble Company	Procédé pour laver la vaisselle à la main avec une mousse de longue durée
EP2420558A1 (fr)	2010-08-17	2012-02-22	The Procter & Gamble Company	Détergents stables et émanants de ressources durables pour laver manuellement la vaisselle
WO2012082097A1 (fr)	2010-12-13	2012-06-21	Colgate-Palmolive Company	Composition de nettoyage concentrée à diluer
US8282743B2 (en)	2007-12-18	2012-10-09	Colgate-Palmolive Company	Alkaline cleaning compositions
US8404630B2 (en)	2005-02-15	2013-03-26	Colgate-Palmolive Company	Fragrance compositions that reduce or eliminate malodor, related methods and related cleaning compositions
WO2013086251A1 (fr)	2011-12-09	2013-06-13	The Procter & Gamble Company	Procédé pour un séchage rapide et/ou conférant le brillant à des surfaces dures
US8540823B2 (en)	2009-05-01	2013-09-24	Colgate-Palmolive Company	Liquid cleaning compositions with films
WO2014099226A2 (fr)	2012-12-19	2014-06-26	Colgate-Palmolive Company	Compositions d'hygiène personnel comprenant un halogénure d'acide aminé/triméthylglycine de zinc
US8765655B2 (en)	2007-12-18	2014-07-01	Colgate-Palmolive Company	Degreasing all purpose cleaning compositions and methods
US8785366B2 (en)	2008-05-23	2014-07-22	Colgate-Palmolive Company	Liquid cleaning compositions and methods
US8895492B2 (en)	2010-12-13	2014-11-25	Colgate-Palmolive Company	Dilutable concentrated cleaning composition comprising a divalent metal salt
US9498421B2 (en)	2012-12-19	2016-11-22	Colgate-Palmolive Company	Two component compositions containing tetrabasic zinc-amino acid halide complexes and cysteine
US9498410B2 (en)	2002-12-30	2016-11-22	Colgate-Palmolive Company	Oral and personal care compositions and methods
US9504858B2 (en)	2012-12-19	2016-11-29	Colgate-Palmolive Company	Zinc amino acid halide complex with cysteine
US9572756B2 (en)	2012-12-19	2017-02-21	Colgate-Palmolive Company	Teeth whitening methods, visually perceptible signals and compositions therefor
US9675823B2 (en)	2012-12-19	2017-06-13	Colgate-Palmolive Company	Two component compositions containing zinc amino acid halide complexes and cysteine
WO2017142869A1 (fr)	2016-02-15	2017-08-24	Hercules Llc	Composition d'entretien domestique
US9750670B2 (en)	2012-12-19	2017-09-05	Colgate-Palmolive Company	Zinc amino acid complex with cysteine
US9757316B2 (en)	2012-12-19	2017-09-12	Colgate-Palmolive Company	Zinc-lysine complex
US9763865B2 (en)	2012-12-19	2017-09-19	Colgate-Palmolive Company	Oral gel comprising zinc-amino acid complex
US9775792B2 (en)	2012-12-19	2017-10-03	Colgate-Palmolive Company	Oral care products comprising a tetrabasic zinc-amino acid-halide complex
US9827177B2 (en)	2012-12-19	2017-11-28	Colgate-Palmolive Company	Antiperspirant products with protein and antiperspirant salts
US9861563B2 (en)	2012-12-19	2018-01-09	Colgate-Palmolive Company	Oral care products comprising tetrabasic zinc chloride and trimethylglycine
WO2018017335A1 (fr)	2016-07-22	2018-01-25	The Procter & Gamble Company	Composition détergente pour lavage de vaisselle
US9901523B2 (en)	2012-12-19	2018-02-27	Colgate-Palmolive Company	Oral care products comprising zinc oxide and trimethylglycine
US9925130B2 (en)	2012-12-19	2018-03-27	Colgate-Palmolive Company	Composition with zinc amino acid/trimethylglycine halide precursors
US9943473B2 (en)	2012-12-19	2018-04-17	Colgate-Palmolive Company	Zinc lysine halide complex
US9980890B2 (en)	2012-12-19	2018-05-29	Colgate-Palmolive Company	Zinc amino acid halide mouthwashes
US10105303B2 (en)	2012-12-19	2018-10-23	Colgate-Palmolive Company	Oral care composition comprising zinc amino acid halides
US10188112B2 (en)	2012-12-19	2019-01-29	Colgate-Palmolive Company	Personal cleansing compositions containing zinc amino acid/trimethylglycine halide
WO2020139337A1 (fr)	2018-12-27	2020-07-02	Colgate-Palmolive Company	Compositions d'entretien ménager
WO2020150384A1 (fr)	2019-01-17	2020-07-23	Isp Investments Llc	Procédé de renforcement de fibres non kératiniques et leurs utilisations
EP4074812A1 (fr)	2021-04-15	2022-10-19	Henkel AG & Co. KGaA	Sachet comprenant une composition pour laver la vaisselle à la main

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE910165C (de) *	1943-01-15	1954-04-29	Hoechst Ag	Verfahren zur Herstellung von Sulfonsaeuren
DE872942C (de) *	1948-10-02	1953-04-09	Krupp Kohlechemie G M B H	Verfahren zur Sulfoxydation von sauerstoffhaltigen Derivaten gesaettigter aliphatischer oder cycloaliphatischer Kohlenwasserstoffe

1940
- 1940-12-10 DE DEI68390D patent/DE735096C/de not_active Expired
1941
- 1941-11-15 CH CH228209D patent/CH228209A/de unknown
- 1941-12-09 BE BE443658A patent/BE443658A/fr unknown
- 1941-12-11 FR FR877672D patent/FR877672A/fr not_active Expired
1942
- 1942-02-09 BE BE444546A patent/BE444546R/fr active
- 1942-04-23 BE BE445312A patent/BE445312R/fr active
- 1942-04-27 BE BE445349A patent/BE445349R/fr active
1943
- 1943-04-09 BE BE450081A patent/BE450081R/fr active
1944
- 1944-08-17 BE BE457246A patent/BE457246R/fr active
- 1944-08-17 BE BE457247A patent/BE457247R/fr active
1959
- 1959-03-28 BE BE457245A patent/BE457245R/fr active

Cited By (76)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2503280A (en) *	1947-10-24	1950-04-11	Du Pont	Azo catalysts in preparation of sulfonic acids
US2507088A (en) *	1948-01-08	1950-05-09	Du Pont	Sulfoxidation process
DE967238C (de) *	1953-02-06	1957-10-24	Basf Ag	Leicht emulgierbare oder kolloidal loesliche Wachsprodukte
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Also Published As

Publication number	Publication date
BE444546R (fr)	1942-03-31
BE457245R (fr)	1944-09-30
FR877672A (fr)	1942-12-14
BE457246R (fr)	1944-09-30
BE445312R (fr)	1942-05-30
BE457247R (fr)	1944-09-30
BE445349R (fr)	1942-05-30
BE450081R (fr)	1943-05-31
CH228209A (de)	1943-08-15
BE443658A (fr)	1942-01-31

Publication	Publication Date	Title
DE735096C (de)	1943-05-06	Verfahren zur Herstellung von Sulfonsaeuren
DE910165C (de)	1954-04-29	Verfahren zur Herstellung von Sulfonsaeuren
DE3545775A1 (de)	1986-07-10	Verfahren zum herstellen von methansulfonylchlorid
DE903814C (de)	1954-02-11	Verfahren zur Herstellung von Sulfonierungserzeugnissen
DE1185178B (de)	1965-01-14	Verfahren zur Herstellung von hellfarbigen Olefinsulfonaten
DE907174C (de)	1954-03-22	Verfahren zur Herstellung von Sulfonsaeuren
DE712742C (de)	1941-10-24	Verfahren zur Herstellung von Kaliumsalzen monosubstituierter Acetylene
DE845341C (de)	1952-07-31	Verfahren zur Herstellung von aetzalkaliarmen Alkalialkoholaten
US2205949A (en)	1940-06-25	Alkyl hydroxy aromatic sulphonates
DE887503C (de)	1953-08-24	Verfahren zur Herstellung von Sulfonsaeuren
DE883753C (de)	1953-07-20	Verfahren zur Herstellung von Diazoaminoverbindungen
GB454128A (en)	1936-09-24	Process for the preparation of 1:1-dichlorethane
DE635464C (de)	1936-09-17	Verfahren zur Herstellung von Anthrachinonfarbstoffen
DE903815C (de)	1954-02-11	Verfahren zur Herstellung von Sulfonsaeuren
DE403193C (de)	1924-09-27	Verfahren zur Herstellung von Formaldehydsulfoxylaten
DE847896C (de)	1952-08-28	Verfahren zur Herstellung von Sulfonaten langkettiger Paraffinkohlenwasserstoffe
DE742148C (de)	1943-11-23	Verfahren zur Herstellung von aetherartigen Kondensationsprodukten
DE854516C (de)	1952-11-04	Verfahren zur Herstellung von ausreichend reinen Sulfonsaeuren
DE873239C (de)	1953-04-13	Verfahren zur Herstellung von Sulfonsaeuren bzw. Sulfonaten hochmolekularer Paraffinkohlenwasserstoffe
DE1618147B2 (de)	1975-08-21	Verfahren zur Herstellung der Sulfoniumsalze von Sulfonsäuren
DE572962C (de)	1933-03-25	Verfahren zur Sulfonierung des Phthalsaeureanhydrids
DE916409C (de)	1954-08-09	Verfahren zur Herstellung von Sulfonsaeuren
DE962786C (de)	1957-04-25	Verfahren zur Herstellung von bestaendigen Chlorkohlenwassersstoffen durch alkalische Behandlung
DE859455C (de)	1952-12-15	Verfahren zur Sulfochlorierung von nichtaromatischen gesaettigten Kohlenwasserstoffen
DE884498C (de)	1953-07-27	Verfahren zur kontinuierlichen Sulfochlorierung von Kohlen-wasserstoffen und bzw. oder deren Derivaten und Gemischen