DK0692016T3 - Enzyme preparation for detergents - Google Patents
Enzyme preparation for detergentsInfo
- Publication number
- DK0692016T3 DK0692016T3 DK94912528.0T DK94912528T DK0692016T3 DK 0692016 T3 DK0692016 T3 DK 0692016T3 DK 94912528 T DK94912528 T DK 94912528T DK 0692016 T3 DK0692016 T3 DK 0692016T3
- Authority
- DK
- Denmark
- Prior art keywords
- enzyme
- granulates
- washing
- alkenylpolyethoxylate
- carboxymethylcellulose
- Prior art date
Links
- 102000004190 Enzymes Human genes 0.000 title abstract 6
- 108090000790 Enzymes Proteins 0.000 title abstract 6
- 239000003599 detergent Substances 0.000 title 1
- 239000008187 granular material Substances 0.000 abstract 3
- 238000005406 washing Methods 0.000 abstract 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 2
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 2
- 229920001223 polyethylene glycol Polymers 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Enzymes And Modification Thereof (AREA)
Abstract
In order to improve the solubility, to increase the storage stability and to reduce enzyme activity losses during production of enzyme granulates suitable to be incorporated into washing or cleaning agents and containing an enzyme and an organic and/or inorganic carrier, a granulation-auxiliary system is used which consists of alkali-carboxymethylcellulose with substitution degrees from 0.5 to 1 and of polyethylene glycol and/or alkyl- or alkenylpolyethoxylate. When more than 2 % by weight alkali-carboxymethylcellulose are contained in the granulates, they contain at least 0.5 % by weight polyethylene glycol with less than 1000 mean molar mass and/or alkyl- or alkenylpolyethoxylate with at least 20 ethoxy groups. The new enzyme granulates have such a high speed of decomposition that when they are used in washing agents the wash bath contains enough enzyme to remove enzymatically removable soil already in the initial phase of machine washing.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4310506A DE4310506A1 (en) | 1993-03-31 | 1993-03-31 | Enzyme preparation for detergents and cleaning agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK0692016T3 true DK0692016T3 (en) | 1998-04-20 |
Family
ID=6484354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK94912528.0T DK0692016T3 (en) | 1993-03-31 | 1994-03-23 | Enzyme preparation for detergents |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0692016B1 (en) |
| AT (1) | ATE157394T1 (en) |
| DE (2) | DE4310506A1 (en) |
| DK (1) | DK0692016T3 (en) |
| WO (1) | WO1994023005A1 (en) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4420730A1 (en) * | 1994-06-15 | 1995-12-21 | Henkel Kgaa | Process for the deodorization and stabilization of biotechnologically obtained valuable substances and their aqueous preparations |
| DE69519944T2 (en) * | 1994-11-18 | 2001-06-13 | Genencor International, Inc. | COATED ENZYME GRANULATES |
| US5571446A (en) * | 1995-07-27 | 1996-11-05 | Diversey Corporation | Anionic stabilized enzyme based clean-in-place system |
| DE19545729A1 (en) | 1995-12-08 | 1997-06-12 | Henkel Kgaa | Bleach and detergent with an enzymatic bleaching system |
| DE19600018A1 (en) | 1996-01-03 | 1997-07-10 | Henkel Kgaa | Detergent with certain oxidized oligosaccharides |
| US6235695B1 (en) * | 1996-04-01 | 2001-05-22 | Henkel Kommanditgesellschaft Auf Aktien | Cleaning agent with oligoammine activator complexes for peroxide compounds |
| DE19620411A1 (en) | 1996-04-01 | 1997-10-02 | Henkel Kgaa | Transition metal amine complexes as activators for peroxygen compounds |
| DE19615776A1 (en) * | 1996-04-20 | 1997-10-23 | Henkel Kgaa | Solubility-enhanced enzyme granules |
| DE19616693A1 (en) * | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Enol esters as bleach activators for detergents and cleaning agents |
| DE19619219A1 (en) † | 1996-05-13 | 1997-12-04 | Hoechst Ag | Enzyme pre-granules for animal feed granules |
| DE19649375A1 (en) | 1996-11-29 | 1998-06-04 | Henkel Kgaa | Acetonitrile derivatives as bleach activators in detergents |
| DE19651446A1 (en) | 1996-12-11 | 1998-06-18 | Henkel Kgaa | Enveloped enzyme preparation with improved solubility |
| DE19713852A1 (en) | 1997-04-04 | 1998-10-08 | Henkel Kgaa | Activators for peroxygen compounds in detergents and cleaning agents |
| DE19732749A1 (en) | 1997-07-30 | 1999-02-04 | Henkel Kgaa | Detergent containing glucanase |
| DE19732751A1 (en) | 1997-07-30 | 1999-02-04 | Henkel Kgaa | New Bacillus beta glucanase |
| DE19732750A1 (en) | 1997-07-30 | 1999-02-04 | Henkel Kgaa | Cleaning agent containing glucanase for hard surfaces |
| DE19819187A1 (en) * | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Solid dishwasher detergent with phosphate and crystalline layered silicates |
| DE19824705A1 (en) | 1998-06-03 | 1999-12-09 | Henkel Kgaa | Detergents and cleaning agents containing amylase and protease |
| DE19850100A1 (en) | 1998-10-29 | 2000-05-04 | Henkel Kgaa | Polymer granules through fluidized bed granulation |
| DE19908051A1 (en) | 1999-02-25 | 2000-08-31 | Henkel Kgaa | Process for the preparation of compounded acetonitrile derivatives |
| HUP0300840A2 (en) | 2000-07-28 | 2003-07-28 | Henkel Kommanditgesellschaft Auf Aktien | Novel, amylolytic enzyme ectracted from bacillus sp. a 7-7 (dsm 12368) and washing and cleaning agents containing this novel amylolytic enzyme |
| DE10058645A1 (en) | 2000-11-25 | 2002-05-29 | Clariant Gmbh | Use of cyclic sugar ketones as catalysts for peroxygen compounds |
| ES2290184T3 (en) | 2000-11-28 | 2008-02-16 | Henkel Kommanditgesellschaft Auf Aktien | CYCLODEXTRINE-GLUCANOTRANSPHERASE (CGTASA) FROM BACILLUS AGARADHERENS (DSM 9948) AS WELL AS WASHING AGENTS AND CLEANING IT WITH THIS NEW CYCLODEXTRINE-GLUCANOTRANSPHERASE. |
| DE10102248A1 (en) | 2001-01-19 | 2002-07-25 | Clariant Gmbh | Use of transition metal complexes with oxime ligands as bleach catalysts |
| DE10163748A1 (en) | 2001-12-21 | 2003-07-17 | Henkel Kgaa | New glycosyl hydrolases |
| DE10211389A1 (en) | 2002-03-15 | 2003-09-25 | Clariant Gmbh | Ammonium nitrile compounds, used as activator for peroxide bleach in laundry, dishwasher and other detergents and disinfectants and in bleaching textile, paper and wood are new |
| DE10304131A1 (en) | 2003-02-03 | 2004-08-05 | Clariant Gmbh | Transition metal complexes with nitrogen-containing ligands are used as catalysts for peroxy compounds, especially in detergent, bleaching and cleansing agents |
| ATE432972T1 (en) | 2003-12-13 | 2009-06-15 | Henkel Ag & Co Kgaa | MULTI-COMPONENT THIN-TO-THICK SYSTEM |
| US8361946B2 (en) | 2004-04-08 | 2013-01-29 | Akzo Nobel N.V. | Detergent composition |
| DE102005039580A1 (en) | 2005-08-19 | 2007-02-22 | Henkel Kgaa | Color protecting detergent |
| EP1754781B1 (en) | 2005-08-19 | 2013-04-03 | The Procter and Gamble Company | A solid laundry detergent composition comprising anionic detersive surfactant and a calcium-augmented technology |
| DE102007016391A1 (en) | 2007-04-03 | 2008-10-09 | Henkel Ag & Co. Kgaa | Detergent or cleaning agent for preventing transfer of textile color of colored textiles from uncolored or different colored textiles in laundry, particularly in tenside containing aqueous solution, has color transfer inhibitor |
| DE102007028310A1 (en) | 2007-06-20 | 2008-12-24 | Clariant International Ltd. | Surfactant mixtures with synergistic properties |
| DE102008013606A1 (en) | 2008-03-11 | 2009-09-17 | Clariant International Ltd. | Process for the preparation of solid alkaline earth metal salts of secondary paraffin sulphonic acids |
| BRPI0909022B1 (en) | 2008-04-09 | 2020-11-10 | Basf Se | use of at least one compound, detergent, cleaner, disinfectant or bleach composition, and granule |
| EP2302025B1 (en) | 2009-09-08 | 2016-04-13 | The Procter & Gamble Company | A laundry detergent composition comprising a highly water-soluble carboxmethyl cellulose particle |
| WO2012000846A1 (en) | 2010-06-28 | 2012-01-05 | Basf Se | Metal free bleaching composition |
| PL2651907T3 (en) | 2010-12-13 | 2015-03-31 | Basf Se | Bleach catalysts |
| DE102011010818A1 (en) | 2011-02-10 | 2012-08-16 | Clariant International Ltd. | Use of transition metal complexes as bleaching catalysts in detergents and cleaners |
| DE102014009836B4 (en) | 2014-07-03 | 2017-04-06 | Weylchem Wiesbaden Gmbh | Sodium salts of secondary alkanesulfonates containing compounds, their preparation and use and washing, disinfecting and cleaning agents containing these |
| DE102015217816A1 (en) | 2015-09-17 | 2017-03-23 | Henkel Ag & Co. Kgaa | Use of highly concentrated enzyme granules to increase the storage stability of enzymes |
| WO2017076771A1 (en) | 2015-11-03 | 2017-05-11 | Basf Se | Bleach catalysts |
| EP3176157A1 (en) | 2015-12-01 | 2017-06-07 | Basf Se | Bleach catalysts |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
| EP3372663A1 (en) | 2017-03-10 | 2018-09-12 | Basf Se | Bleach catalysts |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4816188B1 (en) * | 1970-08-27 | 1973-05-19 | ||
| DE3344104A1 (en) * | 1983-12-07 | 1985-06-13 | Henkel KGaA, 4000 Düsseldorf | ENZYME PREPARATION SUITABLE FOR USE IN POWDERED DETERGENTS |
| JPS60168385A (en) * | 1984-02-09 | 1985-08-31 | Showa Denko Kk | Granulation of enzyme |
| DE4041752A1 (en) * | 1990-12-24 | 1992-06-25 | Henkel Kgaa | ENZYME PREPARATION FOR WASHING AND CLEANING AGENTS |
-
1993
- 1993-03-31 DE DE4310506A patent/DE4310506A1/en not_active Withdrawn
-
1994
- 1994-03-23 WO PCT/EP1994/000934 patent/WO1994023005A1/en not_active Ceased
- 1994-03-23 DE DE59403879T patent/DE59403879D1/en not_active Expired - Fee Related
- 1994-03-23 EP EP94912528A patent/EP0692016B1/en not_active Expired - Lifetime
- 1994-03-23 AT AT94912528T patent/ATE157394T1/en not_active IP Right Cessation
- 1994-03-23 DK DK94912528.0T patent/DK0692016T3/en active
Also Published As
| Publication number | Publication date |
|---|---|
| ATE157394T1 (en) | 1997-09-15 |
| EP0692016A1 (en) | 1996-01-17 |
| DE59403879D1 (en) | 1997-10-02 |
| EP0692016B1 (en) | 1997-08-27 |
| WO1994023005A1 (en) | 1994-10-13 |
| DE4310506A1 (en) | 1994-10-06 |
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