DK175385B1 - Ufarligt surt rensemiddel til hårde overflader samt fremgangsmåde til fjernelse af kalksten, sæbeskum og snavs fra hårde overflader - Google Patents

Ufarligt surt rensemiddel til hårde overflader samt fremgangsmåde til fjernelse af kalksten, sæbeskum og snavs fra hårde overflader Download PDF

Info

Publication number: DK175385B1
Authority: DK; Denmark
Prior art keywords: acid; detergent; phosphonic acid; acids; fatty alcohol
Prior art date: 1988-02-10

Application number

DK198900652A

Other languages

Danish (da)

English (en)

Other versions

DK65289A (da

DK65289D0 (da

Inventor

Michel Thomas

Genevieve Blandiaux

Baudouin Valange

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-02-10

Filing date

1989-02-10

Publication date

2004-09-20

1989-02-10 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1989-02-10 Publication of DK65289D0 publication Critical patent/DK65289D0/da

1989-08-11 Publication of DK65289A publication Critical patent/DK65289A/da

2004-09-20 Application granted granted Critical

2004-09-20 Publication of DK175385B1 publication Critical patent/DK175385B1/da

Links

235000019738 Limestone Nutrition 0.000 title claims description 25
239000006028 limestone Substances 0.000 title claims description 25
230000002378 acidificating effect Effects 0.000 title claims description 22
239000000344 soap Substances 0.000 title claims description 22
239000006260 foam Substances 0.000 title claims description 21
238000000034 method Methods 0.000 title claims description 4
239000003599 detergent Substances 0.000 claims description 92
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 84
239000002253 acid Substances 0.000 claims description 50
239000000203 mixture Substances 0.000 claims description 46
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 41
-1 aminoalkylene phosphonic acid Chemical compound 0.000 claims description 35
125000004432 carbon atom Chemical group C* 0.000 claims description 35
239000004530 micro-emulsion Substances 0.000 claims description 32
239000000839 emulsion Substances 0.000 claims description 29
239000002304 perfume Substances 0.000 claims description 29
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 26
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
210000003298 dental enamel Anatomy 0.000 claims description 24
ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 23
239000012188 paraffin wax Substances 0.000 claims description 19
239000000047 product Substances 0.000 claims description 18
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 17
150000002191 fatty alcohols Chemical class 0.000 claims description 16
229910052708 sodium Inorganic materials 0.000 claims description 16
239000011734 sodium Substances 0.000 claims description 16
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 15
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 15
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 15
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 14
235000011037 adipic acid Nutrition 0.000 claims description 14
235000007586 terpenes Nutrition 0.000 claims description 14
239000001361 adipic acid Substances 0.000 claims description 13
150000003839 salts Chemical class 0.000 claims description 13
150000003505 terpenes Chemical class 0.000 claims description 13
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 12
239000003795 chemical substances by application Substances 0.000 claims description 11
239000007788 liquid Substances 0.000 claims description 11
125000000217 alkyl group Chemical group 0.000 claims description 10
239000007859 condensation product Substances 0.000 claims description 10
WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 claims description 9
150000007513 acids Chemical class 0.000 claims description 9
125000002947 alkylene group Chemical group 0.000 claims description 9
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 8
OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 claims description 8
229940088601 alpha-terpineol Drugs 0.000 claims description 8
150000001991 dicarboxylic acids Chemical class 0.000 claims description 8
HFVMEOPYDLEHBR-UHFFFAOYSA-N (2-fluorophenyl)-phenylmethanol Chemical compound C=1C=CC=C(F)C=1C(O)C1=CC=CC=C1 HFVMEOPYDLEHBR-UHFFFAOYSA-N 0.000 claims description 7
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
238000007792 addition Methods 0.000 claims description 7
125000000129 anionic group Chemical group 0.000 claims description 7
239000012736 aqueous medium Substances 0.000 claims description 7
239000000463 material Substances 0.000 claims description 7
229940116411 terpineol Drugs 0.000 claims description 7
239000000654 additive Substances 0.000 claims description 6
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
229910052845 zircon Inorganic materials 0.000 claims description 6
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
125000001931 aliphatic group Chemical group 0.000 claims description 5
WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims description 5
SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims description 5
239000011777 magnesium Substances 0.000 claims description 5
229910052749 magnesium Inorganic materials 0.000 claims description 5
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 4
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
229910001425 magnesium ion Inorganic materials 0.000 claims description 4
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 3
229910052782 aluminium Inorganic materials 0.000 claims description 3
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
150000003460 sulfonic acids Chemical class 0.000 claims description 3
229910021653 sulphate ion Inorganic materials 0.000 claims description 3
150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 2
229910052799 carbon Inorganic materials 0.000 claims description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 claims 1
229910019142 PO4 Inorganic materials 0.000 claims 1
150000004985 diamines Chemical class 0.000 claims 1
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims 1
229910052757 nitrogen Inorganic materials 0.000 claims 1
239000010452 phosphate Substances 0.000 claims 1
230000002000 scavenging effect Effects 0.000 claims 1
235000011007 phosphoric acid Nutrition 0.000 description 36
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical group [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 12
239000012459 cleaning agent Substances 0.000 description 9
150000001735 carboxylic acids Chemical class 0.000 description 8
150000002500 ions Chemical class 0.000 description 8
239000000243 solution Substances 0.000 description 8
239000004094 surface-active agent Substances 0.000 description 8
230000000694 effects Effects 0.000 description 7
150000003009 phosphonic acids Chemical class 0.000 description 7
229910052943 magnesium sulfate Inorganic materials 0.000 description 6
235000019341 magnesium sulphate Nutrition 0.000 description 6
229910021645 metal ion Inorganic materials 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
229920002257 Plurafac® Polymers 0.000 description 4
150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
150000001768 cations Chemical class 0.000 description 4
239000000975 dye Substances 0.000 description 4
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 4
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
230000002411 adverse Effects 0.000 description 3
239000000443 aerosol Substances 0.000 description 3
150000001450 anions Chemical class 0.000 description 3
239000004927 clay Substances 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000004744 fabric Substances 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
230000001681 protective effect Effects 0.000 description 3
238000000746 purification Methods 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000001384 succinic acid Substances 0.000 description 3
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
229910001018 Cast iron Inorganic materials 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
229910001208 Crucible steel Inorganic materials 0.000 description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
239000004372 Polyvinyl alcohol Substances 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
239000001045 blue dye Substances 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
229910000019 calcium carbonate Inorganic materials 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000007423 decrease Effects 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
238000005187 foaming Methods 0.000 description 2
239000004519 grease Substances 0.000 description 2
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 2
229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 2
239000002609 medium Substances 0.000 description 2
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
150000003016 phosphoric acids Chemical class 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
229920002451 polyvinyl alcohol Polymers 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000003755 preservative agent Substances 0.000 description 2
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
230000003381 solubilizing effect Effects 0.000 description 2
239000007921 spray Substances 0.000 description 2
239000010959 steel Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
125000000204 (C2-C4) acyl group Chemical group 0.000 description 1
CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 1
LEVONNIFUFSRKZ-UHFFFAOYSA-N 3-(carboxymethyl)-2,2-dimethylcyclobutane-1-carboxylic acid Chemical compound CC1(C)C(CC(O)=O)CC1C(O)=O LEVONNIFUFSRKZ-UHFFFAOYSA-N 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
101150042514 B1 gene Proteins 0.000 description 1
239000004135 Bone phosphate Substances 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
CITCOZGDILKPHL-UHFFFAOYSA-N CP(O)(O)=O.CP(O)(O)=O.CP(O)(O)=O.CP(O)(O)=O.CP(O)(O)=O.NCCNCCN Chemical compound CP(O)(O)=O.CP(O)(O)=O.CP(O)(O)=O.CP(O)(O)=O.CP(O)(O)=O.NCCNCCN CITCOZGDILKPHL-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
241000272168 Laridae Species 0.000 description 1
244000131360 Morinda citrifolia Species 0.000 description 1
229910021204 NaH2 PO4 Inorganic materials 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
244000170916 Paeonia officinalis Species 0.000 description 1
235000006484 Paeonia officinalis Nutrition 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
235000011613 Pinus brutia Nutrition 0.000 description 1
241000018646 Pinus brutia Species 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
BDKZHNJTLHOSDW-UHFFFAOYSA-N [Na].CC(O)=O Chemical compound [Na].CC(O)=O BDKZHNJTLHOSDW-UHFFFAOYSA-N 0.000 description 1
235000011054 acetic acid Nutrition 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
150000001279 adipic acids Chemical class 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
229920013820 alkyl cellulose Polymers 0.000 description 1
150000005215 alkyl ethers Chemical class 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
230000003373 anti-fouling effect Effects 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
235000010980 cellulose Nutrition 0.000 description 1
229920006184 cellulose methylcellulose Polymers 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000000368 destabilizing effect Effects 0.000 description 1
125000001142 dicarboxylic acid group Chemical group 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
UTUNZTDXEIGXKD-UHFFFAOYSA-N ethoxyethane;sulfuric acid Chemical class CCOCC.OS(O)(=O)=O UTUNZTDXEIGXKD-UHFFFAOYSA-N 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
230000003090 exacerbative effect Effects 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
150000002311 glutaric acids Chemical class 0.000 description 1
150000004688 heptahydrates Chemical class 0.000 description 1
DKPHLYCEFBDQKM-UHFFFAOYSA-H hexapotassium;1-phosphonato-n,n-bis(phosphonatomethyl)methanamine Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)CN(CP([O-])([O-])=O)CP([O-])([O-])=O DKPHLYCEFBDQKM-UHFFFAOYSA-H 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
239000001095 magnesium carbonate Substances 0.000 description 1
229910000021 magnesium carbonate Inorganic materials 0.000 description 1
150000002691 malonic acids Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000004579 marble Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
238000002156 mixing Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
235000017524 noni Nutrition 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
239000007764 o/w emulsion Substances 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
150000002913 oxalic acids Chemical class 0.000 description 1
JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
239000006072 paste Substances 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
230000002335 preservative effect Effects 0.000 description 1
RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
230000001012 protector Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000009991 scouring Methods 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
210000002784 stomach Anatomy 0.000 description 1
239000004575 stone Substances 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
150000003444 succinic acids Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000003628 tricarboxylic acids Chemical class 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
239000000341 volatile oil Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Detergent Compositions (AREA)

DK198900652A 1988-02-10 1989-02-10 Ufarligt surt rensemiddel til hårde overflader samt fremgangsmåde til fjernelse af kalksten, sæbeskum og snavs fra hårde overflader DK175385B1 (da)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US15483788A	1988-02-10	1988-02-10
US15483788		1988-02-10

Publications (3)

Publication Number	Publication Date
DK65289D0 DK65289D0 (da)	1989-02-10
DK65289A DK65289A (da)	1989-08-11
DK175385B1 true DK175385B1 (da)	2004-09-20

Family

ID=22553011

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DK198900652A DK175385B1 (da)	1988-02-10	1989-02-10	Ufarligt surt rensemiddel til hårde overflader samt fremgangsmåde til fjernelse af kalksten, sæbeskum og snavs fra hårde overflader

Country Status (11)

Country	Link
EP (1)	EP0336878B1 (de)
AR (1)	AR242256A1 (de)
AT (1)	ATE122383T1 (de)
AU (1)	AU625056B2 (de)
BR (1)	BR8900594A (de)
CA (1)	CA1332338C (de)
DE (1)	DE68922522T2 (de)
DK (1)	DK175385B1 (de)
MX (1)	MX170213B (de)
NO (1)	NO174430C (de)
PT (1)	PT89679B (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5192460A (en) *	1988-02-10	1993-03-09	Colgate-Palmolive Company	Safe acidic hard surface cleaner
US5294364A (en) *	1988-02-10	1994-03-15	Colgate Palmolive	Safe acidic hard surface cleaner
US5279758A (en) *	1991-10-22	1994-01-18	The Clorox Company	Thickened aqueous cleaning compositions
NZ248582A (en) *	1992-09-24	1995-02-24	Colgate Palmolive Co	Acidic, thickened cleaner containing dicarboxylic acids and aminoalkylene phosphonic acid for cleaning lime scale from acid-resistant or zirconium white enamel hard surfaces
SK280816B6 (sk) †	1992-10-16	2000-08-14	Unilever Nv	Vodná čistiaca zmes
TR27813A (tr) *	1993-09-23	1995-08-29	Colgate Palmolive Co	Koyulastirilmis asit mikroemülsiyon terkibi.
AU1178995A (en) *	1993-11-22	1995-06-13	Colgate-Palmolive Company, The	Liquid cleaning compositions
US5415813A (en) *	1993-11-22	1995-05-16	Colgate-Palmolive Company	Liquid hard surface cleaning composition with grease release agent
EP0741778A1 (de) *	1994-02-02	1996-11-13	Colgate-Palmolive Company	Flüssige reinigungszusammensetzungen
ES2151538T3 (es) *	1994-02-03	2001-01-01	Procter & Gamble	Composiciones de limpieza acidas.
US5409630A (en) *	1994-02-03	1995-04-25	Colgate Palmolive Co.	Thickened stable acidic microemulsion cleaning composition
WO1996003491A1 (en) *	1994-07-21	1996-02-08	Colgate-Palmolive Company	Liquid cleaning compositions
ATE213016T1 (de) *	1996-03-06	2002-02-15	Colgate Palmolive Co	Flüssigkristall-reinigungsmittel
US5707952A (en) *	1996-04-24	1998-01-13	Colgate-Palmolive Company	Thickened acid composition
US7605114B2 (en)	2005-05-03	2009-10-20	Claudia Rushlow	Multi-purpose cleaner comprising blue iron powder
WO2024031507A1 (en) *	2022-08-11	2024-02-15	Ecolab Usa Inc.	Detergent compositions with enhanced anti-scaling efficacy

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR1529466A (fr) *	1966-07-01	1968-06-14	Monsanto Co	Compositions de lavage renfermant un détergent synthétique et des acides cycloalcanepolycarboxyliques
IT951279B (it) *	1971-07-01	1973-06-30	Benckiser Gmbh Joh A	Processo per impedire il formarsi di depositi che producono incrosta zioni nei sistemi acquosi
GR75249B (de) *	1980-05-10	1984-07-13	Procter & Gamble
ZA826902B (en) *	1981-10-01	1984-04-25	Colgate Palmolive Co	Safe liquid toilet bowl cleaner
US4501680A (en) *	1983-11-09	1985-02-26	Colgate-Palmolive Company	Acidic liquid detergent composition for cleaning ceramic tiles without eroding grout
US5192460A (en) *	1988-02-10	1993-03-09	Colgate-Palmolive Company	Safe acidic hard surface cleaner

1989
- 1989-02-07 EP EP89730026A patent/EP0336878B1/de not_active Expired - Lifetime
- 1989-02-07 DE DE68922522T patent/DE68922522T2/de not_active Expired - Lifetime
- 1989-02-07 AT AT89730026T patent/ATE122383T1/de not_active IP Right Cessation
- 1989-02-09 MX MX014866A patent/MX170213B/es unknown
- 1989-02-09 CA CA000590542A patent/CA1332338C/en not_active Expired - Fee Related
- 1989-02-09 NO NO890559A patent/NO174430C/no unknown
- 1989-02-10 PT PT89679A patent/PT89679B/pt active IP Right Grant
- 1989-02-10 AR AR89313196A patent/AR242256A1/es active
- 1989-02-10 DK DK198900652A patent/DK175385B1/da not_active IP Right Cessation
- 1989-02-10 BR BR898900594A patent/BR8900594A/pt not_active Application Discontinuation
- 1989-02-10 AU AU29874/89A patent/AU625056B2/en not_active Ceased

Also Published As

Publication number	Publication date
ATE122383T1 (de)	1995-05-15
EP0336878B1 (de)	1995-05-10
PT89679A (pt)	1989-10-04
NO174430B (no)	1994-01-24
DE68922522D1 (de)	1995-06-14
BR8900594A (pt)	1989-10-10
DK65289A (da)	1989-08-11
EP0336878A3 (en)	1990-09-19
CA1332338C (en)	1994-10-11
DE68922522T2 (de)	1995-09-14
AU2987489A (en)	1989-08-10
NO890559D0 (no)	1989-02-09
NO890559L (no)	1989-08-11
DK65289D0 (da)	1989-02-10
PT89679B (pt)	1994-04-29
AR242256A1 (es)	1993-03-31
NO174430C (no)	1994-05-04
MX170213B (es)	1993-08-11
AU625056B2 (en)	1992-07-02
EP0336878A2 (de)	1989-10-11

Legal Events

Date	Code	Title	Description
2009-03-02	PUP	Patent expired

Publication	Publication Date	Title
US5039441A (en)	1991-08-13	Safe acidic hard surface cleaner
DK175385B1 (da)	2004-09-20	Ufarligt surt rensemiddel til hårde overflader samt fremgangsmåde til fjernelse af kalksten, sæbeskum og snavs fra hårde overflader
US5192460A (en)	1993-03-09	Safe acidic hard surface cleaner
AU668201B2 (en)	1996-04-26	Thickened acid microemulsion composition
US5294364A (en)	1994-03-15	Safe acidic hard surface cleaner
US4528039A (en)	1985-07-09	Alkaline cleaning compositions non-corrosive toward aluminum surfaces
US4457322A (en)	1984-07-03	Alkaline cleaning compositions non-corrosive toward aluminum surfaces
NL8403429A (nl)	1985-06-03	Zure vloeibare detergentsamenstelling voor het reinigen van keramische tegels zonder de vulspecie te eroderen.
JPH02289697A (ja)	1990-11-29	硬質表面洗浄用組成物
JPH08502095A (ja)	1996-03-05	改良型汎用洗浄組成物
US4938893A (en)	1990-07-03	Detersive systems and low foaming aqueous surfactant solutions containing a mono (C1-4 alkyl)-di(C6-20 alkyl)-amine oxide compound
CA2126626A1 (en)	1994-12-25	Acid microemulsion composition
CN1052028C (zh)	2000-05-03	改良的地板脱漆剂组合物及脱落方法
JP4790130B2 (ja)	2011-10-12	液体漂白洗浄剤組成物
JP2024026937A (ja)	2024-02-29	硬表面用の液体洗浄剤組成物
JP2023081572A (ja)	2023-06-13	洗浄剤組成物及び洗浄方法
MXPA94004665A (en)	2000-08-01	Composition in microemulsion ac