DK2084247T3 - Bulk-gruppe viii/vib-metalkatalysatorer - Google Patents

Bulk-gruppe viii/vib-metalkatalysatorer Download PDF

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DK2084247T3
DK2084247T3 DK07852716.5T DK07852716T DK2084247T3 DK 2084247 T3 DK2084247 T3 DK 2084247T3 DK 07852716 T DK07852716 T DK 07852716T DK 2084247 T3 DK2084247 T3 DK 2084247T3
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catalyst
acid
catalyst precursor
metal
complexing agent
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DK07852716.5T
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English (en)
Inventor
Chuansheng Bai
Zhigou Hou
Jon M Mcconnachie
Pallassana S Venkataraman
Jason Wu
Daniel Giaquinta
Alfred Hagemeyer
Anthony F Volpe Jr
David M Lowe
Jeff Elks
Valery Sokolovskii
Jun Han
Malki El-Mekki El
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Exxonmobil Res & Eng Co
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/049—Sulfides with chromium, molybdenum, tungsten or polonium with iron group metals or platinum group metals
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
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    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/50—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum or tungsten metal, or compounds thereof
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    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2531/64—Molybdenum
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    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
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    • B01J2531/845—Cobalt
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    • B01J2531/847—Nickel
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  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Claims (9)

1. Sulfideret bulkmetalkatalysator fremstillet ved kombinering af et gruppe VIII-metal, et gruppe VIB-metal og en organisk kompleksdanner, som er en organisk syre, der indeholder en -COOH-funktionel gruppe og mindst én yderligere funktionel gruppe valgt blandt carboxylsyre -COOH, hydroxmatsyre -N0H-C=0, hydroxo -OH, keto -C=0, amin -NH2, amid: -CO-NH2, imin: -CNOH, epoxy: =COC= eller thiol: -SH, hvor molforholdet mellem organisk kompleksdanner og metal er større end 3:1, til frembringelse af en katalysatorprækursorsammensætning, hvilken katalysatorprækursorsammensætning har et overfladeareal på 16 m2/g eller mindre baseret på Brunauer-Ernett-Teller (BET)-metoden, og sulfidering af katalysatorprækursorsammensætningen til frembringelse af katalysatoren, hvor katalysatorprækursorsammensætningen indeholder fra 10 vægt-% til 60 vægt-% af en organisk forbindelsebaseret bestanddel dannet af den organiske kompleksdanner.
2. Katalysator ifølge krav 1, hvor gruppe VIII-metallet er nikkel eller kobolt, og gruppe VIB-metallet er molybden eller wolfram.
3. Katalysator ifølge krav 1, hvor katalysatoren indeholder områder af MeS2 med stakhøjder i intervallet fra 1,2 til 2,5 baseret på transmissions-elektronmikroskopi (TEM), hvor Me er et gruppe VIB-metal.
4. Katalysator ifølge krav 1 med et overfladeareal på mindre end 10 m2/g baseret på Brunauer-Ernett-Teller (BET)-metoden.
5. Katalysator ifølge krav 1 med et overfladeareal på mindst 0,1 m2/g baseret på Brunauer-Ernett-Teller (BET)-metoden.
6. Katalysator ifølge krav 1, hvor katalysatorprækursorsammensætningen omfatter fra 12 vægt-% til 25 vægt-% carbon.
7. Katalysator ifølge krav 1, hvor gruppe VIII-metallet og gruppe VIB-metallet er tilvejebragt i form af salte valgt blandt carbonater, nitrater, sulfater, acetater, chlorider, hydroxider, hydroxycarbonater, acetylacetater, acetylacetonater, glyciner, naphthenater, oxider, hydrerede oxider, carboxylater, formater, oxalater, tartrater, lactater, propionater, citrater, glyoxylater, gluconater, glycolater eller ammonium- eller aminformer deraf.
8. Katalysator ifølge krav 1, hvor den organiske kompleksdanner er valgt blandt pyrodruesyre, levulinsyre, 4-acetylsmørsyre, 1,3-acetonedicarboxylsyre, 3-oxopropansyre, 4-oxobutansyre, 2,3-diformylravsyre, 5-oxopentansyre, 4-oxopentansyre, thioglycolsyre, ethylglyoxylat, glycolsyre, glucose, gluconsyre, glycin, oxamsyre, glyoxylsyre, glyoxylsyre-2-oxim, ethylendiamintetraeddikesyre, nitrilotrieddikesyre, N-methylaminodieddikesyre, iminodieddikesyre, citronsyre, oxalsyre, 2-ketogulonsyre, ketogluconsyre, alfa-ketoglutarsyre, 2-ketosmørsyre, acetylacetone og oxaleddikesyre.
9. Fremgangsmåde til hydrogenbehandling, som omfatter behandling af et råstof med hydrogen i nærvær af en katalysator ifølge krav 1.
DK07852716.5T 2006-10-11 2007-10-11 Bulk-gruppe viii/vib-metalkatalysatorer DK2084247T3 (da)

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US85084906P 2006-10-11 2006-10-11
US87332606P 2006-12-07 2006-12-07
US11/973,505 US7951746B2 (en) 2006-10-11 2007-10-09 Bulk group VIII/group VIB metal catalysts and method of preparing same
PCT/US2007/021870 WO2008045551A2 (en) 2006-10-11 2007-10-11 Bulk group viii/vib metal catalysts and method of preparing same

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Publication number Priority date Publication date Assignee Title
WO2007059621A1 (en) * 2005-11-23 2007-05-31 Pedro Pereira-Almao Ultradispersed catalyst compositions and methods of preparation
SG10201800494XA (en) * 2006-10-11 2018-03-28 Exxonmobil Res & Eng Co Hydroprocessing methods for bulk group viii/group vib metal catalysts
JP5390530B2 (ja) * 2007-10-31 2014-01-15 シェブロン ユー．エス．エー． インコーポレイテッド 多金属触媒を用いた水素化転化プロセス及びその作製方法
CN101909747B (zh) * 2007-11-09 2014-10-22 埃克森美孚研究工程公司 制备viii族/vib族金属的本体金属催化剂
US20090023965A1 (en) 2008-05-01 2009-01-22 Intevep, S.A. Dispersed metal sulfide-based catalysts
WO2010042153A1 (en) * 2008-10-06 2010-04-15 Exxonmobil Research And Engineering Company Bulk catalysts having increased stability
WO2010100256A2 (en) * 2009-03-06 2010-09-10 Albemarle Europe Sprl Bulk sulfidic mixed metal catalyst and methods for its manufacture and use in converting syngas to alcohol
US7964525B2 (en) * 2009-04-29 2011-06-21 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8383543B2 (en) * 2009-04-29 2013-02-26 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8058203B2 (en) * 2009-04-29 2011-11-15 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7931799B2 (en) * 2009-04-29 2011-04-26 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7964524B2 (en) * 2009-04-29 2011-06-21 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US8080492B2 (en) * 2009-04-29 2011-12-20 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
US7964526B2 (en) * 2009-04-29 2011-06-21 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
WO2010126690A2 (en) * 2009-04-29 2010-11-04 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalyst and method for making thereof
CN101884924B (zh) * 2009-05-15 2012-08-08 中国石油天然气股份有限公司 高分散镍催化剂及其制备方法和应用
US8686203B2 (en) * 2009-06-12 2014-04-01 Exxonmobil Research And Engineering Company Process for preparing diesel fuels using vegetable oils or fatty acid derivatives
US8734638B2 (en) 2009-06-19 2014-05-27 Exxonmobil Research And Engineering Company Ebullating bed methods for treatment of biocomponent feedstocks
AU2010273344A1 (en) * 2009-07-17 2012-02-09 Exxonmobil Research And Engineering Company Hydroprocessing of biocomponent feedstocks with FCC off-gas
JP2013503246A (ja) * 2009-08-28 2013-01-31 エクソンモービル リサーチ アンド エンジニアリング カンパニー バイオ成分供給材料の水素処理における水素消費量の低減方法
CA2773368A1 (en) * 2009-09-08 2011-03-17 Exxonmobil Research And Engineering Company Fuel production from feedstock containing lipidic material
WO2011037901A2 (en) * 2009-09-25 2011-03-31 Exxonmobil Research And Engineering Company Fuel production from feedstock containing triglyceride and/or fatty acid alkyl ester
SG10201406264PA (en) * 2009-10-05 2014-11-27 Exxonmobil Res & Eng Co Stacking of low activity or regenerated catalyst above higher activity catalyst
US8853474B2 (en) * 2009-12-29 2014-10-07 Exxonmobil Research And Engineering Company Hydroprocessing of biocomponent feedstocks with low purity hydrogen-containing streams
AU2011261517B2 (en) * 2010-06-01 2015-06-04 Exxonmobil Research And Engineering Company Hydroprocessing catalysts and their production
US10022712B2 (en) * 2010-06-01 2018-07-17 Exxonmobil Research And Engineering Company Hydroprocessing catalysts and their production
US20120016167A1 (en) 2010-07-15 2012-01-19 Exxonmobil Research And Engineering Company Hydroprocessing of biocomponent feeds with low pressure hydrogen-containing streams
US8557106B2 (en) 2010-09-30 2013-10-15 Exxonmobil Research And Engineering Company Hydrocracking process selective for improved distillate and improved lube yield and properties
KR101816318B1 (ko) * 2010-12-09 2018-01-12 에스케이이노베이션 주식회사 수소 처리 촉매 및 이의 제조방법
US9109176B2 (en) 2011-03-28 2015-08-18 Exxonmobil Research And Engineering Company Method for making marine bunker fuels
US9233367B2 (en) 2011-04-01 2016-01-12 Dow Global Technologies Llc Process for synthesis of molybdenum sulfide-based catalysts
US9199224B2 (en) 2012-09-05 2015-12-01 Chevron U.S.A. Inc. Hydroconversion multi-metallic catalysts and method for making thereof
JP6251107B2 (ja) * 2014-04-01 2017-12-20 Ｊｘｔｇエネルギー株式会社 炭化水素油の水素化脱硫触媒
JP2018501342A (ja) 2014-12-04 2018-01-18 エクソンモービル リサーチ アンド エンジニアリング カンパニーＥｘｘｏｎ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｅｎｇｉｎｅｅｒｉｎｇ Ｃｏｍｐａｎｙ 低硫黄マリンバンカー燃料およびそれを製造する方法
FR3035600B1 (fr) * 2015-04-30 2017-04-21 Ifp Energies Now Catalyseur a base d'acide y-cetovalerique et son utilisation dans un procede d'hydrotraitement et/ou d'hydrocraquage
CA2995001A1 (en) * 2015-09-23 2017-03-30 Exxonmobil Research And Engineering Company Stabilization of bulk catalysts with organo-metalloxane framework
US10053637B2 (en) * 2015-12-15 2018-08-21 Uop Llc Transition metal tungsten oxy-hydroxide
US10233398B2 (en) 2015-12-15 2019-03-19 Uop Llc Crystalline transition metal oxy-hydroxide molybdotungstate
US10005812B2 (en) 2015-12-15 2018-06-26 Uop Llc Transition metal molybdotungsten oxy-hydroxide
US10449523B2 (en) 2015-12-15 2019-10-22 Uop Llc Crystalline bis-ammonia transition metal molybdotungstate
US10046315B2 (en) 2015-12-15 2018-08-14 Uop Llc Crystalline transition metal molybdotungstate
US10399065B2 (en) 2015-12-15 2019-09-03 Uop Llc Crystalline transition metal tungstate
US10400181B2 (en) 2015-12-15 2019-09-03 Uop Llc Crystalline bis-ammonia metal molybdate
US10052616B2 (en) 2015-12-15 2018-08-21 Uop Llc Crystalline ammonia transition metal molybdotungstate
US10322404B2 (en) 2015-12-15 2019-06-18 Uop Llc Crystalline transition metal oxy-hydroxide molybdate
US10399063B2 (en) 2015-12-15 2019-09-03 Uop Llc Mixed metal oxides
US10232357B2 (en) 2015-12-15 2019-03-19 Uop Llc Crystalline ammonia transition metal molybdate
US10052614B2 (en) 2015-12-15 2018-08-21 Uop Llc Mixed metal oxides
CN108698039A (zh) * 2016-02-01 2018-10-23 阿尔比马尔欧洲有限公司 含镍混合金属氧化物/碳一体化加氢处理催化剂及其应用
US10457877B2 (en) 2016-03-31 2019-10-29 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
EP3458552A1 (en) 2016-05-17 2019-03-27 Exxonmobil Research And Engineering Company Jet and diesel selective hydrocracking
CA3038902A1 (en) 2016-10-14 2018-04-19 Exxonmobil Research And Engineering Company Lubricant basestock production with enhanced aromatic saturation
KR20200035067A (ko) 2017-07-21 2020-04-01 알베마를 유럽 에스알엘 티타늄 함유 운반체 및 유기물 첨가제를 이용한 수화 촉매
BR112020000709B1 (pt) 2017-07-21 2023-03-21 Albemarle Europe Srl Catalisador de hidrotratamento com um transportador contendo titânio e aditivo orgânico contendo enxofre, seus métodos de produção, e método para hidrotratar alimentação de hidrocarboneto
US20190040326A1 (en) 2017-08-03 2019-02-07 Exxonmobil Research And Engineering Company Blocked operation for group ii and group iii lubricant production
SG11201912419YA (en) 2017-08-03 2020-02-27 Exxonmobil Res & Eng Co Activation of noble metal catalysts on siliceous supports with water-containing gas stream
US10882030B2 (en) 2017-08-25 2021-01-05 Uop Llc Crystalline transition metal tungstate
US10773245B2 (en) 2017-08-25 2020-09-15 Uop Llc Crystalline transition metal molybdotungstate
US10822247B2 (en) 2017-12-20 2020-11-03 Uop Llc Highly active trimetallic materials using short-chain alkyl quaternary ammonium compounds
US11078088B2 (en) 2017-12-20 2021-08-03 Uop Llc Highly active multimetallic materials using short-chain alkyl quaternary ammonium compounds
US11007515B2 (en) 2017-12-20 2021-05-18 Uop Llc Highly active trimetallic materials using short-chain alkyl quaternary ammonium compounds
US11034591B2 (en) 2017-12-20 2021-06-15 Uop Llc Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds
US10843176B2 (en) 2017-12-20 2020-11-24 Uop Llc Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds
US10875013B2 (en) 2017-12-20 2020-12-29 Uop Llc Crystalline oxy-hydroxide transition metal molybdotungstate
US11117811B2 (en) 2017-12-20 2021-09-14 Uop Llc Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds
US10995013B2 (en) 2017-12-20 2021-05-04 Uop Llc Mixed transition metal tungstate
TWI873087B (zh) 2017-12-21 2025-02-21 美商艾克頌美孚技術工程公司 第ⅲ類基礎油及潤滑劑組成物
TW201930575A (zh) 2017-12-21 2019-08-01 美商艾克頌美孚研究工程公司 具有經改善的低溫性能之潤滑劑組成物
TW201934734A (zh) 2017-12-21 2019-09-01 美商艾克頌美孚研究工程公司 具有改良的氧化效能之潤滑劑組成物
TWI891600B (zh) 2017-12-21 2025-08-01 美商艾克頌美孚技術工程公司 第ⅲ類基礎油及潤滑油組成物
US20190291085A1 (en) 2018-03-22 2019-09-26 Exxonmobil Research And Engineering Company Bulk metallic catalysts and methods of making and using the same
WO2019217044A1 (en) 2018-05-07 2019-11-14 Exxonmobil Research And Engineering Company Process for production of base stocks
CN112105454A (zh) * 2018-05-11 2020-12-18 沙特基础全球技术有限公司 具有提高的生产C3-C4醇的选择性的β-钴钼氧化物催化剂的生产方法和由此得到的催化剂
US10688479B2 (en) 2018-06-26 2020-06-23 Uop Llc Crystalline transition metal tungstate
US11033883B2 (en) 2018-06-26 2021-06-15 Uop Llc Transition metal molybdotungstate material
US10737248B2 (en) 2018-06-26 2020-08-11 Uop Llc Crystalline transition metal tungstate
US10737249B2 (en) 2018-06-26 2020-08-11 Uop Llc Crystalline transition metal molybdotungstate
US20190390129A1 (en) 2018-06-26 2019-12-26 Exxonmobil Research And Engineering Company Production of improved base stocks
US10682632B2 (en) 2018-06-26 2020-06-16 Uop Llc Transition metal tungstate material
US10737246B2 (en) 2018-06-29 2020-08-11 Uop Llc Poorly crystalline transition metal tungstate
US10981151B2 (en) 2018-06-29 2021-04-20 Uop Llc Poorly crystalline transition metal molybdotungstate
US11213803B2 (en) 2018-12-13 2022-01-04 Uop Llc Ammonia-free synthesis for Al or Si based multimetallic materials
US10933407B2 (en) 2018-12-13 2021-03-02 Uop Llc Ammonia-free synthesis for Al or Si based multimetallic materials
KR20200086983A (ko) * 2019-01-10 2020-07-20 코아텍주식회사 대용량 과불화화합물 제거를 위한 금속산화물 촉매 및 그 제조 방법
US11426711B2 (en) 2019-05-22 2022-08-30 Uop Llc Method of making highly active metal oxide and metal sulfide materials
CN111905802B (zh) * 2020-06-15 2022-01-18 厦门大学 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法
WO2023015168A1 (en) 2021-08-06 2023-02-09 ExxonMobil Technology and Engineering Company Hydro-dealkylation process to generate high quality fuels, base stocks and waxes
WO2023114839A1 (en) 2021-12-15 2023-06-22 ExxonMobil Technology and Engineering Company Bulk cobalt-molybdenum catalyst compositions and synthesis methods

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2700015A (en) 1950-11-10 1955-01-18 Gulf Research Development Co High pressure fluid hydrogenation process
US2912375A (en) 1957-12-23 1959-11-10 Exxon Research Engineering Co Hydrogenation of petroleum oils with "shot" size catalyst and regeneration catalyst
US3297563A (en) 1964-08-17 1967-01-10 Union Oil Co Treatment of heavy oils in two stages of hydrotreating
US3615207A (en) * 1969-06-16 1971-10-26 Fmc Corp Production of hydrogen peroxide by anthraquinone process
US4557821A (en) 1983-08-29 1985-12-10 Gulf Research & Development Company Heavy oil hydroprocessing
US4668376A (en) 1984-12-28 1987-05-26 Exxon Research And Engineering Company Supported, Mn sulfide promoted Mo and W sulfide hydroprocessing catalysts and uses thereof
US4902404A (en) * 1988-07-05 1990-02-20 Exxon Research And Engineering Company Hydrotreating process with catalyst staging
US5122258A (en) * 1991-05-16 1992-06-16 Exxon Research And Engineering Company Increasing VI of lube oil by hydrotreating using bulk Ni/Mn/Mo or Ni/Cr/Mo sulfide catalysts prepared from ligated metal complexes
US5413468A (en) 1993-11-23 1995-05-09 Walbro Corporation Pulse damper
JP3802106B2 (ja) * 1995-06-08 2006-07-26 日本ケッチェン株式会社 炭化水素油の水素化処理触媒とその製造方法およびその活性化方法
US6162350A (en) 1997-07-15 2000-12-19 Exxon Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901)
US6635599B1 (en) 1997-07-15 2003-10-21 Exxonmobil Research & Engineering Company Mixed metal catalyst, its preparation by co-precipitation, and its use
US6534437B2 (en) 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
EP1299186B1 (en) 2000-07-12 2008-05-21 Albemarle Netherlands B.V. Process for preparing an additive-based mixed metal catalyst
EP1791639A1 (en) * 2004-09-22 2007-06-06 Exxonmobil Research And Engineering Company BULK Ni-Mo-W CATALYSTS MADE FROM PRECURSORS CONTAINING AN ORGANIC AGENT
US7591942B2 (en) * 2004-09-22 2009-09-22 Exxonmobil Research And Engineering Company Bulk bi-metallic catalysts made from precursors containing an organic agent
DK1960101T3 (da) * 2005-12-14 2014-12-08 Advanced Refining Technologies Llc Fremgangsmåde til fremstilling af en hydrobehandlingskatalysator

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