DK152377B - Vandfri haandvaskepasta - Google Patents
Vandfri haandvaskepasta Download PDFInfo
- Publication number
- DK152377B DK152377B DK451775AA DK451775A DK152377B DK 152377 B DK152377 B DK 152377B DK 451775A A DK451775A A DK 451775AA DK 451775 A DK451775 A DK 451775A DK 152377 B DK152377 B DK 152377B
- Authority
- DK
- Denmark
- Prior art keywords
- mixture
- silicone oil
- sodium perborate
- sodium
- mixed
- Prior art date
Links
- 239000002699 waste material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 16
- 229960001922 sodium perborate Drugs 0.000 claims description 11
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 11
- 239000003638 chemical reducing agent Substances 0.000 claims description 9
- 229920002545 silicone oil Polymers 0.000 claims description 9
- 239000007800 oxidant agent Substances 0.000 claims description 8
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 claims description 6
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- 239000008262 pumice Substances 0.000 claims description 5
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000013312 flour Nutrition 0.000 claims description 3
- 229940051250 hexylene glycol Drugs 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 2
- 239000004166 Lanolin Substances 0.000 claims description 2
- 108010077895 Sarcosine Proteins 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 229940039717 lanolin Drugs 0.000 claims description 2
- 235000019388 lanolin Nutrition 0.000 claims description 2
- 239000010665 pine oil Substances 0.000 claims description 2
- 229940043230 sarcosine Drugs 0.000 claims description 2
- 206010009866 Cold sweat Diseases 0.000 claims 1
- JJCSYJVFIRBCRI-UHFFFAOYSA-K aluminum;hexadecanoate Chemical compound [Al].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O JJCSYJVFIRBCRI-UHFFFAOYSA-K 0.000 claims 1
- 239000007859 condensation product Substances 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 238000005406 washing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000002253 acid Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0042—Reducing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Inorganic Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Devices For Medical Bathing And Washing (AREA)
Description
DK 152377 B
Derr foreliggende opfindelse angår en hidtil ukendt håndvaskepasta, fortrinsvis til fjernelse af tilsmudsning med farvestoffer. Håndvaskepastaen ifølge opfindelsen er vandfri og indeholder reduktions-5 midler og et vandfrit oxidationsmiddel, og den er ejendommelig ved, at den som oxidationsmiddel indeholder 5-15 vægt?0 af et natriumperborat, som er overtrukket med siliconolie . i et vægtforhold mellem natriumperborat og siliconeolie på mellem 2:1 og 4:1.
10 I den tyske patentskrift 1031460 beskrives for første gang en pasta til håndvask, hvor befugtnings-midlet først dannes i brugsøjeblikket. I denne bliver den syre, der er basis for den vaskeaktive substans, på simpel måde indarbejdet i en oliefase på grund 15 af dens olieopløselighed. f.eks. lader den syre, der opstår ved kondensation af fedtsyre med sarkosin, sig indarbejde i en naturlig planteolie, som ricinusolie, idet der til forbedring af konsistensen yderligere kan tilsættes metalsæber. I dette grundmateriale 20 lader en blanding af soda, natriumdithionit og pimpstenspulver sig indarbejde. Disse uorganiske bestanddele bliver omgivet af olie fasen på en sådan mådg at en reaktion med syren under saltdannelse ikke er mulig.
Selv små mængder vand bliver emulgeret på en sådan 25 måde, at de ikke bevirker en for tidlig igangsætning af reaktionen. Når pastaen påføres hænderne, og der tilføres vand, så sker neutraliseringen under dannelse af det virksomme befugningsmiddel, ligesom udvikling af svovldioxid indtræder.
30 Det har nu overraskende vist sig, at den blegende og følgelig den rensende virkning af en vaskepasta med samme sammensætning som i det tyske patentskrift 1031460, som f.eks. indeholder butylglycol, lauridit, emulan, hexylenglycol, fyrrenåleolie, lanolin, 35 triethanolamin, aerosil, pimpstensmel og et vandfrit reduktionsmiddel, som natriumdithionit, kan forøges væsentligt ved, at der samtidig tilblandes granuleret 2
DK 152377B
natriumperborat overtrukket med siliconolie, som oxidationsmiddel.
Natriumperboratgranulatet har fortrinsvis en partikkelstørrelse, der svarer til det anvendte 5 pimpsten, hvilken ligger i størrelsesområdet: fra 30 til 60 |.i (DIN normstørrelse ca. G 1/2). Det er nødvendigt først at blande dette natriumperboratgranulat med siliconolie, idet vægt forholdet mellem natriumperborat og siliconolie kan svinge mellem 2 til 1 og 4 til 10 1. Denne blanding blandes derpå grundigt med den anden blanding, der består af et vandfrit befugtnings-middel, et reduktionsmiddel
og de ovenfor angivne bestanddele. Som reduktions-middel egner sig f.eks. pyrokatekin, natriumsulfit 15 eller -bisulfit, men specielt natriumdithionit. I
den på denne måde fremstillede pasta kan reduktions-midlet ikke reagere med oxidationsmidlet natriumperborat. Denne pasta er uindskrænket lagerbest.andig;
f I
den taber selv efter lang lagringstid ikke sine 20 reducerende og oxiderende egenskaber. Dersom denne pasta benyttes til vask, så træder først den reducerende og derefter, tidsmæssigt forskudt, den oxiderende egenskab i forgrunden.
Det kunne ved vaskeprocessen forventes, at 25 reduktionsmidlet i første række reagerer med oxidationsmidlet på grund af vandets opløsende virkning, forstærket af befugtningsmidlets virkning, og at begge stoffer derefter gensidigt neutraliserer hinanden og derved i stedet for at have en rensende, hen-30 holdsvis blegende virkning, fælder ud på huden eller stoffet. Men det har faktisk vist sig, at reduktionsmidlet ved vaskeprocessen først indvirker på den genstand, der skal renses, og at oxidationsmidlet først senere, efter ca. 2 til 5 minutters forløb, 35 bliver fuldt virksomt.
Den dobbelte rensevirkning af pastaen ifølge opfindelsen til håndvask er af stor betydning, f.eks.
Claims (3)
1. Vandfri håndvaskepasta, som indeholder befugtningsmidler, reducerende midler og et vandfrit oxidationsmiddel, kendetegnet ved, at den som oxidationsmiddel indeholder 5-15 vægtSi af 35 et natriumperborat, som er overtrukket med siliconolie i et vægtforhold mellem natriumperborat og siliconolie på mellem 2:1 og 4:1. DK 152377 B »
2. Håndvaskepasta ifølge krav 1, k e n d e -tegnet ved, at den indeholder natriumdithionit som reduktionsmiddel.
3. Håndvaskepasta ifølge krav 1 eller 2, 5. e n d e t e g n e t ved, at den indeholder vandfrit, hudskånende befugtningsmiddel.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742448716 DE2448716C3 (de) | 1974-10-12 | Handwaschpaste | |
| DE2448716 | 1974-10-12 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DK451775A DK451775A (da) | 1976-04-13 |
| DK152377B true DK152377B (da) | 1988-02-22 |
| DK152377C DK152377C (da) | 1988-07-25 |
Family
ID=5928167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK451775A DK152377C (da) | 1974-10-12 | 1975-10-07 | Vandfri haandvaskepasta |
Country Status (14)
| Country | Link |
|---|---|
| AT (1) | AT342173B (da) |
| BE (1) | BE834410A (da) |
| CH (1) | CH616702A5 (da) |
| DK (1) | DK152377C (da) |
| ES (1) | ES441719A1 (da) |
| FI (1) | FI58512C (da) |
| FR (1) | FR2287506A1 (da) |
| GB (1) | GB1501942A (da) |
| IE (1) | IE43304B1 (da) |
| IT (1) | IT1047535B (da) |
| LU (1) | LU73570A1 (da) |
| NL (1) | NL180851B (da) |
| NO (1) | NO142531C (da) |
| SE (1) | SE417980B (da) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6087310A (en) * | 1998-09-23 | 2000-07-11 | Castrol Limited | Skin cleaning compositions and uses comprising a polymer latex emulsion |
| DE19918265A1 (de) * | 1999-04-22 | 2000-10-26 | Henkel Kgaa | Abrasivstoffhaltiges Reinigungsmittel mit Mikrokapseln |
| FR2843540A1 (fr) * | 2002-11-06 | 2004-02-20 | Oreal | Composition demaquillante transparente |
| JP2008524264A (ja) | 2005-03-04 | 2008-07-10 | ザ プロクター アンド ギャンブル カンパニー | 高弾性率脂質を含有する洗い流しパーソナルケア組成物 |
| DE102018221598A1 (de) | 2018-12-13 | 2020-06-18 | Henkel Ag & Co. Kgaa | Mittel zum reduktiven Farbabzug von gefärbten keratinischen Fasern |
-
1975
- 1975-09-16 IT IT51360/75A patent/IT1047535B/it active
- 1975-09-26 AT AT736275A patent/AT342173B/de not_active IP Right Cessation
- 1975-10-07 DK DK451775A patent/DK152377C/da active
- 1975-10-09 CH CH1313675A patent/CH616702A5/de not_active IP Right Cessation
- 1975-10-10 FR FR7531131A patent/FR2287506A1/fr active Granted
- 1975-10-10 SE SE7511412A patent/SE417980B/xx not_active IP Right Cessation
- 1975-10-10 GB GB41671/75A patent/GB1501942A/en not_active Expired
- 1975-10-10 NO NO753437A patent/NO142531C/no unknown
- 1975-10-10 FI FI752827A patent/FI58512C/fi not_active IP Right Cessation
- 1975-10-10 NL NLAANVRAGE7511930,A patent/NL180851B/xx not_active IP Right Cessation
- 1975-10-10 BE BE160864A patent/BE834410A/xx not_active IP Right Cessation
- 1975-10-10 IE IE2219/75A patent/IE43304B1/en unknown
- 1975-10-10 LU LU73570A patent/LU73570A1/xx unknown
- 1975-10-11 ES ES441719A patent/ES441719A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AT342173B (de) | 1978-03-28 |
| IE43304B1 (en) | 1981-01-28 |
| NL7511930A (nl) | 1976-04-14 |
| DE2448716A1 (de) | 1976-04-22 |
| FI752827A7 (da) | 1976-04-13 |
| FR2287506B1 (da) | 1979-01-05 |
| NL180851B (nl) | 1986-12-01 |
| LU73570A1 (da) | 1977-02-09 |
| CH616702A5 (en) | 1980-04-15 |
| FI58512C (fi) | 1981-02-10 |
| GB1501942A (en) | 1978-02-22 |
| IE43304L (en) | 1976-04-12 |
| FR2287506A1 (fr) | 1976-05-07 |
| SE7511412L (sv) | 1976-04-13 |
| FI58512B (fi) | 1980-10-31 |
| NO142531B (no) | 1980-05-27 |
| ES441719A1 (es) | 1977-11-01 |
| BE834410A (fr) | 1976-04-12 |
| IT1047535B (it) | 1980-10-20 |
| DK152377C (da) | 1988-07-25 |
| DE2448716B2 (de) | 1977-01-13 |
| ATA736275A (de) | 1977-07-15 |
| SE417980B (sv) | 1981-04-27 |
| NO142531C (no) | 1980-09-03 |
| NO753437L (da) | 1976-04-13 |
| DK451775A (da) | 1976-04-13 |
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