DK2276965T3 - Fremgangsmåde til fremstilling af et metalhydrid-hydrogenreservoir - Google Patents

Fremgangsmåde til fremstilling af et metalhydrid-hydrogenreservoir Download PDF

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Publication number
DK2276965T3
DK2276965T3 DK09745738.6T DK09745738T DK2276965T3 DK 2276965 T3 DK2276965 T3 DK 2276965T3 DK 09745738 T DK09745738 T DK 09745738T DK 2276965 T3 DK2276965 T3 DK 2276965T3
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Denmark
Prior art keywords
cell
metal hydride
hydrogen
cells
solid
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DK09745738.6T
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English (en)
Inventor
Olivier Gillia
Michel Latroche
Maxime Botzung
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Commissariat Energie Atomique
Centre Nat Rech Scient
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Publication of DK2276965T3 publication Critical patent/DK2276965T3/da

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0084—Solid storage media characterised by their shape, e.g. porous compacts or hollow particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0026—Metals or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys
    • C01B3/0036—Intermetallic compounds; Metal alloys only containing iron and titanium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys
    • C01B3/0042—Intermetallic compounds; Metal alloys only containing magnesium and nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys
    • C01B3/0047—Intermetallic compounds; Metal alloys containing a rare earth metal
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Claims (11)

1. Fremgangsmåde til fremstilling af et reservoir til lagring af hydrogen i et metalhydrid-pulver, omfattende en lukket indkapsling opdelt i lukkede elementarceller (1), afgrænsede af vægge (2, 3, 4, 5), idet hver af cellerne (1) indeholder metalhydridpulver (6), kendetegnet ved, at hver af cellerne (1) successivt fremstilles ved udøvelse af følgende trin a), b) og c): a) visse, men ikke alle væggene, som afgrænser cellen (1), samles med henblik på derved at danne et åbent hulrum eller en åben alveole; og efterfølgende b) ét eller flere massive (faste) stykker (7) af et materiale, som er i stand til at danne et metalhydrid, placeres i hulrummet eller alveolen, idet den eller de massive stykker af materialet er kompakte og især ikke er dannede ved agglomerering af adskillige partikler, og volumenet af det eller de massive stykker (7) er således, at det eller de efterlader et frirum (8) i cellen (1); og derefter c) de sidste vægge, som afgrænser cellen (1), samles med henblik på at lukke cellen; d) trinnene a), b), c) gentages for det antal gange, som kræves for fremstilling af alle cellerne (1) i indkapslingen; hver af cellerne er forsynede med én eller flere åbninger udformede i dennes vægge med henblik på at lade hydrogen trænge ind i eller forlade cellen; og derefter e) indkapslingen lukkes; f) hydrogen indføres i indkapslingen, hvorved det eller de massive stykker (7) af materiale i hver af cellerne (1) transformeres til metalhydridpulveret (6); g) trin f) gentages eventuelt; trinnene b), c), d) og e) udføres under en beskyttende atmosfære, i en lukket indkapsling.
2. Fremgangsmåde ifølge krav 1, hvor det eller de massive stykker (7) af materialet, som er i stand til at danne et metalhydrid, hårform af et polyeder.
3. Fremgangsmåde ifølge krav 2, hvor det eller de massive stykker (7) af materialet, som er i stand til at danne et metalhydrid, hårform af et parallelepipedum, fortrinsvis et rektangulært parallelepipedum.
4. Fremgangsmåde ifølge ethvert af de foregående krav, hvor det eller de massive stykker (7) af materialet, som er i stand til at danne et metalhydrid, er udskåret af en massiv (fast) blok, stang af en større størrelse, til dimensioner tilpassede til hvert hulrum, fortrinsvis under en beskyttende atmosfære.
5. Fremgangsmåde ifølge ethvert af de foregående krav, hvor det eller de massive stykker (7) underkastes mekanisk bearbejdning under en beskyttende atmosfære før trin b).
6. Fremgangsmåde ifølge krav 5, hvor den mekaniske bearbejdning er slibning, opsplitning, skæring, skrabning, stripning, filing, drejning, fræsning, pudsning eller en kombination deraf.
7. Fremgangsmåde ifølge ethvert af de foregående krav, hvor materialet, som er i stand til at danne et metalhydrid, er valgt blandt intermetalliske forbindelser AB5, AB2, A2B, AB3, A2B7, A2B17, såsom TiFe, LaNi5, Mm-Ni, Ti-Cr, CaNi5, Ti-Cr, Ti-Μη, Zr-Mn, Ti-Mn-V, Zr-Fe-Cr, Ti-Zr-V, Ti-Fe-Mn, Ti-Fe-Ni; blandt materialer i fast opløsning med en BCC struktur, eksempelvis i vanadium, såsom V-Ti-Fe eller V-Ti-Cr; rene metaller såsom Mg, Be, Ti, Zr, V, La, U, Y; metallegeringer, såsom magnesiumlegeringer såsom Mg-Ni, Mg-Cu; og blandinger af to materialer eller af flere end to materialer blandt de materialer som er opremset ovenfor.
8. Fremgangsmåde ifølge ethvert af de foregående krav, hvor frirummet (8) i hver celle udgør i det mindste 20% af volumenet af cellen, fortrinsvis fra 20 til 50%, endnu mere foretrukkent fra 20 til 30%.
9. Fremgangsmåde ifølge ethvert af de foregående krav, hvor metalhydridpulveret (6) er i kontakt med alle væggene (2, 3, 4, 5) i elementarcellen (1), som indeholder dette.
10. Fremgangsmåde ifølge ethvert af de foregående krav, hvor de samlede vægge i cellen (1) danner en varmeveksler.
11. Fremgangsmåde ifølge ethvert af de foregående krav, som yderligere omfatter et trin med montering af tilførsels- og afgivelsesledninger for hydrogen (9) og et trin med montering af ledninger til fremføring af et varmetransmissionsfluid (10).
DK09745738.6T 2008-05-15 2009-05-12 Fremgangsmåde til fremstilling af et metalhydrid-hydrogenreservoir DK2276965T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0853151A FR2931142B1 (fr) 2008-05-15 2008-05-15 Procede de fabrication d'un reservoir d'hydrogene a hydrures metalliques
PCT/EP2009/055728 WO2009138406A1 (fr) 2008-05-15 2009-05-12 Procede de fabrication d'un reservoir d'hydrogene a hydrures metalliques

Publications (1)

Publication Number Publication Date
DK2276965T3 true DK2276965T3 (da) 2019-02-25

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US (1) US9045334B2 (da)
EP (1) EP2276965B1 (da)
JP (1) JP5690718B2 (da)
KR (1) KR20110018310A (da)
CN (1) CN102027283B (da)
BR (1) BRPI0912712A2 (da)
CA (1) CA2724227C (da)
DK (1) DK2276965T3 (da)
EG (1) EG26208A (da)
FR (1) FR2931142B1 (da)
MA (1) MA32529B1 (da)
WO (1) WO2009138406A1 (da)

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Also Published As

Publication number Publication date
CA2724227C (fr) 2016-05-03
MA32529B1 (fr) 2011-08-01
BRPI0912712A2 (pt) 2015-10-13
CN102027283A (zh) 2011-04-20
EG26208A (en) 2013-04-28
EP2276965B1 (fr) 2018-11-07
JP2011521179A (ja) 2011-07-21
KR20110018310A (ko) 2011-02-23
US9045334B2 (en) 2015-06-02
EP2276965A1 (fr) 2011-01-26
CA2724227A1 (fr) 2009-11-19
JP5690718B2 (ja) 2015-03-25
US20110138748A1 (en) 2011-06-16
WO2009138406A1 (fr) 2009-11-19
FR2931142B1 (fr) 2010-08-20
FR2931142A1 (fr) 2009-11-20
CN102027283B (zh) 2013-03-06

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