DK2011850T3 - Fremgangsmåde til omdannelse af svær olie til let olie - Google Patents
Fremgangsmåde til omdannelse af svær olie til let olie Download PDFInfo
- Publication number
- DK2011850T3 DK2011850T3 DK06745778.8T DK06745778T DK2011850T3 DK 2011850 T3 DK2011850 T3 DK 2011850T3 DK 06745778 T DK06745778 T DK 06745778T DK 2011850 T3 DK2011850 T3 DK 2011850T3
- Authority
- DK
- Denmark
- Prior art keywords
- oil
- heat medium
- emulsion
- heating
- upgrading
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 52
- 239000003921 oil Substances 0.000 title description 232
- 239000000295 fuel oil Substances 0.000 title description 30
- 239000000463 material Substances 0.000 claims description 80
- 238000010438 heat treatment Methods 0.000 claims description 79
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 62
- 239000000839 emulsion Substances 0.000 claims description 51
- 239000007788 liquid Substances 0.000 claims description 15
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910001424 calcium ion Inorganic materials 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 230000033116 oxidation-reduction process Effects 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000003860 storage Methods 0.000 description 39
- 239000000567 combustion gas Substances 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 20
- 238000012545 processing Methods 0.000 description 20
- 238000012546 transfer Methods 0.000 description 20
- 238000004227 thermal cracking Methods 0.000 description 19
- 239000000446 fuel Substances 0.000 description 18
- 239000007789 gas Substances 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 16
- 238000010586 diagram Methods 0.000 description 15
- 238000005336 cracking Methods 0.000 description 10
- 238000004891 communication Methods 0.000 description 9
- 238000004821 distillation Methods 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 238000004880 explosion Methods 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 238000004523 catalytic cracking Methods 0.000 description 6
- 238000004517 catalytic hydrocracking Methods 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 4
- 239000011575 calcium Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 239000007762 w/o emulsion Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000008642 heat stress Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/008—Processes for carrying out reactions under cavitation conditions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/02—Feed or outlet devices; Feed or outlet control devices for feeding measured, i.e. prescribed quantities of reagents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/42—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils by passing the material to be cracked in thin streams or as spray on or near continuously heated surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00094—Jackets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00157—Controlling the temperature by means of a burner
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Claims (4)
1. Fremgangsmåde til forbedring af kvaliteten af en olie til fremstilling en lettere raffineret olie ud fra et tungere oliemateriale, hvilken fremgangsmåde omfatter: fremstilling af en emulsion ved emulgering af ioniseret alkalisk vand med et oxidationsreduktionspotentiale på -850 mV eller derunder og en pH-værdi på 12 eller derover i oliematerialet; og pådrypning af dråber af emulsionen på en overflade af et opvarmet opvarmningsmedium, hvor opvarmningsmediet er en flydende carbonhydridolie.
2. Fremgangsmåde til forbedring af kvaliteten af en olie ifølge krav 1, hvor: en partikelstørrelse på det ioniserede alkaliske vand, der er emulgeret i emulsionen, er 3 til 5 pm.
3. Fremgangsmåde til forbedring af kvaliteten af en olie ifølge krav 2, hvor: en andel af en vægt af vand i det ioniserede alkaliske vand i forhold til en vægt af oliematerialet i emulsionen er 5 til 30 vægtprocent.
4. Fremgangsmåde til forbedring af kvaliteten af en olie ifølge krav 3, hvor: det ioniserede alkaliske vand indeholder calciumioner.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2006/308862 WO2007125576A1 (ja) | 2006-04-27 | 2006-04-27 | 重質油軽質化装置及び該方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2011850T3 true DK2011850T3 (da) | 2016-08-01 |
Family
ID=38655123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK06745778.8T DK2011850T3 (da) | 2006-04-27 | 2006-04-27 | Fremgangsmåde til omdannelse af svær olie til let olie |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US8088273B2 (da) |
| EP (1) | EP2011850B1 (da) |
| JP (1) | JP5070205B2 (da) |
| CN (1) | CN101421377B (da) |
| BR (1) | BRPI0621601B1 (da) |
| CA (1) | CA2650466C (da) |
| DK (1) | DK2011850T3 (da) |
| ES (1) | ES2581599T3 (da) |
| HU (1) | HUE030330T2 (da) |
| PL (1) | PL2011850T3 (da) |
| PT (1) | PT2011850T (da) |
| WO (1) | WO2007125576A1 (da) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012206399B4 (de) | 2012-04-18 | 2018-01-04 | Egm-Holding-International Gmbh | Verfahren zur Emulsionsbehandlung |
| UA128198C2 (uk) * | 2016-07-25 | 2024-05-08 | Фордж Хайдрокарбонз Корпорейшн | Способи одержання вуглеводневих композицій зі зниженим кислотним числом і виділення коротколанцюгових жирних кислот |
| MY193838A (en) * | 2017-02-10 | 2022-10-28 | Haldor Tops?E As | A method for the hydroprocessing of renewable feeds |
| KR102398989B1 (ko) * | 2020-04-01 | 2022-05-18 | 한국기초과학지원연구원 | 탄화수소 유분으로부터 황화합물을 제거하는 방법 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US377459A (en) * | 1888-02-07 | Ore-crusher | ||
| US701186A (en) * | 1901-07-25 | 1902-05-27 | William J Faulkner | Apparatus for generating gas. |
| US2723300A (en) * | 1951-10-01 | 1955-11-08 | Exxon Research Engineering Co | Quenching method for short-time, hightemperature gas-phase reactions |
| US3707459A (en) * | 1970-04-17 | 1972-12-26 | Exxon Research Engineering Co | Cracking hydrocarbon residua |
| JPS5742362A (en) * | 1980-08-22 | 1982-03-09 | Ikeuchi:Kk | Atomized spray generator |
| US4434049A (en) | 1982-03-17 | 1984-02-28 | Dean Robert R | Residual oil feed process for fluid catalyst cracking |
| JPS5975986A (ja) | 1982-10-25 | 1984-04-28 | Asahi Chem Ind Co Ltd | 重質炭化水素の軽質化法 |
| US4840725A (en) | 1987-06-19 | 1989-06-20 | The Standard Oil Company | Conversion of high boiling liquid organic materials to lower boiling materials |
| GB8816740D0 (en) * | 1988-07-14 | 1988-08-17 | Univ Waterloo | Upgrading crude oil emulsions |
| JPH0711259A (ja) | 1993-06-22 | 1995-01-13 | Idemitsu Kosan Co Ltd | 重質油の処理方法 |
| US5885441A (en) | 1997-04-11 | 1999-03-23 | Intevep, S.A. | Steam conversion process and catalyst |
| US6169054B1 (en) | 1997-04-11 | 2001-01-02 | Intevep, S.A. | Oil soluble coking additive, and method for making and using same |
| FR2741889B1 (fr) | 1995-12-04 | 1999-01-29 | Total Raffinage Distribution | Perfectionnements apportes aux procedes et aux dispositifs de viscoreduction de charges lourdes d'hydrocarbures |
| US6043182A (en) | 1997-04-11 | 2000-03-28 | Intevep, S.A. | Production of oil soluble catalytic precursors |
| US6030522A (en) | 1997-04-11 | 2000-02-29 | Intevep, S.A. | Combined steam conversion process for treating vacuum gas oil |
| JP4861652B2 (ja) * | 2005-04-28 | 2012-01-25 | タピオカ コマーシオ エ サービコス ソシエダーデ ウニペッソアル エルディーエー | 加熱油化装置及び加熱油化方法 |
-
2006
- 2006-04-27 EP EP06745778.8A patent/EP2011850B1/en not_active Expired - Lifetime
- 2006-04-27 CA CA2650466A patent/CA2650466C/en not_active Expired - Fee Related
- 2006-04-27 US US12/226,556 patent/US8088273B2/en not_active Expired - Fee Related
- 2006-04-27 WO PCT/JP2006/308862 patent/WO2007125576A1/ja not_active Ceased
- 2006-04-27 BR BRPI0621601A patent/BRPI0621601B1/pt not_active IP Right Cessation
- 2006-04-27 ES ES06745778.8T patent/ES2581599T3/es not_active Expired - Lifetime
- 2006-04-27 CN CN2006800542615A patent/CN101421377B/zh not_active Expired - Fee Related
- 2006-04-27 PT PT67457788T patent/PT2011850T/pt unknown
- 2006-04-27 HU HUE06745778A patent/HUE030330T2/en unknown
- 2006-04-27 DK DK06745778.8T patent/DK2011850T3/da active
- 2006-04-27 PL PL06745778.8T patent/PL2011850T3/pl unknown
- 2006-04-27 JP JP2008513024A patent/JP5070205B2/ja not_active Expired - Fee Related
-
2011
- 2011-11-02 US US13/287,448 patent/US8298377B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US8088273B2 (en) | 2012-01-03 |
| PL2011850T3 (pl) | 2016-11-30 |
| EP2011850B1 (en) | 2016-04-13 |
| BRPI0621601A2 (pt) | 2011-12-13 |
| PT2011850T (pt) | 2016-07-18 |
| ES2581599T3 (es) | 2016-09-06 |
| US20120043179A1 (en) | 2012-02-23 |
| CA2650466C (en) | 2014-01-28 |
| JPWO2007125576A1 (ja) | 2009-09-10 |
| JP5070205B2 (ja) | 2012-11-07 |
| US8298377B2 (en) | 2012-10-30 |
| HUE030330T2 (en) | 2017-05-29 |
| US20100187157A1 (en) | 2010-07-29 |
| CA2650466A1 (en) | 2007-11-08 |
| CN101421377A (zh) | 2009-04-29 |
| EP2011850A1 (en) | 2009-01-07 |
| BRPI0621601B1 (pt) | 2015-11-10 |
| EP2011850A4 (en) | 2011-02-09 |
| WO2007125576A1 (ja) | 2007-11-08 |
| CN101421377B (zh) | 2012-06-27 |
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