DK1274652T3 - Fremgangsmåde til rensning af vand ved anvendelse af kationiske dispersionspolymerer med lav molekylvægt - Google Patents
Fremgangsmåde til rensning af vand ved anvendelse af kationiske dispersionspolymerer med lav molekylvægt Download PDFInfo
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- DK1274652T3 DK1274652T3 DK01924243.7T DK01924243T DK1274652T3 DK 1274652 T3 DK1274652 T3 DK 1274652T3 DK 01924243 T DK01924243 T DK 01924243T DK 1274652 T3 DK1274652 T3 DK 1274652T3
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- Prior art keywords
- water
- molecular weight
- polymer
- low molecular
- dispersion
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- 229920000642 polymer Polymers 0.000 title claims description 101
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 66
- 125000002091 cationic group Chemical group 0.000 title claims description 50
- 239000006185 dispersion Substances 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 33
- 230000008569 process Effects 0.000 title claims description 19
- 238000000746 purification Methods 0.000 title 1
- 239000007787 solid Substances 0.000 claims description 40
- 239000007864 aqueous solution Substances 0.000 claims description 27
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 17
- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 125000000129 anionic group Chemical group 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 229920001897 terpolymer Polymers 0.000 claims description 9
- 238000012546 transfer Methods 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 8
- 238000005345 coagulation Methods 0.000 claims description 7
- 230000015271 coagulation Effects 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 claims description 5
- 239000007764 o/w emulsion Substances 0.000 claims 1
- 239000008213 purified water Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 description 32
- 150000003839 salts Chemical group 0.000 description 31
- 239000004815 dispersion polymer Substances 0.000 description 21
- 239000000203 mixture Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- CEJFYGPXPSZIID-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClCC1=CC=CC=C1.CN(C)CCOC(=O)C=C CEJFYGPXPSZIID-UHFFFAOYSA-N 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 239000010802 sludge Substances 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 11
- -1 acrylic compound Chemical class 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
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- 239000000126 substance Substances 0.000 description 11
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
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- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- 241000724205 Rice stripe tenuivirus Species 0.000 description 6
- 239000004280 Sodium formate Substances 0.000 description 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 6
- 235000019254 sodium formate Nutrition 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
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- 125000003545 alkoxy group Chemical group 0.000 description 4
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- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
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- 235000011187 glycerol Nutrition 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
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- 239000008394 flocculating agent Substances 0.000 description 3
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- 125000001188 haloalkyl group Chemical group 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 229940050176 methyl chloride Drugs 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- BHDFTVNXJDZMQK-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C(C)=C BHDFTVNXJDZMQK-UHFFFAOYSA-N 0.000 description 2
- ZTUMLBMROBHIIH-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound ClCC1=CC=CC=C1.CN(C)CCOC(=O)C(C)=C ZTUMLBMROBHIIH-UHFFFAOYSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- DOKHEARVIDLSFF-UHFFFAOYSA-N prop-1-en-1-ol Chemical group CC=CO DOKHEARVIDLSFF-UHFFFAOYSA-N 0.000 description 2
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- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
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- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- WUIJTQZXUURFQU-UHFFFAOYSA-N 1-methylsulfonylethene Chemical compound CS(=O)(=O)C=C WUIJTQZXUURFQU-UHFFFAOYSA-N 0.000 description 1
- FDRMJKDXTZDBHQ-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate;methyl hydrogen sulfate Chemical compound COS([O-])(=O)=O.C[NH+](C)CCOC(=O)C(C)=C FDRMJKDXTZDBHQ-UHFFFAOYSA-N 0.000 description 1
- RFPLNIBCLGFBKV-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate;methyl hydrogen sulfate Chemical compound COS([O-])(=O)=O.C[NH+](C)CCOC(=O)C=C RFPLNIBCLGFBKV-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
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- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
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- 229910002651 NO3 Inorganic materials 0.000 description 1
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- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- OKPYIWASQZGASP-UHFFFAOYSA-N n-(2-hydroxypropyl)-2-methylprop-2-enamide Chemical compound CC(O)CNC(=O)C(C)=C OKPYIWASQZGASP-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
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- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002891 organic anions Chemical class 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004344 phenylpropyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000012086 standard solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000002349 well water Substances 0.000 description 1
- 235000020681 well water Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/682—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of chemical compounds for dispersing an oily layer on water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/147—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using organic substances
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
- C02F11/148—Combined use of inorganic and organic substances, being added in the same treatment step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/001—Runoff or storm water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/553,876 US6398967B2 (en) | 2000-04-20 | 2000-04-20 | Method of clarifying water using low molecular weight cationic dispersion polymers |
| PCT/US2001/009060 WO2001081252A1 (en) | 2000-04-20 | 2001-03-20 | Method of clarifying water using low molecular weight cationic dispersion polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK1274652T3 true DK1274652T3 (da) | 2014-03-10 |
Family
ID=24211126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK01924243.7T DK1274652T3 (da) | 2000-04-20 | 2001-03-20 | Fremgangsmåde til rensning af vand ved anvendelse af kationiske dispersionspolymerer med lav molekylvægt |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6398967B2 (da) |
| EP (1) | EP1274652B1 (da) |
| KR (1) | KR100777638B1 (da) |
| AR (1) | AR028540A1 (da) |
| AU (1) | AU2001250915A1 (da) |
| DK (1) | DK1274652T3 (da) |
| ES (1) | ES2442290T3 (da) |
| TW (1) | TWI246987B (da) |
| WO (1) | WO2001081252A1 (da) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0018314D0 (en) * | 2000-07-27 | 2000-09-13 | Ciba Spec Chem Water Treat Ltd | Processes of reducing contamination from cellulosic suspensions |
| US6712976B2 (en) * | 2001-09-13 | 2004-03-30 | Abtech Industries, Inc. | Dual-action decontamination system |
| NZ536432A (en) * | 2002-05-15 | 2006-07-28 | Akzo Nobel Nv | A water-soluble polymer dispersion and a method of producing a water-soluble polymer dispersion |
| CA2508339C (en) * | 2002-12-02 | 2006-10-24 | Genesis International Oilfield Services Inc. | Drilling fluid and methods of use thereof |
| US6784141B1 (en) * | 2003-04-21 | 2004-08-31 | Halliburton Energy Services, Inc. | Methods, aqueous well treating fluids and friction reducers therefor |
| US7531600B1 (en) | 2003-11-12 | 2009-05-12 | Kroff Chemical Company | Water-in-oil polymer emulsion containing microparticles |
| US7482310B1 (en) | 2003-11-12 | 2009-01-27 | Kroff Chemical Company, Inc. | Method of fracturing subterranean formations utilizing emulsions comprising acrylamide copolymers |
| KR20050058785A (ko) * | 2003-12-12 | 2005-06-17 | 김재봉 | 벤토나이트를 함유하는 수용성 중합체 분산액 및 그의제조방법 |
| US20050173338A1 (en) * | 2004-02-11 | 2005-08-11 | Bretsch Mary K. | Method of treating water for fine suspended solids using confined exposure to a living colony of hydrocotyle ranunculoides |
| US20050215439A1 (en) * | 2004-03-29 | 2005-09-29 | Blair Cecil C | Clay stabilization in sub-surface formations |
| US7160470B2 (en) * | 2004-04-19 | 2007-01-09 | Davis Robert A | Method of clarifying industrial laundry wastewater using cationic dispersion polymers and anionic flocculent polymers |
| US7291275B1 (en) | 2004-04-19 | 2007-11-06 | Davis Robert A | Method for clarifying industrial wastewater while minimizing sludge |
| US20060084771A1 (en) * | 2004-10-15 | 2006-04-20 | Wong Shing Jane B | Method of preparing modified diallyl-N,N-disubstituted ammonium halide polymers |
| US7473334B2 (en) * | 2004-10-15 | 2009-01-06 | Nalco Company | Method of preparing modified diallyl-N,N-disubstituted ammonium halide polymers |
| US8299183B2 (en) | 2004-12-28 | 2012-10-30 | Akzo Nobel N.V. | Polymer dispersion and process for preparing a polymer dispersion |
| US20060289358A1 (en) * | 2005-06-22 | 2006-12-28 | Geospec, Inc. | Methods and apparatus for removing contaminants from storm water |
| US20090035247A1 (en) * | 2007-07-31 | 2009-02-05 | Gabelnick Stephanie E | Method of stabilizing a polysiloxane emulsion and compositions containing stabilized emulsions |
| US8921478B2 (en) * | 2008-10-17 | 2014-12-30 | Nalco Company | Method of controlling gas hydrates in fluid systems |
| US8865632B1 (en) | 2008-11-10 | 2014-10-21 | Cesi Chemical, Inc. | Drag-reducing copolymer compositions |
| CN101812157B (zh) * | 2010-03-31 | 2011-12-21 | 淮阴师范学院 | 聚(n-异丙基丙烯酰胺)/凹凸棒土复合水凝胶的合成方法 |
| US8618025B2 (en) | 2010-12-16 | 2013-12-31 | Nalco Company | Composition and method for reducing hydrate agglomeration |
| CN105399896A (zh) * | 2014-09-06 | 2016-03-16 | 天津市金鳞水处理科技有限公司 | 一种吸附重金属离子和酚类化合物的凝胶材料的制备方法及其产品 |
| KR102710461B1 (ko) | 2017-12-15 | 2024-09-25 | 케미라 오와이제이 | 용존 기체 부상에 의한 수성 공급물의 처리 방법 |
| FR3082197B1 (fr) * | 2018-06-08 | 2021-04-23 | Coatex Sas | Recyclage d'eau dans un derive minier |
| WO2020047181A1 (en) | 2018-08-29 | 2020-03-05 | Ecolab Usa Inc. | Use of multiple charged ionic compounds derived from polyamines for waste water clarification |
| US20230357067A1 (en) * | 2022-05-04 | 2023-11-09 | Solenis Technologies, L.P. | Cationic emulsion terpolymer to increase cake solids in centrifuges |
| CN117960126A (zh) * | 2024-03-20 | 2024-05-03 | 中国科学院赣江创新研究院 | 一种短链分子刷改性活性炭及其制备方法与应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1267483A (en) | 1984-11-19 | 1990-04-03 | Hisao Takeda | Process for the production of a water-soluble polymer dispersion |
| JPH0651755B2 (ja) | 1988-10-14 | 1994-07-06 | ハイモ株式会社 | 水溶性カチオンポリマー分散液の製造方法 |
| CA2125545C (en) | 1993-06-10 | 2005-11-01 | Manian Ramesh | Hydrophobic dispersants used in forming polymer dispersions |
| US5597858A (en) | 1993-06-10 | 1997-01-28 | Nalco Chemical Company | Hydrophobically associating dispersants used in forming polymer dispersions |
| GB2284205B (en) * | 1993-11-25 | 1998-04-29 | Nalco Ltd | Treatment of agricultural waste |
| AU8024794A (en) | 1993-12-09 | 1995-06-15 | Nalco Chemical Company | An improved process for the preparation of water soluble polymer dispersion |
| US5451326A (en) * | 1994-05-16 | 1995-09-19 | Nalco Chemical Company | Chemical treatment of food processing wastes using dispersion polymers |
| US5938937A (en) * | 1995-08-16 | 1999-08-17 | Nalco Chemical Company | Hydrophilic dispersion polymers for treating wastewater |
| US6007679A (en) * | 1996-05-01 | 1999-12-28 | Nalco Chemical Company | Papermaking process |
| US5614602A (en) | 1996-07-09 | 1997-03-25 | Betzdearborn Inc. | Process for the preparation of aqueous dispersion polymers |
| US6059930A (en) * | 1996-09-24 | 2000-05-09 | Nalco Chemical Company | Papermaking process utilizing hydrophilic dispersion polymers of dimethylaminoethyl acrylate methyl chloride quaternary and acrylamide as retention and drainage aids |
| US6071379A (en) | 1996-09-24 | 2000-06-06 | Nalco Chemical Company | Papermaking process utilizing hydrophilic dispersion polymers of diallyldimethyl ammonium chloride and acrylamide as retention and drainage aids |
| US5733462A (en) | 1996-10-03 | 1998-03-31 | Cytec Technology Corp. | Cationic water-soluble polymer precipitation in salt solutions |
| US5750034A (en) | 1996-11-01 | 1998-05-12 | Nalco Chemical Company | Hydrophilic dispersion polymers for the clarification of deinking process waters |
| US6019904A (en) * | 1996-11-01 | 2000-02-01 | Nalco Chemical Company | Hydrophilic dispersion polymers of diallyldimethyl ammonium chloride and acrylamide for the clarification of deinking process waters |
| US6171505B1 (en) * | 1998-04-03 | 2001-01-09 | Nalco Chemical Company | Higher actives dispersion polymer to aid clarification, dewatering, and retention and drainage |
| US6036868A (en) * | 1998-07-23 | 2000-03-14 | Nalco Chemical Company | Use of hydrophilic dispersion polymers for oily wastewater clarification |
| JP2002540941A (ja) * | 1999-04-09 | 2002-12-03 | ナルコ ケミカル カンパニー | 浄化、脱水および保持かつ排水を補助する、より高活性な分散ポリマー |
| US6315866B1 (en) * | 2000-02-29 | 2001-11-13 | Nalco Chemical Company | Method of increasing the dry strength of paper products using cationic dispersion polymers |
-
2000
- 2000-04-20 US US09/553,876 patent/US6398967B2/en not_active Expired - Lifetime
-
2001
- 2001-03-20 ES ES01924243.7T patent/ES2442290T3/es not_active Expired - Lifetime
- 2001-03-20 DK DK01924243.7T patent/DK1274652T3/da active
- 2001-03-20 WO PCT/US2001/009060 patent/WO2001081252A1/en not_active Ceased
- 2001-03-20 AU AU2001250915A patent/AU2001250915A1/en not_active Abandoned
- 2001-03-20 KR KR1020027013832A patent/KR100777638B1/ko not_active Expired - Lifetime
- 2001-03-20 EP EP01924243.7A patent/EP1274652B1/en not_active Expired - Lifetime
- 2001-04-03 TW TW090107968A patent/TWI246987B/zh not_active IP Right Cessation
- 2001-04-19 AR ARP010101839A patent/AR028540A1/es active IP Right Grant
-
2002
- 2002-01-04 US US10/035,872 patent/US6517677B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2442290T3 (es) | 2014-02-11 |
| EP1274652A1 (en) | 2003-01-15 |
| AR028540A1 (es) | 2003-05-14 |
| AU2001250915A1 (en) | 2001-11-07 |
| KR100777638B1 (ko) | 2007-11-27 |
| EP1274652B1 (en) | 2013-12-18 |
| EP1274652A4 (en) | 2004-09-15 |
| WO2001081252A1 (en) | 2001-11-01 |
| US6398967B2 (en) | 2002-06-04 |
| US6517677B1 (en) | 2003-02-11 |
| KR20030001427A (ko) | 2003-01-06 |
| TWI246987B (en) | 2006-01-11 |
| US20010052501A1 (en) | 2001-12-20 |
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